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2001 Fiscal Year Final Research Report Summary

Development of Carbon Nanotube Based Cold Electron Sources with Low Energy Consumption and High Emission Current

Research Project

Project/Area Number 11792003
Research Category

Grant-in-Aid for University and Society Collaboration

Allocation TypeSingle-year Grants
Research Field 表面界面物性
Research InstitutionMie University

Principal Investigator

SAITO Yahachi  MIE UNIVERSITY, DEPARTMENT OF ELECTRICAL AND ELECTRONIC ENGINEERING, PROFESSOR, 工学部, 教授 (90144203)

Co-Investigator(Kenkyū-buntansha) SATO Hideki  MIE UNIVERSITY, DEPARTMENT OF ELECTRICAL AND ELECTRONIC ENGINEERING, ASSISTANT PROFESSOR, 工学部, 助手 (40324545)
UEMURA Sashiro  ISE ELECTRONICS, TECHNOLOGY RESEARCH LABORATORY, DIRECTOR, 技術部・取締役
HATA Koichi  MIE UNIVERSITY, DEPARTMENT OF ELECTRICAL AND ELECTRONIC ENGINEERING, LECTURER, 工学部, 講師 (30228465)
Project Period (FY) 1999 – 2001
KeywordsCarbon nanotube / Field emission / Electron source / Current density / Brightness / Field ion microscopy / Pentagon / Light source
Research Abstract

Development of carbon nanotube (CNT) production and elucidation of fundamental properties of CNT field emitters were carried out with the aim of showing applicability of CNTs as field emission electron sources. Followings are the main achievement of the present study.
1. Growth conditions of CNTs
Growth conditions for obtaining high purity multiwall CNTs (MWCNTs) and special MWCNTs called nanografibers were found. Efficient catalysts such as Rh-Pt for synthesizing single-wall CNTs (SWCNTs) were also found.
2. Electron emission from clean MWNTs and the effects of adsorbates
Field emission occurred preferentially from carbon pentagons when the CNT surfaces were clean, while the enhanced emission was observed through adsorbates when the gas molecules were on the CNT tip.
3. Effect of ambient gases on the CNT field emitters
Among various ambient studied, oxygen, methane and carbon monoxide were the most hazardous gases degrading the electron emission from CNTs.
4. Energy distribution, brightness, and angular current density of CNT-electron sources
An electron energy distribution from one MWNT had a width of 330 meV. Emission current density and angular current density were respectively 10^8A/cm^2 and 10^<-7>A/sr, giving 10^<10>A/cm^2 sr as brightness at 100 kV acceleration.
5. Experimental fabrication of ultra-high luminance CNT light sources
The fabricated ultra-high luminance light-sources by using nanografibers showed 10^6 cd/m^2 at 30kV dc-driving, the brightness being more than 10 times higher than that manufactured previously.

  • Research Products

    (81 results)

All Other

All Publications (81 results)

  • [Publications] Y.Saito: "Field Emission from Carbon Nanotubes and Its Application to Cathode Ray Tube Lighting Elements"Appl.Surface Sci. 146. 305-311 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito: "Synthesis, Structure and Field Emission of Carbon Nanotubes"Fullerene Sci.Tech. 7(4). 653-664 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hata: "Selective Formation of C_<20> Cluster Ions by Field Evaporation from Carbon Nanotubes"Chem.Phys.Lett. 308(3/4). 343-346 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito: "Field Emission from Carbon Nanotubes and its Application to Electron Sources"Carbon. 38. 169-182 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito: "Diameters of Single-Wall Carbon Nanotubes Depending on Helium Gas Pressure in Arc Discharge"J.Phys.Chem.B. 104(11). 2495-2499 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito: "Field Emission Patterns Originating from Pentagons at the Tip of a Carbon Nanotube"Jpn.J.Appl.Phys. 39(4A). L271-L272 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito: "Field Emission of Electrons from Graphitic Nanofibers Produced in a Hydrogen Arc Discharge"Jpn.J.Appl.Phys. 39(7A). 1468-1473 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito: "Field Emission and Field Evaporation of Carbon Nanotubes"Trans.Mater.Res.Soc.Jpn. 25(3). 811-816 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Hino: "Energy Distribution of Field Emitted Electrons from Multiwall Carbon Nanotubes"Synthetic Metals. 121. 1213-1214 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hata: "Field-Evaporation of Magic Cluster Ions, C_<20^+>, from Carbon Nanotubes"Scripta Materialia. 44. 1571-1574 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hata: "Field Emission Microscopy of Adsorption and Desorption of Residual Gas Molecules on a Carbon Nanotube Tip"Surface Science. 490. 296-300 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hata: "Field Emission from Carbon Nanotubes with Clean Surfaces and Adsorbed Molecules"AIP Conference Proceedings Nanonetwork Materials. 590. 113-116 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] C.Oshima: "Electron Emission Sites on Carbon Nanotubes and the Energy Spectra"Jpn.J.Appl.Phys. 40. 1257-1259 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito: "Field Ion Microscopy of Multiwall Carbon Nanotubes : Observation of Pentagons and Cap Breakage under High Electric Field"Surface Science Lett.. 499(1). 119-123 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito: "Field Emission of Carbon Nanotubes and Its Application as Electron Sources of Ultra-High Luminance Light-Source Devices"Physica B. (印刷中). (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hata: "Field emission from multiwall carbon nanotubes in controlled ambient gases, H_2, CO, N_2 and O_2"Ultramicroscopy. (印刷中). (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Takakura: "Energy distributions of field emitted electrons from a multi-wall carbon nanotube"Ultramicroscopy. (印刷中). (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito: "Field Emission Properties of Carbon Nanotubes and their Application to Display Devices"Molecular Cryst.& Liquid Cryst.. (印刷中). (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブ電界放出ディスプレイの最前線"機能材料. 21(5). 40-44 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブ電子源とFEDへの応用"月刊ディスプレイ. 7(7). 60-64 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブFEDの開発と実用化への課題"M&E(工業調査会). 28(7). 174-179 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブ膜の作製とその電界放出特性"表面技術. 52(10). 664-667 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "希土類とカーボンナノチューブ"希土類. No.39. 51-55 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブの応用"マテリアルインテグレーション. 14(12). 13-16 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 余谷純子: "カーボンナノチューブを電子源とした超高輝度光源管"真空. 44(11). 956-962 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブの電子放出とその応用"材料科学. 38(6). 277-281 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブ"機能材料. 22(1). 39-43 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブフィールドエミッタ"表面科学. 23(1). 38-43 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "ナノカプセル-異種物質を内包し,単層ナノチューブ成長を促すカーボンナノ粒子-"日本化学会編,学会出版センター. 258 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 田中一義: "化学フロンティア2「カーボンナノチューブ,ナノデバイスへの挑戦」"化学同人. 213 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 小泉光恵: "ナノマテリアルの最新技術"シーエムシー. 340 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Eiji Ohsawa: "Perspectives of Fullerene Nanotechnology"Kluwer Academic Publishers. 375 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y. Saito, K. Hamaguchi, R. Mizushima, S. Uemura, T. Nagasako, J. Yotani and T. Shimojo: ""Field Emission from Carbon Nanotubes and Its Application to Cathode Ray Tube Lighting Elements""Appl. Surface Sci.. 146. 305-311 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito, R. Mizushima, T. Tanaka, K. Tohji, K. Uchida, M. Yumura and S. Uemura: ""Synthesis, Structure and Field Emission of Carbon Nanotubes""Fullerene Sci. Tech.. 7(4). 653-664 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Hata, M. Ariff and Y. Saito: ""Selective Formation of C20 Cluster Ions by Field Evaporation from Carbon Nanotubes""Chem. Phys. Lett.. 308(3/4). 343-346 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito and S. Uemura: ""Field Emission from Carbon Nanotubes and its Application to Electron Sources""Carbon. 38. 169-182 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito, Y. Tani and A. Kasuya: ""Diameters of Single-Wall Carbon Nanotubes Depending on Helium Gas Pressure in Arc Discharge""J. Phys. Chem. B. 104(11). 2495-2499 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito, K. Hata and T. Murata: ""Field Emission Patterns Originating from Pentagons at the Tip of a Carbon Nanotube""Jpn. J. Appl. Phys.. 39(4A). L271-L272 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito, R. Mizushima, S. Kondo and M. Maida: ""Field Emission of Electrons from Graphitic Nanofibers Produced in a Hydrogen Arc Discharge""Jpn. J. Appl. Phys.. 39(7A). 1468-1473 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: ""Field Emission and Field Evaporation of Carbon Nanotubes""Trans. Mater. Res. Soc. Jpn.. 25(3). 811-816 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Hino, N. Miyazaki, K. Iwasaki, S. Kondo and Y. Saito: ""Energy Distribution of Field Emitted Electrons from Multiwall Carbon Nanotubes""Synthetic Metals. 121. 1213-1214 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Hata, Y. Kiya, M. Ohata and Y. Saito: ""Field-Evaporation of Magic Cluster Ions, C20+, from Carbon Nanotubes""Scripta Materialia. 44. 1571-1574 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Hata, A. Takakura and Y. Saito: ""Field Emission Microscopy of Adsorption and Desorption of Residual Gas Molecules on a Carbon Nanotube Tip""Surface Sci.. 490. 296-300 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Hata, A. Takakura and Y. Saito: ""Field Emission from Carbon Nanotubes with Clean Surfaces and Adsorbed Molecules""AIP Conference Proceedings, Nanonetwork Materials (ed. S. Saito et al., American Institute of Physics.. 590. 113-116 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] C. Oshima, K. Mastuda, T. Kona, Y. Mogami, M. Komaki, Y. Murata, T. Yamamshita, Y. Saito, K. Hata and A. Takakura: ""Electron Emission Sites on Carbon Nanotubes and the Energy Spectra""Jpn. J. Appl. Phys.. 40(11B). L1257-L1259 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito, R. Mizushima and K. Hata: ""Field Ion Microscopy of Multiwall Carbon Nanotubes : Observation of Pentagons and Cap Breakage under High Electric Field""Surface Sci.. 499(1). L119-L123 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito, K. Hata, A. Takakura, J. Yotani and S. Uemura: ""Field Emission of Carbon Nanotubes and Its Application as Electron Sources of Ultra-High Luminance Light-Source Devices""Physica B. (in press). (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Hata, A. Takakura and Y. Saito: ""Field emission from multiwall carbon nanotubes in controlled ambient gases, H2, CO, N2 and 02""Ultramicroscopy. (in press). (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Takakura, K. Hata, Y. Saito, K. Matsuda, T. Kona and C. Oshima: ""Energy distributions of field emitted electrons from a multi-wall carbon nanotube""Ultramicroscopy. (in press). (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito, T. Nishiyama, T. Kato, S. Kondo, T. Tanaka, J. Yotani and S. Uemura: ""Field Emission Properties of Carbon Nanotubes and their Application to Display Devices""Molecular Cryst. & Llquid Cryst.. (in press). (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Carbon Nanotubes and Nanocapsules Produced by Arc Discharge and Their Applications (in Japanese)""J. Plasma and Fusion Research. 75(8). 908-913 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Carbon Nanocapsules and Single-Wall Nanotubes (in Japanese)""Electron Microscopy. 34(2). 115-116 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yahachi Saito: ""Carbon Nanotubes Produced by Arc Discharge""New Diamond and Frontier Carbon Tech.. 9(1). 1-30 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: ""Preparation and Electron Emission Properties of Carbon Nanotubes (in Japanese)""Vacuum. 42(8). 717-721 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Carbon Nanotube Science Developing into a New Phase (in Japanese)""Parity. 14(12). 101-103 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Electron Emission from Carbon Nanotubes (in Japanese)""Display and Imaging. 8(1). 69-75 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito and S. Uemura: ""Field Emission from Carbon Nanotubes and Its Application to Display Devices (in Japanese)""Oyo Buturi. 69(3). 314-317 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Electron and Carbon Ion Sources Utilizing Carbon Nanofibers (in Japanese)""Material Technology. 18(1). 5-11 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Field Emission from Carbon Nanofibers : Fundamental and Application to Display Devices (in Japanese)""Tanso. No. 193. 186-191 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Field Emission of Electrons and Field Evaporation of C_<20> from Carbon Nanotubes (in Japanese)""Hyoumen Kagaku (J. Surface Scl. Soc. Jpn). 21(9). 534-539 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Application of Carbon Nanotubes (in Japanese)""Kotaibutusri (Solid State Physics). 35(10). 819-828 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Application of Carbon Nanotubes as Electron Sources (in Japanese)""Ceramic Data Book 2000 (Kogyo to Seihin, vol. 28). 204-206 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Application of Carbon Nanotubes to Field Emission Cathodes (in Japanese)""MRS-J News. 21(4). 2-3 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Carbon Nanotubes in a Phase Toward Applications (in Japanese)""KAST Report. 12(1). 24-29 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. SAITO: ""Application of Carbon Nanotubes (in Japanese)""New Diamond. 16(4). 25-28 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Hata, A. Takakura and Y. Saito: ""Field Emission from Pentagons on a Carbon Nanotube Tip Revealed by Field Emission Microscopy""MRS Symp. Proc. vol. 633, "Nanotubes and Related Materials" ed. A. M. Rao. A18. 4. 1-A18. 4. 5 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: ""Frontier of Carbon Nanotube Field Emission Display (in Japanese)""Kinou-Gairyou (Function & Materials). 21(5). 40-44 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: ""Application of Carbon Nanotubes as Field Emission Electron Sources (in Japanese)""Kobunshi (High Polymers, Japan). 50(5). 319 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: ""Carbon Nanotubes Electron Sources and Their Application to FED (in Japanese)""Monthly Display. 7(7). 60-64 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: ""Development of Carbon Nanotube Based FEDs and Hurdles against Practical Application (in Japanese)""M&E. 28(7). 174-179 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: ""Formation of Carbon Nanotube Films and their Field Emission Properties (in Japanese)""Hyomen Gijutsu. 52(10). 664-667 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: ""Rare Earth elements and Carbon Nanotubes""Rare Earths. No. 39. 51-55 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Ogata and Y. Saito: ""Hydrogen Storage using Carbon Nanotubes (in Japanese)""Eco Industry. 6(12). 5-11 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J. Yotani, S. Uemura, T. Nagasako, H. Kurachi, H. Yamada, T. Ezaki, Y. Saito, Y. Ando, X. Zhao and M. Yumura: ""Super-High Luminance Light-Source Device with with Carbon Nanotube Emitter (in Japanese)""J. Vac. Soc. Jpn.. 44(11). 956-962 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: ""Field Emission of Carbon Nanotubes and Its Application (in Japanese)""J. Mater. Sci. Soc. Jpn.. 38(6). 277-281 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: ""Carbon Nanotube (in Japanese)""Kinou-Gairyou (Function & Materials). 22(1). 39-43 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: ""Carbon Nanotube Field Emitter (in Japanese)""Hyoumen Kagaku (J. Surface Sci. Soc. Jpn). 23(1). 38-43 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: "Carbon Nanocapsules - Carbon Nanoparticles Encaging Foreign Materials and Assisting the Growth of Single-Wall Nanotubes, Kikan Kagaku Sousetu (Quarterly Chemistry Review) 43 (in Japanese)"Kagakudoujin. 57-61 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: "Chap. 13, Carbon Nanotube Field Electron Emitter, Chemistry Frontier 2 (in Japanese)"Kagakudoujin. 175-184 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito: "Chap. 1, Carbon Nanotube, Latest Nanomaterials (in Japanese)"CMC publication. 283-287 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Saito, K. Hata, A. Takakura, K. Matsuda, T. Kona and C. Ohshima: "Field Emission Microscopy of Carbon Nanotubes, Perspectives of Fullerene Nanotechnology, ed. E. Osawa"Kluwer Academic Publishers, London. 49-55 (2002)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2003-09-17  

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