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2001 Fiscal Year Final Research Report Summary

Development of Polarizer Using Anisotropic Light Scattering in Polymer

Research Project

Project/Area Number 12555003
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Applied materials science/Crystal engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

TOKITA Masatoshi  Tokyo Institute of Technology, Assist. Prof., 大学院・理工学研究科, 助手 (30301170)

Co-Investigator(Kenkyū-buntansha) FURUKI Makoto  Fiji Xerox Co. Ltd., Senior Researcher, 総合研究所, 主任研究員
OGINO Kenji  Tokyo Univ. of Agri. & Tech., Assoc. Prof., 大学院・生物システム応用科学研究科, 助教授 (10251589)
WATANABE Toshiyuki  Tokyo Univ. of Agri. & Tech., Assoc. Prof., 工学部, 助教授 (10210923)
Project Period (FY) 2000 – 2001
KeywordsPolymer / Polymer blends / Polarizer / Light scattering / Polycarbonate / Birefringence / Fiber
Research Abstract

We demonstrate optical characteristics of polymeric linear polarizers produced from oriented two-component amorphous polymer blends. Refractive index of dispersed phase of blend is closely to ordinary refractive index of birefringent continuous phase, while refractive index mismatch is simultaneously generated in the perpendicular direction. Films are therefore transparent or opaque depending on the polarization direction of the incident light.
However, both transmittance and polarizing efficiency measured by UV-VIS spectra depends on incident wavelength, which is ascribed to wavelength dependence of light scattering by small particles. To eliminate this character, we tried to increase length of dispersed phase to drawing direction. By changing dispersed phase contents, we could control particle (dispersed phase) size to the perpendicular direction, but could not increase particle size to the drawing direction.
So we introduce aligned fibers in polymer matrix instead of dispersed phase, … More which increase particle size to the refractive index mismatch direction. Both transmittance and polarizing efficiency were drastically improved.
It was found that the sum of the light intensities in the forward and backward direction approaches unity, which indicates that light losses due to, for instance, absorption are virtually eliminated. In the opaque state, a large portion of the incident light (80 %) is scattered in the backward direction, whereas in the transparent state 90 % of the incident light is transmitted in the forward direction. This feature is especially useful in devices that are constructed to recycle light and that are designed to enhance the efficiency to produce polarized light from natural light.
Apart from a high efficiency to produce linearly polarized light, the polarizers possess a variety of other potential advantages. In comparison to dichroic polarizers, an enhanced temperature and humidity resistance and an enhanced light stability are expected, which are useful properties in, for instance, projection displays, projection screens, and displays in automotive dashboards. Less

  • Research Products

    (40 results)

All Other

All Publications (40 results)

  • [Publications] M.Nakao, K.Ogino, H.Sato, Y.Ito: "Synthesis and Characterization of Crosslinkable Hole Transporting Polymers"Koubunshi Ronbunshu. 57. 1-7 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Furukawa, O.Uchinokura, Y.Takahashi, M.Tokita, K.Osada J.Watanabe: "Dieletric Relaxation and Molecular Motion in the Chiral Main-chian Liquid Crystalline Polymer"Polym. J.. 32. 122-126 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kada, A.Obara, T.Watanabe, S.Miyata, C.X.Liang, H.Machida, K.Kiso: "Thermotropic Liquid Crystals of Main-chain Polyesters Having a Mesogenic 4,4"-Biphenyldicarboxylate Unit. 13. Characteristic Deformation of Smetic Layer Structure Induced by Elongation of Uniaxially Oriented Fiber Composed of Smectic CA Glass"J. Appl. Phys. 87. 638-642 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tokita, J.Watanabe: "Red Light-Emitting Organic Electroluminescent Devices with Bisanil Dye as Emitter"Macromolecules. 33. 7420-7425 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.-H.Park, K.Ogino, H.Sato: "Synthesis and Characterization of Photorefractive Polymers with Triphenylamine Unit and NLO Chromophore Unit on Side Chain"Polymers for Advanced Technology. 11. 349-358 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] X.Wang, Z.Chen, K.Ogino, H.Sato, S.Miyata, H.Tan: "Synthesis of New Hole Transport Polymers Basedon N, N'-diphenyl-N, N'-bis(4-methylphenyl)-1,4-phenylenediamine"Polym. J. 32. 778-783 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Fu, T.Nematsu, M.Sone, T.Itoh, T.Hayakawa, M.Ueda, M.Tokita, J.Watanabe: "Aromatic Polyesters with Flexible Side Chains. 8. Studies on Long Periodical Structure Observed in Layerd"Macromolecules. 33. 8367-8370 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Z.Chen, J.Yu, M.Tokita, S.Miyata: "The Full-Width at Half-Maximum of Emission Narrowing in Electroluminescent Devices"J. Phys. D : Apply. Phys. 33. 1643-1646 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Suzuki, D.C.Zou, T.Izumi, H.Yamamoto, X.T.Tao, T.Watanabe, S.Miyata: "Luminescence of Dye Doped Polymer Films Induced by Corona Discharge"J. Appl. Phys.. 88. 5791-5795 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.-H.Lee, T.Watanabe, K.Kagoshima, S.Fujita, S.Mashiko, M.Talukder, G.A.Lindsay, W.N.Herman.K.Wynne, S.Miyata: "Orientation of Main-Chain Accordion Polymers Having Different Alkyl Chains"Mol. Cryst. Liq. Cryst.. 349. 171-174 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Li, J.Yu, Z.Chen, K.Totani, T.Watanabe, S.Miyata: "New Red Electroluminescent Devices using Tris(2,2'-bipyridine) Ruthenium (II) Hexafluorophospahte as Emitter"Jpn. J. Appl. Phys.. L1171-L1173 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kada, A.Obara, T.Watanabe, S.Miyata, C.X.Liang, H.Machida, K.Kiso.H.Shirai: "Refractive Index Changes of Nitrone Derivatives by Use of Photochemical Reaction"Nonlinear. Opt.. 24. 111-116 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Yu, Z.Chen, T.Watanabe, S.Miyata: "Influence of Sensitizer on Organic Electro luminescence"J. Apply. Phys.. 89. 7895-7898 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Sakuratani, M.Asai, M.Tokita, S.Miyata: "Enhanced Electron Injection and Electroluminescence in Polu(N-vinyl carbazole) Film Doped with Ammonium Salt"Synth. Met. 123. 207-210 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Sakuratani, T.Watanabe, S.Miyata: "All-wet fabrication of an organic electroluminescent device"Thin Solid Films. 388. 256-259 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.M.Kuebler, M.Rumi, T.Watanabe, K.Braun, B.H.Cumpston, A.A.Heikal, L.L.Erskine, S.Thayumanavan, S.Barlow, S.R.Marder, J.W.Perry: "Optimizing Two-Photon Initiators and Exposure Conditions for Three-Dimensional Lithographic Microfabrication"J. Photopoly. Sci. Tech.. 14. 657-668 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.S.Yu, Z.J.Chen, M.Sone, S.Miyata ; M.Li, T.Watanabe: "Red Light-Emitting Organic Electroluminescent Devices with Bisanil Dye as Emitte"Jpn. J. Appl. Phys. 40. 3201-3205 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Itoh, N.Tomikawa, M.Yamada, M.Tokita, A.Hirao, J.Watanabe: "Side-Chain Liquid Crystalline Block Copolymers with Well Defined Structures Prepared by Living Anionic Polymerization. Part IV. Microphase Morphology in Blends with Coil Homopolystyrenes"Polym. J. 33. 783-791 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Sato, K.Ogino, H.Hirai: "Preparation of Hole Transporting Polymers by Condensation Polymerization of Triphenylamine Derivatives"Macromolecular Symposia. 175. 159-168 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] X.Wang, M.Nakao, K.Ogino, H.Sato, H.Tan: "Synthesis and Characterization of New Triarylamine-Based Polymers"Macromolecular Chemistry and Physica. 202. 117-125 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M. Nakao, K. Ogino, H. Sato, Y. Ito: "Synthesis and Characterization of Crosslinkable Hole Transporting Polymers"Koubunshi Ronbunshu. 57(1). 1-7 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Furukawa, O. Uchinokura, Y. Takahashi, M. Tokita, K. Osada, J. Watanabe: "Relaxation and Molecular Motion in the Chiral Main-chian Liquid Crystalline Polymer"Polym. J.. 32(2). 122-126 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Kada, A. Obara, T. Watanabe, S. Miyata, C. X Liang, H. Machida, K. Kiso: "Fabrication of Refractive Index Distributions in Polymer Using a Photochemical Reaction"J. Appl. Phys.. 87. 638-642 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Tokita, J. Watanabe: "Thermotropic Liquid Crystals of Main-chain Polyesters Having Mesogenic 4,4"-Biphenyldicarboxylate Unit. 13 Characteristic Deformation of Smectic Layer Structure Induced by Elongation of Uniaxially Oriented Fiber Composed of Smectic CA Glass"Macromolecules. 33(20). 7420-7425 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.-H. Park, K. Ogino, H. Sato: "Synthesis an Characterization of Photorefractive Polymer with Triphenylamine Unit and NLO Chromophore Unit on Side Chain"Polymers for Advanced Technology. 11(7). 349-358 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X. Wang, Z. Chen, K. Ogino, H. Sato, S. Miyata, H. Tan: "Synthesis of New Hole Transport Polymers Basedon N,N'-diphenyl-N,N'-bis(4-memyipfienyl ) - l ,4 -phenylenediamine"Polym. J.. 32(9). 778-783 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Fu, T. Nematsu, M. Sone, T. Itoh, T. Hayakawa, M. Ueda, M. Tokita, J. Watanabe: "Aromatic Polyesters with Flexible Side Chains. 8. Studies on Long Periodical Structure Observed"Macromolecules. 33(22). 8367-8270 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Z. Chen, J. Yu, M. Tokita, S. Miyata: "The Full-Width at Half-Maximum of Emission Narrowing in Electroluminescent Devices"J. Phys. D: Appl. Phys.. 33. 1643-1646 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Suzuki, D. C. Zou, T. Izumi, H. Yamamoto, X. T. Tao, T. Watanabe, S. Miyata: "Luminescence of Dye Doped Polymer Films Induced by Corona Discharge"J. Appl. Phys.. 88. 5791-5795 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. -H. Lee, T. Watanabe, K. Kagoshima, S Fujita, S. Mashiko, M. Talukder, G. A. Lindsay, W. N. Herman, K. Wynne, S. Miyata: "Orientation of Main-Chain Accordion Polymers Having Different Alkyl Chain"Mol. Cryst. Liq: Cryst. 349. 171-174 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Li, J. Yu, Z. Chen, K. Totani, T. Watanabe, S. Miyata: "New Red Electroluminescent Devices using Tris(2,2'-bipyridine) Ruthenium (II) Hexafluorophosphate as Emitter"Jpn. J. Appl. Phys.. 1171-L1173 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Kada, A. Obara, T. Watanabe, S. Miyata, C. X. Liang, H. Machida, K. Kiso, H. Shirai: "Refractive Index Changes of Nitrone Derivatives by Use of Photochemical Reaction"Nonlinear. Opt.. 24. 111-116 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J. Yu, Z. Chen, T. Watanabe, S. Miyata: "Influence of. Sensitizer on Organic Electro luminescence"J. Appl. Phys.. 89. 7895-7898 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Sakuratani, M. Asai, M. Tokita, S. Miyata: "Enhanced Electron injection and Electroluminescence in Polu(N-vinyl carbazole) Film Doped with Ammonium Salt"Synth. Met.. 123(2). 207-210 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Sakuratani, T. Watanabe, S. Miyata: "All-wet fabrication of an organic electroluminescent device"Thin Solid Films. 388. 256-259 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. M. Kuebler, M. Rumi, T. Watanabe, K. Braun, B. H. Cumpston, A. A. Heikal, L. L. Erskine, S. Thayumanavan, S. Barlow, S. R. Marder, and J. W. Perry: "Optimizing Two-Photon Initiators and Exposure Conditions for Three-Dimensional Lithograp hic Micro fabrication"J. Photopoly. Sci. Tech.. 14(4). 657-668 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J. S. Yu, Z. J. Chen, M. Sone, S. Miyata; M. Li, T. Watanabe: "Red Light-Emitting Organic Electroluminescent Devices with Bisanil Dye as Emitter"Jpn. J. Appl. Phys.. 40. 3201-3205 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Itoh, N. Tomikawa, M. Yamada, M. Tokita, A. Hirao, J. Watanabe: "Side-Chain Liquid Crystalline Block Copolymers with Well Defined Structures Prepared by Living Anionic Polymerization. Part IV. Microphase Morphology in Blends with Coil Homopolystyrenes"Polym. J.. 33(10). 783-791 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Sato, K. Ogino, H. Hirai: "Preparation of Hole Transporting Polymers by Condensation Polymerization of Triphenylamine Derivative"Macromolecular Symposia. 175. 159-168 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X. Wang, M. Nakao, K. Ogino, H. Sato, H. Tan,: "Synthesis and Characterization of New Triarylamine-Based Polymers"Macromolecular Chemistry and Physica. 202. 117-125 (2001)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2003-09-17  

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