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2001 Fiscal Year Final Research Report Summary

"Insulated gate structures on GaN and their interface properties"

Research Project

Project/Area Number 11650309
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

HASHIZUME Tamotsu  Hokkaido Univ., Res. Center for Integrated Quantum Electronics, Ass. Pro., 量子集積エレクトロニクス研究センター, 助教授 (80149898)

Co-Investigator(Kenkyū-buntansha) TAKEYAMA Mayumi  Kitami Inst. Technol., Ass. Pro., 工学部, 助教授 (80236512)
KANESHIRO Chinami  Kanagawa Inst. Technol., Faculty of Eng., Inst., 工学部, 助手 (30318993)
MOTOHISA Junichi  Hokkaido Univ., Res. Center for Integrated Quantum Electronics, Ass. Pro., 量子集積エレクトロニクス研究センター, 助教授 (60212263)
FUJIKURA Hajime  Hitachi Cable LTD., Senior Researcher, 主任研究員(研究職)
Project Period (FY) 1999 – 2001
KeywordsGallium Nitride / surface control / interface control / MIS structure / surface treatment / Fermi level pinning / SiN_χ / Al_2O_3
Research Abstract

For the application to high-power/high-frequency electronic devices, we have investigated the formation processes of insulated structures on GaN and their interface properties. The main results obtained are listed below :
(1) Chemistry and electronic properties of GaN surfaces after various kinds of surface treatments were characterized by x-ray photoelectron spectroscopy (XPS). Strong upward band bending of 1.4 eV was found at the air-exposed GaN surface. This is due to the high density of surface states. The surface treatment in the NH_40H solution and the ECR-excited N_2 plasma significantly decreased the surface band bending to 0.5 eV, indicating the reduction of the Fermi level pinning.
(2) We have successfully fabricated the SiN_χ gate structure on the treated n-GaN surface by the ECR-CVD process. The SiN_χ/n-GaN structure showed the type-I band lineup and a low interface state density distribution in the range of 10^<11> cm^<-2> eV^<-1>. The surface passivation utilizing the ECR-C … More VD SiNx film enhanced the drain saturation current and improved the stability in the GaN/AlGaN heterostructure field effect transistors.
(3) Electrical characterization of AlN/GaN interfaces was carried out by the C-V technique in samples grown by metal organic chemical vapor deposition. A low value of interface state density D_<it> of < 1x 10^<11> cm^<-2> eV^<-1> was achieved around the energy position of Ec-0.8eV. This indicates that the AlN/GaN structures have good interface properties with low interface state density, and are very promising for advanced MIS devices.
(3) A novel surface passivation process for AIGaN/GaN heterostructures utilizing an ultrathin Al_20_3 layer (〜1 nm) was proposed. The reverse leakage current for the Schottky gate contact on the Al_20_3-passivated heterostructure surface was reduced by three orders of magnitude than that for the conventional Schottky gate structure. C-V results showed good gate controllability of two-dimensional electron gas (2DEG) by the novel gate structure. Less

  • Research Products

    (30 results)

All Other

All Publications (30 results)

  • [Publications] Y.Koyama: "Formation Processes and Properties of Schottky and Ohmic Contacts on n-type GaN for Field Effect Transistor Applications"Solid-State Electron. 43. 1483-1488 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Hasegawa: "Properties of Metal-Semiconductor Interfaces Formed on n-type GaN"Japanese Journal of Applied Physics. 38. 2634-2639 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hashizume: "A novel surface passivation structure for III-V compound semiconductors utilizing a silicon interface control layer and its application"Materials Research Society Proceedings. 573. 45-46 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Nakasaki: "Insulator-GaN Interface Structures Formed by Plasma-Assisted Chemical Vapor Deposition"Physica E. 7. 953-957 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hashizume: "X-ray photoelectron spectroscopy characterization of AlGaN surfaces exposed to air and treated in NH4OH solution"Appl. Phys. Lett.. 76. 2880-2882 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hashizume: "Capacitance-voltage characterization of AlN/GaN metal-insulator-semiconductor structures grown on sapphire substrate by metal organic chemical vapor deposition"J. Appl. Phys.. 88. 1983-1986 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Ootomo: "Properties of as-grown, chemically treated and thermally oxidized surfaces of AlGaN/GaN heterostructure"The Institute of Pure and Applied Physics(IPAP) Conference Series. 1. 934-937 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hashizume: "Surface Characterization of GaN and AlGaN Layers Grown by MOVPE"Mater. Sci. Eng. B. 80. 309-312 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hashizume: "Surface Passivation Process for GaN-Based Electronic Devices Utilizing ECR-CVD SiN_x Film"IEICE Trans. Electron. E84-C. 1455-1461 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hashizume: "Chemistry and Electrical Properties of Surfaces of GaN and AlGaN/GaN Heterostructures"J. Vac. Sci. Technol.B. 19. 1675-1681 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Ootomo: "Surface passivation of AiGaN/GaN heterostructures using an ultrathin A12O3 layer"phys. stat. sol. A. 188. 371-374 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Oyama: "Mechanism of Current Leakage through Metal/n-GaN Interfaces"Applied Surface Science. (in press). (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Z.Jin: "Effects of nitrogen addition on methan-based ECR plasma etching of gallium nitride"Applied Surface Science. (in press). (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Konishi: "In-situ XPS and Photoluminescence Characterization of GaN Surfaces Grown by MBE on MOVPE GaN Templates"Inst. Phys. Conf. Ser.. (in press). (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hashizume: "A discrete surface state related to nitrogen-vacancy defect on plasma treated GaN surface"Applied Physics Letters. (投稿中). (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y. Koyama., T. Hashizume, H. Hasegawa: ""Formation Processes and Properties of Schottky and Ohmic Contacts on n-type GaN for Field Effect Transistor Applications""Solid-State Electron. vol 43. 1483-88 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Hasegawa., Y. Koyama., H. Hashizume: ""Properties of Metal-Semiconductor Interfaces Formed on n-type GaN""Jpn. J. Appl. Phys.. vol. 38. 2634-9 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Hashizume, H. Hasegawa: ""A novel surface passivation structure for III-V compound semiconductors utilizing a silicon inierface control layer and its application""Materials Research Society Proceedings. vol. 573. 45-56 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R. Nakasaki, T. Hashizume, H. Hasegawa: ""Insulator-GaN Interface Structures Formed by Plasma-Assisted Chemical Vapor Deposition""Physica E.. vol. 7. 953-957 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Hasizume, S. Ootomo, R. Nakasaki, S. Oyama, M. Kihara: ""X-ray photoelectron spectroscopy characterization of AlGaN surfaces exposed to air and treated in NH4OH solution""Appl. Phys. Lett.. 76. 2880-2882 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Hashizume, E. Aleksee, D. Pavlidis, K. S. Boutros, J. Redwing: ""Capacitance-voltage characterization of AIN/GaN metal-insulator-semiconductor structures grown on sapphire substrate by metal organic chemical vapor deposition""J. Appl. Phys.. vol. 88. 1983-1986 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Ootomo, S. Oyama, T. Hashizume, H. Hasegawa: ""Properties of as-grown, chemically treated and thermally oxidized surfaces of AlGaN/GaN heterostructure""The Institute of Pure and Applied Physics (IPAP) Conference Series. vol. 1. 934-937 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Hashizume, R. Nakasaki, S. Ootomo, S. Oyama, H. Hasegawa: ""Surface Characterization of GaN and AlGaN Layers Grown by MOVPE""Mater. Sci. Eng. B. vol. 80. 309-312 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Hashizume, R. Nakasaki, S. Ootomo, S. Oyama, H. Hasegawa: ""SurfacePassivation Process for GaN-Based Electronic Devices Utilizing ECR-CVD SiNx Film""IEICE Trans. Electron.. vol. E84-C. 1455-1461 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Hashizume, S. Ootomo, S. Oyama, M. Konishi, H. Hasegawa: ""Chemistry and Electrical Properties of Surfaces of GaN and AlGaN/GaN Heterostructures""J. Vac. Sci. Technol. B. 19. 1675-1681 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Ootomo. T. Hashizume, H. Hasegawa: ""Surface passivation of AlGaN/GaN heterostructures using an ultlathin Al2O3 layer""phys. stat. sol. A. 188. 371-374 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Oyama, T. Hashizume, H. Hasegawa: ""Mechanism of Current Leakage through Metal/n-GaN Interfaces""Appl. Sur. Sci.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Z. Jin, T. Hashizume, H. Hasegawa: ""Effects of nitrogen addition on methan-based ECR plasma etching of gallium nitride""Appl. Sur. Sci.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Konishi, T. Hashizume H. Hasegawa: ""In-situ XPS and Photoluminescence Characterization of GaN Surfaces Grown by MBE on MOVPE GaN Templates""Inst. Phys. Conf. Ser.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Hashizume, R. Nakasaki: ""A discrete surface state related to nitrogen-vacancy defect on plasma treated GaN surface""Appl. Phys. Lett.. (submitted to).

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2003-09-17  

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