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2001 Fiscal Year Final Research Report Summary

Synthesis and Photochemistry of Stable Unsaturated Compounds of Group-14 Metals

Research Project

Project/Area Number 11440185
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionTohoku University

Principal Investigator

KIRA Mitsuo  Tohoku University, Department of Chemistry, Professor, 大学院・理学研究科, 教授 (40004452)

Co-Investigator(Kenkyū-buntansha) IWAMOT Takeaki  Tohoku University, Department of Chemistry, Instructor, 大学院・理学研究科, 助手 (70302081)
Project Period (FY) 1999 – 2001
Keywordsstable silylene / stable disilene / photochemistry / disilabicyclobutane / inverted sigma bond / spiropentasiladiene / transition metal complex / silatriafulvene
Research Abstract

The aim of our study has been to synthesize novel stable group-14 element unsaturated compounds and to reveal their structure and reactions.
The following are the major results: (1) Unusual reactions of stable dialkylsilylene with dichloromethane and chloromethylcyclopropane were discovered. The results were explained by invoking the ambiphilic nature of silylene. (2) The reactions of the electronically excited silylene with benzene derivatives were first observed. The excited silylene should have the nature of the singlet 1,1-biradical. (3) An apparent discrepancy for the dimer structure of bis(diisopropyl-amino)silylene between experiment and theory was solved by the detailed theoretical study. (4) Rates and mechanism of the E,Z-isomerization in tetrakis(trialkylsilyl)disilenes were revealed. (5) Unique mechanisms of the reactions of disilenes with alcohols and chloroalkanes were proposed on the basis of the theoretical and experimental studies. (6) A new silyllithium reagent, a 1,2-d … More ilithiodisilane (1), was prepared by the reaction of a tetrakis(trialkylsilyl)disilene with lithium in THF. (7) A 1,3-disilabicyclo[1.1.0]butane was synthesized using the reaction of the 1,2-dilithio-disilane 1 with a ketone. The disilabicyclobutane was found to have a unique inverted σ bridge bond. (8) A disilene-platinum complex, which has a metallacyclopropane type structure, was synthesized using the reaction of 1 with a dichloroplatinum and its structure was determined by X-ray crystallography. (9) A silicon-bowtie compound (spiropentasiladiene), whose carbon analogs have never been isolated, was first synthesized. The unique spiro-conjugation in the molecule was revealed by X-ray crystallography and theoretical calculations. (10) A stable 4-silatriafulvene having an Si=C bond with inverted polarity was synthesized and characterized by X-ray crystallography and various spectroscopies.
All these results will contribute to construct a new concepts of structure and bonding in the chemistry of main-group elements and to offer the basic structures for the future functional materials. Less

  • Research Products

    (95 results)

All Other

All Publications (95 results)

  • [Publications] W.Setaka: "An ESR study of a tetrasilaspirobiindane anion radical. Stereoelectronic electron-accepting effects of a trialkylsilyl group"Chem. Lett.. 34(9). 317-318 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Obata: "Synthesis, structure, and spectroscopic properties of perhexyloligosilanes"Organometallics. 18. 2216-2222 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] C.Liu: "Optical limiting performance of a novel σ-π alternating polymer"Optics Communications. 162. 53-56 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Zeng: "Scanning second-harmonic microscopy of a thin film of σ-π copolymer with 2,2-bipyridine in the backbone"J. Phys. : Condens. Matter. 11. 333-340 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Zeng: "Excime Excimer-like emission of a novel σ-π alternating polymer with 2,2-bipyridyl in the backbone"J. Phys. B : At. Mol. Opt. Phys.. 32. 225-230 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Takahashi: "A theoretical study of mechanisms of 1,3-silyl migration in formylmethylsilane and related compounds. Comparison with allylsilane"J. Am. Chem. Soc.. 121(37). 8597-8603 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Kanno: "Direct reactions of zirconacyclopentadienes with halosilanes as a convenient synthetic method for siloles"Chem. Lett.. 1127-1128 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "The first isolable dialkylsilylene"J. Am. Chem. Soc.. 121(41). 9722-9723 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "X-Ray crystal structure and dynamic behavior of pentafluoro-9,10-disila-9,10-dihydroanthracene anion salts having transannular 1,4-fluorine bridge"Chem. Lett.. 1183-1184 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Hashimoto: "Substituent effects on catalytic synthesis and properties of poly(phenylsilane)"Chem. Lett.. 188-189 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Manaka: "Large order-disorder transition in polydihexylsilane films as studied by second-harmonic generation spectroscopy"Chem. Phys. Lett.. 317. 260-263 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "Facile rotation around Si=Si double bonds in tetrakis(trialkylsilyl)disilenes"Organometallics. 19(10). 1817-1819 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Arai: "Observation of polysilane by near-field scanning optical microscope for ultraviolet (UV) region"J. Lumin.. 87-89. 951-953 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] W.Setaka: "Multiplicity of planar hexasilylbenzene dianions. Effects of substituents and countercations"J. Am. Chem. Soc.. 122(32). 7781-7786 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Iwamoto: "A stable bicyclic compound with two Si=Si double bonds"Science. 200. 504-506 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Takahashi: "Theoretical study on stereochemical diversity in the addition of water to disilene"Organometallics. 19(23). 4660-4662 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Miyazawa: "Remarkable temperature dependence of two-photon absorption of poly(dihexylsilylene) in solution"Chem. Lett. 1264-1265 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Zeng: "Optical limiting and bistability of a σ-π photoconductive copolymer"Chem. Phys. Lett.. 331(1). 71-77 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] E.Kwon: "Hydrogenation of silyl-substituted alkynes using diimide. Application to the synthesis of saturated sila-macrocycles"Chem. Lett.. 1416-1417 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.F.Stange: "Ruthenium and rhenium complexes with silyl-substituted bipyridyl ligands"J. Organomet. Chem.. 612. 117-124 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Takahashi: "Dimers of diaminosilylenes -Doubly bonded or bridged? The dimers of (i-Pr_2N)_2Si"J. Am. Chem. Soc.. 123(2). 347-348 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "A mechanistic study of reactions of stable disilenes with haloalkanes"J. Am. Chem. Soc.. 123(8). 1676-1682 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "Novel 1,2-dilithiodisilanes derived from reduction of stable tetrakis(trialkylsilyl)disilene with lithium metals"Chem. Lett.. 910-911 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Takahashi: "Theoretical prediction of vertical transition energies of diaminosilylenes and aminosubstituted disilenes"J. Comput. Chem.. 22. 1536-1541 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Obata: "Novel polysilane synthesis using chemical vapor deposition"Macromolecules. 34(9). 2739-2741 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Ichino: "Molecular orientation in vacuum-deposited peralkyloligosilane thin films"J. Phys. Chem. B. 105(19). 4111-4117 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Takahashi: "Importance of frontier orbital interactions in addition reaction of water to disilene"Int. J. Quantum Chem.. 84. 192-197 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Takahashi: "Substituent effects on inversion motion of 4-silatriafulvene derivatives : An ab initio MO study"Int. J. Quantum Chem.. 84. 198-207 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Veszpremi: "The mechanism of 1,2-addition of disilene and silene. 1. Water and alcohol addition"J. Am. Chem. Soc. 123(27). 6629-6638 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Hashimoto: "Synthesis, characterization, and photoreactions of 1,2-disiladigermacyclobutane"Heteroatom Chemistry. 12. 398-405 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "Novel 1,2-dilithiodisilanes derived from reduction of stable tetrakis(trialkylsilyl)disilene with lithium metals"Chem. Lett.. 910-911 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Takahashi: "Theoretical prediction of vertical transition energies of diaminosilylenes and aminosubstituted disilenes"J. Comput. Chem. 22. 1536-1541 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] W.Setaka: "Synthesis and structure of stable tri(tert-butyl)germyl-substituted stannylene and germylene"Organometallics. 20(22). 4460-4462 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Ishida: "Unexpected reactions of an isolable dialkylsilylene with haloalkanes"Chem. Lett.. 1102-1104 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "New synthesis of a stable dialkylstannylene and its reversible complexation with tetrahydrofuran"J. Organomet. Chem.. 636. 144-147 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Kanno: "Synthesis and electronic spectra of 2,5-bis(2-arylethenyl)siloes"Chem. Heterocycl. Compds. 1519-1523 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Iwamoto: "The first 1,3-disilabicyclo[1.1.0]butane with long bridge silicon-silicon bond"J. Am. Chem. Soc.. 123(50). 12730-12731 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Hashimoto: "Synthesis and X-ray structure of novel platinum η^2-disilene complex"Organometallics. 21(3). 454-456 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "Metal-ion induced intramolecular charge-transfer fluorescence of p-pentamethyldisilanylacetophenone"Chem. Lett.. 242-244 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "Hexakis(trialkylsilyl)cyclotrisilanes and photochemical generation of bis(trialkylsilyl)silylenes"J. Chem. Soc., Dalton Trans.. 1539-1544 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Takahashi: "Role of initial complexes in 1,2-addition reactions of disilene derivatives"Mol. Phys.. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Sakamoto: "The first isolable 4-silatriafulvene"Angew, Chem. Int. Ed. Engl.. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Hashimoto: "Interconversion among μ-silylene, μ-silyl, and μ-silane diruthenium complexes in the presence of dihydrosilane"Organometallics. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] B.Hajgat: "The mechanism of 1,2-addition of disilene and silene II.Hydrogen halide addition"Chem. Eu r.. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "Excited-state reactions of an isolable silylene with aromatic compounds"J. Am. Chem. Soc.. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 吉良満夫: "有機ポリシランの構造、物性と光反応"電気情報通信学会技術研究報告. (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "Stable Cyclic and Acyclic Persilyldisilenes"J. Organomet. Chem.. 611. 236-247 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "Comparative chemistry of unsaturated compounds of group-14 elements"Pure & Appl. Chem.. 72(12). 2333-2342 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 吉良満夫: "保存可能なケイ素二価化合物"ケイ素化学協会誌. No.15. 11-14 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 野依良治: "有機典書型元素化学"東京化学同人. (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kira: "Silyl migrations "The Chemistry of Organic Silicon Compounds""John-Wiley. 96 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 吉良満夫: "有機量子化学「ケイ素など高周期14族元素化合物の電子構造と反応」"朝倉書店. 24 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] W. Setaka, C. Kabuto, and M. Kira: "An ESR study of a tetrasilaspirobiindane anion radical. Stereoelectronic electron-accepting effects of a trialkylsilyl group"Chem. Lett.. (4). 317-318 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Obata and M. Kira: "Synthesis, structure, and spectroscopic properties of perhexyloligosilanes"Organometallics. 18. 2216-2222 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] C. Liu, H. Zeng, Y. Segawa, and M. Kira: "Optical limiting performance of a novel σ-π alternating polymer"Optics Communications. 162. 53-56 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Zeng, C. Liu, S. Tokura, M. Kira, and Y. Segawa: "Scanning second-harmonic microscopy of a thin film of σ-π copolymer with 2,2'-bipyridine in the backbone"J. Phys.: Condens. Matter. 11. L333-340 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Zeng, C. Liu, M. Kira, and Y. Segawa: "Excime Excimer-like emission of a novel σ-π alternating polymer with 2,2'-bipyridyl in the backbone"J. Phys. B: At. Mol. Opt. Phys.. 32. L225-230 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Takahashi and M. Kira: "A theoretical study of mechanisms of 1,3-silyl migration in formylmethylsilane and related compounds. Comparison with allylsilane"J. Am. Chem. Soc.. 121(37). 8597-8603 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Kanno and M.Kira: "Direct reactions of zircinacyclopentadienes with halosilanes as a convenient synthetic method for siloles"Chem. Lett.. (10). 1127-1128 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kira, S. Ishida, T. Iwamoto, and C. Kabuto: "The first isolable dialkylsilylene"J. Am. Chem. Soc.. 121(41). 9722-9723 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kira, E. Kwon, C. Kabuto, and K. Sakamoto: "X-Ray crystal structure and dynamic behavior of pentafluoro-9,10-disila-9,10-dihydroanthracene anion salts having transannular 1,4-fluorine bridge"Chem. Lett.. (11). 1183-1184 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Hashimoto, S. Obara, and M. Kira: "Substituent effects on catalytic synthesis and properties of poly (phenylsilane)"Chem. Lett.. 188-189 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Manaka, H, Hoshi, K. Ishikawa, H. Takazoe, S. Koshihara, M. Kira, and T. Miyazawa: "Large order-disorder transition in polydihexylsilane films as studied by second-harmonic generation spectroscopy"Chem. Phys. Lett.. 317. 260-263 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kira, S. Ohya, T. Iwamoto, M. Ichinohe and C. Kabuto: "Facile rotation around Si=Si double bonds in tetrakis (trialkylsilyl) disilenes"Organometallics. 19(10). 1817-1819 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Arai, S. Koshihara, M. Ueda, M. Yoshimoto, T. Saiki, S. Mononobe, M. Ohtsu, T. Miyazawa and M. Kira: "Observation of polysilane by near-field scanning optical microscope for ultraviolet (UV) region"J. Lumin.. 87-89. 951-953 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] W. Setaka, K. Ebata, H. Sakurai, and M. Kira: "Multiplicity of planar hexasilylbenzene dianions. Effects of substituents and countercations"J. Am. Chem. Soc.. 122(32). 7781-7786 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Iwamoto, M. Tamura, C. Kabuto, and M. Kira: "A stable bicyclic compound with two Si=Si double bonds"Science. 200. 504-506 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Takahashi, T. Veszpremi, B. Hajgato, and M. Kira: "Theoretical study on stereochemical diversity in the addition of water to disilene"Organometallics. 19(23). 4660-4662 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Miyazawa, T. Saeki, C. Liu, and M. Kira: "Remarkable temperature dependence of two-photon absorption of poly(dihexylsilylene) in solution"Chem. Lett.. (11). 1264-1265 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Zeng, C. Liu, S. Tokura, M. Kira and Y. Segawa: "Optical limiting and bistability of a σ-π photoconductive copolymer"Chem. Phys. Lett.. 331(1). 71-77 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] E. Kwon, K. Sakamoto, C. Kabuto, and M. Kira: "Hydrogenation of silyl-substituted alkynes using diimide. Application to the synthesis of saturated sila-macrocycles"Chem. Lett.. (12). 1416-1417 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. F. Stange, S. Tokura, and M. Kira: "Ruthenium and rhenium complexes with silyl-substituted bipyridyl ligands"J. Organomet. Chem.. 612. 117-124 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Takahashi, S. Tsutsui, K. Sakamoto, M. Kira, T. Muller, and Y. Apeloig: "Dimers of diaminosilylenes - Doubly bonded or bridged? The dimers of (i-Pr_2N)_2Si:"J. Am. Chem. Soc.. 123(2). 347-348 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kira, T. Ishima, T, Iwamoto, and M. Ichinohe: "A mechanistic study of reactions of stable disilenes with haloalkanes"J. Am. Chem. Soc.. 123(8). 1676-1682 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Obata, K. Sakamoto, and M. Kira: "Novel polysilane synthesis using chemical vapor deposition"Macromolecules. 34(9). 2739-2741 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Ichino, N. Minami, T. Yatabe, K. Obata, and M.Kira: "Molecular orientation in vacuum-deposited peralkyloligosilane thin films"J. Phys. Chem. B.. 105(9). 4111-4117 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Takahashi, T. Veszpremi, and M. Kira: "Importance of frontier orbital interactions in addition reaction of water to disilene"Int. J. Quantum Chem.. 84. 192-197 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Takahashi, K. Sakamoto, and M. Kira: "Substituent effects on inversion motion of 4-silatriafulvene derivatives: An ab initio MO study"Int. J. Quantum Chem.. 84. 198-207 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Veszpremi, M. Takahashi, B. Hajgato, and M. Kira: "The mechanism of 1,2-addition of disilene and silene. 1. Water and alcohol addition"J. Am. Chem. Soc.. 123(27). 6629-6638 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Hashimoto, Y. Yagihashi, L. Ignatovich, and M. Kira: "Synthesis, characterization, and photoreactions of 1,2-disiladigermacyclobutane"Heteroatom Chemistry. 12 (Inamoto issue). 398-405 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kira, T. Iwamoto, D. Yin, T. Maruyama, and H. Sakurai: "Novel 1,2-dilithiodisilanes derived from reduction of stable tetrakis (trialkylsilyl) disilene with lithium metals"Chem. Lett.. (9). 910-911 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Takahashi, M. Kira, K. Sakamoto, T. Muller, and Y. Apeloig: "Theoretical prediction of vertical transition energies of diaminosilylenes and amino-substituted disilenes"J. Comput. Chem.. 22. 1536-1541 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] W. Setaka, K. Sakamoto, M. Kira, and P.P. Power: "Synthesis and structure of stable tri (tert-butyl) germyl-substituted stannylene and germylene"Organometallics. 20(22). 4460-4462 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Ishida, T. Iwamoto, C. Kabuto, and M. Kira: "Unexpected reactions of an isolable dialkylsilylene with haloalkanes"Chem. Lett.. (11). 1102-1104 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kira, S. Ishida, T. Iwamoto, R. Yauchibara, and H. Sakurai: "New synthesis of a stable dialkylstannylene and its reversible complexation with tetrahydrofuran"J. Organomet. Chem.. 636(Nefedov issue). 144-147 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Kanno and M. Kira: "Synthesis and electronic spectra of 2,5-bis (2-arylethenyl) siloles"Chem. Heterocycl. Compds.. 1519-1523 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Iwamoto, D. Yin, C. Kabuto, and M. Kira: "The first l,3-disilabicyclo[1.1.0]butane with long bridge silicon bond"J. Am. Chem. Soc.. 123(50). 12730-12731 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Hashimoto, Y. Sekiguchi, T. Iwamoto, C. Kabuto, and M. Kira: "Synthesis and X-ray structure of novel platinum η_2-disilene Complex"Organometallics. 21(3). 454-456 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kira, R. Badugu, T. Li, W. Setaka, K. Sakamoto, and H. Hashimoto: "Metal-ion induced intramolecular charge-transfer fluorescence of p-pentamethyldisilanylacetophenone"Chem. Lett.. (2). 242-243 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kira, T. Iwamoto, T. Maruyama, T. Kuzuguchi, D. Yin, C. Kabuto, and H. Sakurai: "Hexakis (trialkylsilyl) cyclotrisilanes and photochemical generation of bis (trialkylsilyl) silylenes"J. Chem. Soc., Dalton Trans.. 1539-1544 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Takahashi, T. Veszpremi, K. Sakamoto, and M. Kira: "Role of initial complexes in 1,2-addition reactions of disilene derivatives"Mol. Phys.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Sakamoto, J. Ogasawara, Y. Kon, T. Sunagawa, C. Kabuto and M. Kira: "The first isolable 4-silatriafulvene"Angew, Chem. Int. Ed. Engl.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Hashimoto, Y. Hayashi, I. Aratani, C. Kabuto, and M. Kira: "Interconversion among μ-silylene, μ-silyl, and μ-silar diruthenium complexes in the presence of dihydrosilane"Organometallics. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] B. Hajgato, M. Takahashi, M. Kira, and T. Veszpremi: "The mechanism of 1,2-addition of disilene and silene II. Hydrogen halide addition"Chem. Eur.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kira, S. Ishida, T. Iwamoto, and C. Kabuto: "Excited-state reactions of an isolable silylene with aromatic compounds"J. Am. Chem. Soc.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2003-09-17  

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