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2005 Fiscal Year Annual Research Report

ナノ構造配列を基盤とする分子ナノ工学の構築とマイクロシステムへの展開

Research Project

Project/Area Number 13CE2003
Research InstitutionWaseda University

Principal Investigator

大泊 巌  早稲田大学, 理工学術院, 教授 (30063720)

Co-Investigator(Kenkyū-buntansha) 逢坂 哲彌  早稲田大学, 理工学術院, 教授 (20097249)
西出 宏之  早稲田大学, 理工学術院, 教授 (90120930)
堀越 佳治  早稲田大学, 理工学術院, 教授 (60287985)
松本 和子  早稲田大学, 理工学術院, 教授 (60111457)
船津 高志  東京大学, 大学院薬学系研究科, 教授 (00190124)
Keywordsナノ理工学研究機構 / プロトタイプ / 生体分子 / 一分子観察 / 酸素センサ / 磁気記録 / 酸素富化膜 / マイクロ流路
Research Abstract

拠点の整備状況
本拠点を中核として、ナノテクファウンドリ、21世紀COEに係る2拠点などを統合した「ナノ理工学研究機構」の設立(平成15年12月)に加え、平成16年度には、文科省科学技術振興調整費「戦略的研究拠点形成プログラム」にかかわる「早稲田大学先端科学・健康医療融合研究機構」が発足、本拠点との連携によって、ナノバイオテクノロジー研究推進体制が強化された。
研究成果
各個研究に加え、チーム内外の共同研究を督励し、13件の研究を推進。また、プロトタイプ(PT)研究として、平成15年度に5件、16年度に更に2件の研究課題を選定。以下、グループ(G)毎に主要な研究成果をまとめる。
<ナノ物性G>
大泊研
・ドーパント原子の規則配列をもつ新規半導体を創製、特性揺らぎ減少を確認。本成果はNature誌に掲載。
・有機シラン単分子膜をレジストとする電子線リソグラフィを開発、分解能10nmの高精細パターン形成に成功。
・スライドガラスにナノ加工を施し、従来不可能な高濃度蛍光色素条件下での蛋白質間相互作用の1分子観察技術を実現。(共同-船津研)
・Si酸化過程を原子スケールで再現する大規模シミュレータの開発(PT研究)により、従来理論を覆す新理論の発見、酸化種拡散に関する理論予測の放射光X線回折実験による実証、に成功。(共同-阪大グループ)
・ナノ改質の原子的素過程の解明のために、独自開発した「イオン銃/超高真空高温STM複合装置」を用い、イオン照射誘起欠陥の動態、スパッタリング素過程のリアルタイム観察に成功。
川原田研
・ボロン(アクセプタ)を大量にドープした気相合成ダイヤモンドでの超伝導を発現。本成果はNature誌に掲載。
・100nmゲートダイヤモンドバイオセンサ開発に成功、MEMS技術を併用して、zept(10^<-19>〜10^<-21>)molの高感度検出を可能とした。
・表面修飾ダイヤモンドトランジスタ試作により、50GHzの動作周波数確認。1GHzでの出力密度2.1W/mmを実現。
・表面修飾ダイヤモンドによりDNAの局所固定およびDNAアクティブセンサ開発に成功。(共同-大泊研)
星野研
・蛋白質とナノ構造基板間の相互作用を理論的に計算し、基板の疎/親水性による水溶性蛋白質の小さな選択吸着性を発見、ナノ構造配列による蛋白質の結晶成長装置を試作。(共同-大泊研)
<ケミカルナノプロセスG>
逢坂研
・新電析浴により実用的に十分な腐食耐性を有する軟磁性CoFe薄膜の作製に成功。記録媒体薄膜の作製では、磁壁やラフネスの制御により低雑音化を実現。(PT研究)
・超小型燃料電池の試作セルにて、0.81mW/cm^2の出力密度と安定動作を実現。(共同-庄子研)
黒田研
・メソポーラス金属層の形成に成功。それを応用した新規デバイスの開発を開始。(共同-逢坂研)
・センチメートルスケールで単結晶様の細孔構造の配向性3次元メソポーラスシリカ薄膜作製に成功。
西出研
・高分子配列固定の研究において、電気化学的に有機ラジカル公文氏のスピン密度を可逆変化させることに成功。(共同-大泊研)
・Coポルフィリンに替る安価な材料としてCoフタロシアニンにおいて酸素促進輸送を確認。Coポルフィリンを多孔ガラスに担持させることによりマスクとしての使用に必要な高流量を達成。(PT研究)
<バイオマイクロシステムG>
松本研
・生体関連物質の超高感度検出のために新規希土類蛍光錯体の開発、DNA分析への応用、白金ナノワイヤ合成のための多核錯体の合成を行った。
・MEMS技術を活用した細胞破砕の基礎実験を行い、破砕時間200msを確認。(共同-庄子研)
庄子研
・バイオマイクロシステム構築のため、インジェクタ、フィルタ、バルブなどのマイクロ流体素子の試作、評価を行った。
・燃料電池および高感度酵素検出システムのマイクロ化。(共同-逢坂研)
船津研
・細胞内情報伝達の可視化のために、イントロンとエキソンを異なる蛍光色素で標識し、スプライシングを1分子レベルで検出する技術を開発。
・ガラス基板へのナノ開口配列形成により1分子レベルの生体分子間相互作用の検出技術を開発。(共同-大泊研、庄子研)
<ナノ理工学基礎G>
堀越研
・希薄磁性半導体GaMnAsにおいて世界最高のキュリー温度(250K)を達成。
・シングルイオン注入法による半導体中強磁性体クラスタ配列形成(共同-大泊研)、ペロブスカイト系強磁性体を用いる極微小不揮発性メモリなそ、半導体内スピンに関する研究を開始。
大場研
・ナノ実験系の基礎理論からの指導原理の提示を目的に、ナノ構造体と環境系との相互作用のモデル化、半導体中の励起子のトンネル現象(共同-堀越研)、半導体中の不純物原子配列が固体物性に及ぼす効果(共同-大泊研)の評価、などを進めた。

  • Research Products

    (160 results)

All 2006 2005

All Journal Article (125 results) Book (19 results) Patent(Industrial Property Rights) (16 results)

  • [Journal Article] Enhancement of field emission characteristics of tungsten emitters by single-walled carbon nanotube modification2006

    • Author(s)
      D.Ferrer, I.Ohdomari
    • Journal Title

      Appl.Phys.Lett. 88

      Pages: 033116-1-033116-3

  • [Journal Article] Analysis of Interactions between Luciferase and Si Substrates Using Molecular Dynamics Simulations2006

    • Author(s)
      K.Nishiyama, I.Ohdomari
    • Journal Title

      Jpn.J.Appl.Phys. Vol.45 No.2A

      Pages: 1021-1025

  • [Journal Article] DNA micropatterning on polycrystalline diamond via one-step direct amination2006

    • Author(s)
      G.-J.Zhang, I.Ohdomari
    • Journal Title

      Langmuir (in press)

  • [Journal Article] Structural investigation of organosilane self-assembled monolayers by atomic scale simulation2006

    • Author(s)
      H.Yamamoto, I.Ohdomari
    • Journal Title

      Journal de Physique IV(in press)

  • [Journal Article] シリコンナノ構造配列の作製とバイオアプリケーション2006

    • Author(s)
      谷井孝至, 大泊 巌
    • Journal Title

      金属 Vol.76 No.3

      Pages: 41-47

  • [Journal Article] Diamond MISFETs for High Frequency Applications2006

    • Author(s)
      H.Umezawa, H.Kawarada
    • Journal Title

      Jpn.J.Appl.Phys. 45(in press)

  • [Journal Article] 70 nm Channel Diamond MISFET and Suppression of Short Channel Effect2006

    • Author(s)
      H.Umezawa, H.Kawarada
    • Journal Title

      IEEE Elect.Device Lett. 27(in press)

  • [Journal Article] Advantage on Supercondutivity of Heavily Boron-Doped (111) Diamond Films2006

    • Author(s)
      H.Umezawa, H.Kawarada
    • Journal Title

      Phys.Rev.B 73(in press)

  • [Journal Article] Behavior of water molecules in ATPase pocket of myosin2006

    • Author(s)
      K.Yamanaka, T.Hoshino
    • Journal Title

      J.Mol.Struct : THEOCHEM Vol.758

      Pages: 97-105

  • [Journal Article] Enhancement of the Ductility of Electrodeposited Copper Films by Room-Temperature Recrystallization2006

    • Author(s)
      Madoka Hasegawa, Tetsuya Osaka
    • Journal Title

      J.Electrochem.Soc. 153

      Pages: C117-C120

  • [Journal Article] New Propasal of Evaluation Method for DMFC Catslyst Layers By Means of Electrochemical Impedance Spectroscopy2006

    • Author(s)
      Tetsuya Osaka
    • Journal Title

      Chem.Lett. 35

      Pages: 10-11

  • [Journal Article] Incident angle dependence of MCD at the Dy M5-edge of perpendicular magnetic DyxCo100-x films2006

    • Author(s)
      Akane Agui, Tetsuya Osaka
    • Journal Title

      J.Alloy Compd. 408-412

      Pages: 741-745

  • [Journal Article] Preparation of Layered Inorganic/Organic Nanocomposite Thin Films Using Chlorophyll Derivatives Possessing Triethoxysilyl Groups and Alkyltrialkoxysilane2006

    • Author(s)
      H.Furukawa, K.Kuroda
    • Journal Title

      J.Sol-Gel Sci.Technol (in press)

  • [Journal Article] Room-temperature high-spin organic single molecule : Nanometer-sized and hyperbranched poly[1,2,(4)-phenylenevinyleneanisylaminium]2006

    • Author(s)
      E.Fukuzaki, H.Nishide
    • Journal Title

      J.Am.Chem.Soc. 128

      Pages: 996-1001

  • [Journal Article] Synthesis of the isotope-labeled derivatization reagent for carboxylic acids,・・・・and its application to the quantification and the determination of relative amount of fatty acids in rat plasma samples by high-performance liquid chromatography/mass spectrometry2006

    • Author(s)
      Tsukamoto Y, T.Funatsu
    • Journal Title

      Biomedical Chromatography (in press)

  • [Journal Article] Catecholamine analysis with microcolumn LC-peroxyoxalate chemiluminescence reaction detection2006

    • Author(s)
      Tsunoda, M., T.Funatsu
    • Journal Title

      Clin.Chim.Acta. (in press)

  • [Journal Article] Analysis of Nuclear Microenvironments by Translational Diffusion of GFP Using Fluorescence Correlation Spectroscopy2006

    • Author(s)
      Terada, N., T.Funatsu
    • Journal Title

      bioimages (in press)

  • [Journal Article] A further study on the combined use of internal standard and isotope-labeled derivatization reagent for expansion of linear dynamic ranges in liquid chromatography-electrospray mass spectrometry2006

    • Author(s)
      Tsukamoto, Y., T.Funatsu
    • Journal Title

      Biomed.Chromatogr. (in press)

  • [Journal Article] Potential Errors in a Scheme of Universal Quantum Gates in.Kane's Model2006

    • Author(s)
      Y.Ota, I.Ohba
    • Journal Title

      Phys.Rev.A 73(in press)

  • [Journal Article] On the assumption of initial factorization in the master equation for weakly coupled systems I : General framework, quant-ph/06021842006

    • Author(s)
      S.Tasaki, I.Ohba
    • Journal Title

      Annals of Physics (be submitted)

  • [Journal Article] On the assumption of initial factorization in the master equation for weakly coupled systems II : Solvable model, quant-ph/06021852006

    • Author(s)
      K.Yuasa, I.Ohba
    • Journal Title

      Annals of Physics (be submitted)

  • [Journal Article] Nanoscale Patterning of Protein Using Electron Beam Lithography of Organosilane Self-Assembled Monolayers2005

    • Author(s)
      G.-J.Zhang, I.Ohdomari
    • Journal Title

      Small 1(8-9)

      Pages: 833-837

  • [Journal Article] A Novel Process for Fabrication of Gateed Silicon Field Emitter Array Taking Advantage of Ion Bombardment Retarded Etching2005

    • Author(s)
      T.Tanii, I.Ohdomari
    • Journal Title

      Jpn.J.Appl.Phys. Vol.44 No.7A

      Pages: 5191-5192

  • [Journal Article] Hybridization of Deoxyribonucleic Acid and Immobilization of Green Fluorescent Protein on Nanostructured Organosilane Templates2005

    • Author(s)
      T.Tanii, I.Ohdomari
    • Journal Title

      Jpn.J.Appl.Phys. Vol.44 No.7B

      Pages: 5851-5855

  • [Journal Article] Reactions and Diffusion of Atomic and Molecular Oxygen in the SiO_2 Network2005

    • Author(s)
      K.Tatsumura, I.Ohdomari
    • Journal Title

      Phys.Rev.B 72

      Pages: 045205

  • [Journal Article] ダイナミックボンド型分子動力学法の開発2005

    • Author(s)
      渡邉孝信
    • Journal Title

      化学工業 Vol.56 No.5

      Pages: 65-71

  • [Journal Article] Enhancing semiconductor device performance using ordered dopant arrays2005

    • Author(s)
      T.Shinada, I.Ohdomari
    • Journal Title

      Nature Vo1.437/20

      Pages: 1128-1131

  • [Journal Article] Analysis of Interactions between Green Fluorescent Protein and Si Substrates Using Molecular Dynamics Simulations2005

    • Author(s)
      K.Nishiyama, I.Ohdomari
    • Journal Title

      Jpn.J.Appl.Phys. Vol.44 No.11

      Pages: 8210-8215

  • [Journal Article] Development of liquid-metal-ion source low-energy ion gun/high-temperature ultrahigh vacuum scanning tunneling microscope combined system2005

    • Author(s)
      M.Uchigasaki, I.Ohdomari
    • Journal Title

      Rev.Sci.Instrum. Vol.76 No.126109

      Pages: 126109-1-126109-4

  • [Journal Article] Direct Evidence for Root Growth of Vertically Aligned Single-Walled Carbon Nanotubes by Microwave Plasma Chemical Vapor Deposition2005

    • Author(s)
      T.Iwasaki, H.Kawarada
    • Journal Title

      J.Phys.Chem.B 109, 42

      Pages: 19556-19559

  • [Journal Article] 先端放電型マイクロ波プラズマCVDによる単層カーボンナノチューブ配向成長2005

    • Author(s)
      岩崎 孝之, 鍾 国倣, 大泊 巌, 川原田 洋
    • Journal Title

      プラズマ・核融合学会誌 81, (9)

      Pages: 665-668

  • [Journal Article] Characterization of the Locally Modified Diamond Surface using a Kelvin Probe Force Microscope2005

    • Author(s)
      M.Tachiki, H.Kawarada
    • Journal Title

      Surf.Sci. 581, 2-3

      Pages: 207-212

  • [Journal Article] 多結晶ダイヤモンドを用いた電解質溶液FETsのバイオセンサへの応用2005

    • Author(s)
      宋 光燮, 川原田 洋
    • Journal Title

      日本結晶成長学会誌 58, 4

      Pages: 473-476

  • [Journal Article] 表面修飾ダイヤモンドトランジスタによるDNA及びバイオセンシング応用2005

    • Author(s)
      川原田 洋, 宋 光燮
    • Journal Title

      化学と工業 58-4

      Pages: 473-476

  • [Journal Article] Low Temperature Synthesis of Extremely Dense and Vertically Alined Single-Walled Carbon Nanotubes2005

    • Author(s)
      G.Zhong, H.Kawarada
    • Journal Title

      Jpn.J.Appl.Phys. 44

      Pages: 1558-1561

  • [Journal Article] Very high yield growth of vertically aligned single-walled carbon nanotubes by point-arc microwave plasma CVD2005

    • Author(s)
      G.Zhong, H.Kawarada
    • Journal Title

      Chem.Vapor.Depos. 11(3)

      Pages: 127-130

  • [Journal Article] Micropatterning Oligonucleotides on Single Crystal Diamond Surface by Photolithography2005

    • Author(s)
      G.J.Zhang, H.Kawarada
    • Journal Title

      Jpn.J.Appl.Phys. 44

      Pages: 295-298

  • [Journal Article] Characteristics of Diamond Electrolyte Solution-Gate FETs (SGFETs) and Applications to Biosensors2005

    • Author(s)
      K.S.Song, H.Kawarada
    • Journal Title

      New Diamond and Frontier Carbon Technology 15

      Pages: 325-335

  • [Journal Article] Origin of the metallic properties of heavily boron-doped superconducting diamond2005

    • Author(s)
      T.Yokoya, H.Kawarada
    • Journal Title

      Nature 438(7068)

      Pages: 647-650

  • [Journal Article] Computational analysis on the transient movement of helices in sensory rhodopsin II2005

    • Author(s)
      Y.Sato, T.Hoshino
    • Journal Title

      Protein Science Vol.14

      Pages: 183-192

  • [Journal Article] Resistant Mechanism against Nelfinavir of Human Immunodeficiency Virus Type 1 Proteases2005

    • Author(s)
      H.Ode, T.Hoshino
    • Journal Title

      J.Phys.Chem.B Vol.109

      Pages: 564-574

  • [Journal Article] Control of iron(III) spin state in the model complexes of azide hemoprotein by porphycene, corrphycene, and hemiporphycene macrocycles2005

    • Author(s)
      S.Neya, T.Hoshino
    • Journal Title

      Inorg.Chem. Vol.44

      Pages: 1193-1194

  • [Journal Article] Theoretical Study on Monooxygenation Mechanism by Cytochrome P450 : An Ultimate Species in the Substrate Oxidation Process2005

    • Author(s)
      M.Hata, T.Hoshino
    • Journal Title

      J.Mol.Struct. : THEOCHEM Vol.722

      Pages: 133-137

  • [Journal Article] A Theoretical Study on the Substrate Deacylation Mechanism of Class C beta-Lactamase2005

    • Author(s)
      M.Hata, T.Hoshino
    • Journal Title

      J.Phys.Chem. Vol.109

      Pages: 16153-16160

  • [Journal Article] Quantum chemical study on the deacylation step of human chymase2005

    • Author(s)
      Y.Hirano, T.Hoshino
    • Journal Title

      J.Mol.Struct. : THEOCHEM Vol.757

      Pages: 19-27

  • [Journal Article] Analysis of Interactions between Green Fluorescent Protein and Si Substrates Using Molecular Dynamics Simulations2005

    • Author(s)
      K.Nishiyama, T.Hoshino, I.Ohdomari
    • Journal Title

      Jpn.J.Appl.Phys. Vol.44

      Pages: 8210-8215

  • [Journal Article] Common semi-open conformations of Mg2+-free Ras, Rho, Rab, Arf, and Ran proteins combined with GDP and their similarity with GEF-bound forms2005

    • Author(s)
      K.Mori, T.Hoshino
    • Journal Title

      J.Am.Chem.Soc. Vol.127

      Pages: 15127-15137

  • [Journal Article] Estimation of ligand receptor binding affinity from the fluctuation of their interface2005

    • Author(s)
      K.Iwamoto, T.Hoshino
    • Journal Title

      Jpn.J.Appl.Phys. Vol.44

      Pages: L1370-L1372

  • [Journal Article] A Micro Direct Methanol Fuel Cell Using Platinum and Platinum-Ruthenium Electroplated Microchannel Electrodes2005

    • Author(s)
      Shinji Motokawa, Tetsuya Osaka
    • Journal Title

      Electrochemistry 73

      Pages: 346-351

  • [Journal Article] Fabrication Process of Sloped Micro-channel Electrodes for m-DMFC2005

    • Author(s)
      Shinji Motokawa, Tetsuya Osaka
    • Journal Title

      Electrochemistry 73

      Pages: 352-355

  • [Journal Article] Surface Conductivity in Methyl-monolayer/Si Heterojunction Structure in the Presence of Water2005

    • Author(s)
      Daisuke Niwa, Tetsuya Osaka
    • Journal Title

      Chem.Lett. 34

      Pages: 520-521

  • [Journal Article] Effects of additives on copper electrodeposition in submicrometer trenches2005

    • Author(s)
      Madoka Hasegawa, Tetsuya Osaka
    • Journal Title

      J.Electrochem.Soc. 152

      Pages: C221-C228

  • [Journal Article] Synthesis and characterization of mesostructured alloys with controlled compositions2005

    • Author(s)
      Y.Yamauchi, T.Osaka, K.Kuroda
    • Journal Title

      Stud.Surf.Sci.and Catal. 156

      Pages: 457-464

  • [Journal Article] Highly ordered mesostructured Ni particles prepered from lyotropic liquid crystals by electroless deposition : the effect of reducing agents on the ordering of mesostructure2005

    • Author(s)
      Yusuke Yamauchi, Kazuyuki Kuroda, Tetsuya Osaka
    • Journal Title

      J.Mater.Chem. 15

      Pages: 1987-1994

  • [Journal Article] Organosilane self-assembled monolayer-modified field effect transistors for on-chip ion and biomolecule sensing2005

    • Author(s)
      Daisuke Niwa, Tetsuya Osaka
    • Journal Title

      Sens.Act.B 108

      Pages: 721-726

  • [Journal Article] Direct Physical Casting of the Mesostructure in Lyotropic Liquid Crystalline Media by Electroless Deposition : Confirmation by TEM2005

    • Author(s)
      Yusuke Yamauchi, Tetsuya Osaka, Kazuyuki Kuroda
    • Journal Title

      8

      Pages: C141-C144

  • [Journal Article] Development of high-performance magnetic thin film for high-density magnetic recording2005

    • Author(s)
      Tetsuya Osaka
    • Journal Title

      Electrochim.Act. 50

      Pages: 4576-4585

  • [Journal Article] Preparation and Characterization of TiO2 Filled Sulfonated Poly(ether ether ketone) Nanocomposite Membranes for Direct Methanol Fuel Cells2005

    • Author(s)
      Han-Joo Kim, Tetsuya Osaka
    • Journal Title

      5-C

      Pages: 165-170

  • [Journal Article] Preparation and Electrochemical Characteristics of CNFs/DAAQ Electrode for Energy Storage2005

    • Author(s)
      Hong-II Kim, Tetsuya Osaka
    • Journal Title

      5-C

      Pages: 171-175

  • [Journal Article] Changes of Electro-Deposited Sn-Ni Alloy Thin Film for Lithium Ion Battery Anodes during Charge Discharge Cycling2005

    • Author(s)
      Hitomi Mukaibo, Tetsuya Osaka
    • Journal Title

      J.Power Sources 146

      Pages: 457-463

  • [Journal Article] Preparation and characterization of electroplated amorphous gold-nickel alloy film for electrical contact applications2005

    • Author(s)
      Norihiro Togasaki, Tetsuya Osaka
    • Journal Title

      Electrochim.Act. 51

      Pages: 882-887

  • [Journal Article] Surface modification of γ-Fe2O3 nanoparticles with aminopropylsilyl groups and interparticle linkage with α,ω-dicarboxylic acids2005

    • Author(s)
      Hironori Iida, Tetsuya Osaka
    • Journal Title

      Electrochim.Act. 51

      Pages: 855-859

  • [Journal Article] All-wet fabrication process for ULSI interconnect technologies2005

    • Author(s)
      M.Yoshino, T.Osaka
    • Journal Title

      Electrochim.Act. 51

      Pages: 916-920

  • [Journal Article] 半導体技術を用いた薄膜キャパシタ受動部品の作2005

    • Author(s)
      小岩一郎, 逢坂哲彌
    • Journal Title

      エレクトロニクス実装学会誌 8

      Pages: 517-522

  • [Journal Article] The study of antimicrobial activity and preservative effects of nanosilver ingredient2005

    • Author(s)
      K.H.Cho, T.Osaka
    • Journal Title

      Electrochim.Act. 51

      Pages: 956-960

  • [Journal Article] Unique Microstructure of Mesoporous Pt(H1-Pt) Prepared via Direct Physical Casting in Lyotropic Liquid Crystalline Media2005

    • Author(s)
      Yusuke Yamauchi, Tetsuya Osaka
    • Journal Title

      Chem.Mater. 17

      Pages: 6342-6348

  • [Journal Article] Fabrication of mesoporous Pt inside micrometer channels via "solvent-evaporation-mediated direct physical casting"2005

    • Author(s)
      Yusuke Yamauchi, Tetsuya Osaka
    • Journal Title

      Electrochem.Commun. 7

      Pages: 1364-1370

  • [Journal Article] SmCo5 Thin Films with High Magnetic Anisotropy for Perpendicular Magnetic Recording2005

    • Author(s)
      Junichi Sayama, Tetsuya Osaka
    • Journal Title

      IEEE Trans.Magn. 41

      Pages: 3133-3135

  • [Journal Article] Mesophase of colloidally dispersed nanosheets prepared by exfoliation of layered titanate and niobate2005

    • Author(s)
      Y.Nakato, K.Kuroda
    • Journal Title

      Thins Solid Films 495, 24

  • [Journal Article] Synthesis of Thermally Stable and 2-D Hexagonal Super-Microporous Silica from Hydrated α-Sodium Disilicate2005

    • Author(s)
      M.Kato, K.Kuroda
    • Journal Title

      Chem.Mater. 17

      Pages: 6416

  • [Journal Article] Unique Microstructure of Mesoporous Pt Prepared from Lyotropic Liquid Crystalline Media2005

    • Author(s)
      Y.Yamauchi, K.Kuroda
    • Journal Title

      Chem.Mater. 17

      Pages: 6342

  • [Journal Article] Layered Assembly of Alkoxy-Substituted Bis(trichlorosilanes) Containing Various Organic Bridges via Hydrolysis of Si-Cl Groups2005

    • Author(s)
      Y.Fujimoto, K.Kuroda
    • Journal Title

      J.Mater.Chem. 15

      Pages: 5151

  • [Journal Article] Fabrication of mesoporous Pt inside micrometer channels via "solvent-evaporation-mediated direct physical casting2005

    • Author(s)
      Y.Yamauchi, K.Kuroda
    • Journal Title

      Electorochem.Common. 7(12)

      Pages: 1364

  • [Journal Article] Self-Assembly of Designed Siloxane Oligomers with Alkyl Chains into Silica-Based Hybrid Mesostructures2005

    • Author(s)
      A.Shimojima, K.Kuroda
    • Journal Title

      J.Am.Chem.Soc. 127

      Pages: 14108-14116

  • [Journal Article] Adsorption of alcohols from aqueous Solutions into a layered silicate modified with octyltrichlorosilane2005

    • Author(s)
      I.Fujita, K.Kuroda
    • Journal Title

      Chem.Mater. 17

      Pages: 3717-3722

  • [Journal Article] Interlayer Esterification of Layered Silicic Acid-Alchol Nanostructured Materials Derived from Alkoxytrichlorosilane2005

    • Author(s)
      Y.Fujimoto, K.Kuroda
    • Journal Title

      Langmuir 21

      Pages: 7513-7517

  • [Journal Article] Direct Physical Casting of the Mesostructure in Lyotropic Liquid Crystalline Media by Electroless Deposition : Confirmation by TEM2005

    • Author(s)
      Y.Yamauchi, K.Kuroda
    • Journal Title

      Electrochem.Solid-State.Lett. 8

      Pages: C141-C144

  • [Journal Article] Synthesis and Characterization of Mesostructured Alloys with Controlled Compositions2005

    • Author(s)
      Y.Yamauchi, K.Kuroda
    • Journal Title

      Stud.Surf.Sci.Catal. 156

      Pages: 457

  • [Journal Article] Molecular Manipulation of Two- and Three-Dimensional Silica Nanostructures by Alkoxysilylation of a Layered Silicate Octosilicate and Subsequent Hydrolysis of Alkoxy Groups2005

    • Author(s)
      D.Mochizuki, K.Kuroda
    • Journal Title

      J.Am.Chem.Soc. 127

      Pages: 7183-7191

  • [Journal Article] Highly Ordered Mesostructured Ni Particles Prepared from Lyotropic Liquid Crystals by Electroless Deposition : The Effect of Reducing Agents on the Ordering of Mesostructure2005

    • Author(s)
      Y.Yamauchi, K.Kuroda
    • Journal Title

      J.Mater.Chem. 15

      Pages: 1987-1994

  • [Journal Article] Energy Transfer between Chlorophyll Derivatives in Silica MesostruCtured Films and Photocurrent Generation2005

    • Author(s)
      H.Furukawa, K.Kuroda
    • Journal Title

      Langmuir 21

      Pages: 3992-3997

  • [Journal Article] Orientation of Mesochannels in Continuous Mesoporous Silica Films by a High Magnetic Field2005

    • Author(s)
      Y.Yamauchi, K.Kuroda
    • Journal Title

      J.Mater.Chem. 11

      Pages: 1137-1140

  • [Journal Article] Synthesis and Electroluminescent Property of Poly(p-phenylenevinylene)s Bearing Triarylamine Pendants2005

    • Author(s)
      F.Liang, H.Nishide
    • Journal Title

      Polymer. 46

      Pages: 3767-3775

  • [Journal Article] Heat-Resistant Oxygen-Carrying Hernoproteins Consist of Recombinant Xylanases and Synthetic Iron(II)2005

    • Author(s)
      T.Komatsu, H.Nishide
    • Journal Title

      Biomacromolecules 6

      Pages: 1489-1494

  • [Journal Article] Rearrangement of Hollow Fibers for Enhancing Oxygen Transfer in an Artificial Gill Using Oxygen Carrier Solution2005

    • Author(s)
      K.Nagase, H.Nishide
    • Journal Title

      J.Membr.Sci. 254

      Pages: 207-217

  • [Journal Article] Radical Polymer and its Nano-Sized Thin Film Device2005

    • Author(s)
      Y.Yonekuta, H.Nishide
    • Journal Title

      J.Photopolym.Sic.Tech. 18

      Pages: 39-40

  • [Journal Article] A Helical Ladder Polymer : Synthesis and Magnetic Circular Dichroism of Poly[phenylene-4,6-bis(methylsulfonio)-1,3-diyl triflate]2005

    • Author(s)
      T.Iwasaki, H.Nishide
    • Journal Title

      Polym.J. 37

      Pages: 592-598

  • [Journal Article] Oxidative Polymerization in Water to Form Sulfoalkoxy Poly(phenylene oxide)s2005

    • Author(s)
      K.Saito, H.Nishide
    • Journal Title

      Bull.Chem.Soc Jpn. 78

      Pages: 1699-1701

  • [Journal Article] Electro- and Magneto-Responsible Chiral Polymers2005

    • Author(s)
      T.Iwasaki, H.Nishide
    • Journal Title

      Curr.Org.Chem. 9

      Pages: 1665-1684

  • [Journal Article] Acid-Functionalized Poly(phenylene oxide)s : Their Preparation and Properties2005

    • Author(s)
      K.Saito, H.Nishide
    • Journal Title

      Ind.Eng.Chem.Res. 44

      Pages: 8626-8630

  • [Journal Article] Synthesis and Electrochemical and Electroluminescent Properties of N-phenylcarbazole-Substituted Poly(p-phenylenevinylene)2005

    • Author(s)
      F.Liang, T.Kurata, H.Nishide
    • Journal Title

      J.Polym.Sci.Polym.Chem. 43

      Pages: 5765-5773

  • [Journal Article] Synthesis and Magnetic Property of Poly[bis(4-methoxyphenyl)aminiumacetylene]s2005

    • Author(s)
      H.Murata, H.Nishide
    • Journal Title

      Polym.J. 37

      Pages: 818-825

  • [Journal Article] Porphyrin Capped with Calix[4]arene Derivative via Hydrogen Bonds2005

    • Author(s)
      S.Arai, H.Nishide
    • Journal Title

      Bull.Chem.Soc Jpn. 78

      Pages: 2007-2013

  • [Journal Article] Poly[4,6-bis(bis(4-methoxyphenyl)arninium)-1,2-phenylenevinylene] : A High-Spin and Durable Polyradical2005

    • Author(s)
      H.Murata, H.Nishide
    • Journal Title

      Polyhedron 24

      Pages: 2309-2314

  • [Journal Article] Isomerization Reaction of Head-to-Head α-Pyridonato-Bridged Ethylenediaminepalladium(II) Binuclear Complex, [Pd_2(en)_2(C_5H_4NO)_2]^<2+>, in Aqueous Solution2005

    • Author(s)
      S.Iwatsuki, K.Matsumoto
    • Journal Title

      Dalton Transactions (in press)

  • [Journal Article] Rapid and Simple Quantitatlon of Methamphetamine by Using a Homogenous Time-Resolved Fluoroimmunoassay Based on Fluorescence Resonance Energy Transfer from Europium to Cy52005

    • Author(s)
      H.Kimura, K.Matsumoto
    • Journal Title

      J.Anal.Toxicol. 29

      Pages: 799-804

  • [Journal Article] Synthesis of the Pivalamidate-Bridged Pentanuclear Platinum (II, III) Linear Complexes with Pt-Pt Interactions2005

    • Author(s)
      Kazuko Matsumoto
    • Journal Title

      Organometallics 24

      Pages: 5528-5536

  • [Journal Article] Synthesis of Aryl-Platinum Dinuclear Complexes via ortho C-H Bond Activation of Phenol and Transmetalation of Arylboronic Acid2005

    • Author(s)
      Masahiko Ochiai, Kazuko Matsumoto
    • Journal Title

      Organometallics 24

      Pages: 5528-5536

  • [Journal Article] Precise investigation of the Axial Ligand Substitution Mechanism on a Hydrogenphosphato-Bridged Lantem-Type Platinum (III) Binuclear Complex in Acidic Aqueous Solution2005

    • Author(s)
      Satoshi Iwatsuki, Kazuko Matsumoto
    • Journal Title

      Inorg Chem. 44

      Pages: 8097-8104

  • [Journal Article] Thermodynamic Aspect of Reversible Structural Conversion Induced by Guest Adsorption/Desorption Based on Infinite Co(NCS)_2Py_4 (Py=pyridine) System2005

    • Author(s)
      Kazuhiro Uemura, Kazuko Matsumoto
    • Journal Title

      J.Therm.Anal.Calorim. 81

      Pages: 529-532

  • [Journal Article] Synthesis and fluorescence properties of the europium(III) chelate of a polyacid derivative of terpyridine2005

    • Author(s)
      Zhen Wang, Kazuko Matsumoto
    • Journal Title

      Luminescence 20

      Pages: 374-351

  • [Journal Article] Rapid increase in serum lipid peroxide 4-hydroxynonenal (HNE) through monocyte NADPH oxidase in early endo-toxemia2005

    • Author(s)
      Hiroko Kimura, Kazuko Matsumoto
    • Journal Title

      Free Radical Research 39(8)

      Pages: 845-851

  • [Journal Article] Paramagnetic Platinum-Rhodium Octamers Bridged by Halogen Ions To Afford a Quasi-ID System2005

    • Author(s)
      Kazuhiro Uemura, Kazuko Matsumoto
    • Journal Title

      Angew.Chem.Int.Edi. 44

      Pages: 2-7

  • [Journal Article] Picoliter Volume Glass Tube Array Fabricated by Si Electrochemical Etching Process2005

    • Author(s)
      H.Sato, T.Homma, K.Mori, T.Osaka, S.Shoji
    • Journal Title

      Electrochimica Acta Vol.51

      Pages: 844-848

  • [Journal Article] PDMS microchannels with slanted grooves embedded in three walls to realize efficient spiral flow2005

    • Author(s)
      H.Sato, S.Ito, K.Tajima, N.Orirnoto, S.Shoji
    • Journal Title

      Sensors and Actuators A Vol.119

      Pages: 365-371

  • [Journal Article] High efficiency electrochemical immuno sensors using 3D comb electrodes2005

    • Author(s)
      N.Honda, M.Inaba, T.Katagiri, S.Shoji
    • Journal Title

      Biosensors and Bioelectronics Vol.20, Issue 11

      Pages: 2306-2309

  • [Journal Article] マクロ流体素子を目的とした金属電極埋め込みPDMS三次元構造体組み立て技術2005

    • Author(s)
      石束真典, 阿部昌昭, 北條洋明, 水野潤, 庄子習一
    • Journal Title

      電気学会論文誌E Vol.125 No.9

      Pages: 393-397

  • [Journal Article] On-Chip Cell Sorting System Using Laser-Induced Heating of a Thermoreversible Gelation Polymer to Control Flow2005

    • Author(s)
      Y.Shirasaki, S.Shoji
    • Journal Title

      Analytical Chemistry Vol.78, No.3

      Pages: 695-701

  • [Journal Article] Rapid assay for catechol-O- methyltransferase activity by high-performance liquid chromatography-fluorescence detection2005

    • Author(s)
      Hirano, Y., T.Funatsu
    • Journal Title

      J.Chromatogr.B 819

      Pages: 41-46

  • [Journal Article] Synthesis of benzofurazan derivatization regents for carboxylic and acids and its application to analysis of fatty acids in rat plasma by high-performance liquid chromatography/electrospray ionization mass spectrometry2005

    • Author(s)
      Tsukamoto Y., T.Funatsu
    • Journal Title

      Biomed.Chromatogy. 19

      Pages: 802-808

  • [Journal Article] Hybridization of deoxyribonucleic acid immobilization of green fluorescent protein on nanostructured porganosilane templates2005

    • Author(s)
      Tanii, T., T.Funatsu
    • Journal Title

      Jpn.J.App.Phys. 44

      Pages: 5851-5855

  • [Journal Article] Nanoscale patterning of protein using electron beam lithography of organosilane self-assembled monolayers2005

    • Author(s)
      Zhang, G.-J., T.Funatsu
    • Journal Title

      Small 1

      Pages: 833-837

  • [Journal Article] Facilitated release of substrate protein from prefoldin by chaperonin2005

    • Author(s)
      Zako T., T.Funatsu
    • Journal Title

      FEBS Lett. 579

      Pages: 3718-3724

  • [Journal Article] Determination of methylated arginines by column-switching high-performance liquid chromatography-fluorescence detection2005

    • Author(s)
      Tsunoda, M., T.Funatsu
    • Journal Title

      Analyst 130

      Pages: 1410-1413

  • [Journal Article] On-chip cell sorting system using laser-induced heating of a thermo-reversible gelation.polymer to control flow2005

    • Author(s)
      Shirasaki, Y., T.Funatsu
    • Journal Title

      Anal.Chem. 78

      Pages: 695-701

  • [Journal Article] Nucleocytoplasmic transport of fluorescent mRNA in living mammalian cells : Nuclear mRNA export is coupled to ongoing gene transcription2005

    • Author(s)
      Tokunaga, K., T.Funatsu
    • Journal Title

      Genes to Cells 11

      Pages: 305-317

  • [Journal Article] Magnesium/nitrogen and beryllium/nitrogen coimplantation into GaN2005

    • Author(s)
      K.T.Liu, Y.Horikoshi
    • Journal Title

      J.Appl.Phys. 98, (7), No.073702

  • [Journal Article] Effects of MgO-buffer layer on the structural and optical properties of polycrystalline ZnO films grown on glass substrate2005

    • Author(s)
      Y.Deesirapipat, Y.Horikoshi
    • Journal Title

      Jpn.J.Appl.Phys.PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS 44 (7A)

      Pages: 5150-5155

  • [Journal Article] C and N co-implantation in Be-doped GaN2005

    • Author(s)
      K.T.Liu, Y.Horikoshi
    • Journal Title

      SEMICONDUCTOR SCIENCE AND TECHNOLOGY 20(8)

      Pages: 740-744

  • [Journal Article] ZnO MSM photodetectors with Ru contact electrodes2005

    • Author(s)
      T.K.Lin, Y.Horikoshi
    • Journal Title

      J.Crystal Growth 281

      Pages: 513-517

  • [Journal Article] Spatially separated Mn and Be doping for high hole concentration in GaMnAs by using MEE2005

    • Author(s)
      K.Onomitsu, Y.Horikoshi
    • Journal Title

      J.Cryst.Growth 278

      Pages: 699-703

  • [Journal Article] Mechanical and optical characteristics of Al-doped C60 films2005

    • Author(s)
      J.Nishinaga, Y.Horikoshi
    • Journal Title

      J.Crystal Growth 278

      Pages: 633-637

  • [Journal Article] Molecular abeam epitaxial growth of hexagonal ZnMgO films on Si(111) substrates using thin MgO buffer Layer2005

    • Author(s)
      M.Fujita, Y.Horikoshi
    • Journal Title

      J.Crystal Growth 278

      Pages: 293-298

  • [Journal Article] Crack-free ZnO layer growth on grass substrates by MgO-buffer Layer2005

    • Author(s)
      Y.Deesirapipat, Y.Horikoshi
    • Journal Title

      Inst.Phys.Conf.Ser. 184

      Pages: 307-310

  • [Journal Article] Growth and UV-A sensor applications of MgCdS/ZnCdS superlattices2005

    • Author(s)
      M.Kobayashi, Y.Horikoshi
    • Journal Title

      J.Crystal Growth 278

      Pages: 273-277

  • [Book] 電池革新が拓く次世代電源2006

    • Author(s)
      須賀 健雄, 西出 宏之
    • Publisher
      エヌ・ティー・エス
  • [Book] Carbon-Based Magnetism2006

    • Author(s)
      H.Murata, H.Nishide
    • Publisher
      T.Makarova, F.Palacio : Elsevier
  • [Book] バイオテクノロジーシリーズ「ナノテク・バイオMEMS時代の分離・計測技術」マイクロ流体制御素子2006

    • Author(s)
      庄子習一
    • Publisher
      シーエムシー出版
  • [Book] 化学と生物44(1)1分子蛍光イメージング法による生体分子の機能と相互作用の解析2006

    • Author(s)
      船津高志
  • [Book] ゾル-ゲル法のナノテクノロジーへの応用(作花済夫 監修)2005

    • Author(s)
      下嶋敦, 黒田一幸
    • Publisher
      シーエムシー出版
  • [Book] ナノコンポジットマテリアル(井上明久 編集)2005

    • Author(s)
      下嶋敦, 黒田一幸
    • Publisher
      フロンティア出版
  • [Book] 無機ナノシートの科学と応用(黒田一幸、佐々木高義 監修)2005

    • Author(s)
      下嶋敦, 黒田一幸
    • Publisher
      シーエムシー出版
  • [Book] 無機ナノシートの科学と応用(黒田一幸、佐々木高義 監修)2005

    • Author(s)
      望月大, 黒田一幸
    • Publisher
      シーエムシー出版
  • [Book] 無機ナノシートの科学と応用(黒田一幸、佐々木高義 監修)2005

    • Author(s)
      木村辰雄, 黒田一幸
    • Publisher
      シーエムシー出版
  • [Book] 実験化学講座(第5版)2005

    • Author(s)
      木村辰雄, 黒田一幸
    • Publisher
      丸善
  • [Book] Arrangement of Polymer Nanoparticles on Micro- and Nano-fabricated Silicon Substrate" in "Functional Nanomaterials2005

    • Author(s)
      M.Tanaka, H.Nishide
    • Publisher
      K.E.Geckeler, E.Rosenberg : American Scientific Publisher
  • [Book] Organic Radical Battery2005

    • Author(s)
      H.Nishide, T.Suga
    • Publisher
      The Electrochemical Society Interface, winter
  • [Book] 標準化学用語辞典 第二版(日本化学会編)2005

    • Author(s)
      松本和子(編集幹事)
    • Publisher
      丸善
  • [Book] 化学測定の事典(梅澤喜夫編)2005

    • Author(s)
      松本和子(分担執筆)
    • Publisher
      朝倉書店
  • [Book] ナノインプリントの開発と応用-マイクロ流体デバイス-2005

    • Author(s)
      水野 潤, 庄子習一
    • Publisher
      シーエムシー出版
  • [Book] ポリマーフロンティア21シリーズ「ナノバイオ-微細加工と計測技術の新展開」マイクロ/ナノシステムの創製と化学・生化学への応用(高分子学会編)2005

    • Author(s)
      庄子習一
    • Publisher
      高分子学会
  • [Book] バイオイメージングがわかる「1分子イメージングの考え方と実際」(高松哲郎 編)2005

    • Author(s)
      船津高志
    • Total Pages
      125
    • Publisher
      羊土社
  • [Book] 光学34(10)エバネッセント場蛍光顕微鏡による生体分子の1分子機能解析2005

    • Author(s)
      船津高志, 上野太郎
  • [Book] "Semiconductor Microstructure Fabrication by Area Selective Epitaxy for Optical Integrated Circuit Applications" Photonics Based on Wavelength Integration and Manipulation2005

    • Author(s)
      Yoshiji Horikoshi, Koji Onomitsu
    • Publisher
      IPAP Books 2
  • [Patent(Industrial Property Rights)] 微小開口膜、生体分子間相互作用解析方法及びその装置2006

    • Inventor(s)
      谷井孝至, 大泊巌, 船津高志
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2006-015559(日本)
    • Filing Date
      2006-01-24
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    • Inventor(s)
      逢坂哲彌他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2006-024476(日本)
    • Filing Date
      2006-02-01
  • [Patent(Industrial Property Rights)] 微小開口膜、生体分子間相互作用解析方法及びその装置2006

    • Inventor(s)
      船津高志他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2006-15559
    • Filing Date
      2006-01-24
  • [Patent(Industrial Property Rights)] PERPENDICULAR MAGNETIC RECORDING MEDIUM PRODUCTION PROCESS THFREOF AND PERPENDICULAR MAGNETIC RECORDING AND REPRODUCING APPARATUS2005

    • Inventor(s)
      M.Ohmori, T.Osaka et al.
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2005-7007730(韓国)
    • Filing Date
      2005-04-30
  • [Patent(Industrial Property Rights)] 金属針構造体及びその製造方法2005

    • Inventor(s)
      逢坂哲彌他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2005-109563(日本)
    • Filing Date
      2005-04-06
  • [Patent(Industrial Property Rights)] PERPENDICULAR MAGNETIC RECORDING MEDIUM PRODUCTION PROCESS THFREOF AND PERPENDICULAR MAGNETIC RECORDING AND REPRODUCING APPARATUS2005

    • Inventor(s)
      M.Ohmori, T.Osaka et al.
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願11/118,468(米国)
    • Filing Date
      2005-05-02
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    • Inventor(s)
      逢坂哲彌他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2005-286759(日本)
    • Filing Date
      2005-09-30
  • [Patent(Industrial Property Rights)] 燃料電池2005

    • Inventor(s)
      逢坂哲彌, 門間聰之, 朴鍾殷
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2005-259469(日本)
    • Filing Date
      2005-09-07
  • [Patent(Industrial Property Rights)] 固体高分子電解質型燃料電池用バイポーラプレート及び固体高分子電解質型燃料電池2005

    • Inventor(s)
      逢坂哲彌他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2005-294270(日本)
    • Filing Date
      2005-10-07
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    • Inventor(s)
      逢坂哲彌他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2005-323127(日本)
    • Filing Date
      2005-11-08
  • [Patent(Industrial Property Rights)] 軟磁性薄膜の製造方法2005

    • Inventor(s)
      逢坂哲彌他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2005-352193(日本)
    • Filing Date
      2005-12-06
  • [Patent(Industrial Property Rights)] アモルファス金-ニッケル系合金めっき皮膜形成用電気めっき液及び電気めっき方法2005

    • Inventor(s)
      逢坂哲彌他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2005-368186(日本)
    • Filing Date
      2005-12-21
  • [Patent(Industrial Property Rights)] 高感度免疫測定法2005

    • Inventor(s)
      松本和子他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      ZL008064053(中国)
    • Filing Date
      2005-11-16
  • [Patent(Industrial Property Rights)] 微粒子分別マイクロシステムおよび微粒子分別方法2005

    • Inventor(s)
      庄子習一他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2005-0345393
    • Filing Date
      2005-11-30
  • [Patent(Industrial Property Rights)] 分子振動計測法、分子振動計測装置、試料調製用キット及び分子振動計測システム2005

    • Inventor(s)
      船津高志他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2005-219539
    • Filing Date
      2005-07-28
  • [Patent(Industrial Property Rights)] 微粒子分別マイクロシステムおよび微粒子分別方法2005

    • Inventor(s)
      船津高志他
    • Industrial Property Rights Holder
      早稲田大学
    • Industrial Property Number
      特願2005-345393
    • Filing Date
      2005-11-30

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Published: 2007-04-02   Modified: 2016-04-21  

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