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2001 Fiscal Year Final Research Report Summary

Biological and Chemistry in Adaptation of Highland Plants

Research Project

Project/Area Number 11695083
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionRIKKYO UNIVERSITY

Principal Investigator

HORIUCHI Akira  RIKKYO UNIV COLLEGE OF SCIENCE PROFESSOR, 理学部, 教授 (60062650)

Co-Investigator(Kenkyū-buntansha) SUHARA Junpei  RIKKYO UNIV COLLEGE OF SCIENCE ASSIST PROFESSOR, 理学部, 助教授 (70062635)
KURODA Chiaki  RIKKYO UNIV COLLEGE OF SCIENCE PROFESSOR, 理学部, 教授 (40158887)
HIEDA Koutarou  RIKKYO UNIV COLLEGE OF SCIENCE PROFESSOR, 理学部, 教授 (20062656)
KATO Nakahide  RIKKYO UNIV COLLEGE OF SCIENCE LECTURER, 理学部, 講師 (00142547)
HANAI Ryo  RIKKYO UNIV COLLEGE OF SCIENCE ASSIST PROFESSOR, 理学部, 助教授 (30287916)
Project Period (FY) 1999 – 2001
Keywordscomposivion of barley / ICP-MS method / delphinium / green-house / bryophyte / C. japonicum / L. lankongensis and L. ala / C. chamlagu
Research Abstract

Drs. T. Takada, K. Hieda, and R. Hanai, all from Rikkyo University, carried out a field work at East Tibet in August, 1999. Continuously, Drs. C. Kuroda and J. Suhara botanized at Yunnan areas in August, 2000 and 2001. A survey of floweing plants, measurment of UV intensity, collection of barley for analysis of trace rare-earth elements, adaptation of bryophytes to environmental chenges, and the chemical components of various Ligularia spceies were studied.
It was found from these field works to draw the following facts :
1. Elements determined were Ti, V, Zn, W, Au, Pb, and rare earth elements in barley samples by ICP-MS method. The results showed increasing concentration of trace metal elements in stems and whisker than seeds. The results are also presented that the Tibetan barley samples contained much higher levels of rare earth metals (the highest conc. : Ce 1.05 μg/g, the lowest conc. : Dy 0.05 μg/g in seeds) than that of Japan.
2. A plant observed on most of the route was Delphiniu … More m, of which several species were found. Species with smaller plant sizes but with larger flowers were found in regions with larger elevation and drier and chiller climate, as the trip proceeded, westward.
3. Morphologies typical of cold regions were observed. For instance, the "green-house" morphology was observed for Saussarea and Ajuga species. Many species with the "cushion" morphology were also observed.
4. A new allele, designated as "Y-type", was identified in north Yunnan (near Kunming), on the other hand, samples in south Yunnan had the S-type allele. The results seem to indicate that C. japonicum in Japan mostly originated in south Yunnan. The plant in north Yunnan (Lijian, Dali, Kunming, Zhaotong, and Daguan) was identified that the rbcL allele of all the samples was the Y-type.
5. It was found that the main component of L. lankongensis and L. alatipes are eremophilan-7(11)-en-8-one(compound 1) and bakkenolide A(compound 3), respectively. While benzofuran derivative (compound 4) was isolated from L. longihastata as the major component.
6. It was found that the plant cultured cells of Caragana chamlagu are more effective as biocatalyzer for allylic oxidation of terpenoids. Less

  • Research Products

    (20 results)

All Other

All Publications (20 results)

  • [Publications] H.Suzuki, A.Monda, C.Kuroda: "Synthesis of eleven-membered carbocycles by a new five-carbon ring expansion reaction"Tetrahedron Lett.. 42(10). 1915-1917 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] C.Kuroda, ^* K.Kobayashi, A.Koito, S.Anzai: "Intramolecular Cyclization of (2-Functionalized Allyl) trimethylsilane with Acid Chloride. Synthesis of Two Guaianolide-Type α-Methylene γ-Lactones"Bull.Chem.Soc.Jpn.. 74(10). 1947-1961 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] W.Chai, H.Hamada, J.Suhara, C.A.Horiuchi: "Biotransformationh of (+)-and (-)-camporquinones by pliant cultured cells"Phytochemistry. 57. 669-673 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Sakamaki, S.Kitanaka, W.Chai, Y.Hayashida, Y.Takagi, C.A.Horiuchi: "Biotransformation of Thujopsene by Caragana chamlagu"J.Natural Prod.. 64. 630-631 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kobayashi, R.Hanai: "M phase-specific association of human topoisomerase IIIβ with chromosomes"Bichem.Biophys.Res.Commun.. 287. 282-287 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Kubo, S.-K.Kim, R.Hanai: "Isolation and characterization of novel F-plasmid sop B mutants defective in gene silencing"Mol.Genet.Genomics. 266. 806-812 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Takinami, M.Mochizuki, H.Hayatsu, O.Nikaido, M.Kubota, M.Watanabe, M.Hieda, K.Hieda, T.Negishi: "Somatic cell mutation and photoproduct formation induced by solar UV-radiation in Drosophila"Environment Toxicology. 15. 496-499 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Munakata, S.Kazadzis, A.Bais, K.Hieda, G.Ronto, P.Rettberg, G.Horneck: "Comparisons of spore dosimetry and spectral photometer of solar-UV radiation at four sites in Japan and Europe"Photochem.Photobiol.. 72. 739-745 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Negishi, O.Nagaoka, H.Hayatsu, K.Suzuki, T.Hara, M.Kubota, M.Watanabe, K.Hieda: "Somatic-cell mutation induced by UVA and monochromatic UN radiation in repair-proficient and -deficient Drosophila melanogaster"Photochem.Photobiol.. 73. 493-498 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Toyoshima1, S.Takinami1, K.Hieda2, Y.Furusawa, T.Negishi: "The involvement of cell cycle checkpoint-mutation in the mutagenesis induced by longer wavelength light band of solar UV in Drosophila"Photochemical and Photobiological Sciences. 1. 178-183 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M. Kobayashi and R. Hanai: ""M phase-specific association of human topoisomerase IIIβ with chromosomes""Biochem. Biophys. Res. Commun. No.287. 282-287 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Kubo, S.-K. Kim, and R. Hanai: ""Isolation and characterization of novel F-plasmid sop B mutants defective in gene silencing""Mol. Genet. Genomics. No.266. 806-812 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Takinami, M. Mochizuki, H. Hayatsu, O. Nikaido, M. Kubota, M. Watanabe, M. Hieda, K. Hieda and T. Negishi: ""Somatic cell mutation and photoproduct formation induced by solar UV-radiation in Drosophila""Environment Toxicology. No.15. 496-499 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Munakata, S. Kazadzis, A. Bais, K. Hieda, G. Ronto, P. Rettberg and G. Horneck: ""Comparisons of spore dosimetry and spectral photmeter of solar-UV radiation at four sites in Japan and Europe""Photochem Photobiol.. No.72. 739-745 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Negishi, C. Nagaoka, H. Hayasu, K. Suzuki, T. Hara, M. Kubota, M. Watanabe and K. Hieda: ""Somatic-cell mutation induced by UVA and monochromatic UV radiation in repair-proficient and -deficient Drosophila melanogaster""Photochem. Photobiol.. No.73. 493-498 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Toyoshima1, S. Takinami1, K. Hieda2, Y. Furusawa and T. Negishi: ""The Involvement of cell cycle checkpoint-mutation in the mutagenesis induced by longer wavelength light band of solar UV in Drosophila""Photochemical and Photobiological Sciences. No. 1. 178-183 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Suzuki, A. Monda, and C. Kuroda: ""Synthesis of eleven-membered carbocycles by a new five-carbon ring expansion reaction""Tetrahedron Lett.. No.42(10). 1915-1917 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] C. Kuroda, ^*K. Kobayashi, A. Koito, and S. Anzai: ""Intramolecular Cyclization of (2-Functionalized Allyl)trimethylsilane with Acid Chloride. Synthesis of Two Guaianolide-Type α-Methylene γ-Lactones""Bull. Chem. Soc. Jpn.. No.74(10). 1947-1961 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] W. Chai, H. Hamada, J. Suhara, and C. A. Horiuchi: ""Biotransformation of (+)- and (-)-camporquinones by plant cultured cells""Phytochemistry. No.57. 669-673 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Sakamaki, S. Kitanaka, W. Chai, Y. Hayashida, Y. Takagi, and C. A. Horiuchi: ""Biotransformation of Thujopsene by Caragana chamlagu""J. Natural Prod.. No.64. 630-631 (2001)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2003-09-17  

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