2002 Fiscal Year Annual Research Report

アルキル置換芳香族の100%選択的部分酸素化反応の開発

Research Project

Project/Area Number	13555247
Research Institution	Osaka University
Principal Investigator	福住俊一大阪大学, 大学院・工学研究科, 教授 (40144430)
Co-Investigator(Kenkyū-buntansha)	末延知義大阪大学, 大学院・工学研究科, 助手 (90271030) 小江誠司大阪大学, 大学院・工学研究科, 助教授 (60290904)
Keywords	芳香族アルデヒド / 部分酸素化 / 光触媒 / 電子移動 / アクリジニウムイオン / アルキルベンゼン / 酸素 / α-メチルスチレン
Research Abstract	アルキル置換芳香族を対応する芳香族アルデヒドに選択的に部分酸素化させる反応は、医薬品、染料、殺虫剤、香料などの種々の薬品の製造中間体として有用な芳香族アルデヒドを製造する上で、工業化学的に非常に重要な反応である。従来、アルキルベンゼンの部分酸素化には無機酸化剤が用いられて来たが、これらの酸化剤を用いてアルキルベンゼンの酸素化を行った場合には、生成する芳香族アルデヒドの収率が低く、選択性が悪いという欠点がある。また、化学量論量の無機酸化剤が必要となるため、環境汚染が深刻な問題となる。従って、酸化剤として酸素を用いる芳香族アルデヒドの触媒的製造法の開発が待ち望まれている。酸素分子は基底状態が三重項であるため、一重項分子と直接反応して一重項の生成物を与えることはできない。酸素分子は二重項であるラジカル種とは反応できるが、ラジカル反応は一般的には制御が困難であり、選択的な基質酸化が不可能である場合が多い。本研究では、適当な光増感剤(10-メチルアクリジニウムイオン)を光触媒として用い、光誘起電子移動反応を利用することにより、分子状酸素によるα-メチルスチレンおよびアルキルベンゼン類の選択的酸素化反応が可能になることを見出した。光電子移動を利用して基質の酸素化を行なうことで、基質の種類と反応性に応じた適切な酸化力を有する光増感剤を選択して反応設計が可能となり、基質の選択的酸素化反応が可能になることがわかった。

Research Products

(56 results)

All Other

All Publications (56 results)

[Publications] Fukuzumi, S. et al.: "Effects of Hydrogen Bonding on Metal Ion-Promoted Intramolecular Electron Transfer and Photoinduced Electron Transfer in a Ferrocene-Quinone Dyad with a Rigid Amide Spacer"Journal of the American Chemical Society. 125・4. 1007-1013 (2003)
[Publications] Ogo, S.et al.: "Isolation and Crystal Structure of Water-Soluble Iridium Hydride. Robust and Highly Active Catalyst for Acid-Catalyzed Transfer Hydrogenations of Carbonyl Compounds in Acidic Media"Journal of the American Chemical Society. 125(in press). (2003)
[Publications] Fukuzumi, S. et al.: "Scandium Ion-Promoted Reduction of Heterocyclic N : N Double Bond. Hydride Transfer vs Electron Transfer"Journal of the American Chemical Society. 124・42. 12566-12573 (2002)
[Publications] Fukuzumi, S. et al.: "Direct detection of radical cations of NADH analogues"Journal of the American Chemical Society. 124・49. 14538-14539 (2002)
[Publications] Fukuzumi, S. et al.: "Metal Ion-Catalyzed Diels-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Electron-Transfer Step"Journal of the American Chemical Society. 124・47. 14147-14155 (2002)
[Publications] Fukuzumi, S. et al.: "A Negative Temperature Dependence of the Electron Self-Exchange Rates of Zinc Porphyrin π Radical Cations"Journal of the American Chemical Society. 124・37. 10974-10975 (2002)
[Publications] Fukuzumi, S. et al.: "Fluorescence Maxima of 10-Methylacridone-Metal Ion Salt Complexes : A Convenient and Quantitative Measure of Lewis Acidity of Metal Ion Salts"Journal of the American Chemical Society. 124・35. 10270-10271 (2002)
[Publications] Fukuzumi, S. et al.: "Asymmetric Sulfoxidation and Amine Binding by H64D/V68A and H64D/V68S Mb : Mechanistic Insight into the Chiral Discrimination Step"Journal of the American Chemical Society. 124・29. 8506-8507 (2003)
[Publications] Fukuzumi, S. et al.: "Significant Enhancement of Electron Transfer Reduction of NAD+ Analogues by Complexation with Scandium Ion and the Detection of the Radical Intermediate-Scandium Ion Complex"Journal of the American Chemical Society. 124・31. 9181-9188 (2002)
[Publications] Fukuzumi, S. et al.: "Exciplex intermediates in photoinduced electron transfer of porphyrin-fullerene dyads"Journal of the American Chemical Society. 124・27. 8067-8077 (2002)
[Publications] Fukuzumi, S. et al.: "Hydrogen-bonding dynamics in photoinduced electron transfer in a ferrocene-quinone linked dyad with a rigid amide spacer"Journal of the American Chemical Society. 124・24. 6794-6795 (2002)
[Publications] Fukuzumi, S. et al.: "Fine-Tuning of Copper(I)-Dioxygen Reactivity by 2-(2-Pyridyl)ethylamine Bidentate Ligands"Journal of the American Chemical Society. 124・22. 6367-6377 (2002)
[Publications] Fukuzumi, S. et al.: "Stepwise charge separation and charge recombination in ferrocene-meso, meso-linked porphyrin dimer-fullerene triad"Journal of the American Chemical Society. 124・18. 5165-5174 (2002)
[Publications] Fukuzumi, S. et al.: "Oxo-Transfer Reaction from a Bis(μ-oxo)dicopper(III) Complex to Sulfides"Journal of the American Chemical Society. 124・6. 998-1002 (2002)
[Publications] Fukuzumi, S. et al.: "Large Photocurrent Generation of Gold Electrodes Modified with [60]Fullerene-Linked Oligothiophenes Bearing a Tripodal Rigid Anchor"Journal of the American Chemical Society. 124・4. 532-533 (2002)
[Publications] Fukuzumi, S. et al.: "Comparison of reorganization energies for intra-and intermolecular electron transfer"Angewandte Chemie, International Edition. 41・13. 2344-2347 (2002)
[Publications] Fukuzumi, S. et al.: "Thermal intramolecular electron transfer in a ferrocene-naphthoquinone linked dyad promoted by metal ions"Angewandte Chemie, International Edition. 41・4. 620-622 (2002)
[Publications] Fukuzumi, S. et al.: "Mechanisms of Electron Transfer Oxidation of NADH Analogs and the Chemiluminescence. Detection of the Keto and Enol Radical Cations"Journal of the American Chemical Society. 125(in press). (2003)
[Publications] Fukuzumi, S. et al.: "Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation"Chemical Communications (Cambridge, United Kingdom). 17. 1984-1985 (2002)
[Publications] Fukuzumi, S. et al.: "Evidence that gold(III) porphyrins are not electrochemically inert : facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl) porphyrin"Chemical Communications (Cambridge, United Kingdom). 4. 356-357 (2002)
[Publications] Fukuzumi, S. et al.: "Driving Force Dependence of Intermolecular Electron Transfer Reactions of Fullerenes"Chemistry A European Journal. 9(in press). (2003)
[Publications] Fukuzumi, S. et al.: "Formation of a Supramolecular Porphyrin-Spacer-Acceptor Ternary Complex and Intracomplex Electron Transfer"Journal of Physical Chemistry A. 107・3. 379-385 (2003)
[Publications] Fukuzumi, S. et al.: "Small Reorganization Energy of Intramolecular Electron Transfer in Fullerene-Based Dyads with Short Linkage"Journal of Physical Chemistry A. 106・46. 10991-10998 (2002)
[Publications] Fukuzumi, S. et al.: "Effects of Metal Ions Distinguishing between One-Step Hydrogen-and Electron-Transfer Mechanisms for the Radical-Scavenging Reaction of (+)-Catechin"Journal of Physical Chemistry A. 106・46. 11123-11126 (2002)
[Publications] Fukuzumi, S. et al.: "Photophysical and Electrochemical Properties of New Bacteriochlorins and Characterization of Radical Cation and Radical Anion Species"Journal of Physical Chemistry A. 106・20. 5105-5113 (2002)
[Publications] Fukuzumi, S. et al.: "Linkage dependent charge separation and charge recombination in porphyrin-pyromellitimide-fullerene triads"Journal of Physical Chemistry A. 106・12. 2803-2814 (2002)
[Publications] Fukuzumi, S. et al.: "Electron transfer properties of singlet oxygen and promoting effects of scandium ion"Journal of Physical Chemistry A. 106・7. 1241-1247 (2002)
[Publications] Fukuzumi, S. et al.: "Dehydrogenation vs. Oxygenation in Photosensitized Oxidation of 9-Substituted 10-Methyl-9,10-dihydroacridine in the Presence of Scandium Ion"Journal of Physical Chemistry A. 106・7. 1465-1472 (2002)
[Publications] Fukuzumi, S. et al.: "Uphill photooxidation of NADH analogues by hexyl viologen catalyzed by zinc porphyrin-linked fullerenes"Journal of Physical Chemistry A. 106・10. 1903-1908 (2002)
[Publications] Fukuzumi, S. et al.: "DNA Cleavage via Superoxide Anion Formed in Photoinduced Electron Transfer from NADH to γ-Cyclodextrin-Bicapped C_<60> in an Oxygen-Saturated Aqueous Solution"Journal of Physical Chemistry B. 106・9. 2372-2380 (2002)
[Publications] Ogo, S.et al.: "Structural and Spectroscopic Features of a cis (Hydroxo)-Fe^<III>-(Carboxylato) Configuration as an Active Site Model for Lipoxygenases"Inorganic Chemistry. 41・21. 5513-5520 (2002)
[Publications] Fukuzumi, S. et al.: "Enhancement of photocurrent generation by ITO electrodes modified chemically with self-assembled monolayers of porphyrin-fullerene dyads"Advanced Materials (Weinheim, Germany). 14・12. 892-895 (2002)
[Publications] Fukuzumi, S. et al.: "A key role for old yellow enzyme in the metabolism of drugs by Trypanosoma cruzi"Journal of Experimental Medicine. 196・9. 1241-1251 (2002)
[Publications] Fukuzumi, S. et al.: "A Planar Catechin Analogue as a Promising Antioxidant with Reduced Prooxidant Activity"Chemical Research in Toxicology. 16・1. 81-86 (2003)
[Publications] Fukuzumi, S. et al.: "Acceleration and deceleration of photoinduced electron transfer rates by an electric field in porphyrin-fullerene dyads"Chemical Physics Letters. 368・1,2. 230-235 (2002)
[Publications] Fukuzumi, S. et al.: "Porphyrin-fullerene dyad with a long linker : formation of charge transfer conformer in Langmuir-Blodgett film"Chemical Physics Letters. 366・3,4. 245-252 (2002)
[Publications] Fukuzumi, S. et al.: "Dioxygen activation by copper complexes. Mechanistic insights into copper monooxygenases and copper oxidases"Bulletin of the Chemical Society of Japan. 75・10. 2081-2095 (2002)
[Publications] Fukuzumi, S. et al.: "Formation of superoxide-metal ion complexes and the electron transfer catalysis"Coordination Chemistry Reviews. 226・1-2. 71-80 (2002)
[Publications] Fukuzumi, S. et al.: "Direct detection of superoxide anion generated in C_<60>-photosensitized oxidation of NADH and an analogue by molecular oxygen"Journal of the Chemical Society, Perkin Transactions 2. 11. 1829-1833 (2002)
[Publications] Fukuzumi, S. et al.: "Effects of magnesium ion on kinetic stability and spin distribution of phenoxyl radical derived from a vitamin E analogue : mechanistic insight into antioxidative hydrogen-transfer reaction of vitamin E"Journal of the Chemical Society, Perkin Transactions 2. 9. 1520-1524 (2002)
[Publications] Fukuzumi, S. et al.: "Catalysis in electron transfer reactions : Facts and mechanistic insights"Journal of Physical Organic Chemistry. 15・8. 448-460 (2002)
[Publications] Fukuzumi, S. et al.: "Photocurrent generation using gold electrodes modified with self-assembled monolayers of a fullerene-porphyrin dyad"Journal of Materials Chemistry. 12・7. 2034-2040 (2002)
[Publications] Fukuzumi, S. et al.: "Enhancement of Light-Harvesting and Photocurrent Generation by ITO Electrodes Modified with meso, meso-Linked Porphyrin Oligomers"Nano Letters. 3(in press). (2003)
[Publications] Fukuzumi, S. et al.: "Electron transfer reduction of a highly electron-deficient fullerene, C_<60>F_<18>"Chemical Communications (Cambridge, United Kingdom). 17. 1952-1953 (2002)
[Publications] Fukuzumi, S. et al.: "Electron transfer in electron donor-acceptor ensembles containing porphyrins and metalloporphyrins"Journal of Porphyrins and Phthalocyanines. 6・4. 289-295 (2002)
[Publications] Fukuzumi, S. et al.: "Electron-Transfer Mechanism in Radical-Scavenging Reactions of Flavonoids"Free Radical Biol. Med.. 33. S308-S309 (2002)
[Publications] Fukuzumi, S. et al.: "Conducting molecular materials and electrochemistry. 1. Photoelectron transfer at electrodes modified with fullerene derivatives"Electrochemistry (Tokyo, Japan). 70・4. 274-278 (2002)
[Publications] Fukuzumi, S. et al.: "Clean energy from inexhaustible solar light"Gendai Kagaku. 375. 46-50 (2002)
[Publications] Fukuzumi, S. et al.: "Nanoscale artificial photosynthesis system using porphyrins and fullerenes"Kagaku Furontia (Bunshi Nanotekunoroji). 6. 115-125 (2003)
[Publications] Fukuzumi, S. et al.: "Catalytic Control of Electron Transfer Processes"Pure Appl. Chem.. (in press). (2003)
[Publications] Fukuzumi, S. et al.: "C_<70> vs. C_<60> in zinc porphyrin-fullerene dyads : prolonged charge separation and ultrafast energy transfer from the second excited singlet state of porphyrin"Photochemical & Photobiological Sciences. (in press). (2003)
[Publications] Fukuzumi, S.: "New Perspective of Electron Transfer Chemistry"Organic & Biomolecular Chemistry. (in press). (2003)
[Publications] Fukuzumi, S. et al.: "Electron Transfer Properties of Bisphenol Derivatives in Relation with the Developing Properties in Silver Salt Photothermographic Systems"J. Imag. Sci. Tech.. 47(in press). (2003)
[Publications] Shunichi Fukuzumi et al.: "Fullerenes 2002--Volume 12. (Proceedings of the 201^<st> Meeting of the Electrochemical Society)"The Electrochemical Society, INC. 37 (2002)
[Publications] Fukuzumi, S. et al.: "生産と技術"生産技術振興協会. 3 (2002)
[Publications] Fukuzumi, S. et al.: "先端ウオッチングシリーズ「錯体化学」"日本化学会. 6 (2002)

2002 Fiscal Year Annual Research Report

アルキル置換芳香族の100%選択的部分酸素化反応の開発

Principal Investigator

福住 俊一 大阪大学, 大学院・工学研究科, 教授 (40144430)

Research Products

[Publications] Fukuzumi, S. et al.: "Effects of Hydrogen Bonding on Metal Ion-Promoted Intramolecular Electron Transfer and Photoinduced Electron Transfer in a Ferrocene-Quinone Dyad with a Rigid Amide Spacer"Journal of the American Chemical Society. 125・4. 1007-1013 (2003)

[Publications] Ogo, S.et al.: "Isolation and Crystal Structure of Water-Soluble Iridium Hydride. Robust and Highly Active Catalyst for Acid-Catalyzed Transfer Hydrogenations of Carbonyl Compounds in Acidic Media"Journal of the American Chemical Society. 125(in press). (2003)

[Publications] Fukuzumi, S. et al.: "Scandium Ion-Promoted Reduction of Heterocyclic N : N Double Bond. Hydride Transfer vs Electron Transfer"Journal of the American Chemical Society. 124・42. 12566-12573 (2002)

[Publications] Fukuzumi, S. et al.: "Direct detection of radical cations of NADH analogues"Journal of the American Chemical Society. 124・49. 14538-14539 (2002)

[Publications] Fukuzumi, S. et al.: "Metal Ion-Catalyzed Diels-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Electron-Transfer Step"Journal of the American Chemical Society. 124・47. 14147-14155 (2002)

[Publications] Fukuzumi, S. et al.: "A Negative Temperature Dependence of the Electron Self-Exchange Rates of Zinc Porphyrin π Radical Cations"Journal of the American Chemical Society. 124・37. 10974-10975 (2002)

[Publications] Fukuzumi, S. et al.: "Fluorescence Maxima of 10-Methylacridone-Metal Ion Salt Complexes : A Convenient and Quantitative Measure of Lewis Acidity of Metal Ion Salts"Journal of the American Chemical Society. 124・35. 10270-10271 (2002)

[Publications] Fukuzumi, S. et al.: "Asymmetric Sulfoxidation and Amine Binding by H64D/V68A and H64D/V68S Mb : Mechanistic Insight into the Chiral Discrimination Step"Journal of the American Chemical Society. 124・29. 8506-8507 (2003)

[Publications] Fukuzumi, S. et al.: "Significant Enhancement of Electron Transfer Reduction of NAD+ Analogues by Complexation with Scandium Ion and the Detection of the Radical Intermediate-Scandium Ion Complex"Journal of the American Chemical Society. 124・31. 9181-9188 (2002)

[Publications] Fukuzumi, S. et al.: "Exciplex intermediates in photoinduced electron transfer of porphyrin-fullerene dyads"Journal of the American Chemical Society. 124・27. 8067-8077 (2002)

[Publications] Fukuzumi, S. et al.: "Hydrogen-bonding dynamics in photoinduced electron transfer in a ferrocene-quinone linked dyad with a rigid amide spacer"Journal of the American Chemical Society. 124・24. 6794-6795 (2002)

[Publications] Fukuzumi, S. et al.: "Fine-Tuning of Copper(I)-Dioxygen Reactivity by 2-(2-Pyridyl)ethylamine Bidentate Ligands"Journal of the American Chemical Society. 124・22. 6367-6377 (2002)

[Publications] Fukuzumi, S. et al.: "Stepwise charge separation and charge recombination in ferrocene-meso, meso-linked porphyrin dimer-fullerene triad"Journal of the American Chemical Society. 124・18. 5165-5174 (2002)

[Publications] Fukuzumi, S. et al.: "Oxo-Transfer Reaction from a Bis(μ-oxo)dicopper(III) Complex to Sulfides"Journal of the American Chemical Society. 124・6. 998-1002 (2002)

[Publications] Fukuzumi, S. et al.: "Large Photocurrent Generation of Gold Electrodes Modified with [60]Fullerene-Linked Oligothiophenes Bearing a Tripodal Rigid Anchor"Journal of the American Chemical Society. 124・4. 532-533 (2002)

[Publications] Fukuzumi, S. et al.: "Comparison of reorganization energies for intra-and intermolecular electron transfer"Angewandte Chemie, International Edition. 41・13. 2344-2347 (2002)

[Publications] Fukuzumi, S. et al.: "Thermal intramolecular electron transfer in a ferrocene-naphthoquinone linked dyad promoted by metal ions"Angewandte Chemie, International Edition. 41・4. 620-622 (2002)

[Publications] Fukuzumi, S. et al.: "Mechanisms of Electron Transfer Oxidation of NADH Analogs and the Chemiluminescence. Detection of the Keto and Enol Radical Cations"Journal of the American Chemical Society. 125(in press). (2003)

[Publications] Fukuzumi, S. et al.: "Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation"Chemical Communications (Cambridge, United Kingdom). 17. 1984-1985 (2002)

[Publications] Fukuzumi, S. et al.: "Evidence that gold(III) porphyrins are not electrochemically inert : facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl) porphyrin"Chemical Communications (Cambridge, United Kingdom). 4. 356-357 (2002)

[Publications] Fukuzumi, S. et al.: "Driving Force Dependence of Intermolecular Electron Transfer Reactions of Fullerenes"Chemistry A European Journal. 9(in press). (2003)

[Publications] Fukuzumi, S. et al.: "Formation of a Supramolecular Porphyrin-Spacer-Acceptor Ternary Complex and Intracomplex Electron Transfer"Journal of Physical Chemistry A. 107・3. 379-385 (2003)

[Publications] Fukuzumi, S. et al.: "Small Reorganization Energy of Intramolecular Electron Transfer in Fullerene-Based Dyads with Short Linkage"Journal of Physical Chemistry A. 106・46. 10991-10998 (2002)

[Publications] Fukuzumi, S. et al.: "Effects of Metal Ions Distinguishing between One-Step Hydrogen-and Electron-Transfer Mechanisms for the Radical-Scavenging Reaction of (+)-Catechin"Journal of Physical Chemistry A. 106・46. 11123-11126 (2002)

[Publications] Fukuzumi, S. et al.: "Photophysical and Electrochemical Properties of New Bacteriochlorins and Characterization of Radical Cation and Radical Anion Species"Journal of Physical Chemistry A. 106・20. 5105-5113 (2002)

[Publications] Fukuzumi, S. et al.: "Linkage dependent charge separation and charge recombination in porphyrin-pyromellitimide-fullerene triads"Journal of Physical Chemistry A. 106・12. 2803-2814 (2002)

[Publications] Fukuzumi, S. et al.: "Electron transfer properties of singlet oxygen and promoting effects of scandium ion"Journal of Physical Chemistry A. 106・7. 1241-1247 (2002)

[Publications] Fukuzumi, S. et al.: "Dehydrogenation vs. Oxygenation in Photosensitized Oxidation of 9-Substituted 10-Methyl-9,10-dihydroacridine in the Presence of Scandium Ion"Journal of Physical Chemistry A. 106・7. 1465-1472 (2002)

[Publications] Fukuzumi, S. et al.: "Uphill photooxidation of NADH analogues by hexyl viologen catalyzed by zinc porphyrin-linked fullerenes"Journal of Physical Chemistry A. 106・10. 1903-1908 (2002)

[Publications] Fukuzumi, S. et al.: "DNA Cleavage via Superoxide Anion Formed in Photoinduced Electron Transfer from NADH to γ-Cyclodextrin-Bicapped C_<60> in an Oxygen-Saturated Aqueous Solution"Journal of Physical Chemistry B. 106・9. 2372-2380 (2002)

[Publications] Ogo, S.et al.: "Structural and Spectroscopic Features of a cis (Hydroxo)-Fe^<III>-(Carboxylato) Configuration as an Active Site Model for Lipoxygenases"Inorganic Chemistry. 41・21. 5513-5520 (2002)

[Publications] Fukuzumi, S. et al.: "Enhancement of photocurrent generation by ITO electrodes modified chemically with self-assembled monolayers of porphyrin-fullerene dyads"Advanced Materials (Weinheim, Germany). 14・12. 892-895 (2002)

[Publications] Fukuzumi, S. et al.: "A key role for old yellow enzyme in the metabolism of drugs by Trypanosoma cruzi"Journal of Experimental Medicine. 196・9. 1241-1251 (2002)

[Publications] Fukuzumi, S. et al.: "A Planar Catechin Analogue as a Promising Antioxidant with Reduced Prooxidant Activity"Chemical Research in Toxicology. 16・1. 81-86 (2003)

[Publications] Fukuzumi, S. et al.: "Acceleration and deceleration of photoinduced electron transfer rates by an electric field in porphyrin-fullerene dyads"Chemical Physics Letters. 368・1,2. 230-235 (2002)

[Publications] Fukuzumi, S. et al.: "Porphyrin-fullerene dyad with a long linker : formation of charge transfer conformer in Langmuir-Blodgett film"Chemical Physics Letters. 366・3,4. 245-252 (2002)

[Publications] Fukuzumi, S. et al.: "Dioxygen activation by copper complexes. Mechanistic insights into copper monooxygenases and copper oxidases"Bulletin of the Chemical Society of Japan. 75・10. 2081-2095 (2002)

[Publications] Fukuzumi, S. et al.: "Formation of superoxide-metal ion complexes and the electron transfer catalysis"Coordination Chemistry Reviews. 226・1-2. 71-80 (2002)

[Publications] Fukuzumi, S. et al.: "Direct detection of superoxide anion generated in C_<60>-photosensitized oxidation of NADH and an analogue by molecular oxygen"Journal of the Chemical Society, Perkin Transactions 2. 11. 1829-1833 (2002)

[Publications] Fukuzumi, S. et al.: "Catalysis in electron transfer reactions : Facts and mechanistic insights"Journal of Physical Organic Chemistry. 15・8. 448-460 (2002)

[Publications] Fukuzumi, S. et al.: "Photocurrent generation using gold electrodes modified with self-assembled monolayers of a fullerene-porphyrin dyad"Journal of Materials Chemistry. 12・7. 2034-2040 (2002)

[Publications] Fukuzumi, S. et al.: "Enhancement of Light-Harvesting and Photocurrent Generation by ITO Electrodes Modified with meso, meso-Linked Porphyrin Oligomers"Nano Letters. 3(in press). (2003)

[Publications] Fukuzumi, S. et al.: "Electron transfer reduction of a highly electron-deficient fullerene, C_<60>F_<18>"Chemical Communications (Cambridge, United Kingdom). 17. 1952-1953 (2002)

[Publications] Fukuzumi, S. et al.: "Electron transfer in electron donor-acceptor ensembles containing porphyrins and metalloporphyrins"Journal of Porphyrins and Phthalocyanines. 6・4. 289-295 (2002)

[Publications] Fukuzumi, S. et al.: "Electron-Transfer Mechanism in Radical-Scavenging Reactions of Flavonoids"Free Radical Biol. Med.. 33. S308-S309 (2002)

[Publications] Fukuzumi, S. et al.: "Conducting molecular materials and electrochemistry. 1. Photoelectron transfer at electrodes modified with fullerene derivatives"Electrochemistry (Tokyo, Japan). 70・4. 274-278 (2002)

[Publications] Fukuzumi, S. et al.: "Clean energy from inexhaustible solar light"Gendai Kagaku. 375. 46-50 (2002)

[Publications] Fukuzumi, S. et al.: "Nanoscale artificial photosynthesis system using porphyrins and fullerenes"Kagaku Furontia (Bunshi Nanotekunoroji). 6. 115-125 (2003)

[Publications] Fukuzumi, S. et al.: "Catalytic Control of Electron Transfer Processes"Pure Appl. Chem.. (in press). (2003)

[Publications] Fukuzumi, S. et al.: "C_<70> vs. C_<60> in zinc porphyrin-fullerene dyads : prolonged charge separation and ultrafast energy transfer from the second excited singlet state of porphyrin"Photochemical & Photobiological Sciences. (in press). (2003)

[Publications] Fukuzumi, S.: "New Perspective of Electron Transfer Chemistry"Organic & Biomolecular Chemistry. (in press). (2003)

[Publications] Fukuzumi, S. et al.: "Electron Transfer Properties of Bisphenol Derivatives in Relation with the Developing Properties in Silver Salt Photothermographic Systems"J. Imag. Sci. Tech.. 47(in press). (2003)

[Publications] Shunichi Fukuzumi et al.: "Fullerenes 2002--Volume 12. (Proceedings of the 201^<st> Meeting of the Electrochemical Society)"The Electrochemical Society, INC. 37 (2002)

[Publications] Fukuzumi, S. et al.: "生産と技術"生産技術振興協会. 3 (2002)

[Publications] Fukuzumi, S. et al.: "先端ウオッチングシリーズ「錯体化学」"日本化学会. 6 (2002)

福住俊一大阪大学, 大学院・工学研究科, 教授 (40144430)