• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2005 Fiscal Year Final Research Report Summary

Development of multinuclear, high-temperature, and diffusion NMR probe and dynamics of supercritical aqueous solutions

Research Project

Project/Area Number 15205004
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

NAKAHARA Masaru  Kyoto University, Institute for Chemical Research, Professor, 化学研究所, 教授 (20025480)

Co-Investigator(Kenkyū-buntansha) MATUBAYASI Nobuyuki  Kyoto University, Institute for Chemical Research, Associate Professor, 化学研究所, 助教授 (20281107)
OKAMURA Emiko  Kyoto University, Institute for Chemical Research, Assistant Professor, 化学研究所, 助手 (00160705)
WAKAI Chihiro  Kyoto University, Institute for Chemical Research, Assistant Professor, 化学研究所, 助手 (40293948)
Project Period (FY) 2003 – 2005
Keywordsdiffusion / high-resolution NMR / supercritical water / ion / transport phenomena / ceramic / high-temperature and high-pressure / electric conductivity
Research Abstract

In order to elucidate the dynamics of hot water including supercritical, a high-resolution nuclear magnetic resonance (NMR) probe (500 MHz for ^1H) has been developed for multinuclear pulsed field gradient spin-echo (PGSE) diffusion measurements at high temperatures up to 400℃. The convection effect on the self-diffusion measurement is minimized by achieving the homogeneous temperature distributions of±1 and ±2℃, respectively, at 250 and 400℃. The high temperature homogeneity is attained by using the solid-state heating system composed of a ceramic (AlN) with high thermal conductivity comparable with that of metal aluminium. The self-diffusion coefficients D for light (^1H_2O) and heavy (^2H_2O) water are distinguishably measured at subcritical temperatures of 30-350℃ with intervals of 10-25℃ on the liquid-vapor coexisting curve and at a supercritical temperature of 400℃ as a function of water density between 0.071 and 0.251 g/cm^3. The D value obtained for ^1H_2O is 10%-20% smaller than those previously reported because of the absence of the convection effect. At 400℃, the D value for ^1H_2O is increased by a factor of 3.7 as the water density is reduced from 0.251 to 0.071 g/cm^3. Roughly speaking, the observed self-diffusion coefficient of supercritical water appears, although not exactly, inversely proportional to the density or the number of hydrogen bonds in the low-density region covered in this study. The isotope ratio D(^1H_2O)/D(^2H_2O) decreases from 1.23 to 〜1.0 as the temperature increases from 30 to 400℃. Since ^2H_2O is considered to be more structured than ^1H_2O, the isotope effect is interesting to discuss in terms of intermolecular interaction, typically hydrogen bonding, apart from the density and the temperature dependences.

  • Research Products

    (63 results)

All 2006 2005 2004 2003

All Journal Article (51 results) Book (6 results) Patent(Industrial Property Rights) (6 results)

  • [Journal Article] Pair-correlation entropy of hydrophobic hydration : Decomposition into translational and orientational contributions and analysis of solute-size effects2006

    • Author(s)
      M.Kinoshita, N.Matubayasi, Y.Harano, M.Nakahara
    • Journal Title

      J. Chem. Phys. 124

      Pages: 024512

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Free-energy analysis of solubilization in micelle2006

    • Author(s)
      N.Matubayasi, Kuo-Kan Liang, M.Nakahara
    • Journal Title

      J. Chem. Phys. 124(in press)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Pair-correlation entropy of hydrophobic hydration : Decomposition into translational and orientational contributions and analysis of solute-size effects2006

    • Author(s)
      M.Kinoshita, N.Matubayasi, Y.Harano, M.Nakahara
    • Journal Title

      J.Chem.Phys. 124

      Pages: 024512

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Free-energy analysis of solubilization in micelle2006

    • Author(s)
      N.Matubayasi, Kuo-Kan Liang, M.Nakahara
    • Journal Title

      J.Chem.Phys. 124(in press)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Hydrothermal reactions of formaldehyde and formic acid : Free-energy analysis of equilibrium2005

    • Author(s)
      Matubayasi, N., Nakahara, M.
    • Journal Title

      J. Chem. Phys. 122

      Pages: 074509

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] An approach to the solvation free energy in terms of the distributions functions of the solute-solvent interaction energy2005

    • Author(s)
      N.Matubayasi, M.Nakahara
    • Journal Title

      J. Mol. Liq. 119

      Pages: 23-29

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Nuclear magnetic resonance and molecular dynamics simulation study on the reorientational relaxation of solutes in supercritical methanol2005

    • Author(s)
      T.Yamaguchi, N.Matubayasi, M.Nakahara
    • Journal Title

      J. Mol. Liq. 119

      Pages: 119-123

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Real-time in-cell ^<19>F NMR study on uptake of fluorescent and nonfluorescent ^<19>F-octaarginines into human jurkat cells2005

    • Author(s)
      E.Okamura, K.Ninomiya, S.Futaki, Y.Nagai, T.Kimura, C.Wakai, N.Matubayasi, Y.Sugiura, M.Nakahara
    • Journal Title

      Chem. Lett. 34

      Pages: 1064-1065

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Mechanisms and Kinetics of Noncatalytic Ether Reaction in Supercritical Water. 1. Proton-Transferred Fragmentation of Diethyl Ether to Acetaldehyde in Competition with Hydrolysis2005

    • Author(s)
      Y.Nagai, N.Matubayasi, M.Nakahara
    • Journal Title

      J. Phys. Chem. A 109

      Pages: 3550-3557

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Mechanisms and Kinetics of Noncatalytic Ether Reaction in Supercritical Water. 2. Proton-Transferred Fragmentation of Dimethyl Ether to Formaldehyde in Competition with Hydrolysis2005

    • Author(s)
      Y.Nagai, N.Matubayasi, M.Nakahara
    • Journal Title

      J. Phys. Chem. A 109

      Pages: 3558-3564

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Hydrothermal Carbon-Carbon Bond Formation and Disproportionations of Cl Aldehydes : Formaldehyde and Formic Acid2005

    • Author(s)
      S.Morooka, C.Wakai, N.Matubayasi, M.Nakahara
    • Journal Title

      J. Phys. Chem. A 109

      Pages: 6610-6619

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] A new high-temperature multinuclear-magnetic-resonance probe and the self-diffusion of light and heavy water in sub- and supercritical conditions2005

    • Author(s)
      K.Yoshida, C.Wakai, N.Matubayasi, M.Nakahara
    • Journal Title

      J. Chem. Phys. 123

      Pages: 164506

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synthesis of Bis(germacyclopropa)benzenes and Structures of Their Annealed Benzene Rings2005

    • Author(s)
      T.Tajima, T.Sasamori, N.Takeda, N.Tokitoh, K.Yoshida, M.Nakahara
    • Journal Title

      Organometallics. 25

      Pages: 230-235

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Hydrothermal reactions of formaldehyde and formic acid : Free-energy analysis of equilibrium2005

    • Author(s)
      Matubayasi, N., Nakahara, M.
    • Journal Title

      J.Chem.Phys. 122

      Pages: 074509

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] An approach to the solvation free energy in terms of the distributions functions of the solute-solvent interaction energy2005

    • Author(s)
      N.Matubayasi, M.Nakahara
    • Journal Title

      J.Mol.Liq. 119

      Pages: 23-29

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Nuclear magnetic resonance and molecular dynamics simulation study on the reorientational relaxation of solutes in supercritical methanol2005

    • Author(s)
      T.Yamaguchi, N.Matubayasi, M.Nakahara
    • Journal Title

      J.Mol.Liq. 119

      Pages: 119-123

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Real-time in-cell ^<19>F NMR study on uptake of fluorescent and nonfluorescent ^<19>F-octaarginines into human jurkat cells2005

    • Author(s)
      E.Okamura, K.Ninomiya, S.Futaki, Y.Nagai, T.Kimura, C.Wakai, N.Matubayasi, Y.Sugiura, M.Nakahara
    • Journal Title

      Chemistry Letters 34

      Pages: 1064-1065

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Mechanisms and Kinetics of Noncatalytic Ether Reaction in Supercritical Water. 1.Proton-Transferred Fragmentation of Diethyl Ether to Acetaldehyde in Competition with Hydrolysis2005

    • Author(s)
      Y.Nagai, N.Matubayasi, M.Nakahara
    • Journal Title

      J.Phys.Chem.A 109

      Pages: 3550-3557

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Mechanisms and Kinetics of Noncatalytic Ether Reaction in Supercritical Water. 2.Proton-Transferred Fragmentation of Dimethyl Ether to Formaldehyde in Competition with Hydrolysis2005

    • Author(s)
      Y.Nagai, N.Matubayasi, M.Nakahara
    • Journal Title

      J.Phys.Chem.A 109

      Pages: 3558-3564

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Hydrothermal Carbon-Carbon Bond Formation and Disproportionations of C1 Aldehydes : Formaldehyde and Formic Acid2005

    • Author(s)
      S.Morooka, C.Wakai, N.Matubayasi, M.Nakahara
    • Journal Title

      J.Phys.Chem.A 109

      Pages: 6610-6619

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] A new high-temperature multinuclear-magnetic-resonance probe and the self-diffusion of light and heavy water in sub- and supercritical conditions2005

    • Author(s)
      K.Yoshida, C.Wakai, N.Matubayasi, M.Nakahara
    • Journal Title

      J.Chem.Phys. 123

      Pages: 164506

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis of Bis(germacyclopropa)benzenes and Structures of Their Annealed Benzene Rings2005

    • Author(s)
      T.Tajima, T.Sasamori, N.Takeda, N.Tokitoh, K.Yoshida, M.Nakahara
    • Journal Title

      Organometallics 25

      Pages: 230-235

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Side-Chain Conformational Thermodynamics of Aspartic Acid Residue in the Peptides and Achatin-I in Aqueous Solution2004

    • Author(s)
      T.Kimura, N.Matubayasi, M.Nakahara
    • Journal Title

      Biophysical Journal 86

      Pages: 1124-1137

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] NMR Study on the Reorientational Relaxation in Supercritical Alcohols2004

    • Author(s)
      T.Yamaguchi, N.Matubayasi, M.Nakahara
    • Journal Title

      Journal of Physical Chemistry A 108

      Pages: 1319-1324

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Carbon-Carbon Bond Formation in Glycolic Acid Generated Spontaneously from Dichloromethane in Hot Water2004

    • Author(s)
      C.Wakai, S.Morooka, N.Matubayasi, M.Nakahara
    • Journal Title

      Chemistry Letters 33

      Pages: 302-303

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Desulfurization of Thiophene in Alkaline Supercritical Water Studied by ^1H and ^<13>C NMR2004

    • Author(s)
      S.Yoshida, K.Takewaki, K.Miwa, C.Wakai, M.Nakahara
    • Journal Title

      Chemistry Letters 33

      Pages: 330-331

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synthesis of Dimethyl Ether from Supercritical Methanol in the Presence of Aluminum2004

    • Author(s)
      Y.Usui, C.Wakai, N.Matubayasi, M.Nakahara
    • Journal Title

      Chemistry Letters 33

      Pages: 394-395

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Hot Water Induces an Acid-Catalyzed Reaction in Its Undissociate d Form2004

    • Author(s)
      Nagai, Y., Matubayasi, N., Nakahara, M
    • Journal Title

      Bull. Chem. Soc. Japan 77

      Pages: 691-697

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Effect of Concentration, Acid, Temperature, and Metal on Competitive Reaction Pathways for Decarbonylation and Decarboxylation of Formic Acid in Hot Water2004

    • Author(s)
      Wakai, C., Yoshida, K., Tsujino, Y., Matubayasi, N., Nakahara, M.
    • Journal Title

      Chem. Lett. 33

      Pages: 572-573

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Noncatalytic Disproportionation and Decarbonylation Reactions of Benzaldehyde in Supercritical Water2004

    • Author(s)
      Nagai, Y., Matubayasi, N., Nakahara, M
    • Journal Title

      Chem. Lett. 33

      Pages: 622-623

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Acid-Catalyzed Hydrothermal Formation of Carbon-Carbon Bond in Glycolic Acid from a Series of Formaldehyde Producers2004

    • Author(s)
      Morooka, S., Wakai, C., Matubayasi, N., Nakahara, M
    • Journal Title

      Chem. Lett. 33

      Pages: 624-625

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Noncatalytic kinetic study on site-selective H/D exchange reaction of phenol in sub- and supercritical water2004

    • Author(s)
      Kubo, M., Takizawa., Wakai, C., Matubayasi, N., Nakahara, M
    • Journal Title

      J. Chem. Phys. 121

      Pages: 960-969

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] NMR Study on the Binding of Neuropeptide Achatin-I to Phospholipid Bilayer : The Equilibrium, Location, and Peptide Conformation2004

    • Author(s)
      Kimura, T., Okamura, E., Matubayasi, N., Nakahara, M
    • Journal Title

      Biophysical J. 87

      Pages: 375-385

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] NMR Spectroscopic Evidence for an Intermediate of Formic Acid in the Water-Gas-Shift Reaction2004

    • Author(s)
      Yoshida, K., Wakai, C., Matubayasi, N., Nakahara, M.
    • Journal Title

      J. Phys. Chem. A 108

      Pages: 7479-7482

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] A quantum chemical approach to the free energy calculations in condensed systems : The QM/MM method combined with the theory of energy representation2004

    • Author(s)
      Takahashi, H., Matubayasi, N., Nakahara, M., Nitta, T
    • Journal Title

      J. Chem. Phys. 121

      Pages: 3989-3999

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Mechanisms and kinetics of acetaldehyde reaction in supercritical water : Noncatalytic disproportionation, condensation, and decarbonylation2004

    • Author(s)
      Y.Nagai, S.Morooka, N.Matubayasi, M.Nakahara
    • Journal Title

      J. Phys. Chem. A 108

      Pages: 11635-11643

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Limited slowdown of endocrine-disruptor diffusion in confined fluid lipid membranes2004

    • Author(s)
      E.Okamura, C.Wakai, N.Matubayasi, Y.Sugiura, M.Nakahara
    • Journal Title

      Phys. Chem. Lett. 93

      Pages: 248101

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 超臨界水の構造と物性2004

    • Author(s)
      中原 勝
    • Journal Title

      熱測定 31

      Pages: 14-22

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 膜2004

    • Author(s)
      岡村恵美子, 中原勝
    • Journal Title

      化学 59

      Pages: 66-67

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Hot Water Induces an Acid-Catalyzed Reaction in Its Undissociated Form2004

    • Author(s)
      Nagai, Y., Matubayasi, N., Nakahara, M
    • Journal Title

      Bull.Chem.Soc.Japan 77

      Pages: 691-697

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Effect of Concentration, Acid, Temperature, and Metal on Competitive Reaction Pathways for Decarbonylation and Decarboxylation of Formic Acid in Hot Water2004

    • Author(s)
      Wakai, C., Yoshida, K., Tsujino, Y., Matubayasi, N., Nakahara, M.
    • Journal Title

      Chemistry Letters 33

      Pages: 572-573

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Noncatalytic Disproportionation and Decarbonylation Reactions of Benzaldehyde in Supercritical Water2004

    • Author(s)
      Nagai, Y., Matubayasi, N., Nakahara, M
    • Journal Title

      Chemistry Letters 33

      Pages: 622-623

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Acid-Catalyzed Hydrothermal Formation of Carbon-Carbon Bond in Glycolic Acid from a Series of Formaldehyde Producers2004

    • Author(s)
      Morooka, S., Wakai, C., Matubayasi, N., Nakahara, M
    • Journal Title

      Chemistry Letters 33

      Pages: 624-625

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Noncatalytic kinetic study on site-selective H/D exchange reaction of phenol in sub- and supercritical water2004

    • Author(s)
      Kubo, M., Takizawa., Wakai, C., Matubayasi, N., Nakahara, M
    • Journal Title

      J.Chem.Phys. 121

      Pages: 960-969

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] NMR Spectroscopic Evidence for an Intermediate of Formic Acid in the Water-Gas-Shift Reaction2004

    • Author(s)
      Yoshida, K., Wakai, C., Matubayasi, N., Nakahara, M
    • Journal Title

      J.Phys.Chem.A 108

      Pages: 7479-7482

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] A quantum chemical approach to the free energy calculations in condensed systems : The QM/MM method combined with the theory of energy representation2004

    • Author(s)
      Takahashi, H., Matubayasi, N., Nakahara, M., Nitta, T
    • Journal Title

      J.Chem.Phys. 121

      Pages: 3989-3999

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Mechanisms and kinetics of acetaldehyde reaction in supercritical water : Noncatalytic disproportionation, condensation, and decarbonylation2004

    • Author(s)
      Y.Nagai, S.Morooka, N.Matubayasi, M.Nakahara
    • Journal Title

      J.Phys.Chem.A 108

      Pages: 11635-11643

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Limited slowdown of endocrine-disrupter diffusion in confined fluid lipid membranes2004

    • Author(s)
      E.Okamura, C.Wakai, N.Matubayasi, Y.Sugiura, M.Nakahara
    • Journal Title

      Phys.Chem.Lett. 93

      Pages: 248101

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Noncatalytic Cannizzaro-type Reaction of Acetaldehyde in Supercritical Water2003

    • Author(s)
      Y.Nagai, C.Wakai, N.Matubayasi, M.Nakahara
    • Journal Title

      Chemistry Letters 32

      Pages: 310-311

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Theory of solutions in the energy representation. III. Treatment of the molecular flexibility2003

    • Author(s)
      N.Matubayasi, M.Nakahara
    • Journal Title

      Journal of Chemical Physics 119

      Pages: 9686-9702

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Dipolar Hydration Anomaly in the Temperature Dependence : Crbonyl and Nitrile Solutes Studied by ^<13>C NMR Chemical Shifts2003

    • Author(s)
      Y.Takebayashi, S.Yoda, T.Shigeta, K.Otake, M.Nakahara
    • Journal Title

      Journal of Physical Chemistry B 107

      Pages: 9847-9852

    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 水和の統計熱力学と超臨界水・熱水のエネルギー・環境化学2005

    • Author(s)
      松林 伸幸, 中原 勝
    • Total Pages
      76
    • Publisher
      現代化学
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 第5版実験化学講座第6巻 温度・熱・圧力2005

    • Author(s)
      中原 勝
    • Total Pages
      547
    • Publisher
      丸善
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] Proceedings of the 14^<th> International Conference of Water and Steam "Water, Steam, and Aqueous Solutions"2005

    • Author(s)
      Edited by M.Nakahara, N.Matubayasi, K.Yasuoka, K.Watanabe
    • Total Pages
      770
    • Publisher
      Maruzen
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 理科年表 国立天文台編2005

    • Author(s)
      中原 勝 他執筆者多数
    • Total Pages
      1022
    • Publisher
      丸善
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 化学便覧 基礎編II (日本化学会編)2004

    • Author(s)
      中原 勝
    • Total Pages
      II 127-II 129, II 144-II 149
    • Publisher
      丸善
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] Physicochemistry of Water in Geological and Biological System Structure, Dynamics, and Reactions of Supercritical Water2004

    • Author(s)
      M.Nakahara, N.Matubayasi
    • Total Pages
      281
    • Publisher
      Universal Academy Press
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] エーテルの製造方法2004

    • Inventor(s)
      中原勝, 松林伸幸, 若井千尋, 臼井祐馬
    • Industrial Property Number
      特願2004-013554号
    • Filing Date
      2004-01-21
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 新奇なグリコール酸の製造方法2004

    • Inventor(s)
      中原勝, 松林伸幸, 若井千尋, 諸岡紗以子
    • Industrial Property Number
      特願2004-023654号
    • Filing Date
      2004-01-30
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 芳香族化合物の製造方法2004

    • Inventor(s)
      中原勝, 松林伸幸, 若井千尋
    • Industrial Property Number
      特願2004-032723号
    • Filing Date
      2004-02-09
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 水熱反応を利用した水素の製造方法2004

    • Inventor(s)
      中原勝, 松林伸幸, 若井千尋, 吉田健
    • Industrial Property Number
      特願2004-108287号
    • Filing Date
      2004-03-03
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 高温高勾配磁場NMRプローブの改良2003

    • Inventor(s)
      中原勝, 松林伸幸, 若井千尋, 池田武義
    • Industrial Property Number
      特願2003-305999号
    • Filing Date
      2003-08-29
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] グリコール酸の製造方法2003

    • Inventor(s)
      中原勝, 松林伸幸, 若井千尋
    • Industrial Property Number
      特願2003-386814号
    • Filing Date
      2003-11-17
    • Description
      「研究成果報告書概要(和文)」より

URL: 

Published: 2007-12-13  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi