2000 Fiscal Year Annual Research Report

ディスクリートな集積型金属錯体および集積系ユニットの創出

Research Project

Project/Area Number	10149106
Research Institution	Kyushu University
Principal Investigator	大川尚士九州大学, 大学院・理学研究院, 教授 (00037219)
Co-Investigator(Kenkyū-buntansha)	真島和志大阪大学, 大学院・工学研究科, 助教授 (70159143) 磯辺清大阪市立大学, 理学部, 教授 (70101285) 北川進京都大学, 大学院・工学研究科, 教授 (20140303)
Keywords	フェロ磁性体 / フェリ磁性体 / 合成ゼオライト / 多孔性個体 / 酸化物クラスター / ヘテロ金属錯体
Research Abstract	1)三座ジプロピレントリアミン(dipn)を配位子とする[Ni(dipn)]2+を用いて、擬三次元ネットワーク構造のフェロ磁性体[Ni(dipn)]_3[Fe(CN)_6]_2・7H_2O(Tc=7.8K)の合成に成功した。また、二座グリシンアミド(glya)をエンドキャップ配位子とする[Mn(glya)]_3[Cr(CN)_6]_2・2.5H_2Oを合成した。これは不完全キュバン単位からなる三次元ネットワーク構造を有し、Tc=71Kのフェリ磁性体であることを確認した。又、非等価な金属結合サイトを備えた四核化コンパートメント配位子を設計して、混合金属Cu^<II>_2M^<II>_2(M=Mn,Co,Ni,Zn)錯体の合成に成功した(大川)。 2)錯体モチーフを用いて多孔性配位高分子結晶を合理的に合成して、メタンなどの小分子を高効率的にかつ可逆的に吸脱着(物理吸着能)させることに成功した。又、酸化還元能を示す[MnLm](M=Cr,Mn,Co;L=catecholおよびその誘導体)をモジュールとして用い、それらをπ-πスタッキングにより集積化させることに成功した(北川)。 3)タングステン酸化物クラスター[(CP^*Rh)_4W_4O_<16>]の二つの異性体(windmill型とtriple cubane型)クラスターの生成条件、生成メカニズム、異性化のメカニズムを^<17>O NMR,溶液IRおよびESI-マススペクトロメーター用いて明らかにした。(磯辺)。 4)モリブデン二核錯体Mo_2(pyphos)4(pyphos=6-diphenylphosphinopyridonate)の両端に1価の9族金属を配位させた4核錯体[Mo_2M_2(L)_4(pyphos)_4]^<2+>の合成に成功し。さらに、両端の9族金属の酸化反応によって、4つの金属がそれぞれ金属-金属結合によって結ばれた錯体が合成できることを見出した。(真島)。

Research Products

(18 results)

All Other

All Publications (18 results)

[Publications] N.Fukita: "Trinuclear CuMCu Complexes of An Oxamide/dioxime Ligand and Extension To A bimetallic Magnetic Material"J.Chem.Soc.Dalton Trans. 2001・1. 64-70 (2001)
[Publications] M.Yonemura: "A Mixed-metal Cu^<II>_2Ni^<II>_2 Complex Derived from A Phenol-based Heterotetranucleating Macrocyclic Ligand"J.Chem.Soc.,Chem.Commun.. 2000・9. 817-819 (2000)
[Publications] M.Yonemura: "Macrocyclic Effects upon Isomeric Cu^<II>M^<II> and M^<II>Cu^<II> Cores Formation with Unsymmetric Phenol-Based Macrocyclic Ligands"Proc.Ind.Acad.Sci.. 112・3. 291-310 (2000)
[Publications] M.Suzuki: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 200-202. 105-129 (2000)
[Publications] N.Fukita: "Synthesis, Structure and Magnetism of New Bimetallic Assemblies, [Ni(chxn)_2]_3[M(CN)_6]_2・2H_2O"Mol.Cryst.Liq.Cryst.. 342. 217-224 (2000)
[Publications] H.Furutachi: "Dinuclear Co^<II>M^<II>(M=Pb or Co) Complexes Having A 'Co(salen)' Entity in A Macrocyclic Framework"J.Chem.Soc.,Dalton Trans.. 2000・16. 2761-2769 (2000)
[Publications] M.Shinoura: "A Heteronuclear Co(I)Cu(I) Complex with Co(salen) in A Macrocyclic Framework. Oxygenation Studies in Comparison with Analogous Complexes"Inorg.Chem.. 39・20. 2761-2769 (2000)
[Publications] S.Noro: "New Methane Adsorbent of Porous Coordination Polymer, [Cu(SiF_6)(4,4'-bipyridine)_2]_n "Angew.Chem.,Int.Ed.Engl.. 39・7. 2081-2084 (2000)
[Publications] M.Kondo: "Microporous Materials constructed from the Interpenetrated Coordination Networks. Structures and Methane Adsorption Properties"Chem.Mater.. 2000・12. 1288-1299 (2000)
[Publications] M.Kondo: "A New Self-Assembled Porphyrin-Silver(I) Network"Chem.Lett.. 2000・7. 818-819 (2000)
[Publications] M.K.Kabir: "Novel Layered Structures Constructed From Iron-Chloranilate Compounds"Coord.Chem.Rev.. 198. 157-190 (2000)
[Publications] K.Kitano: "Lantern-type dinuclear Cr^<III>Pt^<II> and V^<IV>Pt^<II> complexes bridged by pyridine-2-thiolate : Synthesis and characterization"J.Chem.Soc.Dalton Trans.. 2000・9. 995-1000 (2000)
[Publications] T.Oshiki: "Substituent Effect on Organotin Tp^* Compounds as the Tp^* Reagent for the Preparation of Mono Tp^* Complexes of Group 4b Metals"Bull.Chem.Soc.Jpn.. 73・8. 1735-1748 (2000)
[Publications] M.Tanaka: "Unique Axial Interaction of a Quadruply-Bonded Cr(II)Cr(II)with Two Pt(II) Atoms in the Linearly Aligned PtCrCrPt"Bull.Chem.Soc.Jpn.. 74・9. 67-75 (2001)
[Publications] K.Mashima: "1-Aza-1,3-butadiene Complexes of Tantalum : Synthesis and Alkylation of TaCl_2(η_5 -C_5Me_5)(1-aza-1,3-butadiene)"J.Organomet.Chem.. 593/594. 69-76 (2000)
[Publications] H.Shimomura: "Formation of μ_4-Se_2 Complex by the Oxidative Coupling of μ-SeH Complex : Double-site Atomic Inversion of the μ_4-Se_2 Complex"J.Organomet.Chem.. 611・2. 386-391 (2000)
[Publications] K.Nishikawa: "Synthesis and X-Ray Analysis of Mn-Mo Mixed Metal Oxide Cluster with Cubic Framework"Chem.Lett.. 2000・8. 1342-1343 (2000)
[Publications] K.Kitano: "Lantern-type Dinuclear Cr(III)Pt(II)and V(IV)Pt(II) Complexes Bridged by Pyridine-2-thiolate. Synthesis and Characterization"J.Chem.Soc.Dalton Trans.. 2000・9. 995-1000 (2000)

2000 Fiscal Year Annual Research Report

ディスクリートな集積型金属錯体および集積系ユニットの創出

Principal Investigator

大川 尚士 九州大学, 大学院・理学研究院, 教授 (00037219)

Research Products

[Publications] N.Fukita: "Trinuclear CuMCu Complexes of An Oxamide/dioxime Ligand and Extension To A bimetallic Magnetic Material"J.Chem.Soc.Dalton Trans. 2001・1. 64-70 (2001)

[Publications] M.Yonemura: "A Mixed-metal Cu^<II>_2Ni^<II>_2 Complex Derived from A Phenol-based Heterotetranucleating Macrocyclic Ligand"J.Chem.Soc.,Chem.Commun.. 2000・9. 817-819 (2000)

[Publications] M.Yonemura: "Macrocyclic Effects upon Isomeric Cu^<II>M^<II> and M^<II>Cu^<II> Cores Formation with Unsymmetric Phenol-Based Macrocyclic Ligands"Proc.Ind.Acad.Sci.. 112・3. 291-310 (2000)

[Publications] M.Suzuki: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 200-202. 105-129 (2000)

[Publications] N.Fukita: "Synthesis, Structure and Magnetism of New Bimetallic Assemblies, [Ni(chxn)_2]_3[M(CN)_6]_2・2H_2O"Mol.Cryst.Liq.Cryst.. 342. 217-224 (2000)

[Publications] H.Furutachi: "Dinuclear Co^<II>M^<II>(M=Pb or Co) Complexes Having A 'Co(salen)' Entity in A Macrocyclic Framework"J.Chem.Soc.,Dalton Trans.. 2000・16. 2761-2769 (2000)

[Publications] M.Shinoura: "A Heteronuclear Co(I)Cu(I) Complex with Co(salen) in A Macrocyclic Framework. Oxygenation Studies in Comparison with Analogous Complexes"Inorg.Chem.. 39・20. 2761-2769 (2000)

[Publications] S.Noro: "New Methane Adsorbent of Porous Coordination Polymer, [Cu(SiF_6)(4,4'-bipyridine)_2]_n "Angew.Chem.,Int.Ed.Engl.. 39・7. 2081-2084 (2000)

[Publications] M.Kondo: "Microporous Materials constructed from the Interpenetrated Coordination Networks. Structures and Methane Adsorption Properties"Chem.Mater.. 2000・12. 1288-1299 (2000)

[Publications] M.Kondo: "A New Self-Assembled Porphyrin-Silver(I) Network"Chem.Lett.. 2000・7. 818-819 (2000)

[Publications] M.K.Kabir: "Novel Layered Structures Constructed From Iron-Chloranilate Compounds"Coord.Chem.Rev.. 198. 157-190 (2000)

[Publications] K.Kitano: "Lantern-type dinuclear Cr^<III>Pt^<II> and V^<IV>Pt^<II> complexes bridged by pyridine-2-thiolate : Synthesis and characterization"J.Chem.Soc.Dalton Trans.. 2000・9. 995-1000 (2000)

[Publications] T.Oshiki: "Substituent Effect on Organotin Tp^* Compounds as the Tp^* Reagent for the Preparation of Mono Tp^* Complexes of Group 4b Metals"Bull.Chem.Soc.Jpn.. 73・8. 1735-1748 (2000)

[Publications] M.Tanaka: "Unique Axial Interaction of a Quadruply-Bonded Cr(II)Cr(II)with Two Pt(II) Atoms in the Linearly Aligned PtCrCrPt"Bull.Chem.Soc.Jpn.. 74・9. 67-75 (2001)

[Publications] K.Mashima: "1-Aza-1,3-butadiene Complexes of Tantalum : Synthesis and Alkylation of TaCl_2(η_5 -C_5Me_5)(1-aza-1,3-butadiene)"J.Organomet.Chem.. 593/594. 69-76 (2000)

[Publications] H.Shimomura: "Formation of μ_4-Se_2 Complex by the Oxidative Coupling of μ-SeH Complex : Double-site Atomic Inversion of the μ_4-Se_2 Complex"J.Organomet.Chem.. 611・2. 386-391 (2000)

[Publications] K.Nishikawa: "Synthesis and X-Ray Analysis of Mn-Mo Mixed Metal Oxide Cluster with Cubic Framework"Chem.Lett.. 2000・8. 1342-1343 (2000)

[Publications] K.Kitano: "Lantern-type Dinuclear Cr(III)Pt(II)and V(IV)Pt(II) Complexes Bridged by Pyridine-2-thiolate. Synthesis and Characterization"J.Chem.Soc.Dalton Trans.. 2000・9. 995-1000 (2000)

大川尚士九州大学, 大学院・理学研究院, 教授 (00037219)