2000 Fiscal Year Final Research Report Summary
Creation of multifunctional microchannels by coordination polymers
| Project/Area Number |
11304047
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| Research Category |
Grant-in-Aid for Scientific Research (A).
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | KYOTO UNIVERSITY |
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Principal Investigator |
KITAGAWA Susumu Kyoto University Graduate School of Engineering Professor, 工学研究科, 教授 (20140303)
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| Co-Investigator(Kenkyū-buntansha) |
KONDO Mitsuru Kyoto University Graduate School of Engineering Assis.t Professor, 工学研究科, 助手 (80254142)
MIZUTANI Tadashi Kyoto University Graduate School of Engineering Assoc. Professor, 工学研究科, 助教授 (40229696)
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| Project Period (FY) |
1999 – 2000
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| Keywords | coordination polymer / porous structure / microchannel / methane adsorption / ordered structure / gas storage |
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| Research Abstract |
The chemistry of microporous compounds have been studied extensively due to unique properties such as separation, adsorption, heterogeneous catalysis, and so on. Especially, creation of novel porous materials as adsorbents is a most attractive research field for the purpose of storage and transport of natural gas. A novel 3-D coordination polymer, [{[CuSiF6 (4,4'-bpy)2] 8H2O)}n](4,4'-bpy= 4,4'-bipyridine) was synthesized and characterized. This network provides channels with dimensions of ca 8 Å * 8 Å along the c-axis and ca 6 Å * 2 A along the a- and b-axes. The differential pore volume plot, represented by the HK method, shows only one sharp peak at ca 7.8 Å. The methane adsorption experiment was also carried out on zeolite 5A, which has the highest known methane adsorption capacity. XRPD measurement shows that the network is retained in the absence of any guest molecules in the channels.
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[Publications] H.Matsuzaka, T.Kamura, K.Ariga, Y.Watanabe, T.Okubo, T.Ishii, M.Yamashita, M.Kondo, S.Kitagawa: "Preparationn, Structure, and Reactivities of Amido-Bridged Dinuclear Rliodium (III) and Rhodium (II) Complexes""Organometallics.. 19. 216-218 (2000)
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