1999 Fiscal Year Annual Research Report

水素-電子相互作用系

Research Project

Project/Area Number	10146103
Research Institution	Osaka University
Principal Investigator	中筋一弘大阪大学, 大学院・理学研究科, 教授 (60028230)
Co-Investigator(Kenkyū-buntansha)	三浦洌熊本大学, 医学部, 教授 (70093466) 坂田祥光大阪大学, 産業科学研究所, 教授 (60029874) 三谷忠興北陸先端科学技術大学院大学, 材料科学研究科, 教授 (50010939) 金藤敬一九州工業大学, 情報工学部, 教授 (70124766) 田所誠大阪市立大学, 大学院・理学研究科, 助教授 (60249951)
Keywords	水素結合 / プロトン / 電荷移動 / 非局在電子系 / 水素-電子相互作用系 / 電子移動
Research Abstract	"水素-電子相互作用系"プロトン移動と電子移動が連動する分子システムの開発であり,連動または複合により,単独では発現しない新しい機能を作り出すことが重要課題である.このような研究の学術的特色をまとめると,1)新しい概念を学際的に探索しつつ,2)生体機能の本質を有機化学的に抽出しつつ,3)非局在電子系を物性科学的観点から応用的側面を重視しつつ,合成・物性グループが互いに連携して特異な水素-電子相互作用系の創出を目指していることにある.これまでの成果を以下にまとめる。 (1)a)プロトン-電子連動を活用した新システムの開発(中筋),b)プロトンダイナミックスによる機能性分子システムの構築(菅原),c)水素結合と配位結合を用いた自己組織体および分子性ゼオライトの開発(田所). (2)a)人工光合成を目指したパイ電子複合系の構築(坂田),b)フラビン酵素における電子移動反応場の作動原理の分子レベルの解明(三浦). (3)a)電解酸化によるπ電子の非局在化と分子形態変化システムの構築(金藤),b)電子-プロトン相互作用に基づく新規素子機能の探索(三谷).

Research Products
(17 results)

All Other

All Publications (17 results)

[Publications] K. Kaneto: "Scanning Tunneling Microscopy (STM) Study on Morphology of Regioregular Poly (3-alkylthiophene) Deposited on Au(111) Surface"Jpn. J. Appl. Phys.. 38. 1062-1065 (1999)
[Publications] K. Kaneto: "Photocarrier Mobility in Regioregular Poly(3-hexylthiphene) Studied by the Time of Flight Method"Jpn. J. Appl. Phys.. 38. 1188-1190 (1999)
[Publications] B. D. Malhotra: "Time of Flight Photocarrier Mobility in Langmuir-Blodgett Films of Regioregular Poly (3-hyxylthiophene)"Jpn. J. Appl. Phys. 38. 6768-6771 (1999)
[Publications] J. Nakazaki: "Novel Spin-polarised TTF Donors Affording Ground State Triplet Cation Diradicals"Tetrahedron Lett.. 40. 5027-5030 (1999)
[Publications] T. Matsuo: "Infrared Absorption by a Tunneling Proton in Crystalline 5-Bromo-9-hydroxyphenalenone"Europhys. Lett.. 47(1). 36-41 (1999)
[Publications] Y. Ishikawa: "New Synthesis of 2-[1, 3-Dithiol-2-ylidene] ?4, 5-dihydro-1, 3-dithiolo [4, 5-b][1, 4] dithiins with Formyl Group on Fused Benzene, [1, 4] Dithiin, or Thiophene Ring"Tetrahedron Lett.. 40. 8819-8822 (1999)
[Publications] K. Tamaki: "Acceleration of Phooinduced Electron Transfer in Porphyrin-linked C70"Chem. Lett.. 227-228 (1999)
[Publications] H. Imahori: "Organic Photoelectrochemical Cell Mimicking Photoinduced Multistep Electron Transfer in Photosynthesis : Interfacial structure and Photoelectrochemical Properties of Self-Assembled Monolayers of Porphyrin-linked Fullerenes on Gold electrode"Bull. Chem. Soc. Jpn.. 72. 485-502 (1999)
[Publications] S. Higashida: "Synthesis and Photoinduced electron Transfer of Pyromellitimide-linked Porphyrin in Constrained Hydrophobic Environment of Unimer Micelle"Chem. Lett.. 191-192 (1999)
[Publications] H. Tamaoki: "Mechanism for recognition and activation of substrate in medium-chain acyl-CoA dehydrogenase"J. Biochem.. 125. 285-296 (1999)
[Publications] K. Sato: "Unusually high standard redox potential of acrylyl-CoA/propionyl-CoA couple among enoyl-CoA/acyl-CoA couples : A reason for the distinct metabolic pathway of propionyl-CoA from longer acyl-CoAs"J. Biochem.. 126. 668-675 (1999)
[Publications] R. Miura: "The reaction scheme fo D-amino acid oxidase : Substrate/product alignment for optimization of reductive and oxidative half-reactions"Flavins and Flavoproteins 1999. 543-550 (1999)
[Publications] M. Tadokoro: "Cation Dependent Superstructures by One-Pot Self-Organization in Hydrogen-Bonded Transition metal Complexes"Angew. Chem. Int. Ed.. 38. 95-98 (1999)
[Publications] M. Tadokoro: "Hydrogen Bonded 2, 2'-Biimidazolate Transition Metal Complexes as a Tool of Crystal Engineering"Coordination Chemistry Review. (in press).
[Publications] K. Goto: "A Stable Neutral Hydrocarbon Radical synthesis, Crystal structure, and Physical Properties of 2, 5, 8-ri-tert-butyl-phenalenyl"J. Am. Chem. soc.. 121. 1619-1620 (1999)
[Publications] M. Tadokoro: "Cation-Dependent Formation of Superstructures by One-Pot Self-Organization of Hydrogen-Boned Nickel Complexes"Angew. Chem. Int. Ed.. 38. 65-98 (1999)
[Publications] Md. B. Zaman: "Hydrogen-bonded CT-complex of cyananilic acid with OMTTF : (OMTF)_3(HCNAL)_2"Synthetic Metals. 102. 1691-1692 (1999)

1999 Fiscal Year Annual Research Report

水素-電子相互作用系

Principal Investigator

中筋 一弘 大阪大学, 大学院・理学研究科, 教授 (60028230)

Research Products

[Publications] K. Kaneto: "Scanning Tunneling Microscopy (STM) Study on Morphology of Regioregular Poly (3-alkylthiophene) Deposited on Au(111) Surface"Jpn. J. Appl. Phys.. 38. 1062-1065 (1999)

[Publications] K. Kaneto: "Photocarrier Mobility in Regioregular Poly(3-hexylthiphene) Studied by the Time of Flight Method"Jpn. J. Appl. Phys.. 38. 1188-1190 (1999)

[Publications] B. D. Malhotra: "Time of Flight Photocarrier Mobility in Langmuir-Blodgett Films of Regioregular Poly (3-hyxylthiophene)"Jpn. J. Appl. Phys. 38. 6768-6771 (1999)

[Publications] J. Nakazaki: "Novel Spin-polarised TTF Donors Affording Ground State Triplet Cation Diradicals"Tetrahedron Lett.. 40. 5027-5030 (1999)

[Publications] T. Matsuo: "Infrared Absorption by a Tunneling Proton in Crystalline 5-Bromo-9-hydroxyphenalenone"Europhys. Lett.. 47(1). 36-41 (1999)

[Publications] Y. Ishikawa: "New Synthesis of 2-[1, 3-Dithiol-2-ylidene] ?4, 5-dihydro-1, 3-dithiolo [4, 5-b][1, 4] dithiins with Formyl Group on Fused Benzene, [1, 4] Dithiin, or Thiophene Ring"Tetrahedron Lett.. 40. 8819-8822 (1999)

[Publications] K. Tamaki: "Acceleration of Phooinduced Electron Transfer in Porphyrin-linked C70"Chem. Lett.. 227-228 (1999)

[Publications] S. Higashida: "Synthesis and Photoinduced electron Transfer of Pyromellitimide-linked Porphyrin in Constrained Hydrophobic Environment of Unimer Micelle"Chem. Lett.. 191-192 (1999)

[Publications] H. Tamaoki: "Mechanism for recognition and activation of substrate in medium-chain acyl-CoA dehydrogenase"J. Biochem.. 125. 285-296 (1999)

[Publications] K. Sato: "Unusually high standard redox potential of acrylyl-CoA/propionyl-CoA couple among enoyl-CoA/acyl-CoA couples : A reason for the distinct metabolic pathway of propionyl-CoA from longer acyl-CoAs"J. Biochem.. 126. 668-675 (1999)

[Publications] R. Miura: "The reaction scheme fo D-amino acid oxidase : Substrate/product alignment for optimization of reductive and oxidative half-reactions"Flavins and Flavoproteins 1999. 543-550 (1999)

[Publications] M. Tadokoro: "Cation Dependent Superstructures by One-Pot Self-Organization in Hydrogen-Bonded Transition metal Complexes"Angew. Chem. Int. Ed.. 38. 95-98 (1999)

[Publications] M. Tadokoro: "Hydrogen Bonded 2, 2'-Biimidazolate Transition Metal Complexes as a Tool of Crystal Engineering"Coordination Chemistry Review. (in press).

[Publications] K. Goto: "A Stable Neutral Hydrocarbon Radical synthesis, Crystal structure, and Physical Properties of 2, 5, 8-ri-tert-butyl-phenalenyl"J. Am. Chem. soc.. 121. 1619-1620 (1999)

[Publications] M. Tadokoro: "Cation-Dependent Formation of Superstructures by One-Pot Self-Organization of Hydrogen-Boned Nickel Complexes"Angew. Chem. Int. Ed.. 38. 65-98 (1999)

[Publications] Md. B. Zaman: "Hydrogen-bonded CT-complex of cyananilic acid with OMTTF : (OMTF)_3(HCNAL)_2"Synthetic Metals. 102. 1691-1692 (1999)

中筋一弘大阪大学, 大学院・理学研究科, 教授 (60028230)