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2002 Fiscal Year Final Research Report Summary

Pational Control of Dimensional Structures of Metal-Assembled Ccmplexes

Research Project

Project/Area Number 10149104
Research Category

Grant-in-Aid for Scientific Research on Priority Areas (A)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

YAMAMOTO Takakazu  Tokyo Institute of Technology, Chemical Reources Laboratory, Professor, 資源化学研究所, 教授 (10016743)

Co-Investigator(Kenkyū-buntansha) KITAGAWA Hiroshi  University of Tsukuba, Department of Chemistry, Associate Professor, 化学系, 助教授 (90234244)
YAMASHITA Masahiro  Tokyo Metropolitan University, Department of Chemistry, Professor, 大学院・理学研究科, 教授 (60167707)
MUNAKATA Megumu  Kinki University, Department of Chemistry, Professor, 理工学部, 教授 (80090942)
HASHIMOTO Kazuhito  The University of Tokyo, Research Center for Advanced Science and Technology, Professor, 先端科学技術研究センター, 教授 (00172859)
Project Period (FY) 1998 – 2001
KeywordsMetal-assembled complex / Dimensional structure / Conductivity / Optical properties / Magnetism / Transition metal complex / Electrochemical response / Polymer-metal complex
Research Abstract

We have carried out research for rational control of dimensional structures of metal-assembled complexes. The complexes were prepared with combination between metals such as silver, palladium, platinum, copper, cobalt, iron, gold, ruthenium and nickel and ligands such as halogen, bisthienylethenes, pyrenes, cyano group, cyclopentadienyls and amines. The prepared metal complexes had 3-, 2-, and one-dimensionally controlled structures, and their chemical and physical properties and their chemical and physical functions were studied. In order to prepare these metal complexes, new ligands were synthesized.
Electrically conducting, o

  • Research Products

    (13 results)

All Other

All Publications (13 results)

  • [Publications] M.Yamashita, S.Miya, T.Tanabe: "Charge Fluctuation in MMX Chain Compounds, P_4[Pt_2(pop)_4].nH_2O"J. Am. Chem. Soc.. 121. 2321-2322 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Yamashita: "Electronic Structures of Quasi-One-dimensional Halogen-Bridged Ni^<III> Complexes"Coord. Chem. Rev.. 190. 309-330 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Munakata, L.P.Swu, G.L.Ning: "A New Type of Multilayer System-Silver(1) Complexes of Polycyclic Aromatic Compounds"Coord. Chem. Rev.. 198. 171-203 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kitagawa, N.Onodera, T.Mitani: "Low-Temperature X-ray Single-Crystal Analysis of a Conductive Mixed-Valence MMX-Chain System, Pt_2(dta)_4l(dta = CH_3CS^_2)"Synth. Met.. 116. 401-404 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Yamamoto, K.Shiraishi, M.Abla, I.Yamaguchi, L.B.Groenendaal: "Neutral Poly(3,4-ethylenedioxythiophene-2,5-diyl)s : Preparation by Organometallic Polycondensation and Their Unique d-doping Behavior"Polymer. 43. 711-719 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Ikeda, S.Ohkoshi, K.Hashimoto: "Second Harmonic Generation (SHG) and Magnetization-induced Second Harmonic Generation (MSHG) in Electrochemically Synthesized Magnetic Films of Ternary Metal Prussian Blue Analogs"Chem. Phys. Lett.. 349. 371-375 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 山本隆一(著、監修): "導電性高分子材料の開発と応用"技術情報協会. 241 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M. Yamashita: "Charge Fluctuation in MMX Chain Compounds, P_4[Pt_2(pop)_4.nH_2O"J. Am. Chem. Soc.. 121. 2321-2322 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Yamashita: "Electronic Structures of Quasi-One-Dimensional Halogen-Bridged Ni^<III> Complexes"Coord. Chem. Rev.. 190. 309-330 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Munakata, L. P. Swu, G. L. Ning: "A New Type of Multilayer System-Silver (1) Complexes of Polycyclic Aromatic Compounds"Coord. Chem. Rev.. 198. 171-203 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Kitagawa, N. Onodera, T. Mitani: "Low-Temperature X-ray Single-Crystal Analysis of a Conductive Mixed-Valence MMX-Chain System, Pt_2(dta)_4](dta = CH_3CS_2)"Synth. Met.. 116. 401-404 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Yamamoto, K. Shiraishi, M. Abla, I. Yamaguchi, L. B. Groenendaal: "Neutral Poly(3,4-ethylenedioxythiophen-2,5-diyl)s : Preparation by Organometallic Polycondensation and Their Unique d-doping Behavior"Polymer. 43. 711-719 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Ikeda, S. Ohkoshi, K. Hashimoto: "Second Harmonic Generation (SHG) and Magnetization-induced Second Harmonic Generation (MSHG) in Electrochemically Synthesized Magnetic Filsm of Ternary Metal Prussian Blue Anaglos"Chem. Phys. Lett.. 349. 371-375 (2001)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2004-04-14  

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