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2001 Fiscal Year Final Research Report Summary

Structural analysis and physical properties of High-Pressure and Low-Temperature Phases of Solid Oxygen

Research Project

Project/Area Number 12640321
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅰ(光物性・半導体・誘電体)
Research InstitutionHimeji Institute of Technology

Principal Investigator

AKAHAMA Yuichi  Himeji Institute of technology Faculty of Science, Assistant, 理学部, 助手 (90202522)

Project Period (FY) 2000 – 2001
Keywordssolid oxygen / insulator-metal transition / molecular dissociation / phase transition / molecular magnetism / high pressure / x-ray diffraction / infrared absorption
Research Abstract

The phase transition of solid oxygen has been investigated at low-temperatures of 19 K, 180 K and 240 K and at high-pressures of up to 12 Gpa using monochromatic synchrotron x-ray diffraction techniques, and the phase relation among α-,β-δ-, and ε-0_2 has been revealed, based on the structural data. The monoclinic α-0_2 phase at 19K, with increasing pressure, directly transformed to theε-0_2 phase at 7.6 Gpa. The α-δ phase boundary was located on a higher temperature region than 240 K and the α-0_2 phase was stable over a wide pressure and temperature range. The b/a ratio of the lattice constants at 19 K exhibited a monotonic increase with pressure and reached 0.708 at 7.6 GPa, while it abruptly decreased to 0.690 by the α-ε transition. From the anisotropy of compressibility, the existence of a collinear antiferromagnetic order in the α-0_2 phase was confirmed at pressure up to 7.2 Gpa. The equation of state of the α-0_2 phase at 19 K has also been determined.
The structure and lattice … More compression of β-0_2 phase have been studied at 277 K and 300 K. The pressure dependence of lattice constants, a and c, obtained from a powder indicated an anisotropic compressibility, a is almost seven times as compressible as c.This large linear compressibility of a may be attributed to the antiferromagnetic interaction in the basal plane. An analogy of the lattice deformation between the α-δ and α-β phase transitions was also suggestive of the magnetic order in theδ phase.
The structure of the metallic ζpnase above 100 Gpa was determined to be a monoclinic lattice (SG : P2/m) with Z=2. This lattice consisted of 0_2 molecules. Therefore, this phase was concluded to be molecular semi metallic.
The single crystal growth of β, δ, and ε-0_2 phases and the structure analyses of these crystals were carried out at room temperature. The sample quality was very good and the full width at half maximum was about 0.005^o. The data collection was carried out by several methods. It is found that the thermal parameter in basal planeβ_<11>, was considerably large. Less

  • Research Products

    (18 results)

All Other

All Publications (18 results)

  • [Publications] Y.Akahama, H.Kawamura: "High-Pressure Infrared Spectroscopy of Solid Oxygen"Phys.Rev.B. 61. 8801-8805 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Akahama, H.Kawamura et al.: "Structural Stability and Equation of State of Simple-Hexagonal Phnophorus to 280GPa"Phys.Rev.B. 61. 3139-3143 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Akahama, H.Kawamura, O.Shimoura: "Structural Phase Transition of Solid Oxygen at Low-Temperature and High-Pressure"Phys.Rev.B. 64. 0541051-0541056 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kawamura, Y.Akahama et al.: "X-ray Poroder Diffraction from Solid Deuterium"Solid State Communications. 119. 29-32 (2001)

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      「研究成果報告書概要(和文)」より
  • [Publications] Y.Akahama, H.Kawamura et al.: "New δ(Distorted-bcc) Titanium to 220GPa"Phys.Rev.Lett.. 87. 2755031-2755034 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Akahama et al.: "Eguation of State of Bismuth to 220GPa and Comparison of gold and Platinum Pressure Scales to 145Gpa"J.Appl.Phys.. (in press). (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y. Akahama, M. Kobayashi and H. Kawamura: "Simple Cubic-Simple Hexagonal Transition in Phosphorus under Pressure"Phys. Rev. B. 59. 8520-25 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Nakahata, N. Matsui, Y. Akahama and H. Kawamura: "Structural Studies of Solid Methane at High Pressure"Chem. Phys. Lett. 302. 359-362 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Akahama, H. Kawamura, S. Carlson, T. Le Bihan and D. Hausermann: "Structural Stability and Equation of State of Simple-Hexagonal Phosphorus to 280 Gpa: Phase Transition at 262 Gpa"Phys. Rev.B. 61. 3139-42 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Akahama and H. Kawamura: "High-Pressure Infrared Spectroscopy of Solid Oxygen"Phys. Rev. B. 61. 8801-05 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Nakano, Y. Akahama, Y. Ohishi, and H. Kawamura: "Ruby Scale at Low Temperatures Calibrated by the NaCI Gauge: Wavelength Shift of Ruby R1 Fluorescence Line at High Pressure at Low Temperature"Jpn. J. Appl. Phys. 39. 1249-51 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Hirano, S. Uehara, A. Mori, A. Onodera, K. Takemura, O. Shimomura, Y. Akahama, and H. Kawamura: "High-Pressure Phase Transitions in AlSb"J. Phys. Chem. Solids. 62. 941-948 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Akahama, H. Kawamura, and 0. Shimomura:: "Structural phase transitions of Solid Oxygen at low-Temperature and High-Pressure"Phys. Rev. B. 64. 054105_1-6 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Akahama, H. Kawamura, and T. Le Bihan: "New (Distorted-bcc) Titanium to 220 Gpa"Phys. Rev, Lett. 87. 275503_1-4 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Kawamura, Y. Akahama, S. Umemoto, T. Takemura, Y. Ohishi, and 0. Shimomura: "X-ray powder diffraction from solid deuterium"Solid State Commun. 119. 29-32 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Akahama, H. Kawamura, and A. K. Singh: "Equation of state of bismuth to 222 Gpa and comparison of gold and platinum pressure scales to 145 Gpa"j. Appl. Phys. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Akahama, and H. Kawamura: "Optical and Electrical Studies on Band-Overlapped Metallization of Narrow-Gap Semiconductor of Black Phosphorus with Layered Structure"Rhys. Stat. Sol. (B). 223. 349-353 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Nakano. Y. Akahama, H. Kawamura, M. Takumi, and K. Nagata: "Pressure-Induced Metallization and Structural Transition of Orthorhombic Se"Phys. Stat. Sol. (B). 223. 397-400 (2001)

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Published: 2003-09-17  

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