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2003 Fiscal Year Final Research Report Summary

Submillimeter-wae Investigations of Reaction Intermediates Relevant to Interstellar and Atmospheric Chemistry

Research Project

Project/Area Number 13440172
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionIbaraki University

Principal Investigator

AMANO Takayoshi  IBARAKI UNIV., COLLEGE OF SCIENCE, PROFESSOR, 理学部, 教授 (60037249)

Co-Investigator(Kenkyū-buntansha) 笠井 康子  独立行政法人通信総合研究所, 主任研究員 (60281630)
Project Period (FY) 2001 – 2003
KeywordsSubmillimeter-wave spectroscopy / Interstellar molecules / Deuterated species / Earth's atmosphere / Molecular ions / Free radicals
Research Abstract

During the past several years, out effort was focused on submillimeter-wave spectroscopic studies of free radicals and molecular ions, in particular, of astrophysical and atmospheric chemical interests. Very high-sensitivity, high-precision, and high efficiency of data acquisition of a spectrometer system are the most crucial factors for successful search of free radicals and ions. To achieve this goal, we employed Russian-made backward-wave oscillators as radiation sources. The oscillation frequencies have been stabilized by using a double phase-lock loop. Below major results are summarized and full report already published on these results will attached as Appendices. The collaboration with the JEM/SMILES group has been measured. These projects are also pursued in collaboration with the JPL group.
Major achievements obtained during this project term are mainly in the following areas: (1)Spectroscopy of unstable species (2)Identification of reaction intermediates in discharge plasma used for plasma CVD processes. (3Precise pressure broadening measurements of molecules relevant to the Earth's atmospheric chemistry.

  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] T.Amano, Z.Zelinger: "Submillimeter-wave Spectroscopy of HNC Produced in an Extended Negative Glow Discharge"J.Mol.Spectrosc. 211. 273-278 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.M.Yamada, M.Kobayashi, H.Habara, T.Amano, B.J.Drouin: "Submillimeter-wave Measurements of the Pressure Broadening of BrO"J.Quant.Spectrosc.Radiation Transfer. 82. 391-399 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Z.Zelinger, T.Amano, B.Ahrens, S.Bruenken, F.Lewen, H.S.P.Mueller, G.Winnewisser: "Submillimeter-wave spectroscopy of HCN in excited vibrational states"J.Mol.Spectrosc. 220. 223-233 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Habara, A.Maeda, T.Amano: "Submillimeter-wave spectrum of the FCO radical."J.Mol.Spectrosc. 221. 31-37 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hirao, T.Amano: "Laboratory Submillimeter-wave Detection of D_2H^+ : A New Probe into Multiple Deuteration?"Astrophys.J.Letters. 597. L85-L87 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Amano, Z.Zelinger: "Submillimeter-wave Spectroscopy of HNC Produced in an Extended Negative Glow Discharge."J.Mol.Spectrosc.. 211. 273-278 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Habara, S.Yamamoto, T.Amano: "Submillimeter-wave spectra of HCS and DCS."J.Chem.Phys.. 116. 9232-9238 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A.Tanabashi, T.Amano: "New Identification of the Visible Bands of the C_2 Swan System."J.Mol.Spectrosc.. 215. 285-294 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.M.Yamada, M.Kobayashi, H.Habara, T.Amano, B.J.Drouin: "Submillimeter-wave Measurements of the Pressure Broadening of BrO."J.Quant.Spectrosc.Radiation Transfer.. 82. 391-399 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Z.Zelinger, T.Amano, B.Ahrens, S.Bruenken, F.Lewen, H.S.P.Mueller, G.Winnewisser: "Submillimeter-wave spectroscopy of HCN in excited vibrational states."J.Mol.Spectrosc.. 220. 223-233 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Habara, A.Maeda, T.Amano: "Submillimeter-wave spectrum of the FCO radical."J.Mol.Spectrosc.. 221. 31-37 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Hirao, T.Amano: "Laboratory Submillimeter-wave Detection of D_2H^+ : A New Probe into Multiple Deuteration?"Astrophys.J.Letters. 597. L85-L87 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Hirao, T.Amano: "Precise Laboratory Rest Frequency of a Submillimeter-Wave Line of D_2H^+."The Interstellar Medium in Galaxies(91 Springer Proceedings in Physics). 103-106 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Amano, M.M.Yamada: "Pressure Broadening Measurements at Ibaraki; BrO and O_3."Proceedings of International Workshop on Critical Evaluation of mm/sub-mm-wave Spectroscopic Data for Atmospheric Observations. 28-31 (2004)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2005-04-19  

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