2003 Fiscal Year Annual Research Report

液液界面ナノ領域の未開拓化学機能の開発

Research Project

Project/Area Number	13129101
Research Institution	Osaka University
Principal Investigator	渡會仁大阪大学, 大学院・理学系研究科, 教授 (30091771)
Co-Investigator(Kenkyū-buntansha)	KOVALENKO Andriy 岡崎国立共同研究機構, 分子科学研究所, 助手 (10332181) 澤田嗣郎東京大学, 大学院・新領域創成科学研究科, 教授 (90011105) 寺前紀夫東北大学, 大学院・理学研究科, 教授 (70114569) 後藤雅宏九州大学, 大学院・工学研究院, 教授 (10211921) 中谷清治筑波大学, 化学系, 助教授 (00250415)
Keywords	液液界面 / 界面構造 / 一分子計測 / 錯形成反応 / 界面分離工学 / 分子認識 / 界面不安定化 / 自己組織化
Research Abstract	平成15年度は、第4回の公開シンポジウムを7月24日、25日に日本化学会化学会館(東京)で開催し、第5回の公開シンポジウムを、12月3日、4日に大阪国際会議場(大阪)で開催した。第4回の公開シンポジウムには、来日中のProf.Unwin(Warwick大学)の界面のナノ電気化学計測の特別講演、と中林誠一郎先生の「極微極限反応場としての単泡性超音波発光気泡」の特別講演、及び、研究班から7件の講演と26件のポスター発表が行われた。第5回の公開シンポジウムでは、中村収先生、井上康志先生の「マイクロ/ナノ領域における新しい分光イメージング」と辻井薫先生の「二分子膜固定化ゲルの液/液界面機構」の特別講演、及び7件の講演と32件のポスター発表が行われた。それぞれの公開シンポジウムでは、要旨集No4、No5の発行があり、両会とも約80名の参加者が討論に参加した。これらの公開シンポジウムは、日本化学会、日本分析化学会及び日本溶媒抽出学会の協賛を得て行われ、日本化学会の「化学と工業」、日本分析化学会の「ぶんせき」等にプログラムが掲載された。両シンポジウムの際に、研究班の合同会議も開催され、共同研究の進捗状況、Anal.Sci.特集号の刊行、Kluwer社からの単行本"Interfacial Nanochemistry"の出版の企画準備について了承された。

Research Products

(10 results)

All Other

All Publications (10 results)

[Publications] Fujiwara Kazuhiko, Watarai Hitoshi: "Interfacial hydrolysis in the m-oxo dimer formation of tetraphenylporphinatomanganese(III) in the toluene/water system"Analytical Sciences. 20. 369-372 (2004)
[Publications] Watarai hitoshi, Tsukahara Satoshi, Nagatani Hirohisa, Ohashi Akira: "Interfacial Nannochemistry in liquid-liquid extraction systems"Bulletin of the Chemical Society of Japan. 76(8). 1471-1492 (2003)
[Publications] Suwa Masayori, Watarai Hitoshi: "Magnetophoretic velocity of microorganic droplets adsorbed by disprosium(III) laurate in water."Journal of Chromatography A. 1013. 3-8 (2003)
[Publications] Tokimoto Takahira, Tsukahara Satoshi, Watarai Hitoshi: "Measurements of interfacial complexation of samarium(III) and its fluorescent lifetime by micro-two-phase sheath flow/fluorescence microscopy"Chemistry Leters. 32(10). 940-941 (2003)
[Publications] Sasaki Naoko, Monjushiro Hideaki, Watarai Hitoshi: "Fabrication of a centrifugal liquid menbrane cell for a direct spectroscopic measurement of electlytic reaction in two-phase liquid-menbrane system"Bunseki Kagaku. 52(9). 701-705 (2003)
[Publications] Nishizawa Seiichi, Yokobori Tomoyuki, Kato Ryo, Yoshimoto Keitaro, Kamaishi Tomoyuki, Teramae Norio: "Hydrogen-bond forming ionophore for highly efficient transport of phosphate anions across the nitrobenzene-water interface."Analyst. 128(6). 663-669 (2003)
[Publications] Fujinami Masanori, Murakawa Hiromi, Sawada Tsuguo: "Highly sensitive detection of molecules at the liquid/liquid interface using total internal reflection-optical beam deflection based on photothermal spectroscopy"Review of Scientific Instruments. 74(1,Pt.2). 352-354 (2003)
[Publications] Chikama Katsumi, Negishi Takayuki, Nakatani Kiyoharu: "Transfer mechanism of dodecyl sulfate with methylene blue across an oil/water interface studied by single-droplet injection and microabsorption methods."Bulletin of the Chemical Society of Japan. 76(2). 295-299 (2003)
[Publications] A.Kovalenko, F.Hirata: "Molecular description of electrolyte solution in a carbon aerogel electrode"Condensed Matter Physics. 36. 583-609 (2003)
[Publications] Miyako Eijiro, Maruyama Tatsuo, Kamiya Noriho, Goto Masahiro: "Transport of organic acids through a supported liquid membrane driven by lipase-catalyzed reactions"Journal of Bioscience and Bioengineering. 96(4). 370-374 (2003)

2003 Fiscal Year Annual Research Report

液液界面ナノ領域の未開拓化学機能の開発

Principal Investigator

渡會 仁 大阪大学, 大学院・理学系研究科, 教授 (30091771)

Research Products

[Publications] Fujiwara Kazuhiko, Watarai Hitoshi: "Interfacial hydrolysis in the m-oxo dimer formation of tetraphenylporphinatomanganese(III) in the toluene/water system"Analytical Sciences. 20. 369-372 (2004)

[Publications] Watarai hitoshi, Tsukahara Satoshi, Nagatani Hirohisa, Ohashi Akira: "Interfacial Nannochemistry in liquid-liquid extraction systems"Bulletin of the Chemical Society of Japan. 76(8). 1471-1492 (2003)

[Publications] Suwa Masayori, Watarai Hitoshi: "Magnetophoretic velocity of microorganic droplets adsorbed by disprosium(III) laurate in water."Journal of Chromatography A. 1013. 3-8 (2003)

[Publications] Tokimoto Takahira, Tsukahara Satoshi, Watarai Hitoshi: "Measurements of interfacial complexation of samarium(III) and its fluorescent lifetime by micro-two-phase sheath flow/fluorescence microscopy"Chemistry Leters. 32(10). 940-941 (2003)

[Publications] Sasaki Naoko, Monjushiro Hideaki, Watarai Hitoshi: "Fabrication of a centrifugal liquid menbrane cell for a direct spectroscopic measurement of electlytic reaction in two-phase liquid-menbrane system"Bunseki Kagaku. 52(9). 701-705 (2003)

[Publications] Nishizawa Seiichi, Yokobori Tomoyuki, Kato Ryo, Yoshimoto Keitaro, Kamaishi Tomoyuki, Teramae Norio: "Hydrogen-bond forming ionophore for highly efficient transport of phosphate anions across the nitrobenzene-water interface."Analyst. 128(6). 663-669 (2003)

[Publications] Fujinami Masanori, Murakawa Hiromi, Sawada Tsuguo: "Highly sensitive detection of molecules at the liquid/liquid interface using total internal reflection-optical beam deflection based on photothermal spectroscopy"Review of Scientific Instruments. 74(1,Pt.2). 352-354 (2003)

[Publications] Chikama Katsumi, Negishi Takayuki, Nakatani Kiyoharu: "Transfer mechanism of dodecyl sulfate with methylene blue across an oil/water interface studied by single-droplet injection and microabsorption methods."Bulletin of the Chemical Society of Japan. 76(2). 295-299 (2003)

[Publications] A.Kovalenko, F.Hirata: "Molecular description of electrolyte solution in a carbon aerogel electrode"Condensed Matter Physics. 36. 583-609 (2003)

[Publications] Miyako Eijiro, Maruyama Tatsuo, Kamiya Noriho, Goto Masahiro: "Transport of organic acids through a supported liquid membrane driven by lipase-catalyzed reactions"Journal of Bioscience and Bioengineering. 96(4). 370-374 (2003)

渡會仁大阪大学, 大学院・理学系研究科, 教授 (30091771)