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2002 Fiscal Year Final Research Report Summary

A Pulsed Slow Positron Beam Apparatus and its Application to Thin Polymer Films

Research Project

Project/Area Number 12555270
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 高分子構造・物性(含繊維)
Research InstitutionHigh Energy Accelerator Research Organization

Principal Investigator

SUZUKI Takenori  Applied Research Laboratory, Professor, 放射線科学センター, 教授 (40162961)

Co-Investigator(Kenkyū-buntansha) NUMAJIRI Masaharu  Applied Research Laboratory, Research Associate, 放射線科学センター, 助手 (20189385)
MIURA Taichi  Applied Research Laboratory, Associate Professor, 放射線科学センター, 助教授 (80209717)
KONDO Kenjiro  Applied Research Laboratory, Professor, 共通研究施設, 教授 (20004434)
何 春清  高エネルギー加速器研究機構, 放射線科学センター, COE研究員
HE Chun-Qing  Applied Research laboratory ; COF Scientist
Project Period (FY) 2000 – 2002
Keywordspositron annihilation / pulsed beam / radio isotopes / slow positron / polymer / surface / thin film / free volume / Low K film
Research Abstract

In order to study the surface of polymers, a pulsed slow positron beam (PSPB) is necessary to determine the injection time in the investigated polymer. Commonly PSPB is made using a linear accelerator, which need large facility. In this project, a small apparatus desk-top size has been built using radio isotopes. The bunched and pulsing beam was obtained by the RF method, in which RF field is applied on a Al tube with 2cm diameter and 5cm length. The length is determined by the flight time of positions through the tube. Thus 40 MHz RF is used to bunch the rundum beam to a bunched beam. The width is 500 to 600ps, which is enough to study polymer samples, which have lifetimes longer than 1.5ns to 2 ns. In order to get a beam with 300pswidth, it is required another main buncher.
In this project, the apparatus to obtain a pulsed and bunched beam has been successfully built and applied to measure lifetimes of polymers : polyethylene, epoxy resin, epoxy composite, epoxy coated films on a Silicon metal.
In this application, the heat expansion coefficient of the surface and the bulk of epoxy resin was obtained. The increase in the positronium formation with increasing the depth was observed in polyethylene. The skin layer of the composite materials was observed by a non destructive method. Low K films on Silicon plate, which are extensively used in 1C and electric industry has been studied. Large holes with about 50 ns positron lifetime hasbeen successfully observed

  • Research Products

    (28 results)

All Other

All Publications (28 results)

  • [Publications] 伊藤泰男, 鈴木健訓: "Effects of electric field on positronium formation in polystylene at various temperature"Radiation Physics and Chemistry. 66. 343-347 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 鈴木健訓, HE C.Q., 他: "The influence of radiation and light on Ps formation in PMMA and PE studied by coincidence Doppler-broadening spectroscopy"Radiation Physics and Chemistry. 66. 161-166 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] HE C.Q., 鈴木健訓, 他: "Characterization of polymer sub-surface using slow positron beam"Journal of Radioanalytical and Nuclear Chemistry. 255. 431-435 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Shantarovich, 鈴木健訓, 他: "A possibility to study substance properties using positronium as the simplest "Labeled" atom"Journal of Radioanalytical and Nuclear Chemistry. 255. 165-170 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] HE C.Q., 鈴木健訓, 他: "Positron annihilation in hypercrosslinked polystylenes"Chemical Physics. 286. 249-256 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] HE C.Q., 鈴木健訓, 他: "Characterization of polymer films using a slow positron beam"Material Research Innovations. 7. 37-41 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 鈴木健訓, HE C.Q., 他: "Relaxation Behavior of Polymers Probed by Positron Annihilation Lifetime Spectroscopy"Material Research Innovations. 7. 31-36 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Shantarovich, 鈴木健訓, 他: "Inhibition of positronium formation by polar groups in polymers-relation with TSL exp."Radiation Physics and Chemistry. 67. 15-23 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Shantarovich, 鈴木健訓, 他: "Positron annihilation study of hyper-cross-linked polystylene networks"Macromolecule. 35. 9723-9729 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Uchiyama H., 鈴木健訓: "The study of 1/I-AlCuRuSi approximate phase by positron annihilation method"Journals of Alloys and Compounds. 342. 153-155 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Goworek T., 鈴木健訓, 他: "On possible deviations of experimental PALS data from positronium pick-off model estimates"Chemical Physics. 280. 295-307 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 熊木, 鈴木, 何春清, 陶: "低速陽電子短パルス化装置を用いた表面自由体積の研究"ネットワークポリマー. 23. 24-31 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] HE C.Q., 鈴木健訓, 他: "Molecular motions at low temperature observed by positron annihilation"Physics Letters. A304. 49-53 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Matsuo M., 鈴木健訓, 他: "Characteristics of ultra-drawn polyethylene films as a function of temperature estimated by the positron annihilation lifetime method"Macromolecule. 35. 3059-3065 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Ito Y. and Suzuki T.: "Effects of electric field on positronium formation in pjolystylene at various temperature"Rad. Phys. Chem.. 66. 343-347 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Siizuki T., He C.Q., Shantarovich V., +4 authors: "The influence of radiation and light on Ps forraati on ir PMMA and PE studied by coincidence Dopplerbroadening spectroscopy"Rad. Phys. Chem.. 66. 161-166 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] HE, C.Q., Suzuki, T., +5 authors: "Characterization of polymer sub-surface using slow positjron beam"J. Radioanaly. Nuc. Chem. 255. 431-435 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shantarovich, V.P., Suzuki, T., and HE, C.Q.: "A possibility to study substance properties using posit|ronium as the simplest Labeled atom"J. Radioanal. Nuc. Chem.. 255. 165-170 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] He, C.Q., Suzuki, T., Kondo, +2 authors: "Positron annihilation in hypercrosslinked polysltylenes"Chemical Physics. 286. 249-256 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] He, C.Q., Suzuki, T., +5 authors: "Characterization of polymer films using a slow positpron beam Materlial Research Innovations (Mat. Res. Innovat.) 7 (20103) 37-41"Mat. Research Innovations. 7. 37-41 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Slizuki, T., He, C.Q., +5 authors: "Relaxation Behavior of Polymers Probed by Positron Annihilation Lifetime Spectroscopy"Mat. Research Innovations. 7. 31-36 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shantarovich V., Suzuki T., 0 authors: "Inhibition of positroniura formation by polar groups in polymers - relation with TSL experiments"Rad. Phys. Chem.. 67. 15-23 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shantarovich, V., Suzuki, T., +6 authors: "Positronannihilation study ofhyper-cross-linke dpolys|tylene networks"Macromolecule. 35. 9723-9729 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Uchiyarama, H.,Hamada, E., Suzuki T.,+ 6 authors: "The study of 1/1-AlCuRuSi approximate phase by pos itron annihilation method"J. of Alloys and Compounds. 342. 153-155 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Goworek T, Jasinska B., Suzuki T., +2 authors: "On possible deviations of experimental PALS data from positronium pick-off model estimates"Chera. Phys.. 280. 295-307 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kumaki T., Sue H., HE C.Q., Suzuki T.: "Free-volume near the polymer surface studied by positron annihilation using short-pulsed slow positron beam (in Japanese)"Network Polymer. 23. 24-31 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Chunqing He, Takenori Suzuki, +5 authors: "Molecular motions at low temperature observed by positron annihilation"Physics Letters. A 304. 49-53 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Matsuo M., Ma Lin, Suzuki T., 0 authors: "Characteristics of ultra-drawn polyethylene films as a function of temperature estimated by the positr on annihilation lifetime method"Macromolecules. 35. 3059-3065 (2002)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2004-04-14  

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