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2000 Fiscal Year Final Research Report Summary

Micro structure analyses of nanotubes and their application to material science

Research Project

Project/Area Number 11165240
Research Category

Grant-in-Aid for Scientific Research on Priority Areas (A)

Allocation TypeSingle-year Grants
Research InstitutionMeijo University

Principal Investigator

ANDO Yoshinori  Faculty of Science & Technology, Meijo University, Professor, 理工学部, 教授 (30076591)

Co-Investigator(Kenkyū-buntansha) BANDOW Shunji  Japan Science and Technology, Meijo University, Researcher, ナノチューブ状物質プロジェクト, 研究員
Project Period (FY) 1999 – 2000
KeywordsMWNTs / SWNTs / micro structure analyses / Arc discharge / Raman spectra / breathing modes / arc plasma jet method / Quantitative production of nanotubes
Research Abstract

In this research, it was aimed to clarify the micro structure of nanotubes and their application to material science. For its purpose, a large amounts of nanotubes are necessary and required. In this two years, we have succeeded to get high quality multiwalled carbon nanotubes (MWNTs) and single-walled carbon nanotubes (SWNTs) in some quantity. Their application to material science has been just started.
By DC arc discharge evaporation of pure graphite rod in pure hydrogen gas, high quality MWNTs of high aspect ratio larger than 1000 and highly crystarized ones could be obtained. Other characteristic feature of the MWNTs is that the inner tube is very thin. The smallest inner tube is 0.4 um, which value is the smallest one theoretically expected. In Raman spectra, the peak of breathing modes corresponding to the thin inner tubes could be observed. Quantitative productions of such high quality MWNTs are planned now.
In order to get a large quantity of SWNTs by arc discharge, we developed a new arc plasma method by inclining the electrode. As the result, soots including 50% SWNTs were obtained in the order of a few gram in a few minutes. It can be tested to practical application, but purification of SWNTs is still left problem.

  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] X.Zhao, M.Ohkohchi, H.Shimoyama and Y.Ando: "Morphology of carbon allotropes prepared by hydrogen arc discharge"J.Crystal Growth. 198/199. 934-938 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Ando, X.Zhao, H.Shimoyama, G.Sakai and K.Kaneto: "Physical Properties of Multiwalled Carbon Nanotubes"J.Inorganic Materials. 1. 77-82 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Ando, X.Zhao and H.Shimoyama: "Carbonaceous Products by Hydrogen Arc Discharge"Cryst.Res.Technol.. 34. 597-603 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Kaneto, M.Tsuruta, G.Sakai, X.Zhao and Y.Ando: "Electrical conductivities of multi-wall carbon nanotubes"Chem.Phys.Letters. 326. 351-357 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] X.Zhao, T.Okazaki, A.Kasuya, H.Shimoyama and Y.Ando: "Optical Emission Spectra during Carbon Nanotube Production by DC Arc Discharge in H_2, CH_4 or He Gas"Jpn.J.Appl.Phys.. 38. 6014-6016 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kataura, Y.Kumazawa, X.Zhao Y.Ando et al.: "Optical Absorption and Resonance Raman Scattering of Carbon Nanotubes"AIP Conference Proceedings. 486. 328-332 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Ando, X.Zhao, H.Kataura, Y.Achiba, K.Kaneto et al.: "Multiwalled carbon nanotubes prepared by hydrogen arc"Diamond and Related Materials. 9,4/5. 847-851 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Ando and X.Zhao: "High Yield Synthesis of Single-Walled Carbon Nanotubes by DC Arc Discharge in High Temperature He Gas"Mol.Cryst.and Liq.Cryst.. 340,6. 707-712 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Ando, X.Zhao, K.Hirahara, K.Suenaga, S.Bandow and S.Iijima: "Mass production of single-wall carbon nanotubes by the arc plasma jet method"Chem.Phys.Letters. 323. 580-585 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Takizawa, S.Bandow, M.Yudasaka, Y.Ando et al.: "Change of tube diameter distribution of single-wall carbon nanotubes induced by changing the bimetallic ratio of Ni and Y catalysts"Chem.Phys.Letters. 326. 351-357 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Ando, X.Zhao, H.Kataura, Y.Achiba, K.Kaneto et al.: "Physical Properties of Carbon Nanografibers"Trans.Mater.Res.Soc.Japan. 25[3]. 817-820 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] L.C.Qin, X.Zhao, K.Hirahara, Y.Miyamoto, Y.Ando, S.Iijima: "The smallest carbon nanotube"Nature. 408. 50 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] X.Zhao, M.Ohkohchi, H.Shimoyama and Y.Ando: "Morphology of carbon allotropes prepared by hydrogen arc discharge"J.Crystal Growth. 198/199. 934-938 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Ando, X.Zhao, H.Shimoyama, G.Sakai and K.Kaneto: "Physical Properties of Multiwalled Carbon Nanotubes"J.Inorganic Materials. 1. 77-82 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Ando, X.Zhao and H.Shimoyama: "Carbonaceous Products by Hydrogen Arc Discharge"Cryst.Res.Technol.. 34. 597-603 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Kaneto, M.Tsuruta, G.Sakai, X.Zhao and Y.Ando: "Electrical conductivities of multi-wall carbon nanotubes"Synthetic Metals. 103. 2543-2546 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.Zhao, T.Okazaki, A.Kasuya, H.Shimoyama and Y.Ando: "Optical Emission Spectra during Carbon Nanotube Production by DC Arc Discharge in H_2, CH_4 or He Gas"Jpn.J.Appl.Phys.. 38. 6014-6016 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Kataura, Y.Kumazawa, X.Zhao, Y.Ando et al.: "Optical Absorption and Resonance Raman Scattering of Carbon Nanotubes"AIP Conference Proceedings. 486. 328-332 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Ando, X.Zhao, H.Kataura, Y.Achiba, K.Kaneto et al.: "Multiwalled carbon nanotubes prepared by hydrogen arc"Diamond and Related Materials. 9. 847-851 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Ando and X.Zhao: "High Yield Synthesis of Single-Walled Carbon Nanotubes by DC Arc Discharge in High Temperature He Gas"Mol.Cryst. and Liq.Cryst.. 340. 707-712 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Ando, X.Zhao, K.Hirahara, K.Suenaga, S.Bandow et al.: "Mass production of single-wall carbon nanotubes by the arc plasma jet method"Chem.Phys.Letter. 323. 580-585 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Takizawa, S.Bandow, M.Yudasaka, Y.Ando et al.: "Change of tube diameter distribution of single-wall carbon nanotubes induced by changing the bimetallic ratio of Ni and Y catalysts"Chem.Phys.Letters. 326. 351-357 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Ando, X.Zhao, H.Kataura, Y.Achiba, K.Kaneto et al.: "Physical Properties of Carbon Nanografibers"Trans.Mater.Res.Soc.Japan. 25[3]. 817-820 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] L.C.Qin, X.Zhao, K.Hirahara, Y.Miyamoto, Y.Ando et al.: "The smallest carbon nanotube"Nature. 408. 50 (2000)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2002-03-26  

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