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2000 Fiscal Year Final Research Report Summary

THE FORMATION AND APPLICATION OF NOVEL MICROPOROUS COMPLEXES

Research Project

Project/Area Number 10554041
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section展開研究
Research Field 機能・物性・材料
Research InstitutionKANAGAWA UNIVERSITY

Principal Investigator

MORI Wasuke  KANAGAWA UNIVERSITY FACULTY OF SCIENCE PROFESSER, 理学部, 教授 (60029709)

Co-Investigator(Kenkyū-buntansha) SEKI Kennji  OSKA GAS CO.LTD.RESEACH AND DEVELOPMENT PROJECT LEADER, 研究開発部, 主任研究員
TAKEDA Sadamu  HOKKAIDOU UNIVERSITY FACULTY OF SCIENCE PROFESSER, 理学部, 教授 (00155011)
NISHIMOTO Yuko  KANAGAWA UNIVERSITY FACULTY OF SCIENCE ASSISTANT PROFESSER, 理学部, 助手 (70241114)
Project Period (FY) 1998 – 2000
Keywordsgas occlusion / microporous substance / trasition-metal dicarboxylates
Research Abstract

The dinuclear transition-metal dicarboxylates (Cu(II), Mo(II), Ru(II,III) ) reversibly occlude a large amount of gases such as N_2, 0_2, Ar, and CH_4. It was concluded that the gas molecules are occluded in uniform micropores constracted by transition-metal complexes. The complexes are useful adsorbent for storing gases, and may be useful catalyst for chemical reactions.

  • Research Products

    (37 results)

All Other

All Publications (37 results)

  • [Publications] S.Takamizawa,M.Furihata,S.Takeda,K.Yamaguchi,and W.Mori: "A Novel Inclusion Complex between Molybdenum (II) Fumarate and Poly (ethylene glycol)"Polymers for Advanced Technology. 11. 840-844 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] W.Mori,H.Hoshino,K.Horikawa,Y.Nishimoto,and S.Takamizawa: "Synthesis and gas occlusion of rhodium (II) benzoate bridged by nitrogen donor ligands"Molecular Crystals and liquid Crystals. 342. 193-198 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Takamizawa,T.Ohmura,K.Yamaguchi,and W.Mori: "Synthesis and gas-occlusion properties of ruthenium (II, III) dicarboxylate bridged by halogen atoms"Molecular Crystals and liquid Crystals. 342. 199-204 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Takamizawa,W.Mori,Y.Yokomichi,Y.Kitagawa,T.Maruta,T.Kawakami,Y.Yoshioka,and K.Yamaguchi: "Molecular Simulations of Argon, Nitrogen, and Hydrogen Adsorption in Microporous Complexes"Molecular Crystals and liquid Crystals. 342. 258-290 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kawakami,S.Takamizawa,Y.Kitagawa,W.Mori,K.Yamaguchi and K.Katsumata: "Theoretical Studies on Radical Spin Arrangements in the Cavity of Microporous Complexes",, Mol.Cryst.Liq.Cryst., 343, (2000)."Molecular Crystals and liquid Crystals. 343. 215-220 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] W.Mori and S.Takamizawa: "Microporous Materials of Metal Carboxylates"Journal of Solid State Chemistry. 152. 120-129 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Takamizawa,M.Furihata,S.Takeda,K.Yamaguchi,and W Mori: "Synthesis and Characterization of a Novel Inclusion Complexes between Microporous Moybdenum (II) Dicarboxylates and Organic Polymers"Macromolecules. 33. 6222-6227 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Kamiguchi,T.Saito,and W.Mori: "Magnetic properties of the octahedral chromium chalcogenide cluster complexes [Cr_6Se_8(PEt_3)_6], [Cr_6Se_8(H)(PEt_3)_6], and [Cr_6Se_8(H)(PEt_3)_6]"Bulletin of Chemical Society of Japan. 73. 2487-2491 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Emori,M.Nakashima,and W.Mori: "Magneto-structural correlations in phenooxo-bridged metal (II) compounds..Magnetic properties of (R_4N)_2[Co_2Cl_4(4-XC_6H_4O)_2(X=H, CH_3; R=CH_3, C_2H_5)"Bulletin of Chemical Society of Japan. 73. 81-84 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Asano,Y.Miyazaki,W.Mori,K.Nakatani,O.Kahn,and M.Sorai: "Calorimetric and magnetic studies on a ferromagnetic phase trasition of the metaiassembled complex MnCu(obbz)・H_2O"Bulletin of Chemical Society of Japan. 73. 885-893 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Ohtsu,Y.Shimazaki,A.Odani,O.Yamauchi,W.Mori,S.Itoh,and S.Fukuzumi,: "Synthesis and chracterization of imidazolate-bridged dinuclear complexes as active site model of Cu,Zn-SOD,"Journal of American Chemical Society. 122. 5733-5741 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tanaka,K.Mashima,M.Nishino,S.Takeda,W.Mori,K.Tani,K.Yamaguchi,and A.Nakamura: "Unique Axial interaction of a Quadruply-Bonded Cr(II)-Cr(II) with Two Pt(II) Atoms in the Linearly Aligned Pt-Cr-Cr-Pt Supported by Four 6-Diphenylphosphino-2-pyridinate Ligands"Bulletin of Chemical Society of Japan. 74. 67-75 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Mimura, T.Matsuo, N.Matsumoto, S.Takamizawa, W.Mori, and N.Re: "Bis[(methanol){N-salicylidene-N^1-(2-phenylimidazol-4-ylmethylidene)-1,3 propanediaminato}nickel (II)] Bridged by Di-μ-phenoxo Moiety and the Deprotonated Imidazolate-Bridged Cyclic-Tetranuclear Complex."Bull.Chem.Soc.. 71. 1831-1837 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Mori, M.Nakano, H.Tamura, Gen-etsu Matsubayashi, and W.Mori: "Paramagnetic Organocobalt (III) Dithiolate complex : Crystal Structure and Magnetic Property of [Co (η^5-C_5Me_5)(C_3S_5) Br]."Chem.Lett.. 729-730 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Takamizawa, K.Yamaguch, W.Mori: "The gas-occlusion properties of dicalboxylate (fumarate, trans-trans-muconate and terephthalate) ruthenium (II) dinucler complexes."Inorg.chem.Comm.. 1. 177-178 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Takamizawa, W.Mori, M.Furihata, S.Takeda, and K.Yamaguchi: "Synthesis and gas-occlusion properties of dinuclear molybdenum (II) dicarboxylate (fumarate, trans-trans-muconate pyridine-2,5-dicarboxylate, and trans-1,4-cvclohexanedicarboxylate)"Inorg.Chim.Scta.. 283. 268-274 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Hosokawa, H.Yamane, Y.Nakao, K.Matsumoto, S.Takamizawa, W.Mori, S.Suzuki, H.Kimoto: "Synthesis, structure and characterizition if dinuclear nickel (II) complexes containing the derivatives of N, N, N', N'-tetrakis [(2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane and an acetate or a propoinatc ion"Inorg.Chim.Acta.. 283. 118-123 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Hirotsu, M.Kojima, W.Mari, and Y.Yoshikawa: "Steric control of polynuclear manganese complexes by the use of tripodal tetradentate ligand"Bull.Chem.Soc.Japan.. 71. 2873-2884 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Nishida, A.Yatani, Y.Nakao, J.Taka, S.Kashino. W.Mori, and S.Suzuki: "The formation of a hydrogencarbonato-bridged dinuclear copper (II) complex by fixation and activation of atmospheric C0_2"Chem.Lett.. 135-136 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Hirotsu, M.Kojima, W.Mori, and Y.Yoshikawa: "Heteronuclear FeIIIMnIIFeIII and homonuclear FeIIIFeIIIFeIII complexes with a tripodal tetra dentate ligand"Chem.Lett.. 229-230 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] W.Mori, H.Hoshino, Y.Nishimoto, and S.Takamizawa: "Synthesis and gas occlusion of new micropore substance rhodium (II) carboxylates bridged by pyrazine"Chem.Lett.. 331-332 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Nukada, W.Mori, S.Takamizawa, M.Mikuriya, M.Handa, and H.Naono: "Microporous structure of a chain compound of copper (II) benzoate bridged by pyrazine"Chem.Lett.. 367-368 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Maekawa, S.Kitagawa, Y.Nakao, S.Sakamoto, A.Yatani, W.Mori, S.Kashino, and M.Munakata: "Synthesis, crystal structures and autoreduction behavior of antiferromagnetically coupled dicopper (II) oximato complexes"Chim.Acta.. 293. 20-29 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Emori, M.Nakashima, and W.Mari: "Magneto-structural correlations in phenooxo-bridged metal (II) compounds. Magnetic properties of (R_4N)_2[C0_2Cl_4(4-XC_6H_4O)_2(X=H, CH_3 ; R=CH_3, C_2H_5)"Bull.Chem.Soc.. 73. 81-84 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Asano, Y.Miyazaki, W.Mori, K.Nakatani, O.Kahn, and M.Sorai: "Calorimetric and magnetic studies on a ferromagnetic phase trasition of the metal-assembled complex MnCu (obbz) H_2O"Bull.Chem.Soc.. 73. 885-893 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Ohtsu, Y.Shimazaki, A.Odani, O.Yamauchi, W.Mori, S.Itoh, and S.Fukuzumi: "Synthesis and chracterization of imidazolate-bridged dinuclear complexes as active site models of Cu, Zn-SOD"J.Am.Chem.Soc.. 122. 5733-5741 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] W.Mari, S.Takamizawa: "Microporous materials of metal carboxylates"J.Solid State Chemistry. 153. 120-129 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] W.Mori, H.Hoshino, K.Horikawa, Y.Nishimoto, and S.Takamizawa: "Synthesis and gas occlusion of rhodium (II) benzoate bridged by pyrazine derivatives"Mol.Cryst.Liq.Cryst.. 342. 193-198 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Takamizawa, T.Ohmura, K.Yamaguchi, and W.Mori: "Synthesis and gas-occlusion properties of ruthenium (II, III) dicarboxylates (fumarate, trans, trans-muconate and terephthalate) bridged by halogen atoms"Mol.Cryst.Liq.Cryst.. 342. 199-204 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Taksmizawa, W.Mori, Y.Yokomichi, Y.Kitagawa, T.Muruta, T.Kawakami, Y.Yoshioka, and K.Yamaguchi: "Molecular simulation of argon, nitrogen, and hysrogen adosorption in microporous complexes, S.Taksmizawa, W.Mori, Y.Yokomichi, Y.Kitagawa, T.Muruta. T.Kawakami.Y.Yoshioka"Mol.Cryst.Liq.Cryst.. 342. 285-290 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kawakami, S.Takamizawa, Y.Kitagawa, F.Matsuoka, T.Maruta, W.Mori, K.Yamaguchi: "Theoretical studies on radical spin arrangements in the cavity of nanoporous complexes"Mol.Cryst.Liq.Cryst.. 343. 215-220 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Takamizawa, M.Furihata, S.Takada, K.Yamagychi, and W.Mori: "Synthesis and characterization of novel inclusion compexes between microporous molybdenum (II) dicarboxylatea and organic polymers"Macromolecules. 33. 6222-6227 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Kamiguchi, T.Saito, amd W.Mori: "Magnetic properties of the octahedral chromium chalcogenide cluster complexes [Cr_6Se_8 (PEt_3)_6], [Cr_6Se_8 (H)(PEt_3)_6], and[Cr_6S_8 (H)(PEt_3)_6]"Bull.Chem.Soc.Jpn.. 73. 2487-2491 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Takamizawa, M.Furihata, S.Takeda, K.Yamaguchi, and W.Mori: "A novel inclusion complex between molybdenum (II) fumarate and poly (ethylene glycol) : first supramolecule formation between a microporous complex and an organic polymer"Polym.Adv.Techmol.. 11. 840-844 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Emori, K.Obata, and W.Mori: "Magnetic characterization of di-μ-hydroxobis (ethylenediamine-N, N-diacetato) dichromium (III). Magneto-structural corrilations in hydroxo-bridged chromium (III) complexes"ITE Letters on Batteries, New Technologies & Medicine. 1 Cl. 938 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tanaka, K.Mashima, M.Nishino, S.Takeda, W.Mori, K.Tani, K.Yamaguchi, and A.Nakamura: "Uniqe axial interaction of a quadruply-bonded Cr (II) -Cr (II) with two Pt (II) atoms in the limearly alegned Pt-Cr-Cr-Pt supported by four 6-diphenylphosphino-pyridomate ligands"Bull.Chem.Soc.Jpn.. 74. 67-75 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Seki, K., Takamizawa, S., Mori, W.: "Characterization of Microporus Copper (II) Dicarboxylates (Fumarate, Terephthalate, and trans-1,4-Cyclohexanedicarboxylate) by Gas Adsorption"Chem.Lett.. (in press.).

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2002-03-26  

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