• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2002 Fiscal Year Final Research Report Summary

A creation of cryogenic electron emission microscope and the applications to solid surfaces.

Research Project

Project/Area Number 11354003
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 固体物性Ⅰ(光物性・半導体・誘電体)
Research InstitutionThe University of Tokyo

Principal Investigator

MASUDA Shigeru  The University of Tokyo, Graduate School of Arts and Sciences, Associate professor, 大学院・総合文化研究科, 助教授 (50173745)

Co-Investigator(Kenkyū-buntansha) SAKAI Yuji  JEOL Ltd., Electron Optics Division, Group leader, 電子光学機器技術本部, グループ長(研究職)
AOKI Masaru  The University of Tokyo, Graduate School of Arts and Sciences, Research associate, 大学院・総合文化研究科, 助手 (50302823)
Project Period (FY) 1999 – 2002
Keywordselectron emission microscope / electron spectroscopy / electronic state / metastable atom / solid surface
Research Abstract

A new electron emission microscope using photons, low-energy electrons, and metastable atoms as an excitation source has been developed to study spatiotemporal phenomena occurring at a solid surface. The metastable atoms such as He*(2^3S) were produced by cold-discharge and the beam intensity was attained to 〜10^16 He(2^3S) atoms s^<-1> sr^<-1>. The electrostatic and magnetic lens systems were designed at our laboratory for the low-energy electron gun and electron emission microscope based on a computer simulation program. The spatial resolution of the microscope thus constructed is 100 nm at present and will be improved by beam adjustment. We also developed a sample cooling system from some K to 1000 K to observe images of samples held at low temperature. Further we have observed PEEM images of stoichiometric NiO and chemisorbed oxygen during heating of the oxygen-exposed Ni(100), indicating that the desorption of the oxide layer proceeds inhomogeneously in space.

  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] A.Abdureyim et al.: "Observation of outermost surface layer of 4-mercaptohydrocynnamic acid self-assembled film on Au(111) by Penning ionization electron spectroscopy"Applied Surface Science. 144-145. 430-434 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Masuda et al.: "Local electron distribution of N_2 adsorbed on a Ni(111) surface probed by metastable impact electron spectroscopy"Journal of Chemical Physics. 113. 3864-3867 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Masuda et al.: "Spatial electron distribution of CO adsorbed on Ni(100) and Ni(111) surfaces probed by metastable impact electron spectroscopy"Journal of Chemical Physics. 114. 8546-8554 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Aoki et al.: "Local electronic states of oxygen on a Ni(111) surface Studied by metastable atom electron spectroscopy"Journal of Electron Spectroscopy and Related Phenomena. 114-116. 507-512 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Abdureyim et al.: "Characterization of 4-mercaptohydrocynnamic acid self-assembled film on Au(111) by means of X-ray photoelectron spectroscopy"Journal of Electron Spectroscopy and Related Phenomena. 114-116. 371-374 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 増田 茂 他: "メタステーブル原子電子分光によるNi(100),Ni(111)上CO分子の局所電子分布"表面科学. 22. 443-448 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Hino et al.: "Ultraviolet photoelectron spectra of metallofullerenes, two Ca@C82 isomers"Chemical Physics Letters. 337. 65-71 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Suzuki et al.: "Local electronic states in the topmost surface layer probed by metastable atom electron spectroscopy : N_2 adsorbed and condensed on Ni(111)"Physical Review B. 65. 035416 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Mutoh, S.Masuda: "Spatial distribution of valence electrons in metallocenes studied by Penning ionization electron spectroscopy"Journal of the Chemical Society. Dalton Transactions. 1875-1881 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Aoki et al.: "Interactions of CHCl_3 molecules with a crystalline ice grown on Pt(111) studied by metastable impact electron spectroscopy"Surface Science. (in press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 増田 茂: "準安定原子電子分光(新訂版・表面科学の基礎と応用,岩澤康裕編)"エヌ・ティー・エス社(出版予定). (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Abdureyim, S.Kera, H.Setoyama, K.K.Okudaira, R.Suzuki, S.Masuda, N.Ueno, Y.Harada: "Observation of outemost surface layer of 4-mercaptohydrocynnamic acid self-assembled film on Au(111)by Penning iorizaion electron spectroscopy"Applied Surface Science. 144-145. 430-434 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Masuda, R.Suzuki, M.Aoki: "Local electron distribution of N_2 absorbed on a Ni(111) surface probed by metastable impact electron spectroscopy"Journal of Chemical Physics. 113. 3864-3867 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Masuda, R.Suzuki, M.Aoki Y.Morikawa, R.Kishi, M.Kawai: "Spatial electron distribution of CO absorbed on Ni(100)and Ni(111) surfaces probed by metastable impact electron spectroscopy"Journal of Chemical Physics. 114. 8546-8554 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Aoki, H.Taoka, T.Kamada, S.Masuda: "Lodal electronic states of oxygan on a Ni(111) surface studied by metastable atom electron spectroscopy"Journal of Electron Spectroscopy and Related Phenomena. 114-116. 507-512 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A.Abduain, KK. Okudaira Y.Harada, S.Masuda, M.Aoki, K.Seki, E.Ito, N.Ueno: "Characterization of 4-mercaptohydrocymamic acid self-assembled film on Au(111) by means of X-ray photoelectron spectroscopy"Journal of Electron Spectroscopy and Related Phenomena. 114-116. 371-374 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Masuda, R.Suzuki, M.Aoki, Y.Morikawa, R.Kishi, M.Kawai: "Local electron distribution of CO absorbed on Ni(100) and Ni(111) surfaces studied by metastable atom electron spectroscopy(in Japanese)"Journal of The Surface Science Society of Japan. 22. 443-448 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Hino, K.Umishita, K.Iwasaki, M.Aoki, K.Kobayashi, S.Nagase T.J.S.Denis, T.Nakane, H.Shinohara: "Ultraviolet photoelectron spectra of metallofullerenes, two Ca@C82 isomers"Chemical Physics Letters. 337. 65-71 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Suzuki, H.Taoka, M.Aoki, S.Masuda, Y.Morikawa: "Local electronic states in the topmost surface layer probed by metastable atom electron spectroscopy, N_2 absorbed and condensed on Ni(111)"Physical Review B. 65. 035416 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Mutoh, S.Masuda: "Spatial distribution of valence electrons in metallocenes studied by penning ionization electron spectroscopy"Journal of the Chemical Society. Dalton Transaction. 1875-1881 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Aoki, Y.Ohashi, S.Masuda: "Interactions of CHCl_3 molecules with a crystalline ice grown on Pt(111) studied by metastable impact electron spectroscopy"Surface Science. in press. (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Masuda , edited by Y.Iwasawa: "Metastable atom electron spectroscopy(in Japanese) , Basics and Applications Surface Science"NTS(in press). (2003)

    • Description
      「研究成果報告書概要(欧文)」より

URL: 

Published: 2004-04-14  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi