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2002 Fiscal Year Final Research Report Summary

Sgncheses of slimulus responsible complexes and their structure, properties and reactivities

Research Project

Project/Area Number 11304046
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionOCHANOMIZU UNIVERSITY

Principal Investigator

FUKUDA Yutaka  OCHANOMIZU UNIV., SCIENCE FACULTY, Professor, 理学部, 教授 (30021950)

Co-Investigator(Kenkyū-buntansha) SUZUKI Noriyuki  The Institution of Physical and Chemical Research, Organometallic, Chemistry Labore Staff, 有機金属化学研究室, 研究員 (90241231)
YAMADA Shinji  OCHANOMIZU UNIV., SCIENCE FACULTY, Associate Professor, 大学院・人間文化研究科, 助教授 (30183122)
Project Period (FY) 1999 – 2002
Keywordsmixed rigand complex / cyclic diamine / β-diketone / chirality / chromotropison / Soluatochyomison / Thermochromism / Electrochromism
Research Abstract

We have studied various kinds of chromotropic systems of the transition metal omplexes. (1) For the Solvatochromism and Thermochromism, many kinds of mixed ligand complexes (Ni(II) and Cu(II)) containing a chirai β-diketonate(dike, such as trifluoro-acetyl-camphororate) and the chiral diamine (N-alkylated-1, 2-diamino-propane, diam) synthesized : general formula, M(diam)(dike)X. Another interesting point of this study is chiral discrimination of the organic ligand due to the chiral mixed ligand complexes containing these types of chiral ligands. The complexes with the ligand of acethylcamphor derivatives could not have a strong power of chiral discrimination, on the other hand, the chiral diamine shows more effective power for the chiral discrimination whose study is now in progress. (2) Solvatochromic systems of the compounds, Ni(cvclic-diamine)(dike)X, where cyclic-diamine = N-methyl-1, 4-diazacycloheptane, dike = various kinds of dike, X = coordinating or non-coordinating monoanion. These mixed ligand complexes with non-coordinating anion, show square planar and those with coordinating anion are octahedral This is called as "Anion effect of structural regulation". (3) Cu(II) complexes with bulky bidentate di-imine ligand synthesized and their crystal structure were determined, which is important work to clarify the intermediate substance of the catalytic complex system. (4) Finally, we obtained two examples of "Electrochromism", which shows reversible color change(deep red < = > colorless) with the redox system of Mn(II) and Mn(III) containing 1,4,7-triazacycIononane-1,4,7-tricarboxylate.

  • Research Products

    (39 results)

All Other

All Publications (39 results)

  • [Publications] T.M.Yoshida et al.: "Phase relation and molecular motions of mixed ligand complex[Zn(hfac)_2(tmen)] as studied by calorimetry and 'H-NMR measurement"J. Phys. Chem. Solids. 60. 1787-1796 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] F.Renz et al.: "Anisotropic effect after Stretching of the Spin Crossover Compound [Fe(11)(2,6-bis(benzimidazol-2'-yl)pyridine)_2](ClO_4)_2 in polyvinylalcoholPolymer Matrix"Mol. Cryst. Liq. Cryst.. 335. 531-540 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] F.Renz et al.: "Spin-Transition in[Fe(11)(2,6-bis(benzimidazol-2'-yl)pyridine)_2](Cl_4)_2 : Hysteresis effect Dependent on the Matrix"Mol. Cryst. Liq. Cryst.. 335. 521-530 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Gou et al.: "Cyano-Bridged dinuclear iron complexes in different oxidation states"Inorg. Chim. Acta. 287. 95-100 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Manseki et al.: "Template Syntheses and properties of Cu(II)-La(III) complexed of phenol-based Symmetric and Unsymmetric dinuclear macrocycles"J. Coord. Chem.. 48. 1-13 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Paulovicova et al.: "Synthesis, characterization and X-ray crystal structures of two five-coordinate ternary copper(II) complexes containing acetylacetonate with 1,10-p henanthroline and 2,9-dimethyl phenanthroline Adriana Paulovicova"Inorg. Chem. Acta.. 321. 56-62 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Boca, et al.: "Spin crossover in mononuclear and dinuclear Fe(III) complexes with pentadentate Schiff-base ligands"Coordination Chemistry at the turn of the Century, Ed. by G. Ondrejavic and A. Shirota, Slovakia Tech. Univ. Press. (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] U.I.El-Ayaan et al.: "Thermochromism and Solvatochromism in Solution"Monatsh. Chem.. 132. 1279-1294 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Hasegawa et al.: "Higher excited state fluorescence of mixed ligand lanthanide(III) complexes with acetylacetonate, nitrate and cerpyridine"Chem. Phys.. 269. 323-337 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] W.Linert et al.: "Chromotropiser of Coordination Compounds in Solution"Coord. Chem. Rev.. 218. 113-152 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Paulovicova et al.: "Mixed Ligand Copper(II) Complexes with the Rigid Bidentate Bis(N-arylimino)acenaphthene Ligand-Synthesis, Spectroscopic and X-ray Structural Characterization"Europ. J. Inorg. Chem.. 2001. 2641-2646 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Hasegawa et al.: "Fluorescence Spectra of Fe(II) spin crossover complexes with 2,6-bis(benzimidazere-2'-yl) Pyridine"Chem. Phys.. 227. 21-30 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kh.S.Abou-El Sherbini et al.: "Study on the complex formation between N-propylsalicylidene based on Silica as ion exchanger and some trantion metal ions"J. Sci. Islamic Rep. Iran. 13. 217-223 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Fukuda et al.: "Syntheses and Specific Structures of Higher-Order Mixed Chelate Lanthanide Complexes Containing Terpyridine, Acetylacetonate, and Nitrate Ligands"J. Chem. Soc. Dalton Frans.. 2002. 527-533 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Enamulla et al.: "Synthesis, Characterization and Spin crossover behaviors of [Co(hydroxy corboxylate)(triphos)] complexes"Bull. Chem. Soc. Jpn.. 75. 2449-2453 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Paulovicova et sl.: "Synthesis and structural studies of diamagnetic first-row transition metal complexes with the rigid nitrogen ligand : bis[N-(2,6-diisopropylphenyl)imino]acenaththene"Inorg. Chim. Acta.. 339. 209-214 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Fukuda et al.: "New Chromotropic behavior of Manganese Complexes with 1,4,7-triazacyclononane-N,N',N"-tricarvoxylates"Inorg. Chim. Acta.. 339. 322-326 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Yamada, A.Honma: "N-Substituent effect on the cis-trans geometry of nine-membered lactams"J. Chem. Soc. Chem. Commun.. 2002. 2656-2657 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Fukuda et al.: "X-Ray crystal structure of bis(N-(2,6-diisopropylphehyl)imino] acenaphthene ligand and some studies including...."J. Coord. Chem.. (in press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] U.I.El-Ayaan et al.: "Structural studies of mixed ligand Cu(II) and Cu(I) Complexes with the rigid nitrogen ligand : Bis(N-(2,6-diiso...."J. Mol. Struc.. (in press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Myoshida, et al.: "Phase relation and molecular motions of mixed ligand complexes [Zn(hfac)2(tmen)] as studied by calorimetry and 1H-NMR measurement"Jphys. Chem. Solids. 60. 1787-1796 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] F. Renz, et al.: "Anisotropic effect after streching of the soin-crossover compound [Fe(II)(2,6-bis(bezirnidazol-2'-yl)pyridine)2](ClO4)2 in polyvinyl-alcohol polymer matrix"MoI. CrystXiq. Cryst.. 335. 531-540 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] F. Renz, et al.: "Spin-transition in [Fe(II)(2,6-bis(benzimidazoI-2'-yl)pyridine)2](ClO4)2 : Hysteresis effect dependent on the matrix"MoI. CrystXiq. Cryst.. 335. 521-530 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Gou, et al.: "Cyano-bridged dinuclear iron complexes in different oxidation states"Inorg. Chim. Acta. 287. 95-100 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Mariseki, et al.: "Template syntheses and properties of Cu(U)-lanthanid(III) complexes of phenol-based symmetric and unsymmetric dinuclear macrocycles"I. Coord. Chem.. 48. 1-13 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] APauIovicova, et al.: "Synthesis, characterization and X-ray crystal structures of two 5-coordinate ternary Cu(II) complexes containing acetylacetonate with 1,10-phenanthroline and 2,9-dimethylphenanthroline"Inore. Chim. Acta. 321. 56-62 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] U. El-Ayaan, et al.: "Thermochromism and solvatochromism in solution"Monath. Chem.. 132. 1279-1294 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Hasegawa, et al.: "Higher excited state fluorescence of mixed ligand lanthanide(III) complexes with acetylacetonate, nitrate and terpyridine"Chem. Phys.. 269. 323-337 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] W. Linert, et al.: "Chromotropism of coordination compounds in solution"Coord. Chem. Rev.. 218. 113-152 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Paubvicova. Et al.: "Mixed ligand Cu(II) complexes with the rigid bidentate bis(N-arylimino) acenaphthene ligand: Synthesis, spectroscopic, and X-ray structural characterization"Europ. J. Inorg. Chem.. 2001. 2641-2646 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Hasegawa, et al.: "Fluorescence spectra of Fe(II) spin-crossover complexes with 2,6-bis(benzimidazol-2'-yl) pyridine"Chem. Phys.. 227. 21-30 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kh. S. Abou-El-Sherbini, et al.: "Study on the complex formation between N-propylsalicylidene based on silica as ion exchange and some transition metalions"J. Sci. Islamic Rep. Iran.. 13. 217-223 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Fukuda, et al.: "Syntheses and specific structures of higher order mixed chelate lanthanide complexes containing terpyridine, acetylacetonate, and nitrate ligands"J. Chem. Soc. Dalton Trans.. 527-533 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Enamullah, et al.: "Synthesis characterization and spin-crossover behaviors of [Co(hydroxycarboxylato)(triphos)] complexes"Bull. Chem. Soc. Jan.. 75. 2449-2453 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Paulovicova, et al.: "Synthesis, and structural studies of diamagnetic first-raw transition metal complexes with the rigid nitrogen ligand: bis[N-(2,6-diisopropylhpenyl)imino]acenaphthene"Inore. Chim. Acta. 339. 209-214 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Fukuda, et al.: "New chromotropic behavior of manganese complexes with 1,4,7-triazacyclononane-N,N',N''-tricarboxylates"Inore. Chim. Acta. 339. 322-326 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Yamada, et al.: "N-Substituent effect on the cis-trans geometry of nine membered lactams"J. Chem. Soc. Chem. Commun.. 2656-2657 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Fukuda, et al.: "X-ray crystal structure of bis[N-(2,6-diisopropylphenyl)imino]acenaphthene ligand and some studies including its Cu(I) and Cu(II) complexes"J. Coord. Chem.. in press. (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] U. El-Ayaan, et al.: "Structural studies of mixed ligand copper(II) and copper(I) complexes with the rigid nitrogen ligand: bis[N-(2,6-diisopropylphenyl)iminol]acenaphthene"J. Mol. Struct.. in press. (2003)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2004-04-14  

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