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2003 Fiscal Year Final Research Report Summary

Construction of Transition Metal Chalcogenide Clusters and Their Functions

Research Project

Project/Area Number 13304052
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionNagoya University

Principal Investigator

TATSUMI Kazuyuki  Nagoya University, Research Center for Materials Science, Professor, 物質科学国際研究センター, 教授 (10155096)

Co-Investigator(Kenkyū-buntansha) OHKI Yasuhiro  Nagoya University, Graduate School of Science, Research Assistant, 大学院・理学研究科, 助手 (10324394)
MATSUMOTO Tsuyoshi  Nagoya University, Graduate School of Science, Research Assistant, 大学院・理学研究科, 助手 (50311717)
Project Period (FY) 2001 – 2003
KeywordsTransition Metal Thiolato Complex / Transition Metal Sulfido Complex / Transition Metal Thiallyl Complex / Alkynethiolate / Diynethiolate / Inorganic Polymer / Activation of Hydrogen Molecule / Metal Cluster
Research Abstract

During this research project, we have made substantial progress in many phases of research items, viz,
1. We have synthesized a novel rhenium selenido cluster, of [Cp^*Re(Se_3)(μ-Se_2)]_8, having a octa-nuclear diamond-crown shape of [Re(μ-Se_2)]_8 24-membered macrocyclic core, from the reaction of Cp^*ReCl_4 with 2-3 equiv of Li_2Se_5. On the other hand, the analogous reaction between Cp^*ReCl_4 and 2 equiv of Li_2Te_5 gave rise to a trinuclear cluster of a birdcage shape, Cp^*3Re_3Te_8.
2. A series of alkynethiolato complexes, alkyneselenolato complexes, diynethiolato complexes have been synthesized. These thiolate ligands are unique in that they carry unsaturated C-C bonds as substituents, and have shown interesting reactivity at various transition metal centers. For instance, we found unusual C-C coupling reactions, cyclic dimerizatino/trimerization of the functional carbon sites, C-S bond cleavage occurring at the thiolate ligands.
3. Thiolate-type sulfur is coordinated at transition … More metal centers relatively strongly, while thioether-type sulfur forms weak M-S bonds, often exhibiting facile dissociation equilibration. We have utilized the mixed ligands RSCH_2CH_2S(-) (R=Et (etet), R=^iPr (^1ptet), R=Ph (ptet)) for assemblage of iron(II) and Ni(II) metal atoms. For instance, the 1:2 NiCl_2/Li(etet) reaction system gave rise to a linear polymer [Ni(etet)_2]_n, while the analogous 1:2 NiCl_2/Li(ptet) reaction resulted in formation of a cyclic hexamer [Ni_6(ptet)_<12>]. An interesting feature of these 1-dimensional polymers of Ni and Fe is that they can be dissolved in toluene by virtue of coordination of thioether-type sulfur atoms, and that the polymer structures are regenerated upon recrystallization.
4. A series of sulfido-bridged tungsten-ruthenium dinuclear complexes Cp^*W(μ-S)_3RuX(PPh_3)_2, Cp^*W(O) (μ-S)_2RuX(PPh_3)_2, and Cp^*W(NPh) (μ-S)_2RuX(PPh_3)_2 have been synthesized. The heterolytic cleavage of H_2 was found to proceed at room temperature upon treating Cp^*W(O) (μ-S)_2RuX(PPh_3)_2 and Cp^*W(NPh)(μ-S)_2RuX(PPh_3)_2 with NaBArF_4 under atmospheric pressure of H_2, which gave rise to [Cp^*W(OH)(μ-S)_2RuH(PPh_3)_2](BarF_4) and [Cp^*W(NHPh)(μ-S)_2RuH(PPh_3)_2](BarF_4), respectively. The mechanism of the heterolytic H_2 activation and the reverse H_2 evolution reactions have been investigated. Less

  • Research Products

    (81 results)

All Other

All Publications (81 results)

  • [Publications] Ohki, Y., Tatsumi, K., et al.: "Heterolytic Cleavage of Dihydrogen Promoted by Sulfido-Bridged Tungsten-Ruthenium Dinuclear Complexes"J.Am.Chem.Soc.. 125. 7978-7988 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Ohki, Y., Tatsumi, K., et al.: "Synthesis of the P-Cluster Inorganic Core of Nitrogenases"J.Am.Chem.Soc.. 125. 4052-4053 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Komuro, T., Tatsumi, K., et al.: "Unusual Coordination Modes of Arylthiolates in Mo{η^5-SC_6H_3-2,6-(SiMe_3)_2}{η^7-SC_6H_3-2,6-(SiMe_3)_2"J.Am.Chem.Soc.. 125. 2070-2071 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Komuro, T., Tatsumi, K., et al.: "Synthesis and Characterization of Ti(IV) and Ti(III) Complexes with (2-Dimethyl-phosphino)ethane-1-thiolate and (3-Dimethylphosphino) propane-1-thiolate as Ligands"Angew.Chem.Int.Ed.. 41. 465-468 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Komuro, T., Tatsumi, K., et al.: "Coordination Chemistry of Silanedithiolato Ligands Derived from Cyclotrisilathiane : Synthesis and Structures of Complexes of Iron(II),Cobalt(II) Copper(I),and Silver(I)"Inorg.Chem.. 42. 5340-5347 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] G.-X.Jin, Y Arikawa, K.Tatsumi: "Spontaneous Formation of a Diamond-crown Structure of Re_8 Polyselenide and a Cage Structure of Re_3 Polytelluride"J.Am.Chem.Soc.. 123. 735-736 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kawaguchi, K.Tatsumi: "Synthesis of a Pentamethylcyclopentadienyl Complex of Tungsten with Three Different Chalcogenido (O^<2->,S^<2->,Se^<2->) Ligands"Angew.Chem.Int.Ed.. 40. 1266-1268 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Matsumoto, Y.Matsui, Y.Nakaya, K.Tatsumi: "1,2,3,4,5,6,7-Hexathiagermepanes : Synthesis, Structures and the Ring Contraction to 1,2,3,4,5-tetrathiagermolanes."Chem.Lett.. 60-61 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Matsumoto, K.Tatsumi: "Sterically Protected Dipotassium Germanedithiolate"Chem.Lett.. 964-965 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Yu, Q.-F.Xu, Z.-R.Sun, S.-J.Ji, J.-X.Chen, Q.Liu, J.-P.Lang, K.Tatsumi: "Unique Formation of Two Different W/Ag/S Clusters from the Same Components via a Low Heating Temperature Solid State Reaction and a Solution Reaction and Their Third-Order NLO Properties in Solution."Chem.Commun.. 2614-2615 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Sunada, Y.Hayashi, H.Kawaguchi, K.Tatsumi: "Alkynethiolato and Alkyneselenolato Ruthenium Half-sandwich Complexes : Synthesis, Structures, and Reactions with (η^5-C_5H_5)_2Zr."Inorg.Chem.. 40. 7072-7078 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Arikawa, H.Kawaguchi, K.Kashiwabara, K.Tatsumi: "Trithiotungsten(VI) Complexes having Phosphine-Thiolate Hybrid Ligands : Synthesis and Cluster Forming Reactions with CuBr, FeCl_2 and [Fe(CH_3CN)_6](ClO_4)_2."Inorg.Chem.. 41. 513-520 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Yamamoto, H.Suzuki, N.Tajima, K.Tatsumi: "Stepwise Formation of Quasi-Octahedral Macrocyclic Complexes of Rhodium(III) and Iridium(III) Bearing a Pentamethyl-cyclopentadienyl Group"Chem.Eur.J.. 8. 372-379 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Ogata, K.Kuge, K.Tatsumi, Y.Yamamoto: "One-step Synthesis of Alkenyl Ketone Complexes from Cp^*RhCl_2(PPh_3),Alkyne and H_2O in the Presence of KPF_6."Chem.Commun.. 128-129 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Matsumoto, T.Kasai, K.Tatsumi: "Chiral Crystallization of a Linear Two-coordinated Palladium(O) Complex Bearing Propeller-shaped Bulky Phosphine Ligands."Chem.Let.. 346-347 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Komuro, H.Kawaguchi, K.Tatsumi: "Palladium Dimethylsilanedithiolate Complex : A Precursor for Ti-P and Ti-Pd_2 Heterometllic Complexes."Chem.Commun.. 988-989 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Chen, K.Tatsumi: "Synthesis and Molecular Structure of a Novel Dilithium Complex of(i-Pr_2C_6H_3)_<2-> dad."Chin.J. of Org.Chem.. 272-274 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.-P.Lang, H.Kawaguchi, K.Tatsumi: "Reactions of Tetrathiotungstate and Tetrathiomolybdate with Substituted Haloalkanes."J.Chem.Soc.,Dalton. 2753-2580 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Cao, K.Tatsumi: "Alkylation Reactions of [WS_4]^<2-> and [η^5-C_5Me_5)WS_3]^- with 2,6-Bis(bromomethyl) pyridine : The First Isolation of Bis-alkylated Tetrathiometallate WS_2{2,6-(SCH_2)_2-(C_5H_3N)}."Inorg.Chem.. 41. 4102-4104 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.-C.Hong, R.Cao, H.Kawaguchi, K.Tatsumi: "Synthesis and Reactions of Group 6 Metal Half Sandwich Complexes of 2,2-dicyanoethylene-1,1-dichalcogenolates[Cp^*M{E_2C=C(CN)_2}_2]^-(M=Mo, W ; E =S Se)."Inorg.Chem.. 41. 4824-4833 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Cao, K.Tatsumi: "Use of the Dipotassium Salt of Cyanamide for the Synthesis of Tungsten and Cobalt Complexes Having NCN Ligand."Chem.Commun.. 2144-2145 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Komuro, H.Kawaguchi, K.Tatsumi: "Synthesis and Reaction of Triphenylsilanethiolato Complexes of Manganese(II),Iron(II),Cobalt(II) and Nickel(II)."Inorg.Chem.. 41. 5083-5090 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Chen, K.Tatsumi: "Synthesis and Molecular Structure of a Novel Ion Pair Lithium Complex of a Diazabutadiene."J.Coord.Chem.. 1219-1222 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Yamamoto, H.Settu, K.Nishiyama, K.Kuge, K.Tatsumi: "Unprecedented Formation of Dinuclear Macrocyclic Complexes by Insertion of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquino-dimethane (Li[F4-tcnq]) into a C-H Bond and Its Coordination to Metal Atoms."Eur.J.Inorg.Chem.. 2447-2452 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Yamamoto, K.Ogata, K.Kuge, K.Tatsumi: "A Convenient One-step Synthesis of Alkenyl-phosphino Complexes of Ruthenium(II),Rhodium(III) and Iridium(III)."Inorg.Chem.Commun.. 862-864 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.P.Lang, H.Yu, S.J.Ji, K.Tatsumi: "Syntheses and Crystal Structures of Nickel and Manganese Cluster Compounds of the Pentamethylcyclopentadienyl Trisulfido Tungsten"Inorg.Chim.Acta.. 344. 169-173 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.P.Lang, S.J.Ji, Q.F.Su, Q.Shen, K.Tatsumi: "Structural Aspects of Copper(I) and Silver(I) Sulfide Clusters of Pentamethyl-cyclopentadienyl Trisulfido Tungsten(VI) and Molybdenum(VI)."Coord.Chem.Rev.. 241. 47-60 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.E.d'Arbeloff, P.B.Hitchcock, J.F.Nixon, H.Kawaguchi, K.Tatsumi: "[2+2] Cycloaddition Reactions of Bis-Pentamethylcyclopenta-dienyl Zirconium Metal Complexes Containing Terminal Chalcogenide Ligands with the Phospha-alkyne PCBu^t. Synthesis, Crystal and Molecular Structures of [Zr(η^5-(C_5Me_5)_2(SC(^tBu)=P)),[Zr(η^5-(C_5Me_5)_2(SeC(^tBu)=Pse)) and [Zr(η^5-(C_5Me_5)_2(SC(^tBu)=PC(Ph)=N)"J.Organomet.Chem.. 672. 1-10 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Yamamoto, A.Nagata, H.Nagata, Y.Ando, Y.Arikawa, K.Tatsumi, K.Itoh: "Palladium(0)-Catalyzed Intramolecular [2+2+2] Alkyne Cyclotrimerizations with Electron-Deficient Diynes and Triynes"Chem.Eur.J.. 9. 2469-2483 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Kosaka, Y.Shinozaki, Y.Tsutsumi, Y.Yamamoto Y.Sunada, K.Tatsumi: "Stereochemistry of Mono- and Di-nuclear Complexes of Rhodium, Iridium, and Ruthenium Bearing [Bis(diphenylphosphinomethyl)]phenylphosphine"J.Organomet.Chem.. 671. 8-12 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Matsuzaki, H.Kawaguchi, P.Voth, K.Noda, S.Itoh, H.D.Takagi, K.Kashiwabara, K.Tatsumi: "Synthesis and Characterization of Ti(IV) and Ti(III) Complexes with (2-Dimethyl-phosphino)ethane-1-thiolate and (3-Dimethylphosphino)propane-1-thiolate as Ligands."Inorg.Chem.. 42. 5320-5329 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.-P.Lang, Z.-R.Sun, Q.-F.Xu, H.Yu, K.Tatsumi: "Optical Limiting Properties of Two Organometallic Half-open Cubane-like Cluster Compounds [η^5-C_5Me_5]WS_3Cu_3Br_2(EPh_3)_2](E=As, P)."Materials Chem. and Phys.. 82. 493-498 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Arndt, P.M.Zeimentz, T.P.Spaniol, J.Okuda, M.Honda, K.Tatsumi: "Neutral and Cationic Trimethylsilylmethyl Complexes of the Rare Earth Metals Supported by a Crown Ether : Synthesis and Structural Characterization"J.Chem.Soc.,Dalton. 3622-3627 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Tamao, R.West, K.Tatsumi: "A Half Century of Polysilane Chemistry"J.Organomet.Chem. (special issue). (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Yamamoto, Y.Kohsaka, Y.Shinozaki, Y.Tsutsumi, Y.Kaburagi, K.Kuge, Y.Sunada, K.Tatsumi: "Homo- and Heteronuclear Complexes of (Pentamethylcyclopentadienyl)rhodium)(III) Bearing [Bis(diphenylphosphanylmethyl)]phenylphosphate."Eur.J.Inorg.Chem.. 134-142 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Yamamoto, Y.Sinozuka, Y.Tsutsumi, K.Fuse, K.Kuge, Y.Sunada, K.Tatsumi: "Homo- and Heteronuclear Complexes Based on Arene Ruthenium Complexes Bearing Bis(diphenylphosphinomethyl)phenylphosphine (dpmp)."Inorg.Chim.Acta.. (in press). (2004)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Ohki, H.Sadohara, Y.Takikawa, K.Tatsumi: "A Coordinatively Unsaturated 2,6-Dimesitylphenyl Thiolate Complex of Half-Sandwich Ruthenium(II)."Angew.Chem.Int.Ed.. 43. 2290-2293 (2004)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Synthesis and Structural Characterization of Silanethiolato Complexes Having teri-Butyldimethylsilyl and Trimethylsilyl Groups"J.Chem.Soc.,Dalton. (in press). (2004)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Fujita, W.-H.Kim, Y.Sakanishi, K.Fujiwara, S.Hirayama, T.Okuyama, Y.Ohki, K.Tatsumi, Y.Yoshikawa: "Elimination-Addition Mechanism for Nucleophilic Substitution Reaction of Cyclohexenyl Iodonium Salts and Regioselectivity of Nucleophilic Addition to the Cyclohexyne Intermediate."J.Am.Chem.Soc.. (submitted). (2004)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Sugiyama, Y.Hayashi, K.Tatsumi: "Carbon-carbon Bond Forming Reactions of Alkynethiolate and Alkyneselenolate at Ti(III) and Zr(IV) Centers."Organometallics. (submitted). (2004)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 巽 和行, 大木靖, 弘川口博之: "実験化学講座21"丸善株式会社. 83-94 (2004)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] G.-X.Jin, Y Arikawa, K.Tatsumi: "Spontaneous Formation of a Diamond-crown Structure of Re_8 Polyselenide and a Cage Structure of Re_3 Polytelluride"J.Am.Chem.Soc.. 123. 735-736 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Kawaguchi, K.Tatsumi: "Synthesis of a Pentamethylcyclopentadienyl Complex of Tungsten with Three Different Chalcogenido (O^<2->, S^<2->, Se^<2->) Ligands."Angew.Chem.Int.Ed.. 40. 1266-1268 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Matsumoto, Y Matsui, Y Nakaya, K.Tatsumi: "1,2,3,4,5,6,7-Hexathiagermepanes : Synthesis, Structures and the Ring Contraction to 1,2,3,4,5-tetrathiagermolanes."Chem.Lett.. 60-61 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Matsumoto, K.Tatsumi: "Sterically Protected Dipotassium Germanedithiolate."Chem.Lett.. 964-965 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H., Yu, Q.-F.Xu, Z.-R.Sun, S.-J.Ji, J.-X.Chen, Q.Liu, J.-P.Lang, K.Tatsumi: "Unique Formation of Two Different W/Ag/S Clusters from the Same Components via a Low Heating Temperature Solid State Reaction and a Solution Reaction and Their Third-Order NLO Properties in Solution."Chem.Commun.. 2614-2615 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Sunada, Y.Hayashi, H.Kawaguchi, K.Tatsumi: "Alkynethiolato and Alkyneselenolato Ruthenium Half-sandwich Complexes : Synthesis, Structures, and Reactions with (η^5-C_5H_5)_2Zr."Inorg.Chem.. 40. 7072-7078 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Arikawa, H.Kawaguchi, K.Kashiwabara, K.Tatsumi: "Trithiotungsten(VI) Complexes having Phosphine-Thiolate Hybrid Ligands : Synthesis and Cluster Forming Reactions with CuBr,FeCl_2 and [Fe(CH_3CN)_6](ClO_4)_2."Inorg.Chem.. 41. 513-520 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Yamamoto, H.Suzuki, N.Tajima, K.Tatsumi: "Stepwise Formation of Quasi-Octahedral Macrocyclic Complexes of Rhodium(III) and Iridium(III) Bearing a Pentamethyl-cyclopentadienyl Group."Chem.Eur.. 8. 372-379 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Ogata, K.Kuge, K.Tatsumi, Y.Yamamoto: "One-step Synthesis of Alkenyl Ketone Complexes from Cp^*RhCl_2(PPh_3), Alkyne and H_2O in the Presence of KPF_6."Chem.Commun.. 128-129 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Matsumoto, T.Kasai, K.Tatsumi: "Chiral Crystallization of a Linear Two-coordinated Palladium(0) Complex Bearing Propeller-shaped Bulky Phosphine Ligands."Chem.Lett.. 346-347 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Komuro, H.Kawaguchi, K.Tatsumi: "Palladium Dimethylsilanedithiolate Complex : A Precursor for Ti-P and Ti-Pd_2 Heterometllic Complexes."Chem.Commun.. 988-989 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Chen, K.Tatsumi: "Synthesis and Molecular Structure of a Novel Dilithium Complex of (i-Pr_2C_6H_3)_2-dad."Chin.J.of Org.Chem.. 272-274 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.-P.Lang, H.Kawaguchi, K.Tatsumi: "Reactions of Tetrathiotungstate and Tetrathiomolybdate with Substituted Haloalkanes."Chem.Soc, Dalton. 2573-2580 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Cao, K.Tatsumi: "Alkylation Reactions of [WS_4]^<2-> and [(η^5-C_5Me_5)WS_3]^-with 2,6-Bis(bromomethyl)pyridine : The First Isolation of Bis-alkylated Tetrathiometallate WS_2{2,6-(SCH_2)_<2->(C_5H_3N)}."Inorg.Chem.. 1. 4102-4104 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.-C.Hong, R.Cao, H.Kawaguchi, K.Tatsumi: "Synthesis and Reactions of Group 6 Metal Half Sandwich Complexes of 2,2-dicyanoethylene-1,1-dichalcogenolates[Cp^*M{E_2C=C(CN)_2}_2]^-(M=Mo, W; E=S, Se)."Inorg.Chem.. 41. 4824-4833 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Cao, K.Tatsumi: "Use of the Dipotassium Salt of Cyanamide for the Synthesis of Tungsten and Cobalt Complexes Having NCN Ligand."Chem.Commun.. 2144-2145 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Komuro, H.Kawaguchi, K.Tatsumi: "Synthesis and Reaction of Triphenylsilanethiolato Complexes of Manganese(II), Iron(II), Cobalt(II) and Nickel(II)."Inorg.Chem.. 41. 5083-5090 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Chen, K.Tatsumi: "Synthesis and Molecular Structure of a Novel Ion Pair Lithium Complex of a Diazabutadiene."J.Coord.Chem.. 1219-1222 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Yamamoto, H.Settu, K.Nishiyama, K.Kuge, K.Tatsumi: "Unprecedented Formation of Dinuclear Macrocyclic Complexes by Insertion of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquino-dimethane (Li[F4-tcnq]) into a C-H Bond and Its Coordination to Metal Atoms."Eur.J.Inorg.Chem.. 2447-2452 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Yamamoto, K.Ogata, K.Kuge, K.Tatsumi: "A Convenient One-step Synthesis of Alkenyl-phosphino Complexes of Ruthenium(II), Rhodium(III) and Iridium(III)."Inorg.Chem.Commun.. 862-864 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Copper and Silver Complexes Containing a Novel S(SiME_2S)_2^<2-> Efficient Entries into Heterometallic Silfido Clusters."Angew.Chem.Int.Ed.. 41. 465-468 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.P.Lang, H.Yu, S.J.Ji, K.Tatsumi: "Syntheses and Crystal Structures of Nickel and Manganese Cluster Compounds of the Pentamethylcyclopentadienyl Trisulfido Tungsten"Inorg.Chim.Acta. 344. 169-173 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.P.Lang, S.J.Ji, Q.F.Su, Q.Shen, K.Tatsumi: "Structural Aspects of Copper(I) and Silver(I) Sulfide Clusters of Pentamethyl-cyclopentadienyl Trsulfido Tungsten(VI) and Molybdenum(VI)."Coord Chem.Rev.. 241. 47-60 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Unusual Coordination Modes of Arylthiolates in Mo{η^5-SC_6H_3-2,6-(SiMe_3)_2}{η^7-SC_6H_3-2,6-(SiMe_3)_2"J.Am.Chem.Soc.. 125. 2070-2071 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.E.d'Arbeloff, P.B.Hitchcock, J.F.Nixon, H.Kawaguchi, K.Tatsumi: "[2+2] Cycloaddition Reactions of Bis-Pentamethylcyclopenta-dienyl Zirconium Metal Complexes Containing Terminal Chalcogenide Ligands with the Phospha-alkyne PCBu^t. Synthesis, Crystal and Molecular Structures of [Zr(η^5-(C_5Me_5)_2(SC(^tBu)=P)), [Zr(η^5-(C_5Me_5)_2(SeC(-tBu)=P)), [Zr(η^5-(C_5Me_5)_2(SC(^tBu)=Pse)) and [Zr(η^5-(C_5Me_5)_2 (SC(^tNu)=PC(Ph)=N)"J.Organomet.Chem.. 672. 1-10 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Yamamoto, A.Nagata, H.Nagata, Y.Ando, Y.Arikawa, K.Tatsumi, K.Itoh: "Palladium(0)-Catalyzed Intramolecular [2+2+2] Alkyne Cyclotrimerizations with Electron-Deficient Diynes and Triynes."Chem.Eur.J.. 9. 2469-2483 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Ohki, Y.Sunada, M.Honda, M.Katada, K.Tatsumi: "Synthesis of the P-Cluster Inorganic Core of Nitrogenases."J.Am.Chem.Soc.. 125. 4052-4053 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Kosaka, Y.Shinozaki, Y.Tsutsumi, Y.Yamamoto Y Sunada, K.Tatsumi: "Stereochemistry of Mono-and Di-nuclear Complexes of Rhodium, Iridium, and Ruthenium Bearing [Bis(diphenylphosphinomethyl)]phenylphosphine"J.Organomet.Chem.. 671. 8-12 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Ohki, N.Matsuura, T.Marumoto, H.Kawaguchi, K.Tatsumi: "Heterolytic Cleavage of Dihydrogen Promoted by Sulfido-Bridged Tungsten-Ruthenium Dinuclear Complexes"J.Am.Chem.Soc.. 125. 7978-7988 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Matsuzaki, H.Kawaguchi, P.Voth, K.Noda, S.Itoh, H.D.Takagi, K.Kashiwabara, K.Tatsumi: "Synthesis and Characterization of Ti(IV) and Ti(III) Complexes with (2-Dimetphosphino)ethane-1-thiolate and (3-Dimethylphosphino)propane-1-thiolate as Ligands."Inorg.Chem.. 42. 5320-5329 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.-P.Lang, Z.-R.Sun, Q.-F.Xu, H.Yu, K.Tatsumi: "Optical Limiting Properties of Two Organometallic Half-open Cubane-like Cluster Compounds [η~5-C_5Me_5]WS_3Cu_3Br_2(EPh_3)_2] (E=As, P)."Materials Chem.and Phys.. 82. 493-498 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Coordination Chemistry of Silanedithiolato Ligands Derived from Cyclotrisilathiane : Synthesis and Structures 'of Complexes of Iron(II), Cobalt(II) Copper(I), and Silver(I)."Inorg.Chem.. 42. 5340-5347 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Arndt, P.M.Zeimentz, T.P.Spaniol, J.Okuda, M.Honda, K.Tatsumi: "Neutral and Cationic Trimethylsilylmethyl Complexes of the Rare Earth Metals Supported by a Crown Ether : Synthesis and Structural Characterization"J.Chem.Soc., Dalton. 3622-2627 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Tamao, R.West, K.Tatsumi: "A Half Century of Polysilane Chemistry"J.Organomet.Chem.. Special Issue. (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Yamamoto, Y.Kohsaka, Y.Shinozaki, Y.Tsutsumi, Y.Kaburagi, K.Kuge, Y.Sunada, K.Tatsumi: "Homo-and Heteronuclear Complexes of (Pentamethylcyclopentadienyl)rhodium)(III) Bearing [Bis(diphenylphosphanylmethyl)]phenylphosphate."Eur.J.Inorg.Chem.. 134-142 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Yamamoto, Y.Sinozuka, Y.Tsutsumi, K.Fuse, K.Kuge, Y.Sunada, K.Tatsumi: "Homo-and Heteronuclear Complexes Based on Arene Ruthenium Complexes Bearing Bis(diphenylphosphinomethyl)phenylphosphine (dpmp)."Inorg.Chim.Acta. (in press). (2004)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Ohki, H.Sadohara, Y.Takikawa, K.Tatsumi: "A Coordinatively Unsaturated 2,6-Dimesitylphenyl Thiolate Complex of Half-Sandwich Ruthenium(II)."Angew.Chem.Int.Ed.. 43. 2290-2293 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Synthesis and Structural Characterization of Silanethiolato Complexes Having tert-Butyldimethylsilyl and Trimethylsilyl Groups"J.Chem.Soc., Dalton. (in press). (2004)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Fujita, W.-H.Kim, Y Sakanishi, K Fujiwara, S.Hirayama, T.Okuyama, Y Ohki, K.Tatsumi, Y.Yoshikawa: "Elimination-Addition Mechanism for Nucleophilic Substitution Reaction of Cyclohexenyl Iodonium Salts and Regioselectivity of Nucleophilic Addition to the Cyclohexyne Intermediate."J.Am.Chem Soc.. (submitted). (2004)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Sugiyama, Y.Hayashi, K.Tatsumi: "Carbon-carbon Bond Forming Reactions of Alkynethiolate and Alkyneselenolate at Ti(III) and Zr(IV) Centers."Organometallics. (submitted). (2004)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2005-04-19  

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