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2002 Fiscal Year Final Research Report Summary

Gravity Correlation and Separation Effect of Flow in HPLC

Research Project

Project/Area Number 13640599
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 分離・精製・検出法
Research InstitutionOchanomizu University

Principal Investigator

MORI Yoshihito  Ochanomizu University, Science, Associate Professor, 理学部, 助教授 (10239626)

Co-Investigator(Kenkyū-buntansha) SHIBATA Fumiaki  Ochanomizu University, Science, Professor, 理学部, 教授 (20011702)
Project Period (FY) 2001 – 2002
KeywordsHPLC / TLC / microgravity experiment / chromatography / International Space Station / separation analysis / nonlinear / nonequilibrium process
Research Abstract

The selection workings of the space-mission experiments on the International Space Station Project have been run with drop towers and parabolic fight airplanes in many related countries. We have studied the separation processes in the space with a tower and an airplane. The separation processes in a HPLC (high performance liquid chromatography) are phenomena in a reaction-diffusion-flow system and the experimental conditions must be empirically determined to control the processes because many and complex factor are related to them. But we can treat the processes as non-equilibrium and chemical phenomena running under an open condition from viewpoint of gap from a ideal condition. We have had experiments of the pattern dynamics in a TLC (thin layer chromatography) under a micro-gravity in a free-fall facility at JAMIC (Japan Microgravity Center, Kamisunagawa, Hokkaido). The principle of a TLC is as same as that of a HPLC essentially. The rate of the explosion increases as it is under a microgravity and decreases as under overgravity. These are as same as those expected before the experiment and it demonstrates that the expansion in a TLC runs against a gravity.

  • Research Products

    (13 results)

All Other

All Publications (13 results)

  • [Publications] S.Fujieda, Y.Mori: "Effect of Gravity Field on the Nonequilibrium/Nonlinear Chemical Oscillation Reactions"Advanced Space Research. 28, No.4. 537-543 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 森 義仁, 藤枝修子: "強磁場中での還元反応により生成した銀凝集体の回転運動解析"分析化学. 50, No.12. 907-910 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 本田数博, 森 義仁: "ポリアクリル酸アンモニウム界面活性剤共存下Ag(I)イオンのアスコルビン酸による還元反応により生じる銀結晶の形態"化学と教育. 50, No.1. 65-68 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 本田数博, 森 義仁: "ろ紙を用いたリーゼガング環形成"化学と教育. 51, No.2. 130-131 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 本田数博, 森 義仁: "溶存酸素水溶液中の鉄酸化反応に対する強磁場印加効果"表面技術. 54, No.1. 73-75 (2003)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Honda, Y.Mori: "The Oxdative Polymerization of Aniline Hydrochloride by Peroxidisulfate Ion in Strong Magnetic Field"Proceedings of International Symposium on Innovative Material Processing by Controlling Chemical Reaction Field. 156-159 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 本田数博, 森 義仁: "磁気科学(北沢宏一監修)"アイピーシ. 500(299-304) (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S. Fujieda, Y. Mori: "Effect of gravity field on the nonequilibrium / nonlinear chemical oscillation reactions"Advance Space Research. 28-4. 537-543 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Mori, S. Fujieda: "Analysis of rotatory motion of silver aggregate produced through a reduction reaction under a strong magnetic field"Bunsekikagaku. 50-12. 907-910 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Honda, Y. Mori: "Morphology of silver crystalline produced through a reduction reaction of silver ion with ascorbic acid in the presence of surfactant ammonium poyacrylate"Kagakutokyoiku. 50-1. 65-68 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K Honda, Y. Mori: "Pattern formation of the Leisegang ring on a paper filter"Kagakutokyoiku. 51-2. 130-131 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Honda, Y. Mori: "Magnetic effect on oxidation reaction of iron in the aqueous solution in the presence of solved oxygen"Hyomengijutsu. 54-1. 73-75 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Honda, Y. Mori: "The oxidative polymerization of aniline hydrochloride by peroxidisulfate ion in strong magnetic field"Proceedings international symposium on innovative material processing by controlling chemical reaction field. 156-159 (2002)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2004-04-14  

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