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2004 Fiscal Year Final Research Report Summary

Development of thermoelectric power system utilizing waste heat from vehicles

Research Project

Project/Area Number 14380227
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field エネルギー学一般
Research InstitutionYamaguchi University

Principal Investigator

MIKI Toshikatsu  Yamaguchi University, Faculty of Engineering, Professor, 工学部, 教授 (70091212)

Co-Investigator(Kenkyū-buntansha) MATSUURA Mitsuru  Yamaguchi University, Faculty of Engineering, Professor, 工学部, 教授 (60091211)
KOYANAGI Tsuyoshi  Yamaguchi University, Faculty of Engineering, Professor, 工学部, 教授 (90178385)
MURATA Takuya  Yamaguchi University, Faculty of Engineering, Research Associate, 工学部, 助手 (70263796)
Project Period (FY) 2002 – 2004
Keywordsthermoelectric power system / module / unit-type heat exchanger / theoretical calculation / joint
Research Abstract

This research has conducted with aiming to realize thermoelectric power system utilizing vehicle waste heat. Obtained results both from experimentally and theoretically are summarized as follows.
1)Assembling process of thermoelectric power module for mid-temperature range
Using metal-hydrides or hydrogen-accumulated metal foil, firm and Ohmic joint has been achieved between thermoelectric elements (CoSb_3, Yb-CoSb, or Bi_2Te_3) and Cu metal. The joint layer functioned as a barrier for Cu elements migration. Joint process between thermo-conductive AlN ceramics and Cu was also examined using Ti-metal foil, working against the heat stresses arising at the joint.
2)Process control and calculations for electronic states of thermoelectric materials
For improving the figure of merit of the thermoelectric materials, sintering processes of CoSb series, PbTe, and silliside series were examined. Besides, theoretical calculations for the electronic states of CoSb and silliside not only interpreted the experimental results, but also suggested an effective process for clathrate compounds.
3)Unit-type heat-exchanger with thermoelectric module
Unit-type heat-exchanger with thermoelectric module was designed to improve the heat conduction through the thermoelectric module. According to the numerical simulation for the thermoelectric property and the heat conduction, basic feature of the heat-exchanger was satisfied. This is due to the employment of the suited heat recovery fins (at high temperature side) and a thermo-conductive gel-sheet (at low temperature side).

  • Research Products

    (23 results)

All 2005 2004 2003 2002 Other

All Journal Article (20 results) Book (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Electronic structure and optical properties of binaryskutterudite antimonides2005

    • Author(s)
      K.Koga, K.Akai, K.Oshiro, M.Matsuura
    • Journal Title

      Physical Review, B (掲載決定)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Theory of Nonparabolic Effects fo The Thermoelectric Properties2004

    • Author(s)
      M.Matsuura, K.Koga, K.Oshiro, K.Akai
    • Journal Title

      Transactions of the Materials Research Society of Japan 29・6

      Pages: 2763-2766

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Thermoelectric Properties and Electronic Structure of Mg_2Si System2004

    • Author(s)
      N.Arita, S.Sakurai, H.Kurisu, S.Yamamoto, M.Matsuura
    • Journal Title

      Transactions of the Materials Research Society of Japan 29・6

      Pages: 2555-2558

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Electronic Structure of Noble-Metal-Doped Clathrates with Nanostructure Si-Network2004

    • Author(s)
      K.Akai, K.Koga, K.Oshiro, M.Matsuura
    • Journal Title

      Transactions of the Materials Research Society of Japan 29・8

      Pages: 3647-3650

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Electronic structure, and thermoelectronic properties of the clathrates Ba_8Ga_<16>Si_3O and Ba_8Ga_<16>Ge_<30>2004

    • Author(s)
      T.Kamei, K.Koga, K.Akai, K.Osiro, M.Matsuura
    • Journal Title

      Transactions of the Materials Research Society of Japan 29・8

      Pages: 3651-3654

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Effects of X-Ray Irradiation and Barium Deficiency on Grain Boundary States in BaTiO_3 : Ta Ceramics2004

    • Author(s)
      Y.Uchida, A.Kai, T.Murata, T.Miki
    • Journal Title

      Japanese Journal of Applied Physics 43・2

      Pages: 669-673

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Theory of Nonparabolic Effects of The Thermoelectric Properties2004

    • Author(s)
      M.Matsuura, K.Koga, K.Oshiro, K.Akai
    • Journal Title

      Transactions of the Materials Research Society of Japan 29・6

      Pages: 2763-2766

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Thermoelectric Properties and Electronic Structure of Mg_2Si System2004

    • Author(s)
      N.Arita, S.Sakurai, H.Kurisu, S.Yamamoto, M.Matsuura
    • Journal Title

      Transaction of the Materials Research Society of Japan 29・6

      Pages: 2555-2558

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Electronic Structure of Noble-Metal-Doped Clathrates with Nanostructure Si-Network2004

    • Author(s)
      K.Akai, K.Koga, K.Oshiro, M.Matsuura
    • Journal Title

      Transaction of the Materials Research Society of Japan 29・8

      Pages: 3647-3650

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Electronic structure, and thermoelectronic properties of the clathrates Ba_8Ga_<16>Si_3O and Ba_8Ga_<16>Ge_<30>2004

    • Author(s)
      T.Kamei, K.Koga, K.Akai, K.Osiro, M.Matsuura
    • Journal Title

      Transaction of the Materials Research Society of Japan 29・8

      Pages: 3651-3654

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Photoemission spectroscopy of the filled skutterudite compound YbFe_4Sb_<12>2003

    • Author(s)
      T.Okane, S.Fujimori, K.Mamiya, J.Okamoto, Y.Muramatsu, A.Fujimori, Y.Nagamoto, T.Koyanagi
    • Journal Title

      Journal of Physics-Condensed Matter 15・28

      Pages: S2197-S2200

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Influences of potential barrier scattering on the thermoelectric properties of sintered n-type PbTe with a small grain size2003

    • Author(s)
      K.Kishimoto, K.Yamamoto, T.Koyanagi
    • Journal Title

      Japanese Journal of Applied Physics 42・2A

      Pages: 501-508

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Thermoelectric Properties of Mg_2Si Processed by Spark Plasma Sintering Method2003

    • Author(s)
      N.Arita, S.Sakurai, H.Kurisu, S.Yamamoto, M.Matsuura
    • Journal Title

      Transactions of the Materials Research Society of Japan 28・3

      Pages: 797-800

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Thermoelectric Properties of Mn-Si Ceramics2003

    • Author(s)
      S.Sakurai, K.Koga, K, Akai, H.Kurisu, S.Yamamoto, M.Matsuura
    • Journal Title

      Transactions of the Materials Research Society of Japan 28・3

      Pages: 801-804

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Thermoelectric Properties of Mn-Si Ceramics2003

    • Author(s)
      S.Sakurai, K.Koga, K.Akai, H.Kurisu, S.Yamamoto, M.Matsuura
    • Journal Title

      Transactions of the Materials Research Society of Japan 28・3

      Pages: 801-804

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Microstructure and thermoelectric properties of Cr-doped β-FeSi_2 sintered with micrograins treated in radio frequency plasmas of SiH_4 and GeH_4 gases2002

    • Author(s)
      K.Kishimoto, Y.Nagamoto, T.Miki, T.Koyanagi, K.Matsubara
    • Journal Title

      Journal of Applied Physics 92・8

      Pages: 4393-4401

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Photoemission study of the skutterudite compounds CoSb_3 and RhSb_32002

    • Author(s)
      H.Ishii, K.Okazaki, A.Fujimori, Y.Nagamoto, T.Koyanagi, J.O.Sofo
    • Journal Title

      Journal of the Physical Society of Japan 71・9

      Pages: 2271-2275

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Preparation of sintered degenerate n-type PbTe with a small grain size and its thermoelectric properties2002

    • Author(s)
      K.Kishimoto, T.Koyanagi
    • Journal Title

      Journal of Applied Physics 92・5

      Pages: 2544-2549

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Temperature dependence of the Seebeck coefficient and the potential barrier scattering of n-type PbTe films prepared on heated glass substrates by rf sputtering2002

    • Author(s)
      K.Kishimoto, M.Tsukamoto, T.Koyanagi
    • Journal Title

      Journal of Applied Physics 92・9

      Pages: 5331-5339

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Electronic structure and optical properties of binaryskutterudite antimonides

    • Author(s)
      K.Koga, K.Akai, K.Oshiro, M.Matsuura
    • Journal Title

      Phyical Review, B (in press)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Book] CRC handbook of THERMOELECTRICS2005

    • Author(s)
      K.Matsubara, M.Matsuura
    • Publisher
      CRC Press(掲載決定)
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 接合部材の製造方法,及びその接合部材2004

    • Inventor(s)
      三木 俊克, 村田 卓也
    • Industrial Property Rights Holder
      (有)山口ティー・エル・オー
    • Industrial Property Number
      特願2004-21653
    • Filing Date
      2004-01-29
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 熱電変換モジュール2004

    • Inventor(s)
      三木 俊克, 村田 卓也
    • Industrial Property Rights Holder
      山口大学
    • Industrial Property Number
      特願2004-306500
    • Filing Date
      2004-10-21
    • Description
      「研究成果報告書概要(和文)」より

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Published: 2006-07-11  

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