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2002 Fiscal Year Final Research Report Summary

New Protium Function in Sub-Nano Materials

Research Project

Project/Area Number 10148102
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTohoku University

Principal Investigator

OKADA Masuo  Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (80133049)

Co-Investigator(Kenkyū-buntansha) FUJII Hironobu  Hiroshima University, Faculty of Integrated Arts and Sciences, Professor, 総合科学部, 教授 (30034573)
IIJIMA Yoshiaki  Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (70005411)
AOKI Kiyoshi  Kitami Institute of Technology, Faculty of Engineering, Professor, 工学部, 教授 (70124542)
FUKAI Yuh  Chuo University, School of science and Engineering, Professor, 理工学部, 教授 (80055136)
HAYASHI Yasunori  Kyushu University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (80010940)
Project Period (FY) 1998 – 2002
KeywordsProtium / Protium storage Material / Hydrogen / Hydrogen Storage Alloys / Protium-induced new function / Process function of protium / Soluble function of protium / Fining grain size by protium
Research Abstract

In the 21st century that Environmental Science becomes important, the priority area "New Protium Function" aims to systematically understand the useful protium functions and to drastically increase their properties in the various functional materials in which protium can be contained.
During four years, the activities and research results of this priority area turned out to be magnificent. The one of the main results of this project is improving the properties of functional materials by using processing function of protium. Ti based alloys underwent protium absorption-desorption yield almost 9300% elongation of super-plasticity with the fine grain sizes below sub-micron. The second objective of this project where the protium absorbing materials with 3mass% below 100。・must be developed, has almost attained by Ti-Cr-V alloys with low content of V. The V-free Ti-Cr-Mo alloys also yield the same properties. Mechanically ground carbon or Mg-carbon composites also show the absorption properties of 7.3mass%.
The new results in the fields of protium occupancy sites in the high density of protium alloys and the defects induced by protium are also obtained. As the proium-induced new functional materials, the Zr-Cu amorphous alloys show the high damping properties by addition of Si to the alloys. The various porous materials are also developed by using the solubility difference of proium between solid and molten metals. Accordingly, the objectives of the present project are judged to be fully accomplished. In fact, the committee for reviewing the research results gave [A] (research are accomplished expectively) to this priority area of protium new function.

  • Research Products

    (55 results)

All Other

All Publications (55 results)

  • [Publications] M.Okada: "Crystal Structue and Hydrogen Absorption Properties of La(Ni, M)_x (x3~5) Melt-Spun Ribbons"The Third Pacific Rim International Conference on Advanced Materials and Processing. PRICM3. 619-624 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Okada: "Crystal Structure and Protium Absorption Properties of La-rich La(Ni, M)_x (x=3-4.7) (M=A1,Co, Mn, Si) Melt-spun Ribbons"Journal of Alloys and Compounds. 293-295. 130-134 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kuriiwa: "New V-based Alloys with High Protium Absorption and Desorption Capacity"Journal of Alloys and Compounds. 293-295. 433-436 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Unno: "Effects of Silicon and Carbon Addition on Magnetic Properities of Fe_2-W Type Hexagonal Ferrite"Journal of the Magnetics Society of Japan. 23. 329-331 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Takuya Tamura: "New Vanadium-based Protium Absorbing Alloys with Laves Phases Along Grain Boundary"Materials Transactions JIM. 40. 431-434 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Yukio Tominaga: "Protium Absorption-Desorption Properties of Ti-V-Cr Alloys with a BCC Structure"Materials Transactions JIM. 40. 871-874 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hitoshi Takamura: "Protium Absorption Properties of Mg-Al Based Ternary Alloys"Materials Transactions. 41. 1142-1145 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 田村 卓也: "V-Ti-Zr-Ni系プロチウム水素吸蔵合金のニッケル水素電池の負極としての電気化学特性"粉末および粉末冶金. 47. 68-72 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Takeshi Fuda: "Effects of Additions of BCC Former Elements on Protium Absorbing Properties of Cr-Ti-V Alloys"Materials Transactions. 41. 577-580 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Yukio Tominag: "Protium Absorption-Desorption Properties of Ti-V-Cr-(Mn, Ni) Alloys"Materials Transactions. 41. 617-620 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kakuta: "Thermal Stability of Hybrides of Magnesium-Transition Metal System Prepared under a High Pressure"Materials Science Forum. 350-351. 329-332 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Takamura: "Preparation and Protium Absorbing Properties of Mg-based Ternary Alloys"Materials Science Forum. 350-351. 315-320 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Ken Unno: "Synthesis of Vapor-Grown Carbon Fibers Using Nanocrystalline Fe_<91>Zr_7B_2 Alloys as a Catalyst"Materials Transactions. 41. 563-566 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hitoshi Takamura: "High-Pressure Synthesis of Hydrides in Ca-Mg-Ni Systems"Materials Transactions. 42. 1301-1304 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hirofumi Kakuta: "High-Pressure Synthesis of Hydrides of Ca-TM Systems (TM=Mn, Fe, Co and Ni)"Materials Transactions. 42. 443-445 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Ken Unno: "Synthesis of Vapor-Grown Carbon Fibers Using Nanocrystalline Fe_<75>Si_<15>B_<10> Alloy as a Catalyst"Materials Transactions. 42. 838-841 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Yasuyuki Goto: "Synthesis of New Hydrides with Cubic Structures in Mg-Ca-Ni Systems by Using High Pressure"Materials Transactions. 42. 1850-1853 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Takuya Tamura: "Protium Absorption Preperties of Ti-Cr-V Alloys in Low Hydrogen Pressure Regions"Materials Transactions. 42. 1862-1865 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hidehiro Kudo: "Synthesis and Protium Absorbing Properties of VGCF Grown by Fe-based Catalyst"The Fourth Pacific Rim International Conference on Advanced Materials and Processing. PRICM4. 509-512 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Takuya Tamura: "Protium Absorption Preperties of Ti-Cr-V-Mn Alloys in Low Hydrogen Pressure Regions"The Fourth Pacific Rim International Conference on Advanced Materials and Processing. PRICM4. 525-528 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Shirasaki: "Cyclic Properties of Protium Absorption-Desorption Properties of Ti-Cr-V Alloys"The Fourth Pacific Rim International Conference on Advanced Materials and Processing. PRICM4. 529-532 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Yasuyuki Goto: "Synthesis and Crystal Structure of New Hydrides in Ca-Mg-Ni Systems under High Pressure"The Fourth Pacific Rim International Conference on Advanced Materials and Processing. PRICM4. 1219-1222 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Takanobu Miyashita: "Microstructural Evolution of Mg-Al Based Alloy by HDDR"The Fourth Pacific Rim International Conference on Advanced Materials and Processing. PRICM4. 1227-1230 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Okada: "Ti-V-Cr b.c.c. Alloys with High Protium Content"Journal of Alloys and Compounds. 330-332. 511-516 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Takamura: "Crystal Structure of Novel Hydrides in a Mg-Ni-H System Prepared under an Ultra High Pressure"Journal of Alloys and Compounds. 330-332. 157-161 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Tamura: "Protium Absorption Properties of Ti-V-Cr-Mn Alloys with a b.c.c"Journal of Alloys and Compounds. 330-332. 522-525 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Takuya Tamura: "Effects of Compositions on Formation of 1,2 Protorides in Ti-Cr-V Alloys"Materials Transactions. 43. 410-413 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Atsunori Kamegawa: "Crystal Structure and Protium Absorption Properties of Ti-Cr-X Alloys"Materials Transactions. 43. 470-473 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] "Crystal Structue and hydrogen Absorption properties of La(Ni,M)_x (x=3~5) Melt-Spun Ribbons"The Third Pacific Rim International Conference on Advanced Materials and Processing, PRICM3. 619-624 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Okada: "Cristal Structure and protium Absorption Properties of La-rich La(Ni, M)_x(x=3-4, 7) (M=Al, Co, Mn, Si) Melt-spun Ribbons"Journal of Alloys and Compounds. 293-295. 130-134 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Unno: "Effects of Siiicon and Carbon Addition on Magnetic Properities of Fe_2-W Type Hexagonal Ferrite"Journal of the Magnetics Society of Japan. 23. 329-331 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takuya Tamura: "New Vanadium-based Protium Absorbing Alloys with Laves Phases Along Grain Boundary"Materials Transactions, JIM. 40. 431-434 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yukio Tominaga: "Protium Absorption-Desorption Properties of Ti-V-Cr Alloys with a BCC Structure"Materiais Transactions, JIM. 40(9). 871-874 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hitoshi Takamura: "Protium Absorption Properties of Mg-Al Based Ternary Alloys"Materiais Transactions, JIM. 41. 1142-1145 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takuya Tamura: "Electrochemical Characteristics of V-Ti-Zr-Ni Protium Absrbing Alloys for Metal Hydride Electrodes"Japan Society of Powder and Powder Metallurgy, JIM. 47. 68-72 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takeshi Fuda: "Effects of Additions of BCC Former Elements on Protium Absorbing Properties of Cr-Ti-V Alloys"Materials Transactions, JIM. 41 (5). 577-580 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yukio Tominaga: "Protium Absorption-Desorption Properties of Ti-V-Cr-(Mn, Ni) Alloys"Materiais Transactions, JIM. 41 (5). 617-620 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Kakuta: "Thermal Stability of Hydridesof Magnesium-Transition Metal System Prepared under a High Pressure"Materials Science Forum. 350-351. 329-332 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Takamura: "Preparation and Protium Absorbing Properties of Mg-based Ternary Alloys"Materials Science Forum. 350-351. 315-320 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Ken Unno: "Synthesis of Vapor-Grown Carbon Fibers Using Nanocrystalline Fe_<91>Zr_7B_2 Alloys as a Catalyst"Materials Transactions, JIM. 41 (5). 563-566 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hitoshi Takamura: "High-Pressure Synthesis of Hydrides in Ca-Mg-Ni Systems"Materials Transactions, JIM. 42 (7). 1301-1304 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hirofumi Kakuta: "High-Pressure Synthesis of Hydrides of Ca-TM Systems(TM= Mn, Fe, Co and Ni)"Materials Transactions, JIM. 42 (3). 443-445 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Ken Unno: "Synthesis of Vapor-Grown Carbon Fibers Using Nanogrystalline Fe_<75>Si_<16>B_<10> Alloy as a Catalyst"Materials Transactions, JIM. 42 (5). 838-841 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yasuyuki Goto: "Synthesis of New Hydrides with Cubic Structures in Mg-Ca-Ni Systems by Using High Pressure"Materials Transactions, JIM. 42 (9). 1850-1853 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takuya Tamura: "Protium Absorption Preperties of Ti-Cr-V Alloys in Low Hydrogen Pressure Regions"Materials Transactions, JIM. 42 (9). 1862-1865 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hidehiro Kudo: "Synthesis and Protium Absorbing Properties of VGCF Grown by Fe-based Catalyst"The Forth Pacific Rim International Conference on Advanced Materials and Processing(PRICM4). 509-512 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takuya Tamura: "Protium Absorption Properties of Ti-Cr-V-Mn Alloys in Low Pressure Regions"The Forth Pacific Rim International Conference on Advanced Materials and Processing(PRICM4). 525-528 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Shirasaki: "Cyclic Properties of Protium Absorption-Desorption Properties of Ti-Cr-V Alloys"The Fourth Pacific Rim International Conference on Advanced Materials and Processing(PRICM4). 529-532 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yasuyuki Goto: "Synthesis and Crystal Structure of New Hydrides in Ca-Mg-Ni Systems under High Pressure"The Fourth Pacific Rim International Conference on Advanced Materials and Processing(PRICM4). 1219-1222 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takanobu Miyashita: "Microstructural Evolution of Mg-Al Based Alloy by HDDR"The Fourth Pacific Rim International Conference on Advanced Materials and Processing(PRICM4). 1227-1230 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Okada: "Ti-V-Cr b.c.c. Alloys with High Protium Content"Journal of Alloys and Compounds. 330-331. 511-516 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Takamura: "Crystal Structure of Novel Hydrides in a Mg-Ni-H System Prepared under an Ultra High Pressure"Journal of Alloys and Compounds. 330-332. 157-161 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Tamura: "Protium Absoption Properties of Ti-V-Cr-Mn Alloys with a B. c. c. Structure"Journal of Alloys and Compounds. 330-332. 522-525 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takuya Tamura: "Effects of Compositions on Formation of 1,2 Protorides in Ti-Cr-V Alloys"Materials Transactions. 43 (3). 410-413 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Atsunori Kamegawa: "Crystal Structure and Protium Absorption Proporties of Ti-Cr-X Alloys"Materials Transactions. 43 (3). 470-473 (2002)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2004-04-14  

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