Functionalization of Supramolecular Polymers

2006 Fiscal Year Final Research Report Summary

• Project/Area Number: 14103015
• Research Category: Grant-in-Aid for Scientific Research (S)
• Allocation Type: Single-year Grants
• Research Field: 高分子合成
• Research Institution: Osaka University
• Principal Investigator: HARADA Akira Osaka University, Graduate School of Science, Professor, 大学院理学研究科, 教授 (80127282)
• Co-Investigator(Kenkyū-buntansha): YAMAGUCHI Hiroyasu Osaka University, Graduate School of Science, Assistant Professor, 大学院理学研究科, 助手 (00314352) ; TAKASHIMA Yoshinori Osaka University, Graduate School of Science, Assistant Professor, 大学院理学研究科, 助手 (40379277)
• Project Period (FY): 2002 – 2006
• Keywords: Molecular Recognition / Inclusion / Supramolecular Polymer / Cyclodextrin / Rotaxane / Gel / Self-Assembly / Dynamics

Research Abstract

1.Construction of Supramolecular Polymers
When a guest part was covalently attached to cyclodextrin (CD), they formed supramolecular dimers, a cyclic daisy chain, supramolecular oligomers, and polymers. t-Boc-cinnamamide-α-CD was found to form chiral supramolecular polymers in aqueous solutions. Supramolecular poly[2]rotaxane polymers and supramolecular α-, β-CD copolymers were obtained.
2.Dymanics of Supramolecular Polymers
We investigated a new one-pot method to prepare polyrotaxanes containing γ-CDs by the photocyclodimerization reactions of 9-anthryl groups at the ends of the polymer chain in the presence of γ-CDs.
We have constructed pseudo-rotaxanes of α-CD with axle molecules bearing pyridyl end caps via kinetic control of threading of α-CD onto axle molecules. A single substituted pyridyl group attached to the ends of the axle molecule regulated the rate for α-CD passing them. Two methyl substituents could govern the degree of complex formation of a-CD with guest molecules and resu lted in the distinction of face direction of CD molecules entering the axle ends. α-CDs were arranged in one direction at two station units of the axle molecule.
Poly(ethylene glycol) (PEG)-substituted CDs with different chain lengths have been synthesized. PEG-substituted CDs formed self-threading complexes in aqueous solutions, and the conformational exchange dynamics between self-threading and dethreading could be regulated by its chain length.
3.Polymerization of lactones
CDs were found to initiate ring-opening polymerization of some cyclic esters selectively to give a polyester with a CD at the chain end.
4.Gel-to-Sol and Sol-to-Gel Transitions
Using molecular recognition of α-CD, we have successfully constructed a photoresponsive hydrogel system by combination of simple components, α-CD, dodecyl-modified poly(acrylic acid), and a photoresponsive competitive guest, 4,4'-azodibenzoic acid. Gel-to-sol and sol-to-gel transitions occurred repeatedly by repetitive irradiations of UV and visible light.

Research Products

• [Journal Article] A Chemical-Responsive Supramolecular Hydrogel from Modified Cyclodextrins (2007)
  • Author(s): Deng, W., Yamaguchi, H., Takashima, Y., Harada, A.
  • Journal Title: Angew. Chem. Int. Ed. (in press)
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Face Selective [2] and [3] Rotaxanes : Kinetic Control of Threading Direction of Cyclodextrins (2007)
  • Author(s): Oshikiri, T., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Chem. Eur. J. (in press)
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Thermally and Photochemically Switching of Conformation of Poly(ethylene glycol)-Substituted Cyclodextrin with an Azobenzene Group at the Chain End (2007)
  • Author(s): Inoue, Y., Kuad, P., Okumura, Y., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J. Am. Chem. Soc. 129・20 Pages: 6396-6397
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Self-Threading and Dethreading Dynamics of Poly(ethylene glycol)-Substituted Cyclodextrins with Different Chain Lengths (2007)
  • Author(s): Inoue, Y., Miyauchi, M., Nakajima, H., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Macromolecules 40・9 Pages: 3256-3262
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Chemically-Responsive Sol-Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by Hybrids of SWNTs and Cyclodextrins (CDs) (2007)
  • Author(s): Ogoshi, T., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J. Am. Chem. Soc. 129・16 Pages: 4878-4879
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Polymerization of Lactones Initiated by Cyclodextrins : Effects of Cyclodextrins on the Initiation and Propagation Reactions (2007)
  • Author(s): Osaki, M., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Macromolecules 40・9 Pages: 3154-3158
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Contraction of Supramolecular Double-Threaded Dimer Formed by α-Cyclodextrin with a Long Alkyl Chain (2007)
  • Author(s): Tsukagoshi, S., Miyawaki, A., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Org. Lett. 9・6 Pages: 1053-1055
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Preparation and Properties of Rotaxanes Formed by Dimethyl-β-Cyclodextrin and Oligo(thiophene)s with β-Cyclodextrin Stoppers (2007)
  • Author(s): Sakamoto, K., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J. Org. Chem. 72・2 Pages: 459-465
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Enhancement of Photoinduced Electron Transfer from Porphyrin to Methyl Viologen by Binding of an Antibody for Porphyrin (2007)
  • Author(s): Onji, T., Ohara, H., Yamaguchi, H., Ikeda, N., Harada, A.
  • Journal Title: Chem. Lett. 35・10 Pages: 1126-1127
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] A Chemical-Responsive Supramolecular Hydrogel from Modified Cyclodextrins (2007)
  • Author(s): Deng, W., Yamaguchi, H., Takashima, Y., Harada, A.
  • Journal Title: Angew.Chem.Int.Ed.
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Face Selective [2] and [3] Rotaxanes : Kinetic Control of Threading Direction of Cyclodextrins (2007)
  • Author(s): Oshikiri, T., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Chem.Eur.J.
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Thermally and Photochemically Switching of Conformation of Poly(ethylene glycol)-Substituted Cyclodextrin with an Azobenzene Group at the Chain End (2007)
  • Author(s): Inoue, Y., Kuad, P., Okumura, Y., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J.Am.Chem.Soc. 129・20 Pages: 6396-6397
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Self-Threading and Dethreading Dynamics of Poly(ethylene glycol)-Substituted Cyclodextrins with Different Chain Lengths (2007)
  • Author(s): Inoue, Y., Miyauchi, M., Nakajima, H., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Macromolecules 40-9 Pages: 3256-3262
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Chemically-Responsive Sol-Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by Hybrids of SWNTs and Cyclodextrins (CDs) (2007)
  • Author(s): Ogoshi, T., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J.Am.Chem.Soc. 129-16 Pages: 4878-4879
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Polymerization of Lactones Initiated by Cyclodextrins : Effects of Cyclodextrins on the Initiation and Propagation Reactions (2007)
  • Author(s): Osaki, M., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Macromolecules 40-9 Pages: 3154-3158
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Contraction of Supramolecular Double-Threaded Dimer Formed by a-Cyclodextrin with a Long Alkyl Chain (2007)
  • Author(s): Tsukagoshi, S., Miyawaki, A., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Org.Lett. 9-6 Pages: 1053-1055
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Preparation and Properties of Rotaxanes Formed by Dimethyl-β-Cyclodextrin and Oligo(thiophene)s with β-Cyclodextrin Stoppers (2007)
  • Author(s): Sakamoto, K., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J.Org.Chem. 72-2 Pages: 459-465
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Supramplecular Polymers Based on Cyclodextrins (2006)
  • Author(s): Harada, A.
  • Journal Title: J. Polym. Sci. A. Polym. Chem. 44・17 Pages: 5113-5119
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Competitive Photoinduced Electron Transfer by the Complex Formation of Porphyrin with Cyclodextrin Bearing Viologen (2006)
  • Author(s): Deng, W., Onji, T., Yamaguchi, H., Ikeda, N., Harada, A.
  • Journal Title: Chem. Commun. 40 Pages: 4212-4214
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Asymmetric Hydrogenation with Antibody-Achiral Rhodium Complex (2006)
  • Author(s): Yamaguchi, H., Hirano, T., Kiminami, H., Taura, D., Harada, A.
  • Journal Title: Org. Biomol. Chem. 4・19 Pages: 3571-3573
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Cyclodextrin-Grafted Poly(phenylene ethynylene) with Chemical-Responsive Properties (2006)
  • Author(s): Ogoshi, T., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Chem. Commun. 35 Pages: 3702-3704
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Complex Formation of Cyclodextrins with Various Thiophenes and Their Polymerization in Water : Preparation of pseudo-Polyrotaxanes Containing Poly(thiophene)s (2006)
  • Author(s): Takashima, Y., Sakamoto, K., Oizumi, Y., Yamaguchi, H., Kamitori, S., Harada, A.
  • Journal Title: J. Incl. Phenom. Macrocycl. Chem. 56・1-2 Pages: 45-53
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Rotaxanes with Unidirectional Cyclodextrin Arrays (2006)
  • Author(s): Yamaguchi, H., Oshikiri, T., Harada, A.
  • Journal Title: J. Phys. Condens. Matter 18・33 Pages: S1809-S1816
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Interaction of Cyclodextrins with Side Chains of Water Soluble Polymers : A Simple Model for Biological Molecular Recognition and its Utilization for Stimuli-Responsive Systems (2006)
  • Author(s): Hashidzume, A., Tomatsu, I., Harada, A.
  • Journal Title: Polymer 47・17 Pages: 6011-6027
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Syntheses of Group 4 Transition Metal Complexes Bearing 2-Pyridinethiolate Ligands and their Catalytic Activities for Ethylene Polymerization (2006)
  • Author(s): Takashima, Y., Nakayama, Y., Hashiguchi, M., Hosoda, T., Yasuda, H., Hirao T., Harada, A.
  • Journal Title: Polymer 47・16 Pages: 5762-5774
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Self-Threading of a Poly(ethylene glycol) Chain in a Cyclodextrin-Ring : Control of the Exchange Dynamics by Chain Length (2006)
  • Author(s): Inoue, Y., Miyauchi, M., Nakajima, H., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J. Am. Chem. Soc. 128・28 Pages: 8994-8995
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Cyclodextrin-Based Side Chain Polyrotaxane with Unidirectional Inclusion in Aqueous Media (2006)
  • Author(s): Tomatsu, I., Hashidzume, A., Harada, A.
  • Journal Title: Angew. Chem. Int. Ed. 45・28 Pages: 4605-4608
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Cyclodextrin-Based Supramolecular Polymers (2006)
  • Author(s): Harada, A., Hashidzume, A., Takashima, Y.
  • Journal Title: Adv. Polym. Sci. 201 Pages: 1-43
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Synthesis of a Water-Soluble Iridium(III) Complex with pH and Metal Cation Sensitive Photoluminescence (2006)
  • Author(s): Konishi, K., Yamaguchi, H., Harada, A.
  • Journal Title: Chem. Lett. 35・7 Pages: 720-721
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Selection between Pinching-Type and Supramolecular Polymer-Type Complexes by α-Cyclodextrin-β-Cyclodextrin Hetero-Dimer and Hetero-Cinnamamide Guest Dimers (2006)
  • Author(s): Takahashi, H., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J. Org. Chem. 71・13 Pages: 4878-4883
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Novel Switchable Hydrogels via Supramolecular Cross-Linking of Adamantyl Containing LCST-Copolymers with Cyclodextrin Dimers (2006)
  • Author(s): Kretschmann, O., Choi, S.-W., Miyauchi, M., Tomatsu, I., Harada, A., Ritter, H.
  • Journal Title: Angew. Chem. Int. Ed. 45・26 Pages: 4361-4365
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Formation of Chiral Supramolecular Polymer Based on Modified Cyclodextrin by Host-Guest Interactions (2006)
  • Author(s): Miyawaki, A., Miyauchi, M., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Kobunshi Ronbunshu 63・5 Pages: 306-314
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Spectroscopic Study on the Interaction of Cyclodextrins with Naphthyl Groups Attached to Poly(acrylamide) Backbone (2006)
  • Author(s): Harada, A., Ito, F., Tomatsu, I., Shimoda, K., Hashidzume, A., Takashima, Y., Yamaguchi, H., Kamitori, S.
  • Journal Title: J. Photochem. Photobiol., A 179・1-2 Pages: 13-19
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Contrast Viscosity Changes upon Photoirradiation for Mixtures of Poly(acrylic acid)-Based α-Cyclodextrin and Azobenzene Polymers (2006)
  • Author(s): Tomatsu, I., Hashidzume, A., Harada, A.
  • Journal Title: J. Am. Chem. Soc. 128・7 Pages: 2226-2227
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Redox-Responsive Hydrogel System Using the Molecular Recognition of β-Cyclodextrin (2006)
  • Author(s): Tomatsu, I., Hashidzume, A., Harada, A.
  • Journal Title: Macromol. Rapid Commun. 27・4 Pages: 238-241
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Macromolecular Recognition by Cyclodextrins. Interaction of Cyclodextrins with Polymethacrylamides Bearing Hydrophobic Amino Acid Residues (2006)
  • Author(s): Hashidzume, A., Harada, A.
  • Journal Title: Polymer 47・10 Pages: 3448-3454
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Polymer Formation Utilizing "Crisscross" Addition (Crisscross Addition Polymerization) of Acetaldehyde Azine and 1,4-Phenylene Diisocyanate (2006)
  • Author(s): Hashidzume, A., Shiota, J., Ueno, Y., Noda, T., Takashima, Y., Harada, A., Kamachi, M.
  • Journal Title: Polymer 47・2 Pages: 501-505
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Supramplecular Polymers Based on Cyclodextrins (2006)
  • Author(s): Harada, A.
  • Journal Title: J.Polym.Sci.A.Polym.Chem. 44-17 Pages: 5113-5119
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Competitive Photoinduced Electron Transfer by the Complex Formation of Porphyrin with Cyclodextrin Bearing Viologen (2006)
  • Author(s): Deng, W., Onji, T., Yamaguchi, H., Ikeda, N., Harada, A.
  • Journal Title: Chem.Commun. -・40 Pages: 4212-4214
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Enhancement of Photoinduced Electron Transfer from Porphyrin to Methyl Viologen by Binding of an Antibody for Porphyrin (2006)
  • Author(s): Onji, T., Ohara, H.Yamaguchi, H., Ikeda, N., Harada, A.
  • Journal Title: Chem.Lett. 35-10 Pages: 1126-1127
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Asymmetric Hydrogenation with Antibody-Achiral Rhodium Complex (2006)
  • Author(s): Yamaguchi, H., Hirano, T., Kiminami, H., Taura, D., Harada, A.
  • Journal Title: Org.Biomol.Chem. 4-19 Pages: 3571-3573
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Cyclodextrin-Grafted Poly(phenylene ethynylene) with Chemical-Responsive Properties (2006)
  • Author(s): Ogoshi, T., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Chem.Commun. -・35 Pages: 3702-3704
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Complex Formation of Cyclodextrins with Various Thiophenes and Their Polymerization in Water : Preparation of pseudo-Polyrotaxanes Containing Poly(thiophene)s (2006)
  • Author(s): Takashima, Y., Sakamoto, K., Oizumi, Y., Yamaguchi, H., Kamitori, S., Harada, A.
  • Journal Title: J.Incl.Phenom.Macrocycl.Chem. 56-1-2 Pages: 45-53
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Rotaxanes with Unidirectional Cyclodextrin Arrays (2006)
  • Author(s): Yamaguchi, H., Oshikiri, T., Harada, A.
  • Journal Title: J.Phys.Condens.Matter 2006 Pages: S1809-S1816
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Interaction of Cyclodextrins with Side Chains of Water Soluble Polymers : A Simple Model for Biological Molecular Recognition and its Utilization for Stimuli-Responsive Systems (2006)
  • Author(s): Hashidzume, A., Tomatsu, I., Harada, A.
  • Journal Title: Polymer 47-17 Pages: 6011-6027
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Syntheses of Group 4 Transition Metal Complexes Bearing2-Pyridinethiolate Ligands and their Catalytic Activities for Ethylene Polymerization (2006)
  • Author(s): Takashima, Y., Nakayama, Y., Hashiguchi, M., Hosoda, T., Yasuda, H., Hirao T., Harada, A.
  • Journal Title: Polymer 47・16 Pages: 5762-5774
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Self-Threading of a Poly(ethylene glycol) Chain in a Cyclodextrin-Ring: Control of the Exchange Dynamics by Chain Length (2006)
  • Author(s): Inoue, Y., Miyauchi, M., Nakajima, H., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J.Am.Chem.Soc. 128-28 Pages: 8994-8995
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Cyclodextrin-Based Side Chain Polyrotaxane with Unidirectional Inclusion in Aqueous Media (2006)
  • Author(s): Tomatsu, I., Hashidzume, A., Harada, A.
  • Journal Title: Angew.Chem.Int.Ed. 45-28 Pages: 4605-4608
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Cyclodextrin-Based Supramolecular Polymers (2006)
  • Author(s): Harada, A., Hashidzume, A., Takashima, Y.
  • Journal Title: Adv.Polym.Sci. 201・- Pages: 1-43
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Synthesis of a Water-Soluble Iridium(III) Complex with pH and Metal Cation Sensitive Photoluminescence (2006)
  • Author(s): Konishi, K., Yamaguchi, H., Harada, A.
  • Journal Title: Chem.Lett. 35-7 Pages: 720-721
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Selection between Pinching-Type and Supramolecular Polymer-Type Complexes by α-Cyclodextrin-β-Cyclodextrin Hetero-Dimer and Hetero-Cinnamamide Guest Dimers (2006)
  • Author(s): Takahashi, H., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J.Org.Chem. 71・13 Pages: 4878-4883
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Novel Switchable Hydrogels via Supramolecular Cross-Linking of Adamantyl Containing LCST-Copolymers with Cyclodextrin Dimers (2006)
  • Author(s): Kretschmann, O., Choi, S.-W., Miyauchi, M., Tomatsu, I., Harada, A., Ritter, H.
  • Journal Title: Angew.Chem.Int.Ed. 45-26 Pages: 4361-4365
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Formation of Chiral Supramolecular Polymer Based on Modified Cyclodextrin by Host-Guest Interactions (2006)
  • Author(s): Miyawaki, A., Miyauchi, M., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Kobunshi Ronbunshu 63-5 Pages: 306-314
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Spectroscopic Study on the Interaction of Cyclodextrins with Naphthyl Groups Attached to Poly(acrylamide) Backbone (2006)
  • Author(s): Harada, A., Ito, F., Tomatsu, I., Shimoda, K., Hashidzume, A., Takashima, Y., Yamaguchi, H., Kamitori, S.
  • Journal Title: J.Photochem.Photobiol., A 179・1-2 Pages: 13-19
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Contrast Viscosity Changes upon Photoirradiation for Mixtures of Poly(acrylic acid)-Based α-Cyclodextrin and Azobenzene Polymers (2006)
  • Author(s): Tomatsu, I., Hashidzume, A., Harada, A.
  • Journal Title: J.Am.Chem.Soc. 128・7 Pages: 2226-2227
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Redox-Responsive Hydrogel System Using the Molecular Recognition of β-Cyclodextrin (2006)
  • Author(s): Tomatsu, I., Hashidzume, A., Harada, A.
  • Journal Title: Macromol.Rapid Commun. 27-4 Pages: 238-241
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Macromolecular Recognition by Cyclodextrins. Interaction of Cyclodextrins with Polymethacrylamides Bearing Hydrophobic Amino Acid Residues (2006)
  • Author(s): Hashidzume, A., Harada, A.
  • Journal Title: Polymer 47-10 Pages: 3448-3454
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Polymer Formation Utilizing "Crisscross" Addition(Crisscross Addition Polymerization) of Acetaldehyde Azine and 1,4-Phenylene Diisocyanate (2006)
  • Author(s): Hashidzume, A., Shiota, J., Ueno, Y., Noda, T., Takashima, Y., Harada, A., Kamachi, M.
  • Journal Title: Polymer 47-2 Pages: 501-505
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Polymers Involving Cyclodextrin Moieties (2006)
  • Author(s): Harada, A., Hashidzume, A., Miyauchi, M.
  • Journal Title: Cyclodextrins and Their Complexes: Chemistry, Analytical Methods, Applications(Dodziuk H. Ed.)(Wiley)
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Construction of Redox-Induced Systems Using Antigen-Combining Sites of Antibodies and Functionalization of Antibody Supramolecules (2006)
  • Author(s): Yamaguchi, H, Harada, A.
  • Journal Title: Redox Systems under Nano-Space Control(Hirao, T. Ed.)(Springer, Heidelberg) Pages: 263-291
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Comprehensive Nanomaterial Technology, Vol. 2 Nano Metal (2006)
  • Author(s): Harada, A., Yamaguchi, H.
  • Journal Title: Fuji Technosystem Pages: 914
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Cyclic-and Tube-Supramolecular Material Technology (2006)
  • Author(s): Harada, A.
  • Journal Title: CMC Publisher Pages: 246
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Fiber Superbiomimetics〜Creation of Technology in near future〜 (2006)
  • Author(s): Harada, A., Yamaguchi, H., Takashima, Y.
  • Journal Title: NTS Publisher Pages: 1236
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Kinetic Control of Threading of Cyclodextrins onto Axle Molecules (2005)
  • Author(s): Oshikiri, T., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J. Am. Chem. Soc. 127・35 Pages: 12186-12187
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Chiral Supramolecular Polymers Formed by Host-Guest Interactions (2005)
  • Author(s): Miyauchi, M., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J. Am. Chem. Soc. 127・9 Pages: 2984-2989
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] A [2]Rotaxane Capped by a Cyclodextrin and a Guest : Formation of Supramolecular [2]Rotaxane Polymer (2005)
  • Author(s): Miyauchi, M., Hoshino, T., Yamaguchi, H., Kamitori, S., Harada, A.
  • Journal Title: J. Am. Chem. Soc. 127・7 Pages: 2034-2035
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Preparation of Supramolecular Polymers from a Cyclodextrin Dimer and Ditopic Guest Molecules : Control of Structure by Linker Flexibility (2005)
  • Author(s): Ohga, K., Takashima, Y., Takahashi, H., Kawaguchi, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Macromolecules 38・14 Pages: 5897-5904
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Photoresponsive Hydrogel System Utilizing Molecular Recognition of α-Cyclodextrin (2005)
  • Author(s): Tomatsu, I., Hashidzume, A., Harada, A.
  • Journal Title: Macromolecules 38・12 Pages: 5223-5227
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Supramolecular Polymers Formed from β-Cyclodextrins Dimer Linked by Poly(ethylene glycol) and Guest Dimers (2005)
  • Author(s): Hasegawa, Y., Miyauchi, M., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Macromolecules 38・9 Pages: 3724-3730
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Macromolecular Recognition by Polymer-Carrying Cyclodextrins. Interaction of a Polymer Bearing Cyclodextrin Moieties with Poly(acrylamide)s Bearing Aromatic Side Chains (2005)
  • Author(s): Hashidzume, A., Ito, F., Tomatsu, I., Harada, A.
  • Journal Title: Macromol. Rapid Commun. 26・14 Pages: 1151-1154
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Gel-to-Sol and Sol-to-Gel Transitions Utilizing the Interaction of α-Cyclodextrin with Dodecyl Chain Attached to Poly(acrylic acid) Backbone (2005)
  • Author(s): Tomatsu, I., Hashidzume, A., Harada, A.
  • Journal Title: Macromol. Rapid Commun. 26・10 Pages: 825-829
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Steady-State Fluorescence and NMR Study on Self-Association Behavior of Poly(methacrylamides) Bearing Hydrophobic Amino Acid Residues (2005)
  • Author(s): Hashidzume, A., Harada, A.
  • Journal Title: Polymer 46・5 Pages: 1609-1616
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Formation of Self-Assembled Tubular Structures by Mixing Cyclodextrin and Polymers without Solvents (2005)
  • Author(s): Harada, A., Okada, M., Kawaguchi, Y.
  • Journal Title: Chem. Lett. 34・4 Pages: 542-543
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Supramolecular Polymers from a Cyclodextrin Dimer and Ditopic Guest Molecules (2005)
  • Author(s): Ohga, K., Takashima, Y., Takahashi, H., Miyauchi, M., Kawaguchi, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Chem. Lett. 34・3 Pages: 320-321
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] A Helical Supramolecular Polymer Formed by Host-Guest Interactions (2005)
  • Author(s): Miyauchi, M., Harada, A.
  • Journal Title: Chem. Lett. 34・1 Pages: 104-105
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] DNAカテナンのAFM観察 (2005)
  • Author(s): 山口浩靖, 原田 明
  • Journal Title: 高分子 54・10 Pages: 825-825
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Kinetic Control of Threading of Cyclodextrins onto Axle Molecules (2005)
  • Author(s): Oshikiri, T., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J.Am Chem.Soc. 127・35 Pages: 12186-12187
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Chiral Supramolecular Polymers Formed by Host-Guest Interactions (2005)
  • Author(s): Miyauchi, M., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: J.Am Chem.Soc. 127・9 Pages: 2984-2989
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] A [2]Rotaxane Capped by a Cyclodextrin and a Guest: Formation of Supramolecular [2]Rotaxane Polymer (2005)
  • Author(s): Miyauchi, M., Hoshino, Y., Yamaguchi, H., Kamitori, S., Harada, A.
  • Journal Title: J.Am Chem.Soc. 127・7 Pages: 2034-2035
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Preparation of Supramolecular Polymers from a Cyclodextrin Dimer and Ditopic Guest Molecules: Control of Structure by Linker Flexibility (2005)
  • Author(s): Ohga, K., Takashima, Y., Takahashi, H., Kawaguchi, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Macromolecules 38・14 Pages: 5897-5904
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Supramolecular Polymers Formed from β-Cycolodextrins Dimer Linked by Poly(ethylene glycol) and Guest Dimers (2005)
  • Author(s): Hasegawa, Y., Miyauchi, M., Takashima, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Macromolecules 38・9 Pages: 3724-3730
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Macromolecular Recognition by Polymer-Carrying Cyclodextrins. Interaction of a Polymer Bearing Cyclodextrin Moieties with Poly(acrylamide)s Bearing Aromatic Side Chains (2005)
  • Author(s): Hashidzume, A., Ito, F., Tomatsu, I., Harada, A.
  • Journal Title: Macromol.Rapid Commun. 26・14 Pages: 1151-1154
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Gel-to-Sol and Sol-to-Gel Transitions Utilizing the Interaction of α-Cyclodextrin with Dodecyl Chain Attached to Poly(acrylic acid) Backbone (2005)
  • Author(s): Tomatsu, I., Hashidzume, A., Harada, A.
  • Journal Title: Macromol.Rapid Commun 26・10 Pages: 825-829
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Steady-State Fluorescence and NMR Study of Self-Association Behavior of Poly(methacrylamides) Bearing Hydrophobic Amino Acid Residues (2005)
  • Author(s): Hashidzume, A., Harada, A.
  • Journal Title: Polymer 46・5 Pages: 1609-1616
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Formation of Self-Assembled Tubular Structures by Mixing Cyclodextrin and Polymers without Solvents (2005)
  • Author(s): Harada, A., Okada, M., Kawaguchi, Y.
  • Journal Title: Chem.Lett. 34・4 Pages: 542-543
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Supramolecular Polymers from a Cyclodextrin Dimer and Ditopic Guest Molecules (2005)
  • Author(s): Ohga, K., Takashima, Y., Takahashi, H., Miyauchi, M., Kawaguchi, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Chem.Lett. 34・3 Pages: 320-321
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] A Helical Supramolecular Polymer Formed by Host-Guest Interactions (2005)
  • Author(s): Miyauchi, M., Harada, A.
  • Journal Title: Chem.Lett. 34・1 Pages: 104-105
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Observation of DNA Catenane by AFM (2005)
  • Author(s): Yamaguchi, H., Harada, A.
  • Journal Title: Koubunshi 54・10 Pages: 825
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Self-Organization Behavior of Poly(methacrylamides) Bearing Amino Acid Residues (2005)
  • Author(s): Hashidzume, A., Harada, A.
  • Journal Title: Structure and Dynamics in Macromolecular Systems with Specific Interactions.(Adachi, K. and Sato, T. Eds.)(Osaka University Press, Suita, Oosaka, Japan) Pages: 69-79
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Nanomaterial Cyclodextrin (2005)
  • Author(s): Harada, A.
  • Journal Title: Yoneda Publisher Pages: 298
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Construction of Supramolecular Polymers with Alternating α-, β-Cyclodextrin Units Using Conformational Change Induced by Competitive Guests (2004)
  • Author(s): Miyauchi, M., Harada, A.
  • Journal Title: J. Am. Chem. Soc. 126・37 Pages: 11418-11419
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Cyclodextrin-Initiated Polymerization of Cyclic Esters in Bulk : Formation of Polyester-Tethered Cyclodextrins (2004)
  • Author(s): Takashima, Y., Osaki, M., Harada, A.
  • Journal Title: J. Am. Chem. Soc. 126・42 Pages: 13588-13589
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Peroxidase Activity of Cationic Metalloporphyrin-Antibody Complexes (2004)
  • Author(s): Yamaguchi, H., Tsubouchi, K., Kawaguchi, K., Horita, E., Harada, A.
  • Journal Title: Chem. Eur. J. 10・23 Pages: 6179-6186
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Preparation of □-Cyclodextrin Polyrotaxane : Photodimerization of pseudo-Polyrotaxane with 2-Anthryl and Triphenylmethyl Groups at the Ends of Poly(propylene glycol) (2004)
  • Author(s): Okada, M., Harada, A.
  • Journal Title: Org. Lett. 6・3 Pages: 361-364
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] One-Pot Synthesis of γ-Cyclodextrin Polyrotaxane : Trap of γ-Cyclodextrin by Photodimerization of Anthracene-Capped pseudo-Polyrotaxane (2004)
  • Author(s): Okada, M., Takashima, Y., Harada, A.
  • Journal Title: Macromolecules 37・19 Pages: 7075-7077
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Crystal Structure of the Complex of β-Cyclodextrin with Bithiophene and Their Oxidative Polymerization in Water (2004)
  • Author(s): Takashima, Y., Oizumi, Y., Saka K., Miyauchi, M., Kamitori, S., Harada A.
  • Journal Title: Macromolecules 37・11 Pages: 3962-3964
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Complex Formation between Polyisoprene and Cyclodextrins (2004)
  • Author(s): Michishita, T., Takashima, Y., Harada, A.
  • Journal Title: Macromol. Rapid Commun. 25・12 Pages: 1159-1162
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] 抗体超分子を用いたバイオセンシング (2004)
  • Author(s): 山口浩靖, 原田 明
  • Journal Title: 化学工業 55・4 Pages: 249-255
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Construction and Functions of Supramolecular Polymers (2004)
  • Author(s): Harada, A.
  • Journal Title: J. Synth. Org. Chem. JPN 62・5 Pages: 464-470
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Bis(amino)titanium Complexes Having Chelating Diaryloxo Ligands Bridged by Sulfur or Methylene and Their Catalytic Behaviour for Ring-Opening Polymerization of Cyclic Esters (2004)
  • Author(s): Takashima, Y., Nakayama, Y., Hirao, T., Yasuda, H., Harada, A.
  • Journal Title: J. Organomet. Chem. 689・3 Pages: 612-619
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Complex Formation and Gelation between Copolymers Containing Pendant Azobenzene Groups and Cyclodextrin Polymers (2004)
  • Author(s): Takashima, Y., Nakayama, T., Miyauchi, M., Kawaguchi, Y., Yamaguchi, H, Harada, A.
  • Journal Title: Chem. Lett. 33・8 Pages: 890-891
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Formation of Supramolecular Polymers Constructed by Cyclodextrins with Cinnamamide (2004)
  • Author(s): Miyauchi, M., Kawaguchi, Y., Harada, A.
  • Journal Title: J. Inclusion Phenom. 50・1-2 Pages: 57-62
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Polymerizability of Asymmetric Azines Bearing Bicyclic Substituents (2004)
  • Author(s): Tsuchiya, A., Hashidzume, A., Harada, A., Kamachi, M.
  • Journal Title: Designed Monomers and Polymers 7・3 Pages: 277-290
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Polymerization of Azastyrene Derivatives, 4. Spontaneous Copolymerization of 2,6-Diisopropyl-N- Methyleneaniline and Cyclic Acid Anhydride (2004)
  • Author(s): Hashidzume, A., Kurokawa, Y., Harada, A., Kamachi, M.
  • Journal Title: Designed Monomers and Polymers 7・4 Pages: 361-376
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Optimization of Conditions for the Formation of High Molecular Weight Polymer of Acetaldehyde Azine (2004)
  • Author(s): Kamachi, M., Kajiwara, A., Hashidzume, A., Matsuda, K., Harada, A.
  • Journal Title: Designed Monomers and Polymers 7・6 Pages: 701-710
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] 抗体超分子によるターゲット分子検出シグナル増幅効果 (2004)
  • Author(s): 山口浩靖, 原田 明
  • Journal Title: 高分子論文集 61・10 Pages: 533-540
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Construction of Supramolecular Polymers with Alternating α-, β-cyclodextrin Units Using Conformational Change Induced by Competitive Guests (2004)
  • Author(s): Miyauchi, M., Harada, A.
  • Journal Title: J.Am.Chem.Soc. 126・37 Pages: 11418-11419
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Cyclodextrin-Initiated Polymerization of Cyclic Esters in Bulk: Formation of Polyester-Tethered Cyclodextrins (2004)
  • Author(s): Takashima, Y., Osaki, M., Harada, A.
  • Journal Title: J.Am.Chem.Soc. 126・42 Pages: 13588-13589
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Peroxidase Activity of Cationic Metalloporphyrin-Antibody Complexes (2004)
  • Author(s): Yamaguchi, H., Tsubouchi, K., Kawagushi, K., Horita, E., Harada, A.
  • Journal Title: Chem.Eur.J. 10・23 Pages: 6279-6286
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Preparation of β-Cyclodextrin Polyrotaxane : Photodimerization of pseudo-Polyrotaxane with 2-Anthryl and Triphenylmethyl Groups at the Ends of Poly(propylene glycol) (2004)
  • Author(s): Okada, M., Harada, A.
  • Journal Title: Org.Lett. 6・3 Pages: 361-364
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] One-Pot Synthesis of γ-Cyclodextrin Polyrotaxane: Trap of γ-Cyclodextrin by Photodimerization of Anthracene-Capped pseudo-Polyrotaxane (2004)
  • Author(s): Okada, M., Takashima, Y., Harada, A.
  • Journal Title: Macromolecules 37・19 Pages: 7075-7077
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Crystal Structure of the Complex of β-Cyclodextrin with Bithiophene and Their Oxidative Polymerization in Water (2004)
  • Author(s): Takashima, Y., Oizumi, Y., Sakamoto, K., Miyauchi, M., Kamitori, S., Harada, A.
  • Journal Title: Macromolecules 37・11 Pages: 3962-3964
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Complex Formation between Polyisoprene and Cyclodextrins (2004)
  • Author(s): Michishita, T., Takashima, Y., Harada, A.
  • Journal Title: Macromol.Rapid Commun. 25・12 Pages: 1159-1162
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Biosensing with Antibody Supramolecules (2004)
  • Author(s): Yamaguchi, H., Harada, A.
  • Journal Title: Chem.Industry 55・4 Pages: 249-255
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Construction and Functions of Supramolecular Polymers (2004)
  • Author(s): Harada, A.
  • Journal Title: J.Synth.Org.Chem.JPN 62・5 Pages: 464-470
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Bis(amino)titanium Complexes Having Chelating Diaryloxo Ligands Bridged by Sulfur of Methylene and Their Catalytic Behavior for Ring-Opening Polymerization of Cyclic Esters (2004)
  • Author(s): Takashima, Y., Nakayama, Y., Hirano, T., Yasuda, H., Harada, A.
  • Journal Title: J.Organomet.Chem. 689・3 Pages: 612-619
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Complex Formation and Gelation between Copolymers Containing Pendant Azobenzene Groups and Cyclodextrin Polymers (2004)
  • Author(s): Takashima, Y., Bakayama, T., Miyauchi, M., Kawaguchi, Y., Yamaguchi, H., Harada, A.
  • Journal Title: Chem.Lett. 33・8 Pages: 890-891
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Formation of Supramolecular Polymers Constructed by Cyclodextrins with Cinnamamide (2004)
  • Author(s): Miyauchi, M., Kawaguchi, Y., Harada, A.
  • Journal Title: J.Inclusion Phenom. 50・1-2 Pages: 57-62
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Polymerization of Azastyrene Derivatives, 4. Spontaneous Copolymerization of 2,6-Diisopropyl-N-Methyleneaniline and Cyclic Acid Anhydride (2004)
  • Author(s): Hashidzume, A., Kurokawa, Y., Harada, A., Kamachi, M.
  • Journal Title: Designed Monomers and Polymers 7・4 Pages: 361-376
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Amplification Effects on Detection Signals of Target Molecules by Antibody Supramolecules (2004)
  • Author(s): Yamaguchi, H., Harada, A.
  • Journal Title: Kobunshi Ronbunshu 61・10 Pages: 533-540
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Supramolecular Polymers Containing Cyclodextrin (2004)
  • Author(s): Harada, A.
  • Journal Title: Macromolecular Nano-Structured Materials (Ed. by Ueyama, N. and Harada, A.)( Springer Series in Materials Science) 78 Pages: 26-40
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Direct Observation of Supramolecular Structures of Biorelated Materials by Atomic Force Microscopy (2004)
  • Author(s): Yamaguchi, H., Harada, A.
  • Journal Title: Macromolecular Nanostructured Materials (Ed. by Ueyama, N. and Harada, A.)(Springer Series in Materials Science) 78 Pages: 258-272
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Innovation of Organic-Inorganic Hybrid Material (2004)
  • Author(s): Harada, A
  • Journal Title: NTS Publisher Pages: 296
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Creation and Application of Self-Assembled Material (2004)
  • Author(s): Harada, A
  • Journal Title: NTS Publisher Pages: 320
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Formation Process of Cyclodextrin Necklace-Analysis of Hydrogen Bonding on a Molecular Level (2003)
  • Author(s): Miyake, K., Yasuda, S., Harada Sumaoka, J., Komiyama, Shigekawa, H.
  • Journal Title: J. Am. Chem. Soc. 125・17 Pages: 5080-5085
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Antibody Dendrimers (2003)
  • Author(s): Yamaguchi, H., Harada, A.
  • Journal Title: Top. Curr. Chem. 228 Pages: 237-258
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Poly(polyrotaxane) : Photoreactions of 9-Anthracene-Capped Polyrotaxane (2003)
  • Author(s): Okada M., Harada, A.
  • Journal Title: Macromolecules 36・26 Pages: 9701-9703
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Preparation and Characterization of the Inclusion Complexes of Poly(dimethylsilane)s with Cyclodextrins (2003)
  • Author(s): Okumura, H., Kawaguchi, Y., Harada, A.
  • Journal Title: Macromolecules 36・17 Pages: 6422-6429
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Inclusion Complex Formation and Hydrolysis of Lactones by Cyclodextrins (2003)
  • Author(s): Takashima, Y., Kawaguchi, Y., Nakagawa, S., Harada, A.
  • Journal Title: Chem. Lett. 32・10 Pages: 1122-1123
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Supramolecular Polymers Formed by Cinnamoyl Cyclodextrins (2003)
  • Author(s): Harada, A., Miyauchi, M., Hoshino, T.
  • Journal Title: J. Polym. Sci. A Polym. Chem. 41・22 Pages: 3519-3523
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Dendritic Antibody Supramolecules : Combination of IgM and IgG (2003)
  • Author(s): Harada, A., Yamaguchi, H., Tsubouchi, K., Horita, E.
  • Journal Title: Chem. Lett. 32・1 Pages: 18-19
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Formation Process of Cyclodextrin Necklace-Analysis of Hydrogen Bonding on a Molecular Level (2003)
  • Author(s): Miyake, K., Yasuda, S., Harada, A., Sumaoka, J., Komiyama, M., Shigekawa, H.
  • Journal Title: J.Am.Chem.Soc 125・17 Pages: 5080-5085
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Antibody Dendrimers (2003)
  • Author(s): Yamaguchi, H., Harada, A.
  • Journal Title: Top.Curr.Chem. 228・- Pages: 237-258
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Poly(polyrotaxane): Photoreactions of 9-Anthracene-Capped Polyrotaxane (2003)
  • Author(s): Okada M., Harada, A.
  • Journal Title: Macromolecules 36・26 Pages: 9701-9703
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Inclusion Complex Formation and Hydrolysis of Lactones by Cyclodextrins (2003)
  • Author(s): Takashima, Y., Kawaguchi, Y., Nakagawa, S., Harada, A.
  • Journal Title: Chem.Lett. 32・10 Pages: 1122-1123
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Supramolecular Polymers Formed by Cinnamoyl Cyclodextrins (2003)
  • Author(s): Harada, A., Miyauchi, M., Hoshino, T.
  • Journal Title: J.Polym.Sci.A Polym.Chem. 41・22 Pages: 3519-3523
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Dendritic Antibody Supramolecules: Combination of IgM and IgG (2003)
  • Author(s): Harada, A., Yamaguchi, H., Tsubouchi, K., Horita, E.
  • Journal Title: Chem.Lett. 32・1 Pages: 18-19
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Series of Innovation Chemistry I / Organometallics/Chiral/Catalysts/Polymer (2003)
  • Author(s): Harada, A.
  • Journal Title: Maruzen Pages: 285
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Series of Innovation Chemistry III / Organometallics/Chiral/Catalysts/Polymer (2003)
  • Author(s): Harada, A.
  • Journal Title: Maruzen Pages: 280
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Polymerizations of Cyclic Esters Catalyzed by Titanium Complexes Having Chalcogen-Bridged Chelating Diaryloxo Ligands (2002)
  • Author(s): Takashima, Y., Nakayama, Y., Watanabe, K., Itono, T., Ueyama, N., Nakamura, A., Yasuda, H., Harada, A.
  • Journal Title: Macromolecules 35・20 Pages: 7538-7544
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Supramolecular Formation of Antibodies with Viologen Dimers : Utilization for Amplification of Methyl Viologen Detection Signals in Surface Plasmon Resonance Sensor (2002)
  • Author(s): Yamaguchi, H., Harada, A.
  • Journal Title: Biomacromolecules 3・6 Pages: 1163-1169
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Complex Formation between Poly(dimethylsilane) and Cyclodextrins (2002)
  • Author(s): Okumura, H., Kawaguchi, Y., Harada, A.
  • Journal Title: Macromol. Rapid Commun. 23・13 Pages: 781-785
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Steric Isomerization of Alkyne Dialkyltungsten Complexes with a Chelating Diaryloxo Ligand : Crystal Structures of Cs- and C_1-W(η^2-RCCR)[2,2'-S(4-Me-6-R'C_6H_2O)_2](CH_2SiMe_3)_2 (2002)
  • Author(s): Takashima, Y., Nakayama, Y., Yasuda, H., Nakamura, A., Harada, A.
  • Journal Title: J. Organomet. Chem. 664・1-2 Pages: 234-244
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Synthesis of cis-Dichloride Complexes of Group 6 Transition Metal Complexes Bearing Alkyne and Chalcogen-Bridged Chelating Bis(aryloxo) Ligands as Catalyst Precursors for Ring-Opening Metathesis Polymerization (2002)
  • Author(s): Takashima, Y., Nakayama, Y., Yasuda, H., Nakamura, A., Harada, A.
  • Journal Title: J. Organomet. Chem. 654・1-2 Pages: 74-82
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Synthesis of Novel Oxo Complexes of Tungsten and Molybdenum with Various Chalcogen-Bridged Chelating Bis(aryloxo) Ligands and their Catalytic Behavior for Ring-Opening Metathesis Polymerization (2002)
  • Author(s): Takashima, Y., Nakayama, Y., Yasuda, H., Harada, A.
  • Journal Title: J. Organomet. Chem. 651・1-2 Pages: 114-123
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Amplification of Detection Signals for Methyl Viologen by Using Supramolecular Formation of Antibody with Viologen Dimer in Surface Plasmon Resonance Sensor (2002)
  • Author(s): Yamaguchi, H., Harada, A.
  • Journal Title: Chem. Lett. 31・3 Pages: 382-383
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Ring-Opening Metathesis Polymerization by Tungsten Complexes with O,S,O- or O,N,O-Tridentate Chelating Ligands (2002)
  • Author(s): Takashima, Y., Nakayama, Y., Yasuda, H., Nakamura, A., Harada, A.
  • Journal Title: Kobunshi Ronbunshu 59・6 Pages: 298-308
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Polymerizations of Cyclic Esters Catalyzed by Titanium Complexes Having Chalcogen-Bridged Chelating Diaryloxo Ligands (2002)
  • Author(s): Takashima, Y., Nakayama, Y., Watanabe, K., Itono, T., Ueyama, N., Nakamura, A., Yasuda, H., Harada, A.
  • Journal Title: Macromolecules 35-20 Pages: 7538-7544
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Supramolecular Formation of Antibodies with Viologen Dimers: Utilization for Amplification of Methyl Viologen Detection Signals in Surface Plasmon Resonance Sensor (2002)
  • Author(s): Yamaguchi, H., Harada, A.
  • Journal Title: Biomacromolecules 3・6 Pages: 1163-1169
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Complex Formation between Poly(dimethylsilane) and Cyclodextrins (2002)
  • Author(s): Okumura, H., Kawaguchi, Y., Harada, A.
  • Journal Title: Macromol.Rapid Commun. 23・13 Pages: 781-785
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Steric Isomerization of Alkyne Dialkyltungsten Complexes with a Chelating Diaryloxo Ligand: Crystal Structures of Cs- and C1-W(η2-RCCR) [2,2'-S(4-Me-6-R'C6H2O)2](CH2SiMe3)2 (2002)
  • Author(s): Takashima, Y., Nakayama, Y., Yasuda, H., Nakamura, A., Harada, A.
  • Journal Title: J.Organomet.Chem. 664・1-2 Pages: 234-244
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Synthesis of cis-Dichloride Complexes of Group 6 Transition Metal Complexes Bearing Alkyne and Chalcogen-Bridged Chelating Bis(aryloxo) Ligands as Catalyst Precursors for Ring-Opening Metathesis Polymerization (2002)
  • Author(s): Takashima, Y., Nakayama, Y., Yasuda, H., Nakamura, A., Harada, A.
  • Journal Title: J.Organomet.Chem. 654・1-2 Pages: 74-82
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Synthesis of Novel Oxo Complexes of Tungsten and Molybdenum with Various Chalcogen-Bridged Chelating Bis(aryloxo) Ligands and their Catalytic Behavior for Ring-Opening Metathesis Polymerization (2002)
  • Author(s): Takashima, Y., Nakayama, Y., Yasuda, H., Harada, A.
  • Journal Title: J.Organomet.Chem. 651・1-2 Pages: 114-123
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Amplification of Detection Signals for Methyl Viologen by Using Supramolecular Formation of Antibody with Viologen Dimer in Surface Plasmon Resonance Sensor (2002)
  • Author(s): Yamaguchi, H., Harada, A.
  • Journal Title: Chem.Lett. 31・3 Pages: 382-383
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Ring-Opening Metathesis Polymerization by Tungsten Complexes with O,S,O-or 0,N,O-Tridentate Chelating Ligands (2002)
  • Author(s): Takashima, Y., Nakayama, Y., Yasuda, H., Nakamura, A., Harada, A.
  • Journal Title: Kobunshi Ronbunshu 59・6 Pages: 298-308
  • Description: 「研究成果報告書概要(欧文)」より
• [Book] Cyclodextrins and Their Complexes : Chemistry, Analytical Methods, Applications (2006)
  • Author(s): Harada, A., Hashidzume, A., Miyauchi, M.
  • Total Pages: 507
  • Publisher: Wiley
  • Description: 「研究成果報告書概要(和文)」より
• [Book] Redox Systems under Nano-Space Control (2006)
  • Author(s): Yamaguchi, H, Harada, A.
  • Total Pages: 295
  • Publisher: Springer
  • Description: 「研究成果報告書概要(和文)」より
• [Book] ナノマテリアル工学大系第2巻「ナノ金属」 (2006)
  • Author(s): 原田 明, 山口浩靖
  • Total Pages: 914
  • Publisher: フジ・テクノシステム
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 環状・筒状超分子新素材の応用技術 (2006)
  • Author(s): 原田 明
  • Total Pages: 246
  • Publisher: シーエムシー出版
  • Description: 「研究成果報告書概要(和文)」より
• [Book] ファイバー スーパーバイオミメティックス~近未来の新技術創成~ (2006)
  • Author(s): 原田 明, 山口浩靖, 高島義徳
  • Total Pages: 1236
  • Publisher: NTS
  • Description: 「研究成果報告書概要(和文)」より
• [Book] Structure and Dynamics in Macromolecular Systems with Specific Interactions (2005)
  • Author(s): Hashidzume, A., Harada, A.
  • Total Pages: 196
  • Publisher: Osaka University Press
  • Description: 「研究成果報告書概要(和文)」より
• [Book] ナノマテリアル・シクロデキストリン (2005)
  • Author(s): 原田 明
  • Total Pages: 298
  • Publisher: 米田出版
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 有機無機ナノ複合材料の新局面 (2004)
  • Author(s): 原田 明
  • Total Pages: 296
  • Publisher: NTS
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 自己組織化によるナノマテリアルの創成と応用 (2004)
  • Author(s): 原田 明
  • Total Pages: 320
  • Publisher: NTS
  • Description: 「研究成果報告書概要(和文)」より
• [Book] Macromolecular Nano-Structured Materials (2004)
  • Author(s): Harada, A.
  • Total Pages: 336
  • Publisher: Springer
  • Description: 「研究成果報告書概要(和文)」より
• [Book] Macromolecular Nanostructured Materials (2004)
  • Author(s): Yamaguchi, H, Harada, A
  • Total Pages: 336
  • Publisher: Springer
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 先端化学シリーズI有機金属/キラル/触媒/高分子 (2003)
  • Author(s): 原田 明
  • Total Pages: 285
  • Publisher: 丸善
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 先端化学シリーズIII 糖鎖/バイオマテリアル/分子認識/バイオインフォマティクス (2003)
  • Author(s): 原田 明
  • Total Pages: 280
  • Publisher: 丸善
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] 有機高分子化合物の製造方法 (2005)
  • Inventor(s): 原田 明, 高島義徳
  • Industrial Property Rights Holder: 原田 明, 高島義徳
  • Industrial Property Number: 特願2005-357742
  • Filing Date: 2005-05-12
  • Description: 「研究成果報告書概要(和文)」より