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2002 Fiscal Year Final Research Report Summary

Development of a Method to Evaluate the Surface of Single Crystal Substrates for Super-High-Frequency SAW Devices by UMS Technology

Research Project

Project/Area Number 12450119
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionTohoku University

Principal Investigator

KUSHIBIKI Jun-ichi  Tohoku University,Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (50108578)

Co-Investigator(Kenkyū-buntansha) MATSUMOTO Yasushi  Tohoku University,Research Institute of Electrical Communication, Associate Professor, 電気通信研究所, 助教授 (20312598)
IZUMI Takanaga  Tohoku University,Graduate School of Engineering, Research Associate, 大学院・工学研究科, 助手 (30323059)
ARAKAWA Mototaka  Tohoku University,Graduate School of Engineering, Research Associate, 大学院・工学研究科, 助手 (00333865)
ODAGAWA Hiroyuki  Tohoku University,Research Institute of Electrical Communication, Research Assiciate, 電気通信研究所, 助手 (00250845)
CHO Yasuo  Tohoku University,Research Institute of Electrical Communication, Professor, 電気通信研究所, 教授 (40179966)
Project Period (FY) 2000 – 2002
KeywordsUltrasonic microspectroscopy / LFB ultrasonic material characterization / Standard specimen / Damaged surface layer / Leaky surface acoustic wave / Evaluation of single crystal materials / Materials for SAW devices / Scanning nonlinear dielectric microscopy
Research Abstract

In this study, ultrasonic microspectroscopy (UMS) technology, using the line-focus-beam (LFB) and plane-wave ultrasonic material characterization system, has been applied to the problems associated with the homogeneities and modified/damaged surface layers of LiNbO_3 and LiTaO_3 single crystals for super-high-frequency (SHF) surface acoustic wave (SAW) devices. The purpose of this study was to establish the quantitative analysis and evaluation method using this technology.
1. The relative and absolute accuracies for the propagation characteristics of leaky SAW (LSAW) measured by the LFB-UMC system have been improved.
2. Chemical composition dependences of the acoustical physical constants of LiNbO_3 and LiTaO_3 single crystals were determined. This enables us to calculate the propagation characteristics of LSAW and SAW for the crystals with an arbitrary chemical composition.
3. Experimental relationships (calibration lines) among the LSAW velocity, Curie temperature, lattice constants, et … More c., were obtained to evaluate each property of the crystals by a common scale of LSAW velocity.
4. A method for improving the crystal growth conditions through the evaluation of the chemical composition distributions of commercially available LiTaO_3 single crystals was proposed and an extremely homogeneous crystal was successfully grown.
5. For the demonstration of evaluating modified/damaged surface layers, we fabricated several LiTaO_3 substrates with protonexchanged layers and domain-inverted layers as model specimens. The thickness resolution of the surface layers estimated by LSAW velocity was nanometer order.
6. The resolution of scanning nonlinear dielectric microscopy was improved with an atomic size.
7. Center frequencies and SAW velocities were measured for 0.5, 1, and 2 GHz-band SAW filters fabricated on LiTaO_3 wafers whose distributions in chemical composition were preexamined by measuring LSAW velocities. The results exhibited that variations of the center frequencies and differences between the calculated and measured SAW velocities became larger as the frequency became higher. It was considered that problems associated with the damaged surface layers of the substrates were detected. Less

  • Research Products

    (38 results)

All Other

All Publications (38 results)

  • [Publications] J.Kushibiki, T.Okuzawa, J.Hirohashi, Y.Ohashi: "Line-Focus-Beam Acoustic Microscopy Characterization of Optical-Grade LiTaO_3 Single Crystals"J.Appl.Phys.. 87. 4395-4403 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Ono, J.Kushibiki: "Experimental Study of Construction Mechanism of V(z) Curves Obtained by Line-Focus-Beam Acoustic Microscopy"IEEE Trans.UFFC. 47. 1042-1050 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, Y.Ohashi, Y.Ono: "Evaluation and Selection of LiNbO_3 and LiTaO_3 Substrates for SAW Devices by the LFB Ultrasonic Material Characterization System"IEEE Trans.UFFC. 47. 1068-1076 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, M.Arakawa: "Diffraction Effects on Bulk-Wave Ultrasonic Velocity and Attenuation Measurements"J.Acoust.Soc.Am.. 108. 564-573 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, Y.Ono, Y.Ohashi: "Experimental Considerations on Water-Couplant Temperature for Accurate Velocity Measurements by the LFB Ultrasonic Material Characterization System"IEEE Ultrasonics Symp. Proc.. 619-623 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, M.Miyashita: "Quantitative Evaluation of Fabrication Processes of Proton-Exchanged Layers in LiTaO_3 Optoelectronic Devices by the Line-Focus-Beam Ultrasonic Material Characterization System"J.Appl.Phys.. 89. 2017-2024 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, Y.Ono, Y.Ohashi, M.Arakawa: "Development of the Line-Focus-Beam Ultrasonic Material Characterization System"IEEE Trans. UFFC. 49. 99-113 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, Y.Ohashi, T.Ujiie: "Standardized Evaluation of Chemical Compositions of LiTaO_3 Single Crystals for SAW Devices Using the LFB Ultrasonic Material Characterization System"IEEE Trans.UFFC. 49. 454-465 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, I.Takanaga, S.Komatsuzaki, T.Ujiie: "Chemical Composition Dependences of the Acoustical Physical Constants of LiNbO_3 and LiTaO_3 Single Crystals"J. Appl. Phys.. 91. 6341-6349 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, M.Arakawa, R.Okabe: "High-Accuracy Standard Specimens for the Line-Focus-Beam Ultrasonic Material Characterization System"IEEE Trans.UFFC. 49. 827-835 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] I.Takanaga, J.Kushibiki: "A Method of Determining Acoustical Physical Constants for Piezoelectric Materials by Line-Focus-Beam Acoustic Microscopy"IEEE Trans.UFFC. 49. 893-904 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, Y.Ohashi, Y.Ono, T.Sasamata: "Evaluation and Improvement of Optical-Grade LiTaO_3 Single Crystals by the LFB Ultrasonic Material Characterization System"IEEE Trans.UFFC. 49. 905-914 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Miyashita, J.Kushibiki: "Evaluation of the Annealing Effect of Proton-Exchanged LiTaO_3 Optical Waveguides by the Line-Focus-Beam Ultrasonic Material Characterization System"J.Appl.Phys.. 92. 2861-2866 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Miyashita, J.Kushibiki: "Quantitative Characterization of the Fabrication Processes of Domain-Inverted Layers in LiTaO_3 by the Line-Focus-Beam Ultrasonic Material Characterization System"J.Appl.Phys.. 92. 3958-3966 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, Y.Ohashi, N.Mishima: "Calibration of Curie Temperatures for LiTaO_3 Signle Crystals by the LFB Ultrasonic Material Characterization System"IEEE Trans.UFFC. 50. 544-552 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, R.Okabe, M.Arakawa: "Precise Measurements of Bulk-Wave Ultrasonic Velocity Dispersion and Attenuation in Solid Materials in the VHF Range"J.Acoust.Soc.Am.. (in press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Cho, K.Ohara, A.Koike, H.Odagawa: "New Functions of Scanning Nonlinear Dielectric Microscopy -Higher-Order Measurement and Vertical Resolution-"Jpn.J.Appl.Phys.. 40. 3544-3548 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Cho, K.Ohara: "Higher Order Nonlinear Dielectric Imaging Using Scanning Nonlinear Dielectric Microscopy"Jpn.J.Appl.Phys.. 40. 4349-4353 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Ohara, Y.Cho: "Fundamental Study of Surface Layer on Ferroelectrics by Scanning Nonlinear Dielectric Microscopy"Jpn.J.Appl.Phys.. 40. 5833-5836 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Kushibiki, T.Okuzawa, J.Hirohashi, and Y.Ohashi: "Line-Focus-Beam Acoustic Microscopy Characterization of Optical-Grade LiTaO_3 Single Crystals"J.Appl.Phys.. Vol.87, No.9. 4395-4403 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Ono, and J.Kushibiki: "Experimental Study of Construction Mechanism of V(z) Curves Obtained by Line-Focus-Beam Acoustic Microscopy"IEEE Trans. UFFC. Vol.47, No.4. 1042-1050 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kushibiki, Y.Ohashi, and Y.Ono: "Evaluation and Selection of LiNbO3 and LiTaO3 Substrates for SAW Devices by the LFB Ultrasonic Material Characterization System"IEEE Trans. UFFC. Vol.47, No.4. 1068-1076 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kushibiki and M.Arakawa: "Diffraction Effects on Bulk-Wave Ultrasonic Velocity and Attenuation Measurements"J.Acoust. Soc.Am.. Vol.108, No.2. 564-573 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kushibiki, Y.Ono, and Y.Ohashi: "Experimental Considerations on Water-Couplant Temperature for Accurate Velocity Measurements by the LFB Ultrasonic Material Characterization System"IEEE Ultrasonics Symp.Proc.. 619-623 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kushibiki and M.Miyashita: "Quantitative Evaluation of Fabrication Processes of Proton-Exchanged Layers in LiTaO_3 Optoelectronic Devices by the Line-Focus-Beam Ultrasonic Material Characterization System"J.Appl.Phys.. Vol.89, No.4. 2017-2024 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kushibiki, Y.Ono, Y.Ohashi, and M.Arakawa: "Development of the Line-Focus-Beam Ultrasonic Material Characterization System"IEEE Trans.UFFC. Vol.49, No.1. 99-113 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kushibiki, Y.Ohashi, and T.Ujiie: "Standardized Evaluation of Chemical Compositions of LiTaO_3 Single Crystals for SAW Devices Using the LFB Ultrasonic Material Characterization System"IEEE Trans. UFFC. Vol.49, No.4. 454-465 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kushibiki, I.Takanaga, S.Komatsuzaki, and T.Ujiie: "Chemical Composition Dependences of the Acoustical Physical Constants of LiNbO_3 and LiTaO_3 Single Crystals"J,Appl,Phys.. Vol.91, No.10. 6341-6349 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kushibiki, M.Arakawa, and R.Okabe: "High-Accuracy Standard Specimens for the Line-Focus-Beam Ultrasonic Material Characterization System"IEEE Trans. UFFC. Vol.49, No.6. 827-835 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] I.Takanaga and J.Kushibiki: "A Method of Determing Acoustical Physical Constants for Piezoelectric Materials by Line-Focus-Beam Acoustic Microscopy"IEEE Trans. UFFC. Vol.49, No.7. 893-904 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kushibiki, Y.Ohashi, Y.Ono, and T.Sasamata: "Evaluation and Improvement of Optical-Grade LiTaO_3 Single Crystals by the LFB Ultrasonic Material Characterization System"IEEE Trans. UFFC. Vol.49, No.7. 905-914 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Miyashita and J.Kushibiki: "Evaluation of the Annealing Effect of Proton-Exchanged LiTaO_3 Optical Waveguides by the Line-Focus-Beam Ultrasonic Material Characterization System"J,Appl,Phys.. Vol.92, No.5. 2861-2866 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Miyashita and J.Kushibiki: "Quantitative Characterization of the Fabrication Processes of Domain-Inverted Layers in LiTaO_3 by the Line-Focus-Beam Ultrasonic Material Characterization System"J,Appl,Phys.. Vol.92, No.7. 3958-3966 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kushibiki, Y.Ohashi, and N.Mishima: "Calibration of Curie Temperatures for LiTaO_3 Signle Crystals by the LFB Ultrasonic Material Characterization System"IEEE Trans. UFFC. Vol.50, No.5. 544-552 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kushibiki, R.Okabe, and M.Arakawa: "Precise Measurements of Bulk-Wave Ultrasonic Velocity Dispersion and Attenuation in Solid Materials in the VHF Range"J.Acoust.Soc.Am.. in press. (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Cho, K.Ohara, A.Koike, and H.Odagawa: "New Functions of Scanning Nonlinear Dielectric Microscopy -Higher-Order Measurement and Vertical Resolution-"Jpn.J.Appl.Phys.. Vol.40, No.5B. 3544-3548 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Cho and K.Ohara: "Higher Order Nonlinear Dielectric Imaging Using Scanning Nonlinear Dielectric Mictoscopy"Jpn.J.Appl.Phys.. Vol.40, No.6B. 4349-4353 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Ohara and Y.Cho: "Fundamental Study of Surface Layer on Ferroelectrics by Scanning Nonlinear Dielectric Microscopy"Jpn.J.Appl.Phys.. Vol.40, No.9B. 5833-5836 (2001)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2004-04-14  

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