1999 Fiscal Year Final Research Report Summary
PROSPECTIVE CREATION ON ENERGY-RELATED FUNCTION MATERIALS USING ISOTOPE EFFECT
| Project/Area Number |
10308023
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Nuclear engineering
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| Research Institution | NAGOYA UNIVERSITY |
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Principal Investigator |
MATSUI Tsuneo NAGOYA UNIV., QUANTUM ENG., PROF., 工学研究科, 教授 (90135319)
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| Co-Investigator(Kenkyū-buntansha) |
SHIGEMATSU Hirotake NAGOYA UNIV., QUANTUM ENG., RESEARCH ASSOSIATE, 工学研究科, 助手 (40281068)
ARITA Yuji NAGOYA UNIV., QUANTUM ENG., RESEARCH ASSOSIATE, 工学研究科, 助手 (50262879)
NAGASAKI Takanori NAGOYA UNIV., QUANTUM ENG., ASSOCIATE PROF., 工学研究科, 助教授 (40273289)
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| Project Period (FY) |
1998 – 1999
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| Keywords | ISOTOPE EFFECT / SUPER IONIC CONDUCTOR / FERROELECTRIC MATERIALS / THERMOELECTRIC MATERIAL / QUANTUM EFFECT |
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| Research Abstract |
THE ISOTOPE EFFECTS ON THE PHYSICAL PROPERTIES RELATED TO THE ATOMIC VIBRATION, SUCH AS IONIC CONDUCTIVITY OF SUPERIONIC CONDUCTORS, THERMAL CONDUCTIVITIES OF THERMOELECTRIC MATERIALS AND PHASE TRANSITION OF FERROELECTRIC MATERIALS WERE INVESTIGATED.
THE LITHIUM IONIC CONDUCTIVITY OF (LaィイD21/2ィエD2 LiィイD21/2ィエD2)ィイD21-XィエD2SrィイD2XィエD2TiOィイD23ィエD2 (X=0, 0.05), WHICH HAS BEEN KNOWN AS THE CONDUCTOR HAVING THE MOST HIGHEST Li IONIC CONDUCTIVITY, WAS MEASURED USING THE ィイD16ィエD1Li-ENRICHED AND ィイD17ィエD1Li-ENRICHED SAMPLES. THE Li IONIC CONDUCTIVITY OF ィイD16ィエD1Li-ENRICHED SAMPLE WAS ABOUT 1.5 TIMES HIGHER THAN THAT OF ィイD17ィエD1Li-ENRICHED ONE, WHOSE HIGHER VALUE CAN NOT BE EXPLAINED BY THE CLASSICAL DIFFUSION MODEL. THE GLASS TRANSITION TEMPERATURE AND IONIC CONDUCTIVITY OF 0.33LiィイD22ィエD2O-0.67BィイD22ィエD2OィイD23ィエD2 GLASS WERE MEASURED BY VARYING ィイD16ィエD1Li / ィイD17ィエD1Li AND ィイD110ィエD1B / ィイD111ィエD1B ISOTOPE RATIOS IN THE SAMPLES. THE CHANGE IN THE GLASS TRANSITION WAS NOT CLEARLY OBSERVED. HOWEVER THE Li IONIC CONDUCTIVITY OF ィイD16ィエD1 Li-ENRICHED SAMPLE WAS ABOUT 2.2 TIMES HIGHER THAN THAT OF ィイD17ィエD1Li-ENRICHED ONE AT 500K, AND THAT OF ィイD110ィエD1B-ENRICHED SAMPLE WAS ABOUT 1.4 TIMES HIGHER THAN THAT OF ィイD111ィエD1B-ENRICHED SAMPLE AT 500K, SUGGESTING THE PRESENCE OF STRONG CORRELATION BETWEEN Li-IONS AND ALSO THE RELAXATION VIBRATION OF THE B-O NETWORK STRUCTURE.
THE ISOTOPE EFFECT ON FERROELECTRIC PHASE TRANSITION OF PbTiOィイD23ィエD2 WAS MEASURED. THE TRANSITION TEMPERATURE OF ィイD146ィエD1Ti-ENRICHED SAMPLE WAS ABOUT 8.8K HIGHER THAN THAT OF ィイD149ィエD1Ti-ENRICHED SAMPLE.
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