1998 Fiscal Year Annual Research Report

特異反応場を有する界面ナノ組織体の構築

Research Project

Project/Area Number	10126219
Research Institution	Tokyo Institute of Technology
Principal Investigator	大坂武男東京工業大学, 大学院・総合理工学研究科, 教授 (80152099)
Keywords	自己組織化単分子膜 / 大環状金属錯体 / 電極触媒反応 / 電気化学振動現象 / 過酸化水素 / ナノ組織体 / ラジカル修飾電極 / 分光電気化学
Research Abstract	本研究では,新規大環状錯体の自己組織化単分子層(self-assembled monolayer,SAM)を用いる電極界面のナノ組織化及びラジカル修飾電極の構築を実現し,その電子移動と触媒機能を解明した。本年度は次の成果を得た。 1. 新規環状金属錯体とて14員環のペンタアザ環状ニッケル及び銅二量体のテンプレート合成法を確立した。さらに,Au-S結合を利用して金電極表面上にこの環状錯体が自己組織化した単分子層(SAM)修飾電極を構築した。これらSAM電極のレドックス挙動,H_2O_2酸化触媒能,溶存レドックス種に対する選択的電極反応制御能をin situ分光電気化学法で解明した。電極触媒能の新しい概念を提案した。 2. ニトロキシルラジカル高分子修飾電極を構築し,アルコールの酸化に対する特異な電極触媒能を見い出し,その反応機構を回転円盤電極による対流ボルタンメトリー及び分光電気化学測定を用いて定量的に解析することに成功した。

Research Products
(21 results)

All Other

All Publications (21 results)

[Publications] Y.CHE: "New Oscillatory Phenomena in the Redox Reaction of O_2/O_2^- Couple on Hanging Mercury Drop Electrode in Acetone" Chem.Lett.97-98 (1998)
[Publications] Y.CHE: "Solvatochromic Linear Solvation Energy Relationships for Solubility of O_2 in Various Solvents" Bull.Chem.Soc.Jpn.71. 651-656 (1998)
[Publications] K.V.GOBI: "Electrochemical and Spectroscopic Studies on Nickel(II/III)Complexes with Novel 14-membered Hexaaza---" Electrochim.Acta. 43・9. 1013-1021 (1998)
[Publications] K.V.GOBI: "Electrochemical and Spectral Properties of Novel Dinickel(II)and Dicopper Complexes with N,N-linked.--" Electrochim.Acta. 44. 269-278 (1998)
[Publications] K.V.GOBI: "Monolayer Films of a Nickel(II)Pentaazamacrocyclic Complex for the Electrocatalytic Oxidation of Hydrogen--" J.Electroanal.Chem.444. 145-150 (1998)
[Publications] K.V.GOBI: "Electrochemical Characteristics of Self-Assembled Monolayers of a Novel Nickel(II)Pentaazamacrocylic--" Langmuir. 14・5. 1108-1115 (1998)
[Publications] K.YAMADA: "Microelectrode with Leak of Solution" Denki Kagaku. 66・3. 321-325 (1998)
[Publications] F.KITAMURA: "In Situ IR Spectroscopic Study of Water at a Polycrystalline Gold Electrode Surface" J.Electroanal.Chem.452・1〜2. 241-249 (1998)
[Publications] F.KITAMURA: "Kinetic and In Situ Infrared Spectroscopic Study of FeC(N)_6^3-14-Couple on a Platinum Single Crystal Electrode" J.Electroanal.Chem.456・1〜2. 113-120 (1998)
[Publications] S.KISHIOKA: "Spectroelectrochemical Detection of an Intermediate in the Alcohol Oxidation Process with a Nitroxyl Radical" Chem.Lett.343-344 (1998)
[Publications] S.KISHIOKA: "Reaction Mechanism and Kinetics of Alcohol Oxidation at Nitroxyl Radical Modified Electrodes" J.Electroanal.Chem.452・1〜2. 179-186 (1998)
[Publications] Y.B.LIAO: "Normal Pulse Voltammetry for Facilitated Ion Transfer Processes across Two Immiscible Liquid-Liquid--" Electrochim.Acta. 44. 117-124 (1998)
[Publications] 大坂武男: "O_3とO_2-オゾンがこわれるしくみ-" 化学と教育. 46・2. 100-104 (1998)
[Publications] K.V.GOBI: "Interfacial Infrared Reflection Spectroscopic Evidence for Potential-Dependent Electrocatalytic--" J.Phys.Chem.B. 103・1. 83-88 (1999)
[Publications] J.F.WU: "Hydrodynamic Chronocoulometric Determination of Diffusion Coefficients and Concentrations of Dioxygen--" Anal.Chem.(発表予定). (1999)
[Publications] S.A.JOHN: "A Monomer-Dimer Equilibrium in Self-Assembled Monolayers of N-Ethyl-N'-Octadecylviologen--" J.Electroanal.Chem.(発表予定). (1999)
[Publications] K.V.GOBI: "Enhanced Electrostatic Interactions for Selective and Controllable Permeation of Ionic Species--" J.Electroanal.Chem.(発表予定). (1999)
[Publications] S.A.JOHN: "Electrocatalytic Reduction of Dioxygen by the Assembly of Asymmetric Viologen on Gold Electrodes" J.J.Deuterium Sci.(発表予定). (1999)
[Publications] K.V.GOBI: "Selective Anion Recognition and Electrochemical Characteristics of a Self-Assembled Monoluyer of Nickel(II)--" J.Electroanal.Chem.(発表予定). (1999)
[Publications] 大坂武男(分担): "表面技術便覧" 日刊工業新聞社(表面技術協会編), 1386 (1998)
[Publications] 大坂武男(共著): "活性酸素とくらし(発表予定)" 丸善(株), (1999)

1998 Fiscal Year Annual Research Report

特異反応場を有する界面ナノ組織体の構築

Principal Investigator

大坂 武男 東京工業大学, 大学院・総合理工学研究科, 教授 (80152099)

Research Products

[Publications] Y.CHE: "New Oscillatory Phenomena in the Redox Reaction of O_2/O_2^- Couple on Hanging Mercury Drop Electrode in Acetone" Chem.Lett.97-98 (1998)

[Publications] Y.CHE: "Solvatochromic Linear Solvation Energy Relationships for Solubility of O_2 in Various Solvents" Bull.Chem.Soc.Jpn.71. 651-656 (1998)

[Publications] K.V.GOBI: "Electrochemical and Spectroscopic Studies on Nickel(II/III)Complexes with Novel 14-membered Hexaaza---" Electrochim.Acta. 43・9. 1013-1021 (1998)

[Publications] K.V.GOBI: "Electrochemical and Spectral Properties of Novel Dinickel(II)and Dicopper Complexes with N,N-linked.--" Electrochim.Acta. 44. 269-278 (1998)

[Publications] K.V.GOBI: "Monolayer Films of a Nickel(II)Pentaazamacrocyclic Complex for the Electrocatalytic Oxidation of Hydrogen--" J.Electroanal.Chem.444. 145-150 (1998)

[Publications] K.V.GOBI: "Electrochemical Characteristics of Self-Assembled Monolayers of a Novel Nickel(II)Pentaazamacrocylic--" Langmuir. 14・5. 1108-1115 (1998)

[Publications] K.YAMADA: "Microelectrode with Leak of Solution" Denki Kagaku. 66・3. 321-325 (1998)

[Publications] F.KITAMURA: "In Situ IR Spectroscopic Study of Water at a Polycrystalline Gold Electrode Surface" J.Electroanal.Chem.452・1〜2. 241-249 (1998)

[Publications] F.KITAMURA: "Kinetic and In Situ Infrared Spectroscopic Study of FeC(N)_6^3-14-Couple on a Platinum Single Crystal Electrode" J.Electroanal.Chem.456・1〜2. 113-120 (1998)

[Publications] S.KISHIOKA: "Spectroelectrochemical Detection of an Intermediate in the Alcohol Oxidation Process with a Nitroxyl Radical" Chem.Lett.343-344 (1998)

[Publications] S.KISHIOKA: "Reaction Mechanism and Kinetics of Alcohol Oxidation at Nitroxyl Radical Modified Electrodes" J.Electroanal.Chem.452・1〜2. 179-186 (1998)

[Publications] Y.B.LIAO: "Normal Pulse Voltammetry for Facilitated Ion Transfer Processes across Two Immiscible Liquid-Liquid--" Electrochim.Acta. 44. 117-124 (1998)

[Publications] 大坂武男: "O_3とO_2-オゾンがこわれるしくみ-" 化学と教育. 46・2. 100-104 (1998)

[Publications] K.V.GOBI: "Interfacial Infrared Reflection Spectroscopic Evidence for Potential-Dependent Electrocatalytic--" J.Phys.Chem.B. 103・1. 83-88 (1999)

[Publications] J.F.WU: "Hydrodynamic Chronocoulometric Determination of Diffusion Coefficients and Concentrations of Dioxygen--" Anal.Chem.(発表予定). (1999)

[Publications] S.A.JOHN: "A Monomer-Dimer Equilibrium in Self-Assembled Monolayers of N-Ethyl-N'-Octadecylviologen--" J.Electroanal.Chem.(発表予定). (1999)

[Publications] K.V.GOBI: "Enhanced Electrostatic Interactions for Selective and Controllable Permeation of Ionic Species--" J.Electroanal.Chem.(発表予定). (1999)

[Publications] S.A.JOHN: "Electrocatalytic Reduction of Dioxygen by the Assembly of Asymmetric Viologen on Gold Electrodes" J.J.Deuterium Sci.(発表予定). (1999)

[Publications] K.V.GOBI: "Selective Anion Recognition and Electrochemical Characteristics of a Self-Assembled Monoluyer of Nickel(II)--" J.Electroanal.Chem.(発表予定). (1999)

[Publications] 大坂武男(分担): "表面技術便覧" 日刊工業新聞社(表面技術協会編), 1386 (1998)

[Publications] 大坂武男(共著): "活性酸素とくらし(発表予定)" 丸善(株), (1999)

大坂武男東京工業大学, 大学院・総合理工学研究科, 教授 (80152099)