2000 Fiscal Year Annual Research Report

タンパク質繊維の高度のリサイクル化を意図した新加工法に関する研究

Research Project

Project/Area Number	11308003
Research Institution	Heian Jogakuin College
Principal Investigator	伊藤啓平安女学院短期大学, 生活学科, 教授 (20213077)
Co-Investigator(Kenkyū-buntansha)	金澤等福島大学, 教育学部, 教授 (50143128) 呑海信雄県立新潟女子短期大学, 生活学科, 教授 (90237181) 大崎茂芳奈良県立医科大学, 医学部, 教授 (90273911) 米田守宏奈良女子大学, 生活環境学部, 助教授 (20158538) 小原奈津子昭和女子大学, 生活科学部, 教授 (90178301)
Keywords	リサイクル化 / タンパク質繊維 / 繊維加工 / 絹繊維 / 羊毛繊維 / 可溶化法 / セリシン
Research Abstract	タンパク質繊維の高度のリサイクル化を最終目標として、タンパク質の可溶化物を用いてタンパク質繊維を加工する新技術開発を目的とした基礎的かつ応用的研究を行った。すなわち、廃棄タンパク質繊維(絹、羊毛)を原料として種々の機能材料(コーティング、ボンディング剤)を開発すること、及びこれを用いてタンパク質繊維集合体を加工し、タンパク質のみから成り立つ高品質の加工布や不織布を開発することを目的とした。本年度には代表者と分担者はそれぞれの研究領域からのアプローチを行い、絹、羊毛、蜘蛛の糸、合成ポリペプチドなどの領域で以下の成果を得た。人工飼料育蚕糸の構造、溶解性や力学的性質及び酸性染料による染色挙動を検討し、桑葉育のそれらとの明瞭な差異を見出した。サクシニル化羊毛の吸湿・吸収性を未処理羊毛と比較し、その改善を認めた。羊毛や絹の加工工程での構造変化と膨潤状態での構造解析法としてインヴァース液クロ法の有効性を見出した。蜘蛛の糸の力学的性質を調べ、安全工学的な巧妙さを見出すなどの新しい発見があり、また、タンパク質布帛の透湿性を高感度で評価する方法が開発された。具体的応用的な成果としては、スパンレース絹不織布を調製し、その細孔構造と製造条件との関係を調べている。また、人工飼料育繭糸のセリシンが熱水に易溶であることに着目し、これを用いて絹布の表面加工を行いその力学特性について検討し、本課題の実現性を確認した。また、本研究過程で超臨界水法による絹や羊毛の効率的可溶化の可能性を見出し、これに関しては次年度以降の基盤研究(申請中)でさらに発展させる予定である。

Research Products

(16 results)

All Other

All Publications (16 results)

[Publications] T.Baba,H.Ito,T.Miyamoto et al.: "An attempt to recover surface properties and handle of damaged wool"Proc.The 10th Int.Wool Textile Res.Conf.,Aachen. (in press).
[Publications] T.Baba,H.Ito,O.Yaida et al.: "Changes in covalently bound surface lipids layer of damaged wool fibers and its effect on surface"Textile Res.J.. (in press). (2001)
[Publications] T.Baba,H.Ito,O.Yaida et al.: "Recovery of surface properties of damaged wool fibers"Textile Res.J.. (in press).
[Publications] K.Murakami,H.Ito,M.Tosaka et al.: "Effect of silane coupling agent on natural rubber filled with silica generated in situ"Rubber Chemistry and Technology. (in press).
[Publications] Nakashima,H.Ito, et al.: "Biodegradation of High Strength and High Modulus PE-starch Composite Films Buried in Several Soils"J.Macromol.Sci.,Phys.. (in press).
[Publications] K.Yamamoto,S.Osaki et al.: "Crystallization and preliminary X-ray analysis of glicose dehydrogenase from Bacillus megaterium IWG3"Acta Crystallographica Section D. D56. 1433-1445 (2000)
[Publications] S.Osaki: "The Use of Hair Pores to Determine the Orientation of Collagen Fibers in Skin"The Anatomical Record. (in press).
[Publications] H.Sasaki,N.Donkai,H.Ito et al.: "Dyeing properties of silk produced by silkworms reared on artificial and mulberry leaf diets"J.Soc.Dyer Colourist. 116. 349-351 (2000)
[Publications] H.Sasaki,N.Donkai,H.Ito: "New approach to study a swollen wool structure"Proc.10th Wool Textile Res.,Conf.,Aachen. (in press). (2001)
[Publications] K.Kasahara,H.Sasaki,N.Donkai et al.: "Modification of Tencel with Treatment of Ferric Sodium Tartarate Comple Solution I. Effect of"Cellulose. (in press).
[Publications] N.Donkai,K.Kajiwara,T.Miyamoto et al.: "Structure of Various Band Textures in Shear-Deformed Hydroxypropylcellulose Films from its Lyotropic"Macromolecular Chemistry and Physics. (in press).
[Publications] K.Kasahara,H.Sasaki,N.Donkai et al.: "Dyeing properties of modified Tencel yarn with treatment of ferric sodium tartrate complex solution"J.Soc.Dyer Colourist. (in press).
[Publications] H.Kanazawa and N.Sato: "Adsorption of Volatile Organic Compounds on Proteins and Protein Models 1."Science Report,Fukushima Univ.. 64. 27-34 (2000)
[Publications] H.Kanazawa: "Structure of N-Carboxy-L-Phenylalanine Anhydride"Acta Crystallographica. 56. 469-470 (2000)
[Publications] N.Kohara,M.Kanei,T.Nakajima: "Succinylation of Chemically Modified Wool Keratin-Effect on Hygroscopicity and Water Absorption"Cellucon'99 Joint Meeting with ITIT International Symposium Proceedings Book. (in press).
[Publications] 大崎茂芳: "クモの糸のミステリー"中央公論新社. 186 (2000)

2000 Fiscal Year Annual Research Report

タンパク質繊維の高度のリサイクル化を意図した新加工法に関する研究

Principal Investigator

伊藤 啓 平安女学院短期大学, 生活学科, 教授 (20213077)

Research Products

[Publications] T.Baba,H.Ito,T.Miyamoto et al.: "An attempt to recover surface properties and handle of damaged wool"Proc.The 10th Int.Wool Textile Res.Conf.,Aachen. (in press).

[Publications] T.Baba,H.Ito,O.Yaida et al.: "Changes in covalently bound surface lipids layer of damaged wool fibers and its effect on surface"Textile Res.J.. (in press). (2001)

[Publications] T.Baba,H.Ito,O.Yaida et al.: "Recovery of surface properties of damaged wool fibers"Textile Res.J.. (in press).

[Publications] K.Murakami,H.Ito,M.Tosaka et al.: "Effect of silane coupling agent on natural rubber filled with silica generated in situ"Rubber Chemistry and Technology. (in press).

[Publications] Nakashima,H.Ito, et al.: "Biodegradation of High Strength and High Modulus PE-starch Composite Films Buried in Several Soils"J.Macromol.Sci.,Phys.. (in press).

[Publications] K.Yamamoto,S.Osaki et al.: "Crystallization and preliminary X-ray analysis of glicose dehydrogenase from Bacillus megaterium IWG3"Acta Crystallographica Section D. D56. 1433-1445 (2000)

[Publications] S.Osaki: "The Use of Hair Pores to Determine the Orientation of Collagen Fibers in Skin"The Anatomical Record. (in press).

[Publications] H.Sasaki,N.Donkai,H.Ito et al.: "Dyeing properties of silk produced by silkworms reared on artificial and mulberry leaf diets"J.Soc.Dyer Colourist. 116. 349-351 (2000)

[Publications] H.Sasaki,N.Donkai,H.Ito: "New approach to study a swollen wool structure"Proc.10th Wool Textile Res.,Conf.,Aachen. (in press). (2001)

[Publications] K.Kasahara,H.Sasaki,N.Donkai et al.: "Modification of Tencel with Treatment of Ferric Sodium Tartarate Comple Solution I. Effect of"Cellulose. (in press).

[Publications] N.Donkai,K.Kajiwara,T.Miyamoto et al.: "Structure of Various Band Textures in Shear-Deformed Hydroxypropylcellulose Films from its Lyotropic"Macromolecular Chemistry and Physics. (in press).

[Publications] K.Kasahara,H.Sasaki,N.Donkai et al.: "Dyeing properties of modified Tencel yarn with treatment of ferric sodium tartrate complex solution"J.Soc.Dyer Colourist. (in press).

[Publications] H.Kanazawa and N.Sato: "Adsorption of Volatile Organic Compounds on Proteins and Protein Models 1."Science Report,Fukushima Univ.. 64. 27-34 (2000)

[Publications] H.Kanazawa: "Structure of N-Carboxy-L-Phenylalanine Anhydride"Acta Crystallographica. 56. 469-470 (2000)

[Publications] N.Kohara,M.Kanei,T.Nakajima: "Succinylation of Chemically Modified Wool Keratin-Effect on Hygroscopicity and Water Absorption"Cellucon'99 Joint Meeting with ITIT International Symposium Proceedings Book. (in press).

[Publications] 大崎茂芳: "クモの糸のミステリー"中央公論新社. 186 (2000)

伊藤啓平安女学院短期大学, 生活学科, 教授 (20213077)