2001 Fiscal Year Annual Research Report

集積型金属錯体の次元構造の合理的制御

Research Project

Project/Area Number	10149104
Research Institution	Tokyo Institute of Technology
Principal Investigator	山本隆一東京工業大学, 資源化学研究所, 教授 (10016743)
Co-Investigator(Kenkyū-buntansha)	北川宏筑波大学, 化学系, 助教授 (90234244) 山下正廣東京都立大学, 大学院・理学研究科, 教授 (60167707) 宗像恵近畿大学, 理工学部, 教授 (80090942) 橋本和仁東京大学, 先端科学技術研究センター, 教授 (00172859)
Keywords	集積型金属錯体 / 次元構造 / 導電性 / 光学的特性 / 磁性 / 遷移金属錯体 / 電気化学的応答 / 高分子金属錯体
Research Abstract	集積型金属錯体の次元構造の合理的制御について研究を推進した。すなわち、銀、パラジウム、白金、銅、コバルト、鉄、金、ルテニウム及びニッケルの金属錯体について、ハロゲン、ビスチエニルエテン類、ピレン等の多環芳香族化合物類、シアノ基、シクロペンタジエニル基、アミン類等が配位した3次元、2次元、一次元的に秩序ある構造を有する金属錯体を合成し、その物性、機能を評価した。また、これらの集積型金属錯体を形成させるための新規配位子を合成した。集積型金属錯体の物性、機能としては、導電性、光機能性、磁気的応答、電気化学的応答について研究し、集積型金属錯体の分子構造との対比から解析した。その結果、フォトクロミック性銀錯体、ホールドーピングが可能なニッケル-コバルト混合型導電性集積金属錯体、磁場誘起軌道整列と水素ドーピングによる電子・プロトン伝導性を示す金属二量体骨格を有する新規金属錯体、ポリフェロセン構造を有しサイクリックボルタモグラムにおいてピーク電流値が掃引速度の平方根に比例する関係が確認されるポリマー金属錯体が合成され、機能化のための基礎を解明した。集積型金属錯体の構造解析はX線回折法、NMR法等により行なった。

Research Products

(52 results)

All Other

All Publications (52 results)

[Publications] T.Yamamoto, H.Kokubo, T.Morikita: "Molecular Alignment of Head-to-Tail-Type Poly(3-hexylthiophene-2,5-diy) and Related Polymers and Compounds on Substrates"J.Polym.Sci.B, Polym.Phys.. 39. 1713-1718 (2001)
[Publications] I.Nurulla, T.Morikita, H.Fukumoto, T.Yamamoto: "Preparation and Properties of Poly [(2-alkylbenzimidazole)-alt-thiophenels with Long Alkyl Side Chain"Macromol.Chem.Phys.. 202. 2335-2340 (2001)
[Publications] T.Yamamoto, K.Shiraishi, M.Abla, I.Yamaguchi, L.B.Groenendaal: "Neutral Poly (3,4-ethylenedioxythiophene-2,5-diyl)s : Preparation by Organometallic Polycondensation and Their Unique p-doping Behavior"Polymer. 43. 711-719 (2001)
[Publications] K.Shiraishi, T.Kanbara, T.Yamamoto, L.B.Groenendaal: "Preparation of a Soluble and Neutral Alkyl Derivative of Poly(3,4-ethylenedioxythiophene) and its Optical Properties"Polymer. 42. 7229-7232 (2001)
[Publications] T.Yamamoto, I.Nurulla, A Ushiro: "Organometallic C-N Coupling between N, N'-dichloro-p-benzoquinone Diimine and Grignard Reagents and its Application to Synthesis of Polyanilines"Tetrahedron Lett.. 42. 8653-8656 (2001)
[Publications] T.Morikita, T.Yamamoto: "Electrochemical Determination of Diffusion Coefficient of π-Conjugated Polymers Containing Ferrocene Unit"J.Organometal.Chem.. 637-639. 809-812 (2001)
[Publications] J.C.Zhong, M.Munakata, T.K.-Sowa, et al.: "Spiral, Herringbone and Triple-decker Silver(I) Complexes of Benzopyrene Derivatives Assembled with Their h2-Coordinations"Inorg.Chem.. 40. 3191-3199 (2001)
[Publications] M.Munakata, J.C.Zhong, T.K.-Sowa, M.Maekawa, Y.Suenaga, M.Kasahara, H.Konaka: "A Double-decker Silver(1) Coordination Polymer of 1-Methylpyrene with Columnar Aromatic Stacks. Effect of Substituting Groups on Structure of Silver(I) Complexes with Polycyclic Aromatic Hydrocarbons"Inorg.Chem.. 40. 7087-7090 (2001)
[Publications] J.C.Zhong, M.Munakata, Y.Suenaga, T.K.-Sowa, M.Maekawa, et al.: "Silver(I) Coordination Polymer of 2,5-Bis(4,5-bis(methylthio)-1,3-dithiol-2-ylidene)-1,3,4,6-tetra-thiapentalene (TTM-TTP) and Its High Conductive Iodine Derivative"Inorg.Chem.. 40. 7096-7098 (2001)
[Publications] M.Munakata, G.-L.Ning, T.K.-Sowa, et al.: "Construction of Metallocyclophanes from Silver(I) h2-Coordination Complexes with Tri, 1,2-Benztriphenylenes and Phenanthrene"J.Am.Chem.Soc.. (in press). (2001)
[Publications] J.C.Zhong, M.Munakata, T.K.-Sowa, M.Maekawa, Y.Suenaga: "A Novel 2-D Silver(I)-acyclicpolyene Coordination Polymer Assembled with Linear Unsaturated Bridges"Inorg.Chi.Acta. 322. 150-156 (2001)
[Publications] M.Wen, M.Munakata, Y.Suenaga, T.K.-Sowa, M.Maekawa: "Silver(I) Coordination Polymers of Cyclic Sulfur Ligand, 2,2,3-Tetrahydro-4,4-dithia-1, 1-binaphthylidene"Inorg.Chim.Acta. 322. 133-137 (2001)
[Publications] M.Munakata et al.: "1-D Cyano-Bridged Heterometallic Complexes Consisting of 1,4,8,11-Tetraazacyclotetradecanesilver(II) and Tetracyanopalladium(II) or Tetracyanoplatinum(II)"Inorg.Chim.Acta. 317. 268-275 (2001)
[Publications] M.Munakata, M.Wen, Y.Suenaga et al.: "Carbon and Nitrogen Atoms-Coordinated Silver(I) Polymers of 2,4.6-Triphenoxy-1,3,5-triazine"Polyhedron. 20. 2321-2327 (2001)
[Publications] M.Munakata, M.Wen et al.: "Silver(I) Complexes of Triazine Derivatives Having Stepped Interaction and 2D Sheets"Polyhedron. 20. 2037-2037 (2001)
[Publications] S.Onaka, Y.Katsukawa, M.Shiotsuka, O.Kanegawa, M.Yamashita: "Synthesis, X-ray Molecular Structure Analysis, and Study on Ligand Scambling Reactions of New Thiolatogold(I) Complexes with Various Phosphines"Inorg.Chim.Acta. 312. 100-102 (2001)
[Publications] T.Manabe, T.Kawashima, T.Ishii, H.Matsuzaka, M.Yamashita, K.Marumoto, H.Tanaka, S.Kuroda, H.Kitagawa, T.Mitani, H.Okamoto: "Syntheses and Physical Properties of Quasi-One-Dimensional Chioro-Bridged Ni-Pd Mixed-Metal MX-Chain Compounds, Nil-xPdx(chxn)2C13"Synth.Met. 116. 415-417 (2001)
[Publications] T.C.Kobayashi, K.Tanaka, K.Fujiwara, K.Amaya, N.Aizawa, T.Ishii, M.Yamashita: "Proton NMR Study of the Field-induced Long Range Ordering in Haldane Gap System NDMAP"J.Mag.Mag.Mat. 70. 813-817 (2001)
[Publications] T.C.Kobayashi, H.Tatewaki, A.Koda, K.Amaya, Y.Narumi, K.Kindo, N.Aizawa, T.Ishii, M.Yamashita: "Field-induced Long Range Ordering in Haldane Gap System NDMAZ"J.Phys.Soc.Jpn. 70. 813-823 (2001)
[Publications] H.Matsuzaka, H.Okimura, Y.Sato, T.Ishii, M.Yamashita, M.Kondo, S.Kitagawa, M.Shiro, M.Yamasaki: "Synthesis, Structure and Reactivities of the Dinuclear μ-η1:η 6-Arylethnyl Ruthenium Complexes"J.Organomet.Chem.. 625. 133-137 (2001)
[Publications] T.C.Kobayashi, H.Tanaka, K.Fujiwara, K.Amaya, N.Aizawa, T.Ishii, M.Yamashita: "Proton NMR study of the field-induced long-range ordering in Haldane gap system NDMAP"J.Mag.Mag.Mat.. 226・230. 423-424 (2001)
[Publications] K.Marumoto, H.Tanaka, S.Kozaki, S.Kuroda, S.Miya, T.Kawashima, M.Yamashita: "ESR Observation of Average-Valence and Charge-Density-Wave States in Quasi-One-Dimensional Halogen-Bridged Binuclear Metal Complexes"Solid State Commun.. 120. 101 (2001)
[Publications] T.Ishii, N.Aizawa, M.Yamashita, H.Matsuzaka, I.Ikemoto, K.Kikuchi, T.Kodama, Y.Iwasa: "Intermolecular interaction of Complexes with Anti-formed Metal Octaethylporphyrins with C60"Synth.Met.. 121. 1165-1166 (2001)
[Publications] T.Aso, T.Manabe, T.Kawashima, T.Ishii, H.Matsuzaka, M.yamashita, N.Kuroda: "Doping Effect on MX-Chain Compounds"Synth.Met.. 120. 775-776 (2001)
[Publications] H.Tanaka, K.Marumoto, S.Kuroda, T.Manabe, M.Yamashita: "ESR detection of induced moments Pd3+ in halogen-bridged Ni-Pd mixed-metal complexes"Synth.Met.. 120. 949-950 (2001)
[Publications] T.Manabe, T.Ishii, H.Matsuzaka, M.Yamashita, T.Kawashima, K.Marumoto, H.Tanaka: "Syntheses and Physical Properties of Halogen-Bridged Ni-Pd Mixed-Metal Complexes, Ni1-xPdx(chxn)_2XY_2"Synth.Met. 120. 925-926 (2001)
[Publications] N.Kimura, M.Kano, T.Manabe, M.Yamashita, R.Ikeda: "Metal Valence Structures in 1-D Mixed-Metal Complexes [Ni1-xPdxX(chxn)_2]X_2 Studied by Solid NMR"Synth.Met. 120. 777-778 (2001)
[Publications] T.Ishii, N.Aizawa, R.Kanehama, M.Yamashita, H.Matsuzaka, T.Kodama, K.Kikuchi.I.Ikemoto: "DV-Xα Calculation for the Syntheses and Electronic Structure of Macrocyclic Metal Complexes with Fulleren C60"Inorg.Chim. Acta. 317. 81-90 (2001)
[Publications] N.Kimura, S.Ishmaru, T.Kawashima, S.Miya, T.Manabe, M.Yamashita, R.Ikeda: "Valence Structure and Magnetic Interaction in MMX-Type 1D Complexes, A4[Pt_2I(P_2O_5H_2)_4].nH_2O, Studied by 31P Solid NMR"Synth. Met.. 120. 779-780 (2001)
[Publications] T.Ishii, N.Aizawa, H.Hara, M.Yamashita, H.Matsuzaka: "Electronic Structure of the Haldane Gap System derived using DV-Xα Calculation"Polyhedron. 20. 1297-1304 (2001)
[Publications] T.Ishii, R.Kanehama, N.Aizawa, M.Yamashita, H.Matsuzaka, K.Sugiura, H.Miyasaka, T.Kodama, K.Kikuchi, I.Ikemoto: "Fulleren C60 exhibiting a strong intermolecular interaction in a cocrystallite with C4 symmetrical cobalt tetraki (di-tert-butylphenyl) porphyrin"J.Chem.Soc., Dalton Trans/. 2975 (2001)
[Publications] H.Miyasaka, C.Kachi-Terajima, T.Ishii, M.Yamashita: "A New Metal-Metal Bonded Diruthenium(II, III) Compound Bridged by the Dianionic Trident Ligand N-(2-Pyridyl)-2-Oxy-5-Chlorobenzylaminate (5-Clsalpy2-)"J.Chem.Soc., Dalton Trans. 1929-1930 (2001)
[Publications] N.Metoki, Y.Koike, Y.Matsuoka, T.Kobayasi, abd M.Yamashita: "Neutron scattering study of linear-chain Haldane compounds NDMAZ and NDMAP"J.Mag.Mag.Mat.. 226-230. 414-416 (2001)
[Publications] T.Ishii, N.Aizawa, R.Kanehama, M.Yamashita, H.Matsuzaka, H.Miyasaka, T.Kodama, K.Kikuthi, I.Ikemoto, Y.Iwasa, T.Mochida: "Synthesis of Cocrystallite with Biferrocene and C60"Trans.Mater.Res.Soc.Jpn.. 26. 1147 (2001)
[Publications] M.Mitsumi, T.Murase, H.Kishida, T.Yoshinari, Y.Ozawa, K.Toriumi, H.Kitagawa.T.Mitani: "Metallic Behavior and Periodical Valence-Ordering in a New MMX Chain Compound, Pt_2(EtCS_2)_4I"J.Am.Chem.Soc. 123. 11179-11192 (2001)
[Publications] Y.Qi Wang, A.Sato, K.Saito, M.Yamamoto, H.Kitagawa, T.Mitani, M.Sorai: "Heat Capacity of the Halogen-Bridged Mixed-Valence Complex Pt_2(dta)_4I (dta=CH3CS2-)"J.Phys.Chem.. 106. 197-202 (2001)
[Publications] R.Makiura, I.Nagasawa, N.Kimura, S.Ishimaru, H.Kitagawa, R.Ikeda: "An Unusual Six-Co-Ordinate Platinum(II) Complex Containing A Neutral I_2 Ligand"Chem.Commun.. 17. 1642-1643 (2001)
[Publications] M.Fujishima, S.Kanda, T.Mitani, H.Kitagawa: "Hydrogen-Induced Properties of Copper Coordination Polymer : catena-N, N'-bis(hydroxyethyl)dithiooxamidatocopper"Synth.Met. 119. 485-486 (2001)
[Publications] S.Maki, Y.Morita, H.Kitagawa, T.Mitani, K.Nakasuji: "A Novel Charge-Transfer Complex of TTF Having Uracil Moiety with TCNQ"Synth.Met. 120. 741-742 (2001)
[Publications] H.Kitagawa, N.Onodera, T.Mitani: "Low-Temperature X-Ray Single-Crystal Analysis of a Conductive Mixed-Valence MMX-Chain System, Pt_2(dta)_4I (dta=CH_3CS_<2->)"Synth.Met. 116. 401-404 (2001)
[Publications] T.Manabe, T.Kawashima, T.Ishii, H.Matsuzaka, M.Yamashita, K.Marumoto, H.Tanaka, S.Kuroda, H.Kitagawa, T.Mitani, H.Okamoto: "Syntheses and Physical Properties of Quasi-One-Dimensional Chloro-Bridged Ni-Pd Mixed-Metal MX-Chain Compounds, Ni1-xPdx(chxn)_2Cl_3"Synth.Met. 116. 415-418 (2001)
[Publications] T.Kawashima, K.Takai, H.Aso, T.Manabe, K.Takizawa, C.Kachi-Terajima, T.Ishii, H.Miyasaka, H.Matsuzaka, M.Yamashita, H.Okamoto, H.Kitagawa, M.Shiro, K.Toriumi: "Syntheses and Physical Properties of Quasi-One-Dimensional Halogen-Bridged CuII-PtIV Mixed-Metal Complexes, [Cu(chxn)2] [PtX2(chxn)2]X4"Inorg.Chem. 40. 6651-6655 (2001)
[Publications] M.Fujishima, R.Ikeda, S.Kanda, H.Kitagawa: "Electronic State of A Hydrogen-Doped Copper Coordination Polymer : catena-オ-N, N'-bis-(hydroxyethyl)dithiooxamidatocopper(II), (HOC_2H_4)_2dtoaCu"Mol.Cryst.Liq.Cryst.. (in press). (2001)
[Publications] Y.Nagao, S.Kanda, R.Ikeda, H.Kitagawa: "Complex-Plane Impedance Study on A Hydrogen-Doped Copper Coordination Polymer : N, N'-bis-(2-hydroxy-ethyl)dithiooxamidatocopper(II)"Mol.Cryst.Liq.Cryst.. (in press). (2001)
[Publications] S.Ohkoshi, K.Hashimoto: "Photo-magnetic and Magneto-optical effects of Functionalized Prussian Blue Analogs"J.Photochem.Photobio.C. 2. 71-88 (2001)
[Publications] S.Ohkoshi, N.Machida, Z.Zhong, K.Hashimoto: "Photo-induced magnetization in copper (II) octacyanomolybdate (IV)"Synth.Metal. 122. 523-527 (2001)
[Publications] S.Ohkoshi, N.Machida, Y.Abe, Z.Zhong, K.Hashimoto: "Visible light-induced reversible photomagnetism in copper(II) octacyano molybdate(IV)"Chem.Lett.. 312-313 (2001)
[Publications] S.Ohkoshi, T.Houzumi, K.Hashimoto: "The first observation of an inverted hysteresis loop in a bulk magnet"Phys.Rev.B. 64. 132404 (2001)
[Publications] K.Ikeda, S.Ohkoshi, K.Hashimoto: "Second harmonic generation (SHG) and magnetization-induced second harmonic generation (MSHG) in electrochemically synthesized magnetic films of ternary metal Prussian blue analogs"Chem.Phys.Lett.. 349. 371 (2001)
[Publications] T.Yokoyama, K.Okamoto, T.Ohta, S.Ohkoshi, K.Hashimoto: "Local structure and electronic state of a photo-and x-ray-induced magnet of CoW cyanide studied by x-ray-absorption fine structure spectroscopy"Phys.Rev.B. 65. 64438 (2001)
[Publications] S.Ohkoshi, H.Tokoro, M.Utsunomiya, M.Mizuno, M.Abe, K.Hashimoto: "The first observation of spin transition of an otahedorally coordinated magnese(II) compound"J.Phys.Chem B. (in press). (2001)
[Publications] N.Shimamoto, S.Ohkoshi, O.Sato, K.Hashimoto: "Control of charge-transfer induced spin transition temperature on cobal t-iron Prussian blue analogues"Inorg.Chem. (in press). (2001)

2001 Fiscal Year Annual Research Report

集積型金属錯体の次元構造の合理的制御

Principal Investigator

山本 隆一 東京工業大学, 資源化学研究所, 教授 (10016743)

Research Products

[Publications] T.Yamamoto, H.Kokubo, T.Morikita: "Molecular Alignment of Head-to-Tail-Type Poly(3-hexylthiophene-2,5-diy) and Related Polymers and Compounds on Substrates"J.Polym.Sci.B, Polym.Phys.. 39. 1713-1718 (2001)

[Publications] I.Nurulla, T.Morikita, H.Fukumoto, T.Yamamoto: "Preparation and Properties of Poly [(2-alkylbenzimidazole)-alt-thiophenels with Long Alkyl Side Chain"Macromol.Chem.Phys.. 202. 2335-2340 (2001)

[Publications] T.Yamamoto, K.Shiraishi, M.Abla, I.Yamaguchi, L.B.Groenendaal: "Neutral Poly (3,4-ethylenedioxythiophene-2,5-diyl)s : Preparation by Organometallic Polycondensation and Their Unique p-doping Behavior"Polymer. 43. 711-719 (2001)

[Publications] K.Shiraishi, T.Kanbara, T.Yamamoto, L.B.Groenendaal: "Preparation of a Soluble and Neutral Alkyl Derivative of Poly(3,4-ethylenedioxythiophene) and its Optical Properties"Polymer. 42. 7229-7232 (2001)

[Publications] T.Yamamoto, I.Nurulla, A Ushiro: "Organometallic C-N Coupling between N, N'-dichloro-p-benzoquinone Diimine and Grignard Reagents and its Application to Synthesis of Polyanilines"Tetrahedron Lett.. 42. 8653-8656 (2001)

[Publications] T.Morikita, T.Yamamoto: "Electrochemical Determination of Diffusion Coefficient of π-Conjugated Polymers Containing Ferrocene Unit"J.Organometal.Chem.. 637-639. 809-812 (2001)

[Publications] J.C.Zhong, M.Munakata, T.K.-Sowa, et al.: "Spiral, Herringbone and Triple-decker Silver(I) Complexes of Benzopyrene Derivatives Assembled with Their h2-Coordinations"Inorg.Chem.. 40. 3191-3199 (2001)

[Publications] J.C.Zhong, M.Munakata, Y.Suenaga, T.K.-Sowa, M.Maekawa, et al.: "Silver(I) Coordination Polymer of 2,5-Bis(4,5-bis(methylthio)-1,3-dithiol-2-ylidene)-1,3,4,6-tetra-thiapentalene (TTM-TTP) and Its High Conductive Iodine Derivative"Inorg.Chem.. 40. 7096-7098 (2001)

[Publications] M.Munakata, G.-L.Ning, T.K.-Sowa, et al.: "Construction of Metallocyclophanes from Silver(I) h2-Coordination Complexes with Tri, 1,2-Benztriphenylenes and Phenanthrene"J.Am.Chem.Soc.. (in press). (2001)

[Publications] J.C.Zhong, M.Munakata, T.K.-Sowa, M.Maekawa, Y.Suenaga: "A Novel 2-D Silver(I)-acyclicpolyene Coordination Polymer Assembled with Linear Unsaturated Bridges"Inorg.Chi.Acta. 322. 150-156 (2001)

[Publications] M.Wen, M.Munakata, Y.Suenaga, T.K.-Sowa, M.Maekawa: "Silver(I) Coordination Polymers of Cyclic Sulfur Ligand, 2,2,3-Tetrahydro-4,4-dithia-1, 1-binaphthylidene"Inorg.Chim.Acta. 322. 133-137 (2001)

[Publications] M.Munakata et al.: "1-D Cyano-Bridged Heterometallic Complexes Consisting of 1,4,8,11-Tetraazacyclotetradecanesilver(II) and Tetracyanopalladium(II) or Tetracyanoplatinum(II)"Inorg.Chim.Acta. 317. 268-275 (2001)

[Publications] M.Munakata, M.Wen, Y.Suenaga et al.: "Carbon and Nitrogen Atoms-Coordinated Silver(I) Polymers of 2,4.6-Triphenoxy-1,3,5-triazine"Polyhedron. 20. 2321-2327 (2001)

[Publications] M.Munakata, M.Wen et al.: "Silver(I) Complexes of Triazine Derivatives Having Stepped Interaction and 2D Sheets"Polyhedron. 20. 2037-2037 (2001)

[Publications] S.Onaka, Y.Katsukawa, M.Shiotsuka, O.Kanegawa, M.Yamashita: "Synthesis, X-ray Molecular Structure Analysis, and Study on Ligand Scambling Reactions of New Thiolatogold(I) Complexes with Various Phosphines"Inorg.Chim.Acta. 312. 100-102 (2001)

[Publications] T.C.Kobayashi, K.Tanaka, K.Fujiwara, K.Amaya, N.Aizawa, T.Ishii, M.Yamashita: "Proton NMR Study of the Field-induced Long Range Ordering in Haldane Gap System NDMAP"J.Mag.Mag.Mat. 70. 813-817 (2001)

[Publications] T.C.Kobayashi, H.Tatewaki, A.Koda, K.Amaya, Y.Narumi, K.Kindo, N.Aizawa, T.Ishii, M.Yamashita: "Field-induced Long Range Ordering in Haldane Gap System NDMAZ"J.Phys.Soc.Jpn. 70. 813-823 (2001)

[Publications] H.Matsuzaka, H.Okimura, Y.Sato, T.Ishii, M.Yamashita, M.Kondo, S.Kitagawa, M.Shiro, M.Yamasaki: "Synthesis, Structure and Reactivities of the Dinuclear μ-η1:η 6-Arylethnyl Ruthenium Complexes"J.Organomet.Chem.. 625. 133-137 (2001)

[Publications] T.C.Kobayashi, H.Tanaka, K.Fujiwara, K.Amaya, N.Aizawa, T.Ishii, M.Yamashita: "Proton NMR study of the field-induced long-range ordering in Haldane gap system NDMAP"J.Mag.Mag.Mat.. 226・230. 423-424 (2001)

[Publications] K.Marumoto, H.Tanaka, S.Kozaki, S.Kuroda, S.Miya, T.Kawashima, M.Yamashita: "ESR Observation of Average-Valence and Charge-Density-Wave States in Quasi-One-Dimensional Halogen-Bridged Binuclear Metal Complexes"Solid State Commun.. 120. 101 (2001)

[Publications] T.Ishii, N.Aizawa, M.Yamashita, H.Matsuzaka, I.Ikemoto, K.Kikuchi, T.Kodama, Y.Iwasa: "Intermolecular interaction of Complexes with Anti-formed Metal Octaethylporphyrins with C60"Synth.Met.. 121. 1165-1166 (2001)

[Publications] T.Aso, T.Manabe, T.Kawashima, T.Ishii, H.Matsuzaka, M.yamashita, N.Kuroda: "Doping Effect on MX-Chain Compounds"Synth.Met.. 120. 775-776 (2001)

[Publications] H.Tanaka, K.Marumoto, S.Kuroda, T.Manabe, M.Yamashita: "ESR detection of induced moments Pd3+ in halogen-bridged Ni-Pd mixed-metal complexes"Synth.Met.. 120. 949-950 (2001)

[Publications] T.Manabe, T.Ishii, H.Matsuzaka, M.Yamashita, T.Kawashima, K.Marumoto, H.Tanaka: "Syntheses and Physical Properties of Halogen-Bridged Ni-Pd Mixed-Metal Complexes, Ni1-xPdx(chxn)_2XY_2"Synth.Met. 120. 925-926 (2001)

[Publications] N.Kimura, M.Kano, T.Manabe, M.Yamashita, R.Ikeda: "Metal Valence Structures in 1-D Mixed-Metal Complexes [Ni1-xPdxX(chxn)_2]X_2 Studied by Solid NMR"Synth.Met. 120. 777-778 (2001)

[Publications] T.Ishii, N.Aizawa, R.Kanehama, M.Yamashita, H.Matsuzaka, T.Kodama, K.Kikuchi.I.Ikemoto: "DV-Xα Calculation for the Syntheses and Electronic Structure of Macrocyclic Metal Complexes with Fulleren C60"Inorg.Chim. Acta. 317. 81-90 (2001)

[Publications] N.Kimura, S.Ishmaru, T.Kawashima, S.Miya, T.Manabe, M.Yamashita, R.Ikeda: "Valence Structure and Magnetic Interaction in MMX-Type 1D Complexes, A4[Pt_2I(P_2O_5H_2)_4].nH_2O, Studied by 31P Solid NMR"Synth. Met.. 120. 779-780 (2001)

[Publications] T.Ishii, N.Aizawa, H.Hara, M.Yamashita, H.Matsuzaka: "Electronic Structure of the Haldane Gap System derived using DV-Xα Calculation"Polyhedron. 20. 1297-1304 (2001)

[Publications] H.Miyasaka, C.Kachi-Terajima, T.Ishii, M.Yamashita: "A New Metal-Metal Bonded Diruthenium(II, III) Compound Bridged by the Dianionic Trident Ligand N-(2-Pyridyl)-2-Oxy-5-Chlorobenzylaminate (5-Clsalpy2-)"J.Chem.Soc., Dalton Trans. 1929-1930 (2001)

[Publications] N.Metoki, Y.Koike, Y.Matsuoka, T.Kobayasi, abd M.Yamashita: "Neutron scattering study of linear-chain Haldane compounds NDMAZ and NDMAP"J.Mag.Mag.Mat.. 226-230. 414-416 (2001)

[Publications] T.Ishii, N.Aizawa, R.Kanehama, M.Yamashita, H.Matsuzaka, H.Miyasaka, T.Kodama, K.Kikuthi, I.Ikemoto, Y.Iwasa, T.Mochida: "Synthesis of Cocrystallite with Biferrocene and C60"Trans.Mater.Res.Soc.Jpn.. 26. 1147 (2001)

[Publications] M.Mitsumi, T.Murase, H.Kishida, T.Yoshinari, Y.Ozawa, K.Toriumi, H.Kitagawa.T.Mitani: "Metallic Behavior and Periodical Valence-Ordering in a New MMX Chain Compound, Pt_2(EtCS_2)_4I"J.Am.Chem.Soc. 123. 11179-11192 (2001)

[Publications] Y.Qi Wang, A.Sato, K.Saito, M.Yamamoto, H.Kitagawa, T.Mitani, M.Sorai: "Heat Capacity of the Halogen-Bridged Mixed-Valence Complex Pt_2(dta)_4I (dta=CH3CS2-)"J.Phys.Chem.. 106. 197-202 (2001)

[Publications] R.Makiura, I.Nagasawa, N.Kimura, S.Ishimaru, H.Kitagawa, R.Ikeda: "An Unusual Six-Co-Ordinate Platinum(II) Complex Containing A Neutral I_2 Ligand"Chem.Commun.. 17. 1642-1643 (2001)

[Publications] M.Fujishima, S.Kanda, T.Mitani, H.Kitagawa: "Hydrogen-Induced Properties of Copper Coordination Polymer : catena-N, N'-bis(hydroxyethyl)dithiooxamidatocopper"Synth.Met. 119. 485-486 (2001)

[Publications] S.Maki, Y.Morita, H.Kitagawa, T.Mitani, K.Nakasuji: "A Novel Charge-Transfer Complex of TTF Having Uracil Moiety with TCNQ"Synth.Met. 120. 741-742 (2001)

[Publications] H.Kitagawa, N.Onodera, T.Mitani: "Low-Temperature X-Ray Single-Crystal Analysis of a Conductive Mixed-Valence MMX-Chain System, Pt_2(dta)_4I (dta=CH_3CS_<2->)"Synth.Met. 116. 401-404 (2001)

[Publications] M.Fujishima, R.Ikeda, S.Kanda, H.Kitagawa: "Electronic State of A Hydrogen-Doped Copper Coordination Polymer : catena-オ-N, N'-bis-(hydroxyethyl)dithiooxamidatocopper(II), (HOC_2H_4)_2dtoaCu"Mol.Cryst.Liq.Cryst.. (in press). (2001)

[Publications] Y.Nagao, S.Kanda, R.Ikeda, H.Kitagawa: "Complex-Plane Impedance Study on A Hydrogen-Doped Copper Coordination Polymer : N, N'-bis-(2-hydroxy-ethyl)dithiooxamidatocopper(II)"Mol.Cryst.Liq.Cryst.. (in press). (2001)

[Publications] S.Ohkoshi, K.Hashimoto: "Photo-magnetic and Magneto-optical effects of Functionalized Prussian Blue Analogs"J.Photochem.Photobio.C. 2. 71-88 (2001)

[Publications] S.Ohkoshi, N.Machida, Z.Zhong, K.Hashimoto: "Photo-induced magnetization in copper (II) octacyanomolybdate (IV)"Synth.Metal. 122. 523-527 (2001)

[Publications] S.Ohkoshi, N.Machida, Y.Abe, Z.Zhong, K.Hashimoto: "Visible light-induced reversible photomagnetism in copper(II) octacyano molybdate(IV)"Chem.Lett.. 312-313 (2001)

[Publications] S.Ohkoshi, T.Houzumi, K.Hashimoto: "The first observation of an inverted hysteresis loop in a bulk magnet"Phys.Rev.B. 64. 132404 (2001)

[Publications] K.Ikeda, S.Ohkoshi, K.Hashimoto: "Second harmonic generation (SHG) and magnetization-induced second harmonic generation (MSHG) in electrochemically synthesized magnetic films of ternary metal Prussian blue analogs"Chem.Phys.Lett.. 349. 371 (2001)

[Publications] T.Yokoyama, K.Okamoto, T.Ohta, S.Ohkoshi, K.Hashimoto: "Local structure and electronic state of a photo-and x-ray-induced magnet of CoW cyanide studied by x-ray-absorption fine structure spectroscopy"Phys.Rev.B. 65. 64438 (2001)

[Publications] S.Ohkoshi, H.Tokoro, M.Utsunomiya, M.Mizuno, M.Abe, K.Hashimoto: "The first observation of spin transition of an otahedorally coordinated magnese(II) compound"J.Phys.Chem B. (in press). (2001)

[Publications] N.Shimamoto, S.Ohkoshi, O.Sato, K.Hashimoto: "Control of charge-transfer induced spin transition temperature on cobal t-iron Prussian blue analogues"Inorg.Chem. (in press). (2001)

山本隆一東京工業大学, 資源化学研究所, 教授 (10016743)