2000 Fiscal Year Annual Research Report

二次非線形光学顕微鏡(SHGM)の開発に関する研究

Research Project

Project/Area Number	12555240
Research Institution	Utsunomiya University
Principal Investigator	加藤貞二宇都宮大学, 工学部, 教授 (60008068)
Co-Investigator(Kenkyū-buntansha)	飯村兼一宇都宮大学, 工学部, 助手 (10272220) 鈴木昇宇都宮大学, 工学部, 助教授 (40134259) 葭田真昭宇都宮大学, 工学部, 助教授 (90114173)
Keywords	単分子膜 / 二次非線形光学 / YAGレーザー / ブルースター角顕微鏡
Research Abstract	この研究は、固体または液体の表面を1064nmの波長のYAGレーザーの光で照射し、このとき発生する二次非線形光(532nmの可視部の光)で、固体または液体の表面の構造を眼で見えるようにする顕微鏡(SHGM)を開発することを目的としている。ただし、表面からの強い反射光を避けるために、入射角を固体または液体のブルースター角にあわせ、しかも完全なP偏光にする必要があり、YAGレーザー(HOYA、Continuum,Minilite II-10)は垂直面内で角度を変更できるゴニオメーターに取り付けた。このゴニオメーターの反対の腕にはズームできる、作動距離の長い顕微鏡(キーエンス、VQ-Z50)をとりつけ、像の検出には弱い二次非線形光を検出できる超高感度CCDカラーカメラ(FLOVEL,HCC-600)をとりつけた。入射角および反射角はゴニオメーターの角度を変えるシンクロナスモーターによって、垂直から45-75度の範囲で可変できる。この装置を水面の単分子膜に適用するための、この装置に組み合わせるコンピュータ制御のLangmuir水槽装置はまだ完成していない。SHGM本体はほとんど出来上がっているが、本体の性能試験もまだおこなっていない。この研究は2年間の継続であり、新しい年度に入ったら早速SHGM本体の性能試験に取り掛かれるよう、研究を進めている。

Research Products
(17 results)

All Other

All Publications (17 results)

[Publications] Y.Ren,K.Iimura,A.Ogawa,T.Kato: "Sutface Micelles of a Partially Fluorinated Long-Chain Acid on Aqueous La^<3+> Investigated by AFM and FT-IR Spectroscopy"J.Phys.Chem., B. (accepted). (2001)
[Publications] Y.Ren,K.Iimura,T.Kato: "Crystal Lattice Transitions of Behenic Acid Monolayers on Pure Water Surface by Polarization Modulation IR Spectroscopy"J.Chem.Phys.,. (in press). (2001)
[Publications] Y.Ren,K.Iimura,T.Kato: "Structure of Barium Stearate Films st Air/Water Interface Investigated by Polarization Modulation IR Spectroscopy"Langmuir,. (in press). (2001)
[Publications] M.M.Hossain,T.Suzuki,T.Kato: "Phase Behavior of n-Hexadecyl Phosphate in Gibbs Adsorption Layers"Colloids and Surfaces A,. (in press). (2001)
[Publications] M.M.Hossain,T.Okano,T.Kato: "Crystal Lattice of Cadmium Alkanoate Monolayers at the Air/water Interface Investigated by Polarization Modulation IR Spectroscopy"J.Chem.Phys.,. Vol.114. 1945-1951 (2001)
[Publications] M.M.Hossain,T.Kato: "Line Tension Induced Instability of Condensed Domains Formed in Adsorbed Monolayers at the Air/Water Interface"Langmuir,. Vol.16. 10175-10183 (2000)
[Publications] Y.Ren,K.Iimura,T.Kato: "Substrate and Chain Length Dependencies of the Thermal Behavior of Partially Fluorinated Acid Salts Investigated by IRRAS"J.Chem.Phys.,. Vol.114. 923-930 (2000)
[Publications] K.Iimura,T.Kato: "Comparative Studies on Thermal, Solvent, pH, and Mechanical Resistance 1-Layer LB Films and SA Films of Alkylchlorosilanes"Colloids and Surfaces A,. Vol.171. 249-264 (2000)
[Publications] Y.Ren,K.Iimura,T.Kato: "Polarization IR Study on the Structure of Two-Dimensional Nanoclusters of Partially Fluorinated Long-Chain Acid Salts"J.Chem.Phys.,. Vol.113. 1162-1169 (2000)
[Publications] K.Iimura,T.Kato: "A Study on Structures and Formation Mechanisms of SA Monolayers of n-Alkyltrichlorosilanes by IR Spectroscopy and AFM"Thin Solid Films,. Vol.379. 230-239 (2000)
[Publications] 加藤貞二: "プローブ顕微鏡による単分子膜系のダイナミクス(総説)"表面科学(日本表面科学会誌). Vol.21. 608-614 (2000)
[Publications] 加藤貞二: "単分子膜系における構造観察と緩和現象(総説)"日本油化学会誌,. Vol.49. 1089-1098 (2000)
[Publications] Y.Ren,K.Iimura,T.Kato: "Monodispersed Two-Dimensional Nano-Clusters of a Partially Fluorinated Acid on the Aqueous Cd^<2+> Subphase by FT-IR"Chem.Phys.Lett.,. Vol.322. 339-346 (2000)
[Publications] M.M.Hossain,T.Suzuki,T.Kato: "Unusual Transition in a Two-Dimensional Condensed Phase to a Mosaic Texture"Langmuir,. Vol.16. 9109-9112 (2000)
[Publications] Y.Ren,M.M.Hossain,K.Iimura,T.Kato: "Orthrhombic Structure of Cadmium Behenate Monolayers on the Water Surface detected by Polarization Modulation IR Spectroscopy"Chem.Phys.Lett.,. Vol.325. 503-507 (2000)
[Publications] M.M.Hossain,M.Yoshida,T.Kato: "Higher Order Structure Formation in Adsorbed Monolayers at Aqueous Solution Surfaces Studied by BAM"Langmuir,. Vol.16. 3345-3348 (2000)
[Publications] M.M.Hossain,M.Yoshida,K.Iimura,T.Kato: "Phase Transition in Adsorbed Monolayers of 2-Hydroxyethyl Laurate at the Air/Water Interface"Colloids and Surfaces A,. Vol.171. 105-113 (2000)

2000 Fiscal Year Annual Research Report

二次非線形光学顕微鏡(SHGM)の開発に関する研究

Principal Investigator

加藤 貞二 宇都宮大学, 工学部, 教授 (60008068)

Research Products

[Publications] Y.Ren,K.Iimura,A.Ogawa,T.Kato: "Sutface Micelles of a Partially Fluorinated Long-Chain Acid on Aqueous La^<3+> Investigated by AFM and FT-IR Spectroscopy"J.Phys.Chem., B. (accepted). (2001)

[Publications] Y.Ren,K.Iimura,T.Kato: "Crystal Lattice Transitions of Behenic Acid Monolayers on Pure Water Surface by Polarization Modulation IR Spectroscopy"J.Chem.Phys.,. (in press). (2001)

[Publications] Y.Ren,K.Iimura,T.Kato: "Structure of Barium Stearate Films st Air/Water Interface Investigated by Polarization Modulation IR Spectroscopy"Langmuir,. (in press). (2001)

[Publications] M.M.Hossain,T.Suzuki,T.Kato: "Phase Behavior of n-Hexadecyl Phosphate in Gibbs Adsorption Layers"Colloids and Surfaces A,. (in press). (2001)

[Publications] M.M.Hossain,T.Okano,T.Kato: "Crystal Lattice of Cadmium Alkanoate Monolayers at the Air/water Interface Investigated by Polarization Modulation IR Spectroscopy"J.Chem.Phys.,. Vol.114. 1945-1951 (2001)

[Publications] M.M.Hossain,T.Kato: "Line Tension Induced Instability of Condensed Domains Formed in Adsorbed Monolayers at the Air/Water Interface"Langmuir,. Vol.16. 10175-10183 (2000)

[Publications] Y.Ren,K.Iimura,T.Kato: "Substrate and Chain Length Dependencies of the Thermal Behavior of Partially Fluorinated Acid Salts Investigated by IRRAS"J.Chem.Phys.,. Vol.114. 923-930 (2000)

[Publications] K.Iimura,T.Kato: "Comparative Studies on Thermal, Solvent, pH, and Mechanical Resistance 1-Layer LB Films and SA Films of Alkylchlorosilanes"Colloids and Surfaces A,. Vol.171. 249-264 (2000)

[Publications] Y.Ren,K.Iimura,T.Kato: "Polarization IR Study on the Structure of Two-Dimensional Nanoclusters of Partially Fluorinated Long-Chain Acid Salts"J.Chem.Phys.,. Vol.113. 1162-1169 (2000)

[Publications] K.Iimura,T.Kato: "A Study on Structures and Formation Mechanisms of SA Monolayers of n-Alkyltrichlorosilanes by IR Spectroscopy and AFM"Thin Solid Films,. Vol.379. 230-239 (2000)

[Publications] 加藤貞二: "プローブ顕微鏡による単分子膜系のダイナミクス(総説)"表面科学(日本表面科学会誌). Vol.21. 608-614 (2000)

[Publications] 加藤貞二: "単分子膜系における構造観察と緩和現象(総説)"日本油化学会誌,. Vol.49. 1089-1098 (2000)

[Publications] Y.Ren,K.Iimura,T.Kato: "Monodispersed Two-Dimensional Nano-Clusters of a Partially Fluorinated Acid on the Aqueous Cd^<2+> Subphase by FT-IR"Chem.Phys.Lett.,. Vol.322. 339-346 (2000)

[Publications] M.M.Hossain,T.Suzuki,T.Kato: "Unusual Transition in a Two-Dimensional Condensed Phase to a Mosaic Texture"Langmuir,. Vol.16. 9109-9112 (2000)

[Publications] Y.Ren,M.M.Hossain,K.Iimura,T.Kato: "Orthrhombic Structure of Cadmium Behenate Monolayers on the Water Surface detected by Polarization Modulation IR Spectroscopy"Chem.Phys.Lett.,. Vol.325. 503-507 (2000)

[Publications] M.M.Hossain,M.Yoshida,T.Kato: "Higher Order Structure Formation in Adsorbed Monolayers at Aqueous Solution Surfaces Studied by BAM"Langmuir,. Vol.16. 3345-3348 (2000)

[Publications] M.M.Hossain,M.Yoshida,K.Iimura,T.Kato: "Phase Transition in Adsorbed Monolayers of 2-Hydroxyethyl Laurate at the Air/Water Interface"Colloids and Surfaces A,. Vol.171. 105-113 (2000)

加藤貞二宇都宮大学, 工学部, 教授 (60008068)