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2004 Fiscal Year Final Research Report Summary

Development and Application cf Bistability in Molecule-based Magnetic Mterials

Research Project

Project/Area Number 13304054
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 機能・物性・材料
Research InstitutionNagoya University

Principal Investigator

AWAGA Kunio  Nagoya University, Dept.of Chem., Prof., 大学院・理学研究科, 教授 (10202772)

Co-Investigator(Kenkyū-buntansha) FUJITA Wataru  Nagoya University, Research Center of Materials Science, Research Associate, 物質科学国際研究センター, 助手 (50292719)
Project Period (FY) 2001 – 2004
KeywordsMolecular magnetism / Bistability / nanomagnet / Single Molecule Magnet
Research Abstract

The science and technology of spin electronic devices have attracted much interest. In this project, we developed molecule-based magnetic materials for future spintronics.
1)Thiazyl radicals possess chemical stability and strong intermolecular interactions. We carried out a systematic study, namely, chemical syntheses, structural analyses, and physical measurements on this radical family, and discovered room-temperature magnetic bistability, photo-induced phase transition, organic ferromagnetism, etc.
2)Development of molecular-/nano-magnets is a key issue for spintronics. Some of transition-metal cluster complexes exhibit a hysteresis loop on magnetization curve, so that they are called single molecule magnets(SMM). In this project, we performed chemical modifications on SMM, in order to elucidate the magneto-structural correlation and to control the classical and quantum magnetic relaxations. The magneto-structural correlation in SMM was revealed.
We also developed synthesis of novel nanomagnets. We succeeded in uniform coating of polystyrene beads (O.D.300-1000 nm) with cobalt hydroxides, and obtained spherical hollow nanomagnets of fee Co and spinel Co_3O_4.

  • Research Products

    (12 results)

All 2004 2002

All Journal Article (12 results)

  • [Journal Article] Crystal structure and magnetic properties of a thiazyl organic ferromagnet, BBDTA・GaCl_4 with T_c=7.0 K2004

    • Author(s)
      W.Fujita, K.Awaga
    • Journal Title

      Chem.Phys.Lett. 388

      Pages: 186-189

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Packing Motifs and Magneto-Structural Correlations in Crystal structures of Metallo-Tetrakis(1,2,5-thiadiazole)porphyrazine Series, TTDPzM(M=H_2,Fe,Co,Ni,Cu,Zn)2004

    • Author(s)
      Y.Suzuki, M.Fujimori, H.Yoshikawa, K.Awaga
    • Journal Title

      Chem.Euro.J. 10

      Pages: 5158-5164

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Structure and magnetic properties of single-molecule magnet [Mn_<11>CrO_<12>(O_2CCH_3)_<16>(H_2O)_4]・2CH_3COOH・4H_2O : Magnetization manipulation and dipolar-biased tunneling in Mn11Cr/Mn12 mixed crystal2004

    • Author(s)
      H.Hachisuka, K.Awaga, T.Yokoyama, T.Kubo, T.Goto, H.Nojiri
    • Journal Title

      Phys.Rev.B 70

      Pages: 104427

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] "Preparation and Magnetic Properties of Hollow Nano-Spheres of Cobalt and Cobalt Oxide : Drastic Cooling-Field Effects on Remnant Magnetization of Antiferromagnet2004

    • Author(s)
      H.Yoshikawa, K.Hayashida, Y.Kozuka, A.Horiguchi, K.Awaga, S.Bandow, S.Iijima
    • Journal Title

      Appl.Phys.Lett. 85

      Pages: 5287-5289

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Crystal structure and magnetic properties of a thiazyl organic ferromagnet, BBDTA-GaCl_4 with T_c=7.0 K2004

    • Author(s)
      W.Fujita W, K.Awaga
    • Journal Title

      Chem.Phys.Lett. 388

      Pages: 186-189

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Packing Motifs and Magneto-Structural Correlations in Crystal structures of Metallo-Tetrakis(1,2,5-thiadiazole)porphyrazine Series, TTDP zM (M=H_2,Fe,Co,Ni,Cu,Zn)2004

    • Author(s)
      Y.Suzuki, M.Fujimori, H.Yoshikawa, K.Awaga
    • Journal Title

      Chem.Euro.J. 10

      Pages: 5158-5164

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Structure and magnetic properties of single-molecule magnet [Mn_<11> CrO_<12>(O_2CCH_3)_<16>(H_2O)_4]-2CH_3COOH・4H_2O : Magnetization manipulation and dipolar-biased tunneling in Mn_<11>Cr/Mn12 mixed crystal2004

    • Author(s)
      H.Hachisuka, K.Awaga, T.Yokoyama, T.Kubo, T.Goto, H.Nojiri
    • Journal Title

      Phys.Rev.B 70

      Pages: 104427

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation and Magnetic Properties of Hollow Nano-Spheres of Cobalt and Cobalt Oxide : Drastic Cooling-Field Effects on Remnant Magnetization of Antiferromagnet2004

    • Author(s)
      H.Yoshikawa, K.Hayashida, Y.Kozuka, A.Horiguchi, K.Awaga, S.Bandow, S.Iijima
    • Journal Title

      Appl.Phys.Lett. 85

      Pages: 5287-5289

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Room-temperature magnetic bistability in organic radical crystals : Paramagnetic-diamagnetic phase transition in 1,3,5-trithia-2,4,6-triazapentalenyl2002

    • Author(s)
      W.Fujita, K.Awaga, H.Matsuzaki, H.Okamoto
    • Journal Title

      Phys.Rev. B65

      Pages: 064434

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Magnetic anisotropy, tunneling effects, high-frequency EPR, and molecular structure of fast-relaxation species of Mn_<12>2002

    • Author(s)
      K.Takeda, K.Awaga, T.Inabe, A.Yamaguchi, H.Ishimoto, T.Tomita, H.Mitamura, T.Goto, N.Mori, H.Nojiri
    • Journal Title

      Phys.Rev. B65

      Pages: 094424

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Room-temp erature magnetic bistability in organic radical crystals : Paramagn etic-diamagnetic phase transition in 1,3,5-trithia-2,4,6-triazapental enyl2002

    • Author(s)
      W.Fujita, K.Awaga, H.Matsuzaki, H.Okamoto
    • Journal Title

      Phys.Rev.B 65

      Pages: 064434

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Magnetic anisotropy, tunneling effects, high-frequency EPR, and niolecular structure of fast-relaxation species of Mn_<12>2002

    • Author(s)
      K.Takeda, K.Awaga, T.Inabe, A.Yamaguchi, H.Ishimolo, T.Tomita, H.Mitamura, T.Goto, N.Mori, H.Nojiri
    • Journal Title

      Phys.Rev.B 65

      Pages: 094424

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2006-07-11  

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