2001 Fiscal Year Annual Research Report

有害生物の信号物質に関する合成化学的研究

Research Project

Project/Area Number	11480165
Research Institution	Tokyo University of Science
Principal Investigator	森謙治東京理科大学, 理学部・第2部, 教授 (20011843)
Co-Investigator(Kenkyū-buntansha)	田代卓哉東京理科大学, 理学部・第2部, 助手 (20339104)
Keywords	信号物質 / 昆虫フェロモン / オオツノコクヌストモドキ / ツェツェバエ / 光学活性体合成
Research Abstract	1)貯穀害虫であるオオツノコクヌストモドキ(Gnatocerus cornutus)の集合フェロモンの主成分の構造として提案されていた(+)-acoradieneを合成したが、合成品の分光学的性質は天然物と一致しなかった。よってフェロモンの真の構造は、(+)-acoradieneではない。 2)眠り病を媒介するアフリカのツェツェバエ(Glossina austeni)の性フェロモンである13,17-dimethyl-1-tritriaconteneと13,17-dimethyl-1-pentatriaconteneの全立体異性体の合成を完了した。現在アフリカで生物活性試験を実施中である。 3)ツェツェバエGlossina brevipalpisの性フェロモンであろうと考えられている3,7,11,15-tetramethylhentriacontaneと4,8,12,16-tetramethyldotriacontaneを立体異性体混合物として合成した。現在アフリカで生物活性試験を実施中である。

Research Products

(7 results)

All Other

All Publications (7 results)

[Publications] Satoshi Kurosawa, Masahiko Bando, Kenji Mori: "Synthesis of(1R,4R,5S)-(+)-Acoradiene,the Structure Proposed for the Aggregation Pheromone of the Broad-Horned Flour Beetle"Eur.J.Org.Chem.. 4395-4399 (2001)
[Publications] Taichi Kimura, David A.Carlson, Kenji Mori: "Synthesis of All the Stereoisomers of 13,17-Dimethyl-1-tritriacontene and 13,17-Dimethyl-1-pentatriacontene,the Contact Sex Pheromone Components of the Female Tsetse Fly,Glossina austeni"Eur.J.Org.Chem.. 3385-3390 (2001)
[Publications] Ken Fujita, Kenji Mori: "Synthesis of(2R,4R)-Supellapyrone,the Sex Pheromone of the Brownbanded Cockroach,Supella longipalpa,and Its Three Stereoisomers"Eur.J.Org.Chem.. 493-502 (2001)
[Publications] Masanori Seki, Kenji Mori: "Synthesis of a Prenylated and Immunosuppressive Marine Galactosphingolipid with Cyclopropane-Containing Alkyl Chains:(2S,3R,11S,12'''R,5'''Z,11'''S,12'''R)-Makoside A and Its(2S,3R,11R,12S,2'''R,5'''Z,11'''R,12'''S)-Isomer"Eur.J.Org.Chem.. 3797-3809 (2001)
[Publications] Ken Fujita, Kenji Mori: "New Synthesis of Serricornin,the Female Sex Pheromone of the Cigarette Beetle"Biosci.Biotechnol.Biochem.. 65. 1429-1433 (2001)
[Publications] Jesus Razkin Lizarraga, Kenji Mori: "Synthesis of (±)-Leucomalure[(3Z,6R^*,7S^*,9R^*,10S^*)-cis-6,7-cis-9,10-Diepoxy-3-henicosene],the Major Component of the Female Sex Pheromone of the Satin Moth"Natural Product Letters. 15. 89-92 (2001)
[Publications] 森謙治: "生物活性物質の化学-有機合成の考え方を学ぶ-"(株)化学同人. 149 (2002)

2001 Fiscal Year Annual Research Report

有害生物の信号物質に関する合成化学的研究

Principal Investigator

森 謙治 東京理科大学, 理学部・第2部, 教授 (20011843)

Research Products

[Publications] Satoshi Kurosawa, Masahiko Bando, Kenji Mori: "Synthesis of(1R,4R,5S)-(+)-Acoradiene,the Structure Proposed for the Aggregation Pheromone of the Broad-Horned Flour Beetle"Eur.J.Org.Chem.. 4395-4399 (2001)

[Publications] Taichi Kimura, David A.Carlson, Kenji Mori: "Synthesis of All the Stereoisomers of 13,17-Dimethyl-1-tritriacontene and 13,17-Dimethyl-1-pentatriacontene,the Contact Sex Pheromone Components of the Female Tsetse Fly,Glossina austeni"Eur.J.Org.Chem.. 3385-3390 (2001)

[Publications] Ken Fujita, Kenji Mori: "Synthesis of(2R,4R)-Supellapyrone,the Sex Pheromone of the Brownbanded Cockroach,Supella longipalpa,and Its Three Stereoisomers"Eur.J.Org.Chem.. 493-502 (2001)

[Publications] Masanori Seki, Kenji Mori: "Synthesis of a Prenylated and Immunosuppressive Marine Galactosphingolipid with Cyclopropane-Containing Alkyl Chains:(2S,3R,11S,12'''R,5'''Z,11'''S,12'''R)-Makoside A and Its(2S,3R,11R,12S,2'''R,5'''Z,11'''R,12'''S)-Isomer"Eur.J.Org.Chem.. 3797-3809 (2001)

[Publications] Ken Fujita, Kenji Mori: "New Synthesis of Serricornin,the Female Sex Pheromone of the Cigarette Beetle"Biosci.Biotechnol.Biochem.. 65. 1429-1433 (2001)

[Publications] Jesus Razkin Lizarraga, Kenji Mori: "Synthesis of (±)-Leucomalure[(3Z,6R^*,7S^*,9R^*,10S^*)-cis-6,7-cis-9,10-Diepoxy-3-henicosene],the Major Component of the Female Sex Pheromone of the Satin Moth"Natural Product Letters. 15. 89-92 (2001)

[Publications] 森 謙治: "生物活性物質の化学-有機合成の考え方を学ぶ-"(株)化学同人. 149 (2002)

森謙治東京理科大学, 理学部・第2部, 教授 (20011843)

[Publications] Jesus Razkin Lizarraga, Kenji Mori: "Synthesis of (±)-Leucomalure[(3Z,6R^,7S^,9R^,10S^)-cis-6,7-cis-9,10-Diepoxy-3-henicosene],the Major Component of the Female Sex Pheromone of the Satin Moth"Natural Product Letters. 15. 89-92 (2001)

[Publications] 森謙治: "生物活性物質の化学-有機合成の考え方を学ぶ-"(株)化学同人. 149 (2002)