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2001 Fiscal Year Final Research Report Summary

Development of Observation System for Characterization in Supercritical Carbon Dioxide

Research Project

Project/Area Number 11354009
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 分離・精製・検出法
Research InstitutionNagoya University

Principal Investigator

FUNAHASHI Shigenobu  Nagoya University, Graduate School of Science, Professor, 大学院・理学研究科, 教授 (30022700)

Co-Investigator(Kenkyū-buntansha) NAGAMURA Toshihiko  Unisoku Co. Ltd.,Institute for Scientific Instruments, Chief Researcher, 科学機器開発研究所, 主任研究員
INADA Yasuhiro  Nagoya University, Research Center for Materials Science, Research Associate, 物質科学国際研究センター, 助手 (60242814)
Project Period (FY) 1999 – 2001
KeywordsSupercritical Carbon Dioxide / Characterization / Kinetic Analysis / Cosolvent / UV-vis spectroscopy / IR spectroscopy / NMR spectroscopy / Supercritical Extraction
Research Abstract

The purpose of this study was to develop some instruments to characterize the metal complexes in supercritical carbon dioxide (scCO_2) and to clarify the microscopic interactions around the metal complexes in scCO_2.
We developed some spectroscopic cells to measure the UV-vis, IR, NMR, and high-frequency resonance spectra in scCO_2, and a circulation pump to connect the observation cells and to circulate the scCO_2 solution. We also developed the stopped-flow instrument to monitor the fast reactions, which are initiated by the rapid mixing of two scCO_2 solutions of reactants under a constant temperature and pressure. Furthermore, we developed the two-phase distribution cell for the UV-vis absorption measurements. Owing to the developments of these instruments, it becomes to be possible to measure the spectral change as a function of the concentration of species in addition to the temperature and pressure.
By using these instruments, (1) the solubility of porphyrins and metal complexes, … More (2) the metalation rate of porphyrin with bis(β-diketonato)metal(II) complexes (metal = Cu, Ni, and Co), and (3) the complexation and ligand substitution equilibria of the tris(β-diketonato)gadolinium(III) complex with the aromatic amine ligand were investigated in scCO_2 at a variety of temperatures and pressures. Furthermore, under the conditions containing the cosolvent, such as alcohols, water, acetonitrile, and tributyl phosphate (TBP), the reaction rates and the equilibrium constants were systematically determined in order to clarify microscopically the effect of cosolvent. For the metalation reactions of porphyrin, the existence of the cluster shell of cosolvents in the vicinity of solutes and the stabilization of the partial charges generated during the activation process due to the cluster shell are suggested. In the case of the system (3), the equilibrium constants of the ligand substitution reactions were decided in scCO_2, and the Gd(III) species concerning the supercritical extraction were characterized for the scCO_2/water and scCO_2/TBP extraction systems. Less

  • Research Products

    (76 results)

All Other

All Publications (76 results)

  • [Publications] Y.Tsutsui, H.Wasada, S.Funahashi: "Reaction Mechanism of Water Exchange on Di-and Trivalent Cations of the First Transition Series and Structural Stability of Seven-Coordinate Species"Journal of Molecular Structure (Theochem). 461-462. 379-390 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Koshino, Y.Kuchiyama.S.Funahashi, H.D.Takagi: "Free Energy Barrier of Gated Electron Transfer Reactions : Reduction and Oxidation Reactions of Cu(6, 6'-dimethyl-2, 2'-bipyridine)_2^<2+/+> with Ru(hexafluoroacetylace-tone)_3^<0/->"Chemical Physics Letters. 306. 291-296 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Inada, H.Hayashi, K.Sugimoto, S.Funahashi: "Solvation Structures of Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), and Ga(III) Ions in Methanol, Ethanol, Dimerhyl Sulfoxide, and Trimethylphosphate As Studied by EXAFS and Elecironic Spectroscopies"The Journal of Physical Chemistry A. 103. 1401-1406 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Koshino, Y.Kuchiyama, H.Ozaki, S.Funahashi, H.D.Takagi: "An Interpretation of Gated Behavior : Kinetic Studies of the Oxidation and Reduction Reactions of Bis(2, 9-dimethyl-1-1,1O-phenanthroline)copper(I/II) in Acetonitrile"Inorganic Chemistry. 38. 3352-3360 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Inada, Y.Tsutsui, H.Wasada, S.Funahashi: "Solvation Structure of Copper(I) Ion in Nonaqueous Solvents As Studied by EXAFS and ab Initio Molecular Orbital Methods"Zeitschrift fur Naturforschung. 54B. 193-199 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Matsumoto, S.Funahashi, H.D.Takai: "Electrochemical Electron Transfer Reactions of M(ttcn)_2^<3+/2+> (M=Co, Pd, Pt, Au ; ttcn =1, 4, 7-trithiacyclononane) : The Relation of Reaction Volumes and Electron Transfer Rate Constants"Zeitschrift fur Naturforschung. 54B. 1138-1146 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Koshino, Y.Kuchiyama, S.Funahashi, H.D.Takagi: "Electron Self-Exchange, Oxidation, and Reduction Reactions of Bis(2, 9-dimehyl-4, 7-diphenyl-1, 1O-phenanthroline)copper(II/I) and Bis(6, 6'-dimethyl-2, 2-bipyridine)copper(II/I) Couples in Acetonitrile : Gated ET for the Reduction, Oxidation, and Self-Exchange Processes"Canadian Journal of Chemistry. 77. 1498-1507 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Inada, S.Funahashi: "Equilibrium and Structural Study of Chloro Complexes of Iron(III) Ion in Acidic Aqueous Solution by Means of X-Ray Absorption Spectroscopy"Zeitschrift fur Naturforschung. 54B. 1517-1523 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Marsumoto, M.Itoh, S.Funahashi, H.D.Takagi: "Electron Transfer Reactions of Bis(1, 4, 7-trithiacyclononane)palladium(III/II), -platinum(III/II), and -gold(III/II) Complexes in Aqueous Solution and in Acetonitrile"Canadian Journal of Chemistry. 77. 1638-1647 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.D.Takagi, A.Takahashi, S.Iwatsuki, H.Hayashi, S.Funahashi, K.Ogiyama: "An Investigation of the Photodegradation of Tetraphenyltin(IV) in THF"Phosphorus, Sulfur and Silicon. 150-151. 245-250 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Yoshida, M.Itoh, N.Yamamoto, T.Nagamura, M.Oyama, S.Okazaki: "Dynamic Observation of Reaction Processes of Pd with Si on Si(111) Surface after Thermal Treatment by Using UHV-STM"Langmuir. 15. 6813-6820 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 舟橋重信: "金属イオンの動的キャラクタリゼーションと錯形成反応速度"分析化学. 48. 3-20 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Kanekiyo, S.Aizawa, N.Koshino, S.Funahashi: "Complexation Equilibria of Oxy-acid -Amino-2-deoxy-D-gluconic Acid-Metal(II) Ion Ternary Systems in Aqueous Solution As Studied by Potentiometry. Binding Characteristics of Borate and Germanate"Inorganica Chimica Acta. 298. 154-164 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Matsumoto, H.Kodama, S.Funahashi, H.D.Takagi: "Reduction and Oxidation Reactions of Tetrakis(acetylacetonato)cerium(IV) and -(III) Complexes in Acetonitrile : Change in the Reaction Pathways with the Driving Force of the Reaction"Inorganic Reaction Mechanism. 2. 19-31 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Koshino, S.Itoh, Y.Kuchiyama, H.D.Takagi, S.Funahashi: "Outer-Sphere Electron Transfer Reactions of Bis(2,9-R_2-1, 10-phenanthroline)copper(II/I) in Acetonitrile : R = methyl or phenyl"Inorganic Reaction Mechanism. 2. 93-99 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Inada, Y.Itoh, H.Kuwabara, S.Funahashi: "Mechanistic Studies on Solvent Exchange of Tetrahedrally Solvated Cobalt(II) Ion in 1, 1, 3, 3-Tetramethylurea as a Bulky Solvent"Inorganic Reaction Mechanism. 2. 161-168 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Inada, T.Yamaguchi, H.Satoh, S.Funahashi: "Mechanistic Studies of Deprotonation for Sitting-Atop Complex of Copper(II) Ion with 5, 10, 15, 20-Tetraphenylporphyrin in Acetonitrile Relevant to Porphyrin Metalation Mechanism"Inorganic Reaction Mechanism. 2. 277-288 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Yamaguchi, T.Shido, Y.Inada, T.Kogure, K.Asakura, M.Nomura, Y.Iwasawa: "Time-Resolved DXAFS Study on the Reduction Processes of Cu Cations in ZSM-5"Catalysis Letters. 68. 139-145 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Inada, Y.Nakano, M.Inamo, M.Nomura, S.Funahashi: "Structural Characterization and Formation Mechanism of Sitting-Atop (SAT) Complex of 5, 10, 15, 20-Tetraphenylporphyrin with Divalent Metal Ions. Structure of the Cu(II)-SAT Complex as Determined by Fluorescent Extended X-ray Absorption Fine Structure"Inorganic Chemistry. 39. 4793-4801 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Iwatsuki, H.Kato, K.Obeyama, S.Funahashi, N.Koshino, K.Kashiwabara, T.Suzuki, H.D.Takagi: "Cobalt(II) Phosphine Complexes Stable in Aqueous Solution : Spectroscopic and Kinetic Evidence or Low-Spin Co(II)P_6 and Co(II)P_3S_3 with Tripodal 1, 1, 1-Tris(dime-thylphosphinomethyl)ethane"Inorganic Chemistry Communication. 3. 501-504 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 山口有朋, 紫藤貴文, 稲田康宏, 朝倉清高, 野村昌治, 岩澤康裕: "Time-Resolved DXAFS Study on the Reduction Processes of Cu Cations in ZSM-5"触媒. 42. 419-421 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 稲田康宏: "時間分解ストップトフロー広域X線吸収端微細構造法による不安定短寿命中間体の局所構造解析"分析化学. 49. 563-573 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Inada, N.Hotta, H.Kuwabara, S.Funahashi: "Spectrophotometric Analysis of 5-Coordinate Cobalt(II) Species for Ligand Substitution of Hexakis(acetonitrile)cobalt(II) with Bulky 1, 1, 3, 3-Tetramethylurea in Noncoordinating Nitromethane"Analytical Sciences. 17. 187-191 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Itoh, S.Funahashi, H.D.Takagi: "Redox Behavior of Dimeric Bis(1, 2-bis(9-methy1-1, 1O-phenanthrolin-2-yl)ethane) dicopper(I)/monomeric(1, 2-bis(9-methyl-1,10-phenanthrolin-2-yl)ethane)copper Couple : Detection of a Metastable Dimeric Cu(II)"Chemical Physics Letters. 344. 441-449 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Shido, A.Yamaguchi, A.Suzuki, Y.Inada, K.Asakura, M.Nomura, Y.Iwasawa: "DXAFS Study on the Decarbonylation Process of Mo(CO)_6 in NaY Supercages"Journal of Synchrotron Radiation. 8. 628-630 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Yamaguchi, Y.Inada, T.Shido, K.Asakura, M.Nomura, Y.Iwasawa: "Time-Resolved Energy-Dispersive XAFS Study on the Reduction Process of Cu-ZSM-5 Catalysts"Journal of Synchrotron Radiation. 8. 654-656 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Yamaguchi, A.Suzuki, T.Shido, Y.Inada K.Asakura, M.Nomura, Y.Iwasawa: "Energy-Dispersive XAFS Study on the Decarbonylation Processes of Mo(CO)_6 in NaY Zeolite"Catalysis Letters. 71. 203-208 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Yamaguchi, T.Shido, Y.Inada, T.Kogure, K.Asakura, M.Nomura, Y.Iwasawa: "In-Situ Time-Resolved Energy-Dispersive XAFS Study on the Reduction Processes of Cu-ZSM-5 Catalysts"Bulletin of the Chemical Society of Japan. 74. 801-808 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Sato, Y.Inada, T.Nagamura, S.Funahashi: "Newly Devised Spectrophotometric Cell for Measurements of Solubility and Slow Reaction Rate in Supercritical Carbon Dioxide"The Journal of Supercritical Fluids. 21. 71-80 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Inada, H.Sato, T.Horita, T.Nagamura, S.Funahashi: "Development of Stopped-Flow Instrument with Spectrophotometric Detection for study of Fast Reactions in Supercritical Supercritical Carbon Dioxide ; Kinetics of Metalloporphyrin Formation in Supercritical Carbon Dioxide"The Journal of Supercritical Fluids. 21. 205-217 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] E.Ohmichi, T.Ishiguro, T.Nagamura: "Piezoelectrically Driven Rotator for Use High Magnetic Field at Low Temperatures"Review of Scientific Instruments. 72. 1914-1917 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Funahashi, Y.Inada, M.Inamo: "Dynamic Study on Metal-ion Incorporation into Porphyrins on the Basis fo Dynamic Characterization of Metal Ions and Sitting-Atop Comdex Formation"Analytical Sciences. 17. 917-927 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Inamo, N.Kamiya, Y.Inada, M.Nomura, S.Funahashi: "Structural Chardclerization and Formation Kinetics of Sitting-Atop (SAT) Complexes of Some Porphyrins with Copper(II) Ion in Aqueous Acetonitrile Relevant to Porphyrin Metalation Mechanism. Structures of Aquacopper(II) and Cu(II)-SAT Complexes As Determined by XAFS Spectroscopy"Inorganic Chemistry. 40. 5636-5644 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Itoh, S.Funahashi, N.Koshino, H.D.Takagi: "Electron Transfer Reactions of Copper(II)/(I) Couples with Bidentate and Quadridentate Polypyridine Ligands : is Gated Behavior Common among Outer-sphere Electron Transfer Reactions ?"Inorganica Chimica Acta. 324. 252-265 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Iwatsuki, K.Obeyama, N.Koshino, S.Funahashi, K.Kashiwabara, T.Suzuki, H.D.Takagi: "New Low-spin Co(II) Complexes with Novel Tripdal 1, 1, 1-Tris(dimethylphosphinomethyl)ethane Ligand : Electron Transfer Kinetics and Spectroscopic Characterization of Co(II)P6 and Co(II)P_3S_3Ions in Aqueous solution"Canadian Journal of Chemistry. 79. 1344-1351 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Aizawa, T.Iida, Y.Sone, T.Kawamoto, S.Funahashi, S.Yamada, M.Nakamura: "Thiolato-Ligand Substitution Reaction with Halide Ions of Five-Coordinate Trigonal-Bipyramidal Palladium(II) Complexes with Tris(2-(diphenylphosphino)ethyl)phosphine. Electronic and Steric Effects on the Reaction Mechanismand Steric Effects on the Reaction Mechanism"Bulletin of the Chemical Society of Japan. 75. 91-97 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Sato, Y.Inada, T.Horita, S.Funahashi: "Kinetics of Metalloporphyrin Formation in Supercritical Carbon Dioxide. Development of a Stopped-Flow Instrument for Study of Fast Reactions and a Spectrophotometric Cell for Measurement of Slow Reaction Rates"The Journal of Physics : Condensed Matter. (in press). (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 舟橋重信 (分担): "大学院錯体化学"講談社サイエンティフィク. 6 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 舟橋重信, 稲田康宏 (分担): "分析化学便覧 (改訂5版)"丸善. 11 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y. Tsutsui, H.Wasada, and S. Funahashi: "Reaction Mechanism of Water Exchange on Di- and Trivalent Cations of the First Transition Series and Structural Stability of Seven-Coordinate Species"J. Mol. Struct. (THEOCHEM). 461-462. 379-390 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Koshino, Y. Kuchiyama. S. Funahashi, and H. D.Takagi: "Free Energy Barrier of Gated Electron Transfer Reactions : Reduction and Oxidation Reactions of Cu(6,6'-dimethyl-2,2'-bipyridine)_2^<2+/+> with Ru(hexafluoroacetylace-tone)_3^<0/->"Chem. Phys. Lett.. 306(5-6). 291-296 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Inada, H. Hayashi, K. Sugimoto, andS.Funahashi: "Solvation Structures of Mn(II), Fe(II), Co(II), Ni(II), Cu(II)r Zn(II), and Ga(III) Ions in Methanol, Ethanol, Dimethyl Sulfoxide, and Trimethylphosphate As Studied by EXAFS and Electronic Spectroscopies"J. Phys. Chem. A.. 103(10). 1401-1406 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Koshino, Y. Kuchiyama, H. Ozaki, S. Funahashi, and H. D. Takagi: "An Interpretation of Gated Behavior: Kinetic Studies of the Oxidation and Reduction Reactions of Bis(2,9-dimethyl-1,10-chenanthroline)copper(I/II) in Acetonitnle"Inorg. Chem.. 38(14). 3352-3360 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Inada, Y. Tsutsui, H. Wasada, and S. Funahashi: "Solvation Structure of Copper(I) Ion in Nonaqueous Solvents As Studied by EXAFS and ab Initio Molecular Orbital Methods"Z. Naturforsch. 54B(2). 193-199 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Matsumoto, S. Funahashi, and H. D. Takagi: "Electrochemical Electron Transfer Reactions of M(ttcn)_2^<3+/2+> (M = Co, Pd, Pt,.M-R(9)J\ 38-1 146/1 999 Au ; ttcn = 1,4,7-trithiacyclononane) : The Relation of Reaction Volumes and Electron Transfer Rate Constants"Z. Naturforsch. 54B(9). 1138-1146 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Koshino, Y. Kuchiyama, S. Funahashi, and H. D. Takagi: "Electron Self-Exchange, Oxidation, and Reduction Reactions of Bis(2,9-dimethyl-4,7-diphenyl- 1,10-phenanthroline)copper(II/I) and Bis(6,6'-dimethyl-2,2'-bipyridine)copper(II/I) Couples in Acetonitrile : Gated ET for the Reduction. Oxidation, and Self-Exchange Processes"Can. J. Chem.. 77(9). 1498-1507 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Inada and S. Funahashi: "Equilibrium and Structural Study of Chloro Complexes of Iron(III) Ion in Acidic Aaueous Solution by Means of X-Ray Absorption Spectroscopy"Z. Naturforsch.. 54B(12). 1517-1523 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Matsumoto, M. Itoh, S. Funahashi, and H. D. Takagi: "Electron Transfer Reactions of Bis(l,4,7-trithiacyclononane)palladium(III/II), -platinum(III/II), and -gold(III/II) Complexes in Aqueous Solution and in Acetonitrile"Can. J. Chem.. 77(10). 1638-1647 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. D. Takagi, A. Takahashi, S. Iwatsuki, H. Hayashi, S. Funahashi, and K. Ogiyama: "An Investigation of the Photodegradation of Tetraphenyltin(IV) in THF"Phosphorus, Sulfur and Silicon. 150-151. 245-250 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Yoshida, M. Itoh, N. Yamamoto, T. Nagamura, M. Oyama, and S. Okazaki: "Dynamic Observation of Reaction Processes of Pd with Si on Si(111) Surface after Thermal Treatment bv Using UHV-STM"Langmuir. 15(20). 6813-6820 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Funahashi: "Dvnamic Characterization of Metal Ions and Their Complexation Rates"Bunsekikagaku. 48(1). 3-20 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Kanekiyo, S. Aizawa, N. Koshino, and S. Funahashi: "Complexation Equilibria of Oxy-acid -Amino-2-deOxy-D-gluconic Acid-Metal(II) Ion Ternary Systems in Aqueous Solution As Studied by Potentiometry. Binding Characteristics of Borate and Germanate"Inorg. Chim. Acta.. 298(2). 154-164 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Matsumoto, H. Kodama, S. Funahashi, and H. D. Takagi: "Reduction and Oxidation Reactions of Tetrakis(acetylaceronato)cerium(IV) and -(III) Complexes in Acetonitrile: Change in the Reaction Pathways with the Drivine Force of the Reaction"Inorg. React. Mech.. 2(1-2). 19-31 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Koshino, S. Itoh, Y. Kuchiyama, H. D.Takagi, and S. Funahashi: "Outer-Sphere Electron Transfer Reactions of Bis(2,9-R_2-1,10-henanthroline)copper(II/I) in Acetonitrile : R = methyl or phenyl"Inorg. React. Mech.. 2(1-2). 93-99 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Inada, Y. Itoh, H. Kuwabara, and S.Funahashi: "Mechanistic Studies on Solvent Exchange of Tetrahedrally Solvated Cobalt(II) Ion in 1 ,1,3,3-Tetramethylurea as a Bulky Solvent"Inorg. React. Mech.. 2(3). 161-168 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Inada,T. Yamaguchi, H. Satoh, and S. Funahashi: "Mechanistic Studies of Deprotonation for Sitting-Atop Complex of Copper(II) Ion with 5, 10,15,20-Tetraphenylporphyrin in Acetonitrile Relevant to Porphvrin Metalation Mechanism"Inorg. React. Mech.. 2(4). 277-288 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Yamaguchi, T. Shido, Y. Inada, T. Kogure, K. Asakura, M. Nomura, and Y. Iwasawa: "Time-Resolved DXAFS Study on the Reduction Processes of Cu Cations in ZSM-5"Catal. Lett.. 68. 139-145 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Inada, Y. Nakano, M. Inamo, M. Nomura, and S. Funahashi: "Structural Characterization and Formation Mechanism of Sitting-Atop (SAT) Complexes of 5,10,15,20-Tetraphenylporphyrin with Divalent Metal Ions. Structure of the Cu(II)-SAT Complex as Determined by Fluorescent Extended X-ray Absorption Fine Structure"Inorg. Chem.. 39(21). 4793-4801 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Iwatsuki, H. Kato, K. Obeyama, S. Funahashi, N. Koshino, K. Kashiwabara, T. Suzuki, and H. D. Takagi: "Cobalt(II) Phosphine Complexes Stable in Aqueous Solution : Spectroscopic and Kinetic Evidence for Low-Spin Co(II)P_6 and Co(II)P_3S_3 with Tripodal 1,1,1-Tris(dime-thylphosphinomethyl)ethane"Inorg. Chem. Commun.. 3(10). 501-504 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Yamaguchi, T. Shido, Y. Inada, T. Kogure, K. Asakura, M. Nomura, and Y. Iwasawa: "Time-resolved DXAFS Study on the Reduction Processes of Cu Cations in ZSM -5"Shokubai. 42. 419-421 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Inada: "Local Structure Analysis of Short-lived Reaction Intermediates by Means of a Time-resolved Stoped-flow Extended X-ray Absorption Fine-structure Technique"Bunsekikagaku. 49. 563-573 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Inada, N. Hotta, H. Kuwabara, and S. Funahashi: "Spectrophotometric Analysis of 5-Coordinate Cobalt(II) Species for Ligand substitution of Hexakis(acetonitrile)cobalt(II) with Bulky 1,1,3,3-Tetramethylurea in Noncoordinating Nitromethane"Anal. Sci.. 17(1). 187-191 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Itoh, S. Funahashi, and H. D.Takagi: "Redox Behavior of Dimeric Bis(1,2-bis(9-methyl-1,10-phenanthrolin-2-yl)ethane)di-copper(I)/monomeric( 1,2-bis(9-methyl-1,10-phenanthrolin-2yl)ethane)copper Couple : Detection of a Metastable Dimeric Cu(II)"Chem. Phys. Lett.. 344(5-6). 441-449 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Shido, A. Yamaguchi, A. Suzuki, Y. Inada, K. Asakura, M. Nomura, and Y. Iwasawa: "DXAFS Study on the Decarbonylation Process of Mo(CO)_6 in NaY Supercages"J. Synchrotron Rad.. 8(2). 628-630 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Yamaguchi, Y. Inada, T. Shido, K. Asakura, M. Nomura, and Y. Iwasawa: "Time-Resolved Energy-Dispersive XAFS Study on the Reduction Process of Cu-ZSM-5 Catalysts"J. Synchrotron Rad.. 8(2). 654-656 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Yamaguchi, A. Suzuki, T. Shido, Y. Inada, K. Asakura, M. Nomura, and Y. Iwasawa: "Energy-Dispersive XAFS Study on the Decarbonylation Processes of Mo(CO)_6 in NaY Zeolite"Catal. Lett.. 71(3-4). 203-208 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Yamaguchi, T. Shido, Y. Inada, T. Kogure, K. Asakura, M. Nomura, and Y. Iwasawa: "In-Situ Tirrie-Resolved Energy-Dispersive XAFS Study on the Reduction Processes of Cu-ZSM-5 Catalysts"Bull. Chem. Soc. Jpn.. 74(5). 801-808 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Sato, Y. Inada,T. Nagamura, and S. Funahashi: "Newly Devised Spectrophotometric Cell for Measurements of Solubility and Slow Reaction Rate in Supercritical Carbon Dioxide"J. Supercrit. Fluids.. 21(1). 71-80 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Inada, H. Sato, T. Horita. T. Nagamura, and S. Funahashi: "Development of Stopped-Flow Instrument with Spectrophotometric Detection for the Study of Fast Reactions in Supercritical Carbon Dioxide ; Kinetics of Metalloporphyrin Formation in Supercritical Carbon Dioxide"J. Supercrit. Fluids. 21(3). 205-217 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] E. Ohmichi, T. Ishiguro, T. Nagamura: "Piezoelectrically Driven Rotator for Use High Magnetic Field at Low Temperatures"Rev. Sci. Instrum.. 72(3). 1914-1917 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Funahashi, Y. Inada, and M. Inamo: "Dynamic Study on Metal-ion Incorporation into Porphyrins on the Basis of Dynamic Characterization of Metal ions and Sitting-Atop Complex Formation"Anal. Sci.. 17(8). 917-927 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Inamo, N. Kamiya, Y. Inada, M. Nomura, and S. Funahashi: "Structural Characterization and Formation Kinetics of Sitting-Atop (SAT) Complexes of Some Porphyrins with Copper(II) Ion in Aqueous Acetonitrile Relevant to Porphyrin Metalation Mechanism. Structures of Aquacopper(II) and Cu(II)-SAT Complexes As Determined by XAFS Spectroscopy"Inorg. Chem.. 40(22). 5636-5644 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Itoh, S. Funahashi, N. Koshino, and H. D. Takagi: "Electron Transfer Reactions of Copper(II)/(I) Couples with Bidentate and Quadridentate Polypyridine Ligands : Is Gated Behavior Common Among Quler-phere Electron Transfer Reactions?"Inorg. Chim. Acta.. 324(1-2). 252-265 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Iwatsuki, K. Obeyama, N. Koshino, S. Funahashi, K. Kashiwabara, T. Suzuki, and H. D. Takagi: "New Low-Spin Co(II) Complexes with Novel Tripodal 1,1,1-Tris(dimethylphosphino-methyl)ethane Ligand : Electron Transfer Kinetics and Spectroscopic Characterization of Co(II)P_6 and Co(II)P_3S_3 Ions in Aqueous Solution"Can. J. Chem.. 79(9). 1344-1351 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Aizawa, T. lida, Y. Sone, T. Kawamoto, S. Funahashi, S. Yamada, and M. Nakamura: "Thiolato-Ligand Substitution Reaction with Halide Ions of Five-Coordinate Trigonal-Bipyramidal Palladium(II) Complexes with Tris(2-(diphenylphosphino)ethyl)phos-phine. Electronic and Steric Effects on the Reaction Mechanism"Bull. Chem. Soc. Jpn.. 75(1). 91-97 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Sato, Y. Inada, T. Horita, and S. Funahashi: "Kinetics of Metalloporphyrin Formation in Supercritical Carbon Dioxide. Development of a Stopped-Flow Instrument for Study of Fast Reactions and a Spectrophotometric Cell for Measurement of Slow Reaction Rates"J. Phys.: Condensed Matter. (in press).

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2003-09-17  

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