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2003 Fiscal Year Final Research Report Summary

Lowering of Ignition Voltage of Gas Discharge by Using Carbon Nanotube Electrodes and Its Application to Fluorescence Tubes

Research Project

Project/Area Number 13555003
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Applied materials science/Crystal engineering
Research InstitutionMie University

Principal Investigator

SAITO Yahachi  MIE UNIVERSITY, FACULTY OF ENGINEERING, PROFESSOR, 工学部, 教授 (90144203)

Co-Investigator(Kenkyū-buntansha) HIRAKAWA Tetsuya  IWASAKI ELECTRIC CO.LTD., EB DEPARTMENT, RESEARCHER, 産業機器事業部, 研究員
SATO Hideki  MIE UNIVERSITY, FACULTY OF ENGINEERING, ASSISTANT, 工学部, 助手 (40324545)
HATA Koichi  MIE UNIVERSITY, FACULTY OF ENGINEERING, LECTURER, 工学部, 講師 (30228465)
Project Period (FY) 2001 – 2003
KeywordsCarbon nanotube / Single-wall nanotube / Multi-wall nanotube / Gas discharge / Ignition voltage / Sustaining voltage / Penning effect
Research Abstract

Gas discharge experiment was performed using carbon nanotube (CNT) cathodes, and the following results were obtained.
1. When the gap between electrodes (d) was 0.1mm, the CNT cathode ignited gas discharge at a lower voltage compared with a stainless steel (SUS) cathode, irrespective of argon (Ar) gas pressures (100Pa ? 1700Pa) employed in the present experiment. For the wider gap (i.e., d=1mm and 10mm), however, the difference in the ignition voltage became small, and the CNT cathode showed higher voltages at higher gas pressure.
2. The ignition voltage was dependent on the structure and texture of CNT films on the cathode metal. Spray deposited single-wall and multi-wall CNTs that were produced by arc-discharge method exhibited some effects on lowering the ignition voltage, while vertically-aligned CNTs with high density formed on the cathode metal by plasma-CVD method, rarely showed the lowering effect but raised the ignition voltage in some conditions.
3. When CNT films were used on the anode, the ignition voltage was raised.
4. Concerning the voltage for sustaining discharge, CNT cathodes could sustain discharge with lower voltage than the SUS cathode at low pressure of Ar gas (100Pa〜1200pa) when the gap was narrow (d=0.1 mm and 1 mm). For the wide gap (d=10 mm), on the contrary, CNT cathodes needed higher voltage to sustain discharge over the whole range of pressure.
5. The discharge voltage changed by the partial pressure of impurity gases, suggesting the Penning effect.
6. CNT films often peeled off the cathode after the discharge experiment.
In summary, lowering of gas discharge voltages was observed to some extent by using CNT cathode, but the reduction in the voltage was only 10%. For the industrial application of CNT cathodes to gas discharge voltage but also protection of CNT films against peeling-off are necessary.

  • Research Products

    (48 results)

All Other

All Publications (48 results)

  • [Publications] Y.Saito ほか: "Field Ion Microscopy of Multiwall Carbon Nanotubes : Observation of pentagons and Cap Breakage under High Electric Field"Surface Sci.Lett.. 499(1). L119-L123 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito ほか: "Field Emission of Carbon Nanotubes and Its Application as Electron Sources of Ultra-High Luminance Light-Source Devices"Physica B : Condensed Matter. 323(1-4). 30-37 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Sato ほか: "Field Emission Properties of Carbon Nanotubes and their Application to Display Devices"Molecular Cryst.& Liquid Cryst.. 387. 79-86 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito ほか: "Growth Conditions of Double-Walled Carbon Nanotubes in Arc Discharge"J.Phys.Chem.. B107(4). 931-934 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito: "Carbon Nanotube Field Emitter"J.Nanosci.& Nanotech.. 3(1/2). 39-50 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hata ほか: "Field emission from multiwall carbon nanotubes in controlled ambient gases, H_2, CO, N_2 and O_2"Ultramicroscopy. 95. 107-112 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Uemura ほか: "Large Are FEDs with Carbon Nanotube Emitter"J.Soc.Information Display. 11(1). 145-153 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "触媒金属組み合わせによるナノチューブ成長制御とナノチューブ先端構造"日本結晶成長学会誌. 30(4). 285-290 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブの機能と応用の展望"高圧ガス. 41(2). 91-95 (2004)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Sato ほか: "Vertically Aligned Carbon Nanotubes Grown by Plasma Enhanced Chemical Vapor Deposition"J.Vac.Sci.Technol.. B21(6). 2564-2568 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "驚異の新素材,カーボンナノチューブ"まてりあ. 41(11). 813 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブ"機能材料. 22(1). 39-43 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブフィールドエミッタ"表面科学. 23(1). 38-43 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブFED"ニューメディア別冊「プロジェクター総覧」(株)ニューメディア. 8. 46-47 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 余谷純子ほか: "カーボンナノチューブ電子源とディスプレイ"金属. 72(9). 876-879 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 齋藤弥八: "カーボンナノチューブの応用"パリティ. 18(8). 20-24 (2003)

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      「研究成果報告書概要(和文)」より
  • [Publications] E.Osawa: "Perspectives of Fullerene Nanotechnology"Kluwer Academic Publishers. 375 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 日本セラミックス協会編: "セラミック工学ハンドブック(第2版)"技報堂出版. 2500 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 平尾一之 編: "化学フロンティア7「ナノマテリアル最前線」"化学同人. 207 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 川合知二 監修: "図解 ナノテク活用技術のすべて"工業調査会. 298 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] E.Yasuda: "Carbon Alloys"Elsevier Science. 569 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 技術情報協会編: "カーボンナノチューブの合成・評価,実用化とナノ分散・配合制御技術"技術情報協会. 312 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 権田俊一 監修: "21世紀版 薄膜作製応用ハンドブック"エヌ・ティー・エス. 1330 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 篠原久典 監修: "ナノカーボン材料開発の新局面-加速する本格実用化"シーエムシー出版. 300 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Saito, R.mizushima, K.Hata: "Field Ion Microscopy of Multiwall Carbon Nanotubes : Observation of Pentagons and Cap Breakage under High Electric Field"Surface Sci.Lett.. 499(1). L119-L123 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Saito, K.ata, A.Takakura, J.Yotani, S.Uemura: "Field Emission of Carbon Nanotubes and Its Application as Electron Sources of Ultra-High Luminance Light-Source Devices"Physica B : Condensed Matter. 323(1-4). 30-37 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Saito, T.Nishiyama, T.Kato, S.Kondo, T.Tanaka, J.Yotani, S.Uemura: "Field Emission Properties of Double-Walled Carbon Nanotubes in Arc Discharge"Molecular cryst. & Liquid Cryst.. 387. 79-86 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Saito, T.Nakahira, S.Uemura: "Growth Conditions of Double-Walled Carbon Nanotubes in Arc Discharge"J.Phys.Chem.B. 107(4). 931-934 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Saito: "Carbon Nanotube Field Emitter"J.Nanosci. & Nanotech.. 3(1/2). 39-50 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Hata, A.Takakura, Y.Saito: "Field Emission from Multiwall Carbon Nanotubes in Controlled Ambient Gases, H_2, CO, N_2 and O_2"Ultramicroscopy. 95. 107-112 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Uemura, J.Yotani, T.Nagasako, H.Kurachi, H.Yamada, T.Ezaki, T.Maesoba, T.Nakao, Y.Saito, M.Yumura: "Large Are FEDs with Carbon Nanotube Emitter"J.Soc.Information Display. 11(1). 145-153 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] C.Oshima, K.Matsuda, T.Kona, Y.Mogami, T.Yamashita, Y.Saito, K.Hata, A.Takakura: "Energy Spectra of Field Emission Electrons from Multiwalled Carbon Nanotubes"J.Vac.Sci.Technol.B. 21(4). 1700-1704 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Sato, H.Takegawa, Y.saito: "Vertically Aligned Carbon Nanotubes Grown by Plasma Enhanced Chemical Vapor Deposition"J.Vac.Sci.Technol.. B21(6). 2564-2568 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Saito: "Amazing New Material, Carbon Nanotube [in Japanese]"Materia. 41(11). 813 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Saito: "Carbon Nanotubes [in Japanese]"Kinou-zairyou (Functional Materials). 22(1). 39-43 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Saito: "Carbon Nanotube Field Emitters [in Japanese]"Kyoumenn Kagaku (Surface Science). 23(1). 38-43 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Saito: "Carbon Nanotube FED [in Japanese]"New Media. Special Issue "Comprehensive Table of Projectors". 46-47 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Yotani: "Carbon Nanotube Electron Sources and Displays [in Japanese]"Kinzoku (Metal). 72(9). 876-879 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Saito: "Application of Carbon Nanotubes [in Japanese]"Parity. 18(8). 20-24 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Saito: "Growth Control of Carbon Nanotubes by Catalysts Combination and Structure Elucidation of Nanotube Tips [in Japanese]"Kesshou-Seichou Gakkai-shi (J.Crystal Growth). 30(4). 91-95 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] E.Osawa: "Perspectives of Fullerene nanotechnology"Kluwer Academic Publishers, London. 375 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Japan Ceramics Association: "Handbook of Ceramics Technology, 2nd ed. [in Japanese]"Gihoudou publication. 2500 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Hirao: "Carbon nanotube, Challenge to Nanodevices [in Japanese]"Kagaku-Doujin. 207 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kawai: "Illustrated Collection of Nanotechnology Utilization [in Japanese]"Kougyou Chousa-kai. 296 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] E.Yasuda et al.: "Carbon Alloys"Elsevier Science. 569 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Gijutsujyouhou-Kyoukai: "Synthesis, Characterization and Practical Usage of Carbon Nanotubes and Their Dispersion and Combination in Nanometer Scale [in Japanese]"Gijutsujyouhou-Kyoukai. 312 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Gonda: "Handbook of Thin Film Preparation and Application (21st century edition)"NTS Publication. 1330 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Shinohara: "New Phase in Development of Nanocarbon Material -Acceleration to Practical Application-"CMC Publication. 300 (2003)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2005-04-19  

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