1998 Fiscal Year Annual Research Report

超ゼオライト機能性細孔の創成と産業への先進的展開

Research Project

Project/Area Number	10554041
Research Category	Grant-in-Aid for Scientific Research (B)
Research Institution	Kanagawa University
Principal Investigator	森和亮神奈川大学, 理学部, 教授 (60029709)
Co-Investigator(Kenkyū-buntansha)	関建司大阪ガス(株), 研究開発部, 主任研究員武田定群馬大学, 工学部, 助教授 (00155011) 西本右子神奈川大学, 理学部, 助手 (70241114)
Keywords	気体吸蔵 / マイクロポアー物質 / 気体貯蔵 / ジカルボン酸銅(II) / 工業的利用
Research Abstract	活性炭、ゼオライトなど細孔を持っている物質はいまや産業界で不可欠の存在であり、細孔特有の物理的、化学的物質を利用した応用は、分子ふるい、触媒、イオン交換など多岐にわたっている。中でもゼオライトは化学的にも構造的にも均一度が高く、最も価値ある機能性材料として多くの工業的利用法の研究がなされている。我々はテレフタル酸銅(II)などのジカルボン酸銅(II)がN_2、Ar、O_2、メタンなどの気体を多量に吸蔵することを見つけた。これらの銅塩は、いろいろなジカルボン酸を用いることによって、細孔径を制御できる利点を持っている。したがって、我々の見つけたジカルボン酸銅(II)はゼオライトに代わる機能性細孔物質として有望である。本研究では、まず気体貯蔵効率がより高いマイクロポアー物質を開発した。ガス貯蔵効率を高めるために、より大きな細孔径を持つ物質を作り出す目的でtrans,trans-ムコン酸などの長い骨格を持ったジカルボン酸の金属錯体の合成を行った。空洞を大きくするため、理論計算による分子設計を行い、その結果に基づいて積層構造間にピラジン、ピペラジンなどのスペーサーを導入した。 Cu(II)のマイクロポアーから一歩進んで新しい機能を持ったMo、Ruの塩の合成に成功した。また、ブタジエンなどの炭化水素気体を吸蔵させ、NMRを測定して炭化水素分子の吸蔵状態を明らかにした。一方、実用化の点では、天然ガスの吸蔵にジカルボン酸銅(II)が優れていることがわかった。昨今、自動車の排ガスの問題でガソリンに代わる燃料が検討されているが、我々のジカルボン酸銅(II)の開発を進めれば、天然ガス自動車が容易となり、排ガスの問題の改善が期待できる。

Research Products
(20 results)

All Other

All Publications (20 results)

[Publications] R.Nukada, W.Mori, S.Takamizawa, M.Mikuriya, and H.Naono.: "Microporous structure of a chain compound of copper(II) benzoate bridged by pyrazine." Chem.Lett.in press. (1999)
[Publications] W.Mori, H.Hoshino, Y.Nishimoto, and S.Takamizawa.: "Synthsis and gas occlusion of new micropore substance rhodium(II) carboxylates bridged by pyrazine." Chem.Lett.in press. (1999)
[Publications] Y.Nishida, A.Yatani, Y.Nakao, J.Taka, S.Kashino, W.Mori, and S.Suzuki.: "The formation of a hyrogencarbonato-bridged dinuclear copper(II) complex by fixation and activation of atmospheric CO_2." Chem.Lett.135-136 (1999)
[Publications] M.Hirotsu, M.Kojima, W.Mori, and Y.Yoshikawa: "Steric control of polynuclear manganese complexes by the use of tripodal tetradentate ligand." Bull.Chem.Soc.Japan. 71. 2873-2884 (1998)
[Publications] Y.Hosokawa, H.Yamane, Y.Nakao, K.Matsumoto, S.Tamizawa, W.Mori, S.Suzuki, H.Kimoto: "Synthsis, structure and characterizition of dinuclear nickel(II) complexes containing thederivatives of N, N, N', N'-tetrakis[(2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane and an acetate or a propoinate ion." Inorg.Chem.Acta. 283. 118-123 (1998)
[Publications] S.Takamizawa, W.Mori, M.Furihata, S.Takeda, and K.Yamaguchi: "Synthesis and gas occlusion properties of dinuclear molybdenum(II) dicarboxylate (fumarate, trans-trans-muconate, pyridin-2,5-dicarboxylate, and trans-1,4-cyclohexanedicarboxylate)." Inrog.Chem.Acta. 283. 268-274 (1998)
[Publications] T.Minamisono, T.Ohtsubo, K.Sato, S.Takeda, S.Fukuda, T.Izumikawa, M.Tanigaki, T.Miyake, T.Yamaguchi, N.Nakamura, H.Tanji, K.Matsuta, M.Fukuda, and Y.Nojiri: "“Quadrupole Moment of the Proton Rich b-Emitting Nucleus 12N"," Phys.Lett.B. 420. 31-36 (1998)
[Publications] C.Benedict, U.Langer, H.H.Limbach, H.Ogata, and S.Takeda: "“Observation of Thermal Tautomerism of Thermochromic Salicylydeneaniline Derivatives in the Solid State by 15N-CP/MAS NMR down to Clyogenic Temperature"" Ber.Bunsengesr.Phys.Chem.102. 335-339 (1998)
[Publications] H.Huang, T.Sakurai, H.Monjushiro, S.Takeda,: "Magnetic Studies of the Trinuclear Center in Laccase and Ascorbate Oxidase approached by EPR Spectroscopy and Magnetic Susceptibility"," Biochim.Biophys.Acta,. 1348. 160-170 (1998)
[Publications] K.Sato, S.Takeda, S.Fukuda, T.Minamisono, M.Tanigaki, T.Miyake, Y.Maruyama, K.Matsuta, M.Fukuda, Y.Nojiri,: "“FT-NMR Detection of 45Sc, 49Yi and 93Nb in TiO2 Sibgle Crystal"" Z.Naturforsch.53a. 549-551 (1998)
[Publications] Minamisono, T.; Sato, K.; Akai, H.; Takeda, S.; Maruyama, Y.; Matsuta, K.; Fukuda, M.; Miyake, T.; Morishita, A.; Izumikawa, T.; Nojiri,Y.: "“Electric quadrupole interactions of the short-lived b-emitter 12N in insulator crystals (12N implanted in single crystal TiO2)"," Z.Naturforsch., A:Phys.Sci.53. 293-300 (1998)
[Publications] S.Takeda, T.Inabe, C.Benedict, U.Langer, H.H.Limbach,: "“Proton Dynamics in Interacting Hydrogen Bonds in the Solid State: Proton Tunneling in the NHO Hydrogen Bonds of N, N'-Di(2-hydroxy-1-Naphthylmethylene)-p-Phenylenediamine"" Ber.Bunsenges.Phys.Chem.102. 1358-1369 (1998)
[Publications] Tanigaki, M.; Takeda, S.; Matsuta, K.; Matsumoto, Y.; Minamisono, T.; Akai, H.; Sato, K.; Miyake, T.; Maruyama, Y.; Morishita, A.; Fukuda, M.; Norjiri, Y.: "“NMR detection of oxygen isotopes in TiO2 single crystal"," Z.Naturforsch., A: Phys.Sci.,. 53. 305-308 (1998)
[Publications] G.Maruta, S.Takeda, R.Imachi, T.Ishida, T.Nogami, K.Yamaguchi,: "“Solid State High Resolution 1H and 2H NMR Stydies of the Electron Spin Density Distribution and Mechanism of the Magnetic Interaction of Hydrogen-Bonded Organic Ferromagnetic Compound 4-Hydroxyimino-TEMPO"" J.Am.Chem.Soc.121. 424-431 (1999)
[Publications] R.Imamura, K.Matsui, S.Takeda, J.Ozaki and A.Oya,: "“A new role for phosphorous in graphaitization of phenolic resin"" Carbon. 37. 261-267 (1999)
[Publications] G.Maruta, S.Takeda, K.Yamaguchi, K.Ueda, T.Sugimoto,: "Solid State High Resolution NMR Studies of Electron Spin Densities in Charge-Transfer Complex-Based Organic Ferromagnets"" Synth.Metals. (in press.). (1999)
[Publications] S.Takeda, G.Maruta, K.Terasawa, N.Fukuda, K.Yamaguchi,: "“Local Magnetic Structure of Layered Compounds Cu2(OD)3X with Exchangeable Acid Anion X Studied by Solid State High Resolution Deuterium NMR"" Mol.Crys.Liq, Cryst.(in press.). (1999)
[Publications] G.Maruta, S.Takeda, A.Yamaguchi, T.Okuno, K.Awaga, K.Yamaguchi,: "“Magic Angle Spinning 1H-NMR Study of the Spin Density Distribution of Pyrodyl Nitronyl Nitroxides in the Crystalline Phase"," Mol.Crys.Liq, Cryst.(in press.). (1999)
[Publications] A.Oda,T.Kawakami, G.Maruta, S.Takeda, W.Mori, K.Yamaguchi, M.M.Matsushita, T.Sugawara,: "“Theoretical Studies of Magnetic Interactions in 3', 5'-Dihydroxyphenyl Nitronyl Nitroxide Crystal"," Mol.Crys.Liq, Cryst.(in press.). (1999)
[Publications] T.kawakami, A.Oda, S.Takeda, W.Mori, K.Yamaguchi,: "“Theoretical Studies on Magnetic Interaction in TMAO"," Mol.Crys.Liq, Cryst.(in press.). (1999)

1998 Fiscal Year Annual Research Report

超ゼオライト機能性細孔の創成と産業への先進的展開

Principal Investigator

森 和亮 神奈川大学, 理学部, 教授 (60029709)

Research Products

[Publications] R.Nukada, W.Mori, S.Takamizawa, M.Mikuriya, and H.Naono.: "Microporous structure of a chain compound of copper(II) benzoate bridged by pyrazine." Chem.Lett.in press. (1999)

[Publications] W.Mori, H.Hoshino, Y.Nishimoto, and S.Takamizawa.: "Synthsis and gas occlusion of new micropore substance rhodium(II) carboxylates bridged by pyrazine." Chem.Lett.in press. (1999)

[Publications] Y.Nishida, A.Yatani, Y.Nakao, J.Taka, S.Kashino, W.Mori, and S.Suzuki.: "The formation of a hyrogencarbonato-bridged dinuclear copper(II) complex by fixation and activation of atmospheric CO_2." Chem.Lett.135-136 (1999)

[Publications] M.Hirotsu, M.Kojima, W.Mori, and Y.Yoshikawa: "Steric control of polynuclear manganese complexes by the use of tripodal tetradentate ligand." Bull.Chem.Soc.Japan. 71. 2873-2884 (1998)

[Publications] S.Takamizawa, W.Mori, M.Furihata, S.Takeda, and K.Yamaguchi: "Synthesis and gas occlusion properties of dinuclear molybdenum(II) dicarboxylate (fumarate, trans-trans-muconate, pyridin-2,5-dicarboxylate, and trans-1,4-cyclohexanedicarboxylate)." Inrog.Chem.Acta. 283. 268-274 (1998)

[Publications] T.Minamisono, T.Ohtsubo, K.Sato, S.Takeda, S.Fukuda, T.Izumikawa, M.Tanigaki, T.Miyake, T.Yamaguchi, N.Nakamura, H.Tanji, K.Matsuta, M.Fukuda, and Y.Nojiri: "“Quadrupole Moment of the Proton Rich b-Emitting Nucleus 12N"," Phys.Lett.B. 420. 31-36 (1998)

[Publications] C.Benedict, U.Langer, H.H.Limbach, H.Ogata, and S.Takeda: "“Observation of Thermal Tautomerism of Thermochromic Salicylydeneaniline Derivatives in the Solid State by 15N-CP/MAS NMR down to Clyogenic Temperature"" Ber.Bunsengesr.Phys.Chem.102. 335-339 (1998)

[Publications] H.Huang, T.Sakurai, H.Monjushiro, S.Takeda,: "Magnetic Studies of the Trinuclear Center in Laccase and Ascorbate Oxidase approached by EPR Spectroscopy and Magnetic Susceptibility"," Biochim.Biophys.Acta,. 1348. 160-170 (1998)

[Publications] K.Sato, S.Takeda, S.Fukuda, T.Minamisono, M.Tanigaki, T.Miyake, Y.Maruyama, K.Matsuta, M.Fukuda, Y.Nojiri,: "“FT-NMR Detection of 45Sc, 49Yi and 93Nb in TiO2 Sibgle Crystal"" Z.Naturforsch.53a. 549-551 (1998)

[Publications] S.Takeda, T.Inabe, C.Benedict, U.Langer, H.H.Limbach,: "“Proton Dynamics in Interacting Hydrogen Bonds in the Solid State: Proton Tunneling in the NHO Hydrogen Bonds of N, N'-Di(2-hydroxy-1-Naphthylmethylene)-p-Phenylenediamine"" Ber.Bunsenges.Phys.Chem.102. 1358-1369 (1998)

[Publications] Tanigaki, M.; Takeda, S.; Matsuta, K.; Matsumoto, Y.; Minamisono, T.; Akai, H.; Sato, K.; Miyake, T.; Maruyama, Y.; Morishita, A.; Fukuda, M.; Norjiri, Y.: "“NMR detection of oxygen isotopes in TiO2 single crystal"," Z.Naturforsch., A: Phys.Sci.,. 53. 305-308 (1998)

[Publications] R.Imamura, K.Matsui, S.Takeda, J.Ozaki and A.Oya,: "“A new role for phosphorous in graphaitization of phenolic resin"" Carbon. 37. 261-267 (1999)

[Publications] G.Maruta, S.Takeda, K.Yamaguchi, K.Ueda, T.Sugimoto,: "Solid State High Resolution NMR Studies of Electron Spin Densities in Charge-Transfer Complex-Based Organic Ferromagnets"" Synth.Metals. (in press.). (1999)

[Publications] S.Takeda, G.Maruta, K.Terasawa, N.Fukuda, K.Yamaguchi,: "“Local Magnetic Structure of Layered Compounds Cu2(OD)3X with Exchangeable Acid Anion X Studied by Solid State High Resolution Deuterium NMR"" Mol.Crys.Liq, Cryst.(in press.). (1999)

[Publications] G.Maruta, S.Takeda, A.Yamaguchi, T.Okuno, K.Awaga, K.Yamaguchi,: "“Magic Angle Spinning 1H-NMR Study of the Spin Density Distribution of Pyrodyl Nitronyl Nitroxides in the Crystalline Phase"," Mol.Crys.Liq, Cryst.(in press.). (1999)

[Publications] A.Oda,T.Kawakami, G.Maruta, S.Takeda, W.Mori, K.Yamaguchi, M.M.Matsushita, T.Sugawara,: "“Theoretical Studies of Magnetic Interactions in 3', 5'-Dihydroxyphenyl Nitronyl Nitroxide Crystal"," Mol.Crys.Liq, Cryst.(in press.). (1999)

[Publications] T.kawakami, A.Oda, S.Takeda, W.Mori, K.Yamaguchi,: "“Theoretical Studies on Magnetic Interaction in TMAO"," Mol.Crys.Liq, Cryst.(in press.). (1999)

森和亮神奈川大学, 理学部, 教授 (60029709)