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1999 Fiscal Year Final Research Report Summary

Preparation of Organic-Inorganic Nanohybrids by Organo Derivatization Reaction

Research Project

Project/Area Number 09650919
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 無機工業化学
Research InstitutionYAMAGATA UNIVERSITY

Principal Investigator

TAGAYA Hideyuki  Materials Science and Engineering, Yamagata University, Professor, 工学部, 教授 (10154931)

Project Period (FY) 1997 – 1999
KeywordsOrganic-inorganic nanohybrid / Intercalation / Self-assembly / Layered compounds / Hydroxy double salt / Zinc hydroxide / Layered double hydroxide / Organo derivatization reaction
Research Abstract

Organo-inorganic layered nanohybrids were prepared by the reaction of amorphous zinc hydroxide with organic oxychlorides and carboxylic acids. The formation of COO-Zn bond was confirmed by the peaks in IR spectra and interlayer spacings of the hybrids depended on the length and number of carboxylate of organic compound indicating the surface modification of inorganic layers. The layer structures were similar to those of layered double hydroxides (LDHs). Most of obtained hybrids had plate-like structures. However, in the reaction of benzoic acid with zinc hydroxide, the preparation of fibrous compounds were confirmed by SEM images. Similar compounds were obtained by the reactions of bulky organic compounds with zinc hydroxide indicating the importance of steric repulsion between organic compounds on inorganic layers.

  • Research Products

    (19 results)

All Other

All Publications (19 results)

  • [Publications] Ogataら: "New preparation method for organic-inorganic layered compounds by the organo derivatization reaction of Zn(OH)_2"Journal of Materials Chemistry. 10. 321-328 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 藤田ら: "インターカーネーション法による有機・無機ハイブリット材料の創製"高分子論文集. 57. 214-219 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Ogataら: "New preparation method for organic-inorganic layered compounds by the organo derivatization reaction"Transactions of the Materials Research Society of Japan. 24. 501-504 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Morioka,Tagayaら: "Incorporation properties of aromatic compounds into hydroxy double salt"Transactions of the Materials Research Society of Japan. 24. 461-464 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Moriokaら: "Effects of zinc on the new prepatration method of hydroxy double salts"Inorganic Chemistry. 19. 4211-4216 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Ogataら: "Preparation method for organic-inorganic layered compounds including fibrous materials by the reaction of Zn(OH)_2 with organic compounds"Journal of Materials Chemistry. 8. 2813-2817 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Moriokaら: "Preparation of Hydroxy Double Salts Exchanged by Organic Compounds"Journal of Materials Research. 13. 848-851 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Ogataら: "Preparation of New Fibrous Layered Compounds by the Reaction of Zinc Hydroxide with Organic Compounds"Chemistry Letters. 237-238 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Ogata et al.: "New preparation method for organic-inorganic layered compound by the organo derivatization reaction of Zn(OH)ィイD22ィエD2"Journal of Materials Chemistry. 10. 321-328 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Fujita et al.: "Preparation of organic-inorganic hybrids by intercalation"Polymer. 57. 214-219 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Ogata et al.: "New preparation method for organic-inorganic layered compounds by the Organo derivatization reaction"Transactions of the Materials research Society of Japan. 24. 501-504 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Morioka et al.: "Incorporation properties of aromatic compounds into Hydroxy Double Salt"Transactions of the Materials Research Society of Japan. 24. 461-464 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Morioka et al.: "Effects of zinc on the new preparation method of Hydroxy Double Salts"Inorganic Chemistry. 19. 4211-4216 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Ogata et al.: "Preparation method for organic-inorganic layered compounds including fibrous materials by the reaction of Zn(OH)ィイD22ィエD2 with organic compounds"Journal of Materials Chemistry. 8. 2813-2817 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Morioka et al.: "Preparation of Hydoxy Double Salts exchanged by organic compounds"Journal of Materials Research. 13. 848-851 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Ogata et al.: "Preparation of new fibrous layered compounds by the reaction of zinc hydroxide with organic compounds"Chemistry Letters. 237-238 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Morioka et al.: "Studies on the layered basic zinc acetate. Zn(OH)ィイD28ィエD2(OCOCHィイD23ィエD2)ィイD22ィエD22HィイD22ィエD2O"Journal of Materials Science Letters. 18. 995-999 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Tagaya et al.: "Surface modification of inorganic layer compound with organic compound and preparation of thin films"Applied Surface Science. 121/122. 476-479 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Tagaya et al.: "Intercalation of azo compounds into layered aluminium dihydrogentriphosphate and Layered Double Hydroxide"Journal of Inclusion Phenomena. 31. 231-241 (1998)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2001-10-23  

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