1998 Fiscal Year Annual Research Report

アルキン結合を利用した新しい有機金属錯体超分子の構築とその構造および機能

Research Project

Project/Area Number	09740501
Research Institution	Kinki University
Principal Investigator	前川雅彦近畿大学, 理工学総合研究所, 助手 (70229293)
Keywords	銅錯体 / 銀錯体 / ロジウム錯体 / 金属錯体ポリマー / 分子集合体 / X線構造 / 金属錯体超分子 / ロッド型配位子
Research Abstract	金属イオン(Cu(I),Ag(I),Rh(I))と2種のロッド型有機系配位子(1,4-ビス(4-ピリジル)ブタジィン (4-pbd)ならびに1,4-ビス(4′-ピリジルエチニル)ベンゼン(2-pbd))を用いて新規な金属錯体ポリマーを系統的に合成し、その分子構造を明らかにした。 (1) 4-bpbを用いたCu(I)ならびにAg(I)金属錯体ポリマーの構築と分子構造 [Cu(CH_3CN)_4]PF_6,AgCF_3SO_3ならびAgClO_4と4-pbdを反応させ、{[Cu_2(4-pbd)_3(CH_3CN)_2](PF_6)_2}_n(1), {[Ag(4-pbd)](CF_3SO_3)}_n。(2),{[Ag(4-pbd)](ClO_4)}_n(3)の単離・構造決定を行なった。錯体1はCu原子が4-pbdの両端のピリジン環のN原子に順次橋かけされジグザグ型のはしご型一次元無限鎖構造を形成し、この一次元無限鎖がさらにお互い絡みあい、interwoven二次元シート構造を形成している。また錯体2および3はAg原子が4-pbdの両端のピリジン環のN原子により順次橋かけされ、直線型一次元無限鎖構造を形成している。 (2) 2-bpbを用いたCu(I)ならびにAg(I)金属錯体ポリマーの構築と分子構造 [CU(CH_3CN)_4]PF_6ならびにAgCF_3SO_3と2-pbdを用いて金属錯体ポリマーの合成を試み、{[CU(2-pbd)]BF_4}_n(4)および{[Ag(2-pbd)CF_3SO_3]}_n(5)の単離・構造決定を行なった。錯体4はCu原子が2-pbdのピリジン環の両端のN原子により順次橋かけされ3次元ネットワーク構造を形成しており、また錯体5は各々のAgが2-bpdの両端のピリジン環のN原子により順次橋かけされ螺旋状に1次元鎖構造を形成し、さらにこの1次元鎖がCF_3SO_3により橋かけされて2次元シート構造を形成している。 (3) 4-pbdを用いたRh(I)錯体金属のポリマーの構築と分子構造 [Rh(cod)_2]X(cod=1,5-シクロオクタジエン;X=BF_4,PF_6)を用いて金属錯体ポリマーの合成を試み、{[RF(4-pbd)X}_n(X=BF_4(6);PF_6(7))の単離・構造決定を行なった。錯体6および7はRh原子が4-pbdの両端のピリジン環のN原子に順次橋かけされジグザグ型の一次元無限鎖構造を形成している。

Research Products
(16 results)

All Other

All Publications (16 results)

[Publications] M.Munakata and M.Maekawa,et al: "Assembly of a mixed-valence Cu(II)system coupled by multiple hydrogen bonds through tetrahydroxybenzoquinone" Inorg.Chim.Acta. Vol.268. 317-321 (1998)
[Publications] M.Maekawa,et al: "Synthesis and crystal structure of two ternary dicopper(I)complexes having the unsymmetrical coordination arrangement bridged by 1,8-naphtyridine" Inorg.Chim.Acta. Vol.271. 129-136 (1998)
[Publications] M.Munakata and M.Maekawa,et al: "Synthesis and structure of a novel bis(μ-η^2-thianthrene)disilver(I)bis(perchlorate)" Inorg.Chim.Acta. Vol.271. 145-150 (1998)
[Publications] M.Maekawa,et al: "Crystal Structure of Bis(diphenylphosphino)methane Dipalladium(I)Nitrate Complex" Anal.Sci.Vol.14. 447-449 (1998)
[Publications] M.Maekawa,et al: "Crystal Structure of Tetranuclear palladium complex Bridged by Bis(diphenylphosphino)methane" Anal.Sci.Vol.14. 451-453 (1998)
[Publications] Y.Suenaga and M.Maekawa,et al: "Self-assembly of copper(I)and silver(I)complexes with square grid and channel structures" J.Chem.Soc.,Dalton Trans.1121-1125 (1998)
[Publications] M.Munakata and M.Maekawa,et al: "Dicopper complexes derived from 4-amino-2,1,3-benzothiadiazole with versatile coordination number and geometry" J.Chem.Soc.Dalton Trans. 1499-1502 (1998)
[Publications] T.Kuroda-Sowa and M.Maekawa,et al: "A Novel Two-Dimensional Copper(I)Coordination Polymer with Bridging TTF" Chem.Lett.499-450 (1998)
[Publications] Y.Suenaga and M.Maekawa,et al: "Synthesis and structure of a two-dimentional copper(II)coordination polymer with 3,4,9,10-perylenetetracarboxylic acid and ethylendiamine" Polyhedron. Vol.17. 2207-2211 (1998)
[Publications] M.Munakata and M.Maekawa,et al.: "Supramolecular silver(I)complexes with highly strained polycyclic aromatic compounds" J.Am.Chem.Soc.Vol.120. 8610-8618 (1998)
[Publications] J.Dai and M.Maekawa,et al.: "Mercury(II)complexes of 4,5-ethylenedithio-1,3-dithiole-2-thione having S・・・S S・・・Cl contact assembled ribbon structure" Polyherdon. Vol.17. 2267-2270 (1998)
[Publications] M.Maekawa,et al.: "Synthesis and crystal structure of dinuclear palladium(I)dppm complex with 4-mercaptopyridine in the thione mode" Inorg.Chim.Acta. Vol.281. 116-119 (1998)
[Publications] M.Munakata and M.Maekawa,et al: "Construction of copper(I)Coordination Polymers of 1,2,4,5-Tetracyanobenzene with Zig-Zag Sheet and Porous Frameworks" Inorg.Chem.Vol.21. 5651-5656 (1998)
[Publications] M.Maekawa,et al.: "Synthesis and crystal structure of dinuclear and tetranuclear palladium dppm complexes" Polyherdon. Vol.17. 3657-3663 (1998)
[Publications] L,-P.Wu and M.Maekawa,et al.: "S・・・S contact-assembled tetrathiafulvalene derivatives of copper(I)and silver(I)co-ordination polymers and organic radical cation salt" J.Chem.Soc.Dalton Trans.3255-3261 (1998)
[Publications] Y.Suenaga and M.Maekawa,et al.: "A Linear-Chain Copper(I)Coordination Polymer with Hexakis(methylthio)benzene" Acta Cryst.Vol.C54. 1566-1569 (1998)

1998 Fiscal Year Annual Research Report

アルキン結合を利用した新しい有機金属錯体超分子の構築とその構造および機能

Principal Investigator

前川 雅彦 近畿大学, 理工学総合研究所, 助手 (70229293)

Research Products

[Publications] M.Munakata and M.Maekawa,et al: "Assembly of a mixed-valence Cu(II)system coupled by multiple hydrogen bonds through tetrahydroxybenzoquinone" Inorg.Chim.Acta. Vol.268. 317-321 (1998)

[Publications] M.Maekawa,et al: "Synthesis and crystal structure of two ternary dicopper(I)complexes having the unsymmetrical coordination arrangement bridged by 1,8-naphtyridine" Inorg.Chim.Acta. Vol.271. 129-136 (1998)

[Publications] M.Munakata and M.Maekawa,et al: "Synthesis and structure of a novel bis(μ-η^2-thianthrene)disilver(I)bis(perchlorate)" Inorg.Chim.Acta. Vol.271. 145-150 (1998)

[Publications] M.Maekawa,et al: "Crystal Structure of Bis(diphenylphosphino)methane Dipalladium(I)Nitrate Complex" Anal.Sci.Vol.14. 447-449 (1998)

[Publications] M.Maekawa,et al: "Crystal Structure of Tetranuclear palladium complex Bridged by Bis(diphenylphosphino)methane" Anal.Sci.Vol.14. 451-453 (1998)

[Publications] Y.Suenaga and M.Maekawa,et al: "Self-assembly of copper(I)and silver(I)complexes with square grid and channel structures" J.Chem.Soc.,Dalton Trans.1121-1125 (1998)

[Publications] M.Munakata and M.Maekawa,et al: "Dicopper complexes derived from 4-amino-2,1,3-benzothiadiazole with versatile coordination number and geometry" J.Chem.Soc.Dalton Trans. 1499-1502 (1998)

[Publications] T.Kuroda-Sowa and M.Maekawa,et al: "A Novel Two-Dimensional Copper(I)Coordination Polymer with Bridging TTF" Chem.Lett.499-450 (1998)

[Publications] Y.Suenaga and M.Maekawa,et al: "Synthesis and structure of a two-dimentional copper(II)coordination polymer with 3,4,9,10-perylenetetracarboxylic acid and ethylendiamine" Polyhedron. Vol.17. 2207-2211 (1998)

[Publications] M.Munakata and M.Maekawa,et al.: "Supramolecular silver(I)complexes with highly strained polycyclic aromatic compounds" J.Am.Chem.Soc.Vol.120. 8610-8618 (1998)

[Publications] J.Dai and M.Maekawa,et al.: "Mercury(II)complexes of 4,5-ethylenedithio-1,3-dithiole-2-thione having S・・・S S・・・Cl contact assembled ribbon structure" Polyherdon. Vol.17. 2267-2270 (1998)

[Publications] M.Maekawa,et al.: "Synthesis and crystal structure of dinuclear palladium(I)dppm complex with 4-mercaptopyridine in the thione mode" Inorg.Chim.Acta. Vol.281. 116-119 (1998)

[Publications] M.Munakata and M.Maekawa,et al: "Construction of copper(I)Coordination Polymers of 1,2,4,5-Tetracyanobenzene with Zig-Zag Sheet and Porous Frameworks" Inorg.Chem.Vol.21. 5651-5656 (1998)

[Publications] M.Maekawa,et al.: "Synthesis and crystal structure of dinuclear and tetranuclear palladium dppm complexes" Polyherdon. Vol.17. 3657-3663 (1998)

[Publications] L,-P.Wu and M.Maekawa,et al.: "S・・・S contact-assembled tetrathiafulvalene derivatives of copper(I)and silver(I)co-ordination polymers and organic radical cation salt" J.Chem.Soc.Dalton Trans.3255-3261 (1998)

[Publications] Y.Suenaga and M.Maekawa,et al.: "A Linear-Chain Copper(I)Coordination Polymer with Hexakis(methylthio)benzene" Acta Cryst.Vol.C54. 1566-1569 (1998)

前川雅彦近畿大学, 理工学総合研究所, 助手 (70229293)