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2004 Fiscal Year Final Research Report Summary

Interaction between the transition metals and organic molecules in the framework structure of zeolite.

Research Project

Project/Area Number 14340161
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionThe University of Tokyo

Principal Investigator

SUGIYAMA Kazumasa  The University of Tokyo, Graduate School of Science, Research Associate Professor, 大学院・理学系研究科, 助教授 (40196762)

Co-Investigator(Kenkyū-buntansha) TANAKA Masahiko  Institute of Materials Structure Science, High Energy Accelerator research Organization, Research Associate, 物質構造科学研究所, 助手 (60249901)
Project Period (FY) 2002 – 2004
Keywordszeolite / crystal structure / x-ray diffraction / anomalous scattering / laumontite / Zn-Al-P-O system / Co-Al-P-O system
Research Abstract

The purpose of this study is to characterize the interaction between transition metals and organic molecules in zeolites with the porous framework structure. For this purpose a special experimental facility which allows us to perform the single crystal anomalous X-ray scattering measurement was newly built at the Photon Factory at the Institute of Materials Structure Research. Anomalous x-ray scattering method is powerful technique and the environmental structure around a specific element can be obtained from the analysis of the energy dependence of the scattering data. This relatively new method was applied to the analysis of Se@mordenite and the chain like Se molecule in the mordenite channel was quantitatively obtained by suggesting the electron transfer from Se molecules. The solvo-thermal technique in the Zn-Al-P-O and Co-Al-P-O system allowed us to serve the laumontite framework structure. Laumontite in the Zn(Co)-Al-P-O system indicates the ordering of transition metals and incorporated organic molecule and 1,2-aminoethypiperazine@laumontite, in particular, showed the non-centered space group symmetry of Cc. The measurement of the SHG signal for this new material supported the attractive performance and further application of such materials for the optic-electrical will be realized in near future.

  • Research Products

    (14 results)

All 2004 2003

All Journal Article (13 results) Book (1 results)

  • [Journal Article] Crystal Structure of a 2/1 Cubic Approximant in an Al-Rh-Si Alloy.2004

    • Author(s)
      K.Sugiyama, W.Sun, K.Hiraga
    • Journal Title

      Journal of Non-Crystalline Solids 344&345

      Pages: 156-160

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Di(2-methylimidazolium) aluminum diphosphorous hydroxyloxide2004

    • Author(s)
      J.Takashima, K.Sugiyama, T.Tagai, O.Terasaki, J.Yu
    • Journal Title

      Acta Crystallogr. C60

      Pages: m333-m334

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Anomalous X-ray Scattering Study for Determining Cation Distribution in ZnFe_2O_4 and NiFe_2O_4.2004

    • Author(s)
      K.Sugiyama, T.Okamoto, Y.Waseda
    • Journal Title

      High Temperature Materials Processing 23・5&6

      Pages: 357-369

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Crystal Structure of a 2/1 Cubic Approximant in an Al-Rh-Si Alloy.2004

    • Author(s)
      K.Sugiyama, W.Sun, K.Hiraga
    • Journal Title

      J.Non-Crystalline Solids 344&345

      Pages: 156-160

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Di-(2-methylimidazolium) aluminum diphosphorous Hydroxioxide.2004

    • Author(s)
      J.Takashima, K.Sugiyama, T.Tagai, O.Terasaki, J.Yu
    • Journal Title

      Acta Crystallogr. C60

      Pages: 333-334

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Anomalous X-ray Scattering Study for Determining Cation Distribution in ZnFe_2O_4 and NiFe_2O_4.2004

    • Author(s)
      K.Sugiyama, T.Okamoto, Y.Waseda
    • Journal Title

      High Temp.Mater.Processings 23(5-6)

      Pages: 357-369

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Structural Characterization of Non-Crystalline Oxides by the Anomalous X-ray Scattering2003

    • Author(s)
      Y.Waseda, K.Sugiyama
    • Journal Title

      High Temperature Materials Processing 22・2

      Pages: 103-122

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Energy Dispersive X-ray Diffraction Method for Structural Characterization of Non-Crystalline Oxides.2003

    • Author(s)
      Y.Waseda, K.Sugiyama
    • Journal Title

      High Temperature Materials Processing 22・3&4

      Pages: 211-219

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] チャバサイト型骨格構造を持つAl-P-O系物質の合成と結晶構造2003

    • Author(s)
      高島淳矢, 杉山和正, 田賀井篤平
    • Journal Title

      ゼオライト 20・4

      Pages: 156-162

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Structural Characterization of Non-Crystalline Oxides by the Anomalous X-ray Scattering.2003

    • Author(s)
      Y, Waseda, K.Sugiyama
    • Journal Title

      High Temp.Mater.Processing 22(2)

      Pages: 103-122

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Energy Dispersive X-ray Diffraction Method for Structural Characterization of Non-Crystalline Oxides.2003

    • Author(s)
      Y, Waseda, K.Sugiyama
    • Journal Title

      High Temp.Mater.Processing 22(3-4)

      Pages: 211-219

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis and Crystal structure of AIPO-34 with the chabazite structure.2003

    • Author(s)
      J.Takashima, K, Sugiyanma, T.Tagai
    • Journal Title

      ZEORAITO 20(4)

      Pages: 156-162

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Small-angle X-ray Scattering to Characterization of Condensed Mater.2003

    • Author(s)
      Y.Waseda, K.Sugiyama, A.H.Shinohara
    • Journal Title

      Advances in Material Research (Springer-Verlag)

      Pages: 63-91

    • Description
      「研究成果報告書概要(欧文)」より
  • [Book] Small-angle X-ray Scattering to Characterization of Condensed Matter2003

    • Author(s)
      Y.Waseda, K.Sugiyama, A.H.Shinohara
    • Total Pages
      63-91
    • Publisher
      Advances in Material Research, Springer-Verlag
    • Description
      「研究成果報告書概要(和文)」より

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Published: 2006-07-11  

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