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2002 Fiscal Year Final Research Report Summary

Development of In-site measurement for surface electron density using X-ray surface propagation wave

Research Project

Project/Area Number 13450035
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied physics, general
Research InstitutionKyoto University

Principal Investigator

HORIUCHI Toshihisa  Graduate School of Engineering, Research Associate, 大学院・工学研究科, 助手 (10238785)

Co-Investigator(Kenkyū-buntansha) ISHIDA Kenji  Graduate School of Engineering, Lecturer, 大学院・工学研究科, 講師 (20303860)
YAMADA Hirofumi  Graduate School of Engineering, Associate Professor, 大学院・工学研究科, 助教授 (40283626)
KAZUMI Matsushige  Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (80091362)
Project Period (FY) 2001 – 2002
Keywordsanomalous dispersion / X-ray surface propagation wave / GYX-ray anomalous scatterig / X-ray total reflection / surface density / total reflection angle / photo-catalytic reaction / Titanum Oxide
Research Abstract

Total reflection arises when white X-rays irradiate the surface of the materials at small glancing angle. Both measurements of reflectivity and total diffraction can be conducted with specular reflection condition Then, with non-specular one the measurement of surface propagation wave also can be conducted. In this study, by combination of these measurements new evaluation X-ray system was developed and presented following results.
1. It was conformed to be able to get the surface density of Pt stripe and Si substrate by analyzing the surface peaks of surface propagation waves (anomalous scatterings called Yoneda wings).
2. Oxidation processes of H-terminated Si subjected by UV irradiation were investigated using surface propagation waves. The mechanism of its processes were revealed and clarified to be useful tool for observing the most surface density.
3. Oxidation processes of the surface of Cu films prepared by evaporation were investigated during UV irradiation and acid vapor exposure. It was clear that the oxidation processes dose not proceed simply, but there exist mainly three processes, a slight increasing,, an abrupt decreasing, and a gradual decreasing which is called "sealing effect" arresting further oxidation of deeply-lying loose packed copper crystallites.
4. The newly conceptual measurement using X-ray anomalous dispersion effect across the absorption edgies of atoms was presented. The typical measurement of GaAs(111) single crystal was conducted across the absorption edgies of Ga and As atoms by changing of the critical energies of total reflection. It was found that the peak of propagation wave sifted with linear relation to the incident angle corresponding to the the critical energies of total reflection, but at the near energy of the absorption edgies, its peak sift exhibited nonlinear and anomalous relations according to the equation of dispersion, revealing applicable to evaluate Ga and As atomic sites of the single crystal.

  • Research Products

    (17 results)

All Other

All Publications (17 results)

  • [Publications] K.Noda et al.: "Molecular Ferroelectricity of Vinylidene Fluoride oligomer Investigated by Atomic Force Microscopy"Japanese Journal of Applied Physics. Vol.40. 4361-4364 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Fukuma et al.: "Molecular-scale non-contact AFM studies of ferroelectric organic thin films epitaxially grown on alkali halides"Surface Science. Vol.516. 103-108 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Noda et al.: "Remanent Polarization of Evaporated Films of Vinylidene Fluoride Oligomers"Journal of Applied Physics. Vol.93 No.5. 2866-2870 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Noda et al.: "Investigation Of Ferroelectric Properties Of Vinylidene Fluoride Oligomer Evaporated Films"Material Research Society Proceedings. Vol.748(in-press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Horiuchi et al.: "Surface Electrical Measurements on Photo-Catalysis of Rutile TiO_2(110)"Material Research Society Proceedings. Vol.751(in-press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Kaisei et al.: "Observations of TiO_2 Surface Using Totally Reflected X-ray In-plane Diffraction Under UV Irradiation"Material Research Society Proceedings. Vol.751(in-press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 野田 啓 ほか: "原子間力顕微鏡を用いたVDFオリゴマー薄膜の局所強誘電特性評価"応用物理学会、有機分子・バイオエレクトロニクス分科会会誌. Vol.12, No.2. 81-86 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 石田 謙司 ほか: "ポリ-、オリゴ-シラン分子膜の凝集構造と光学特性"月刊マテリアルインテグレーション,(株式会社ティー・アイ・シー). Vol.15, No.5. 31-37 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 籠 恵太郎 ほか: "X線反射率測定用屈折透過型X線フィルタの試作と有用性について"X線分析の進歩. Vol.33. 207-219 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 堀内 俊寿 ほか: "表面X線回折と表面電気計測による光触媒機構の考察"会報光触媒. 第8号. 24-27 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 堀内 俊寿: "カラーラウエ法による薄膜の構造解析"X線分析最前線(改訂版),合志 陽一監修・佐藤 公隆編集,アグネ技術センター. 279-301 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K Noda et al.: "Molecular Ferroelectricity of Vinylidene Fluoride oligomer Investigated by Atomic Force Microscopy"Japanese Journal of Applied Physics. Vol.40. 4361-4364 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T Fukuma et al.: "Molecular-scale non-contact AFM studies of ferroelectric organic thin films epitaxially grown on alkali halides"Surface Science,. Vol.516. 103-108 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K Noda et al.: "Remanent Polarization of Evaporated Films of Vinylidene Fluoride Oligomers"Journal of Applied Physics. Vol.93, No.5. 2866-2870 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K Noda et al.: "Investigation Of Ferroelectric Properties Of Vinylidene Fluoride Oligomer Evaporated Films"Material Research Society Proceedings. Vol. 748, (in-press). (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T Horiuchi et al.: "Surface Electrical Measurements on Photo-Catalysis of Rutile TiO_2(110)"Material Research Society Proceedings. Vol. 751, (in-press). (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K Kaisei et al.: "Observations of TiO_2 Surface Using Totally Reflected X-ray In-plane Diffraction Under UV Irradiation"Material Research Society Proceedings. Vol. 751, (in-press). (2003)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2004-04-14  

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