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2005 Fiscal Year Final Research Report Summary

Second Generation Octahedral Coordination Chemistry based on Hexametal Cluster Units

Research Project

Project/Area Number 15350029
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionHokkaido University

Principal Investigator

SASAKI Yoichi  Hokkaido Univ., Graduate School of Science, professor, 大学院・理学研究科, 教授 (30004500)

Co-Investigator(Kenkyū-buntansha) ABE Masaaki  Hokkaido Univ., Graduate School of Science, Research Associate, 大学院・理学研究科, 助手 (90260033)
TSUGE Kiyoshi  Hokkaido Univ., Graduate School of Science, Research Associate, 大学院・理学研究科, 助手 (60280583)
Project Period (FY) 2003 – 2005
KeywordsMetal Cluster Complexes / Hexanuclear Metal Complexes / Rhenium Complexes / Emissive Complexes / Ligand Substitution Reactions / Self-assembled Monolayers / Redox Reactions / Ligand-Ligand Interactions
Research Abstract

Octahedal hexametal clusters are known for various transition metal ions. Among them, those with d^4 metal ions such as Re(III), Mo(II) and W(II) are particularly stable with twelve electron-precise metal-metal single bonds. In this project, d^4 octahedral hexanuclear cluster complexes are considered as a target of a second generation of octahedral metal coordination chemistry. The purpose of this study is to clarify the similarity and difference between the octahedral cluster complexes and simple mononuclear octahedral complexes. The results are summarized as follows. (i) Ligand substitution properties. Kinetic study of the ligand substitution reactions at the terminal sites of the hexarhenium(III) clusters revealed that pyridine ligand is more rapidly substituted than chloride. This is in reverse trend from that of mononuclear complexes where less basic chloride ligand is replaced more easily. (ii) Redox reactions. Hexarhenium(III) complexes undergo one-electron oxidation. The redox … More potential shifts to positive direction as the number of terminal pyridine ligands increases in the mixed terminal pyridine-chloride system. This is in reverse direction from the expectation by considering the ligand basicity. The two facts, (i) and (ii), manifest unique characteristics of the hexametal clusters ; good π accepting and poor π donoating properties as opposed to typical low-spin d^6 mononuclear metal centers. (iii) Emissions. The d^4 octahedral clusters exhibit strong red emissions. Detailed temperature dependence of the emissions revealed curious behavior of emission life-times and emission energies. These results were successfully analyzed by considering four excited state sublevels. (iv) Self-assembled monolayers. Hexarhenium clusters were successfully fixed onto the gold electrode surfaces by using strong Au-S bond. The S-site was introduced to the ligand pyridine derivatives attached to the hexanuclear unit. Also the hexarhenium cluster unit was chemically combined to oxo-centered triruthenium unit both in solution and on the gold surface. The surface electrochemistry of the hexarhenium clusters and triruthenium-hexarhenium hybrid complexes have been studied. These results (i) - (iv) revealed important differences and similarities of the octahedral hexametal cluster complexes and simple mononuclear metal centers. Less

  • Research Products

    (58 results)

All 2006 2005 2004 2003

All Journal Article (54 results) Book (4 results)

  • [Journal Article] Palladium(II) and Palladium(II)-Platinum(II) Mixed Metal Complexes with Mercapto-1,3,4-thiadiazolate2006

    • Author(s)
      H.Tannai
    • Journal Title

      Bulletin of the Chemical Society of Japan 79巻(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Mixed Re(VII)-Fe(III) and Re(VII)-Cu(II) Complexes prepared by the Use of the Complex Ligand [Re(O)_3(tpenH-k^3N,N",N"')]^<2+> (tpen = N,N,N',N'-tetrakis(N-pyridylmethyl)ethylenediamine)2006

    • Author(s)
      T.Tabeya
    • Journal Title

      Bulletin of the Chemical Society of Japan 79巻(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] The largest Discrete Supramolecular Architecture based on Lanthanide Ion : La^<III>_<18>{N,N'-bis(2-pyridylmethyl)-N,N'-1,2-ethanediylbis(D-alaninate)_<18>(H_2O)_<36>}Cl_<18>2006

    • Author(s)
      K.Omata
    • Journal Title

      Inorganic Chemistry 45巻(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Palladium(II) and Palladium(II)-Platinum(II) Mixed Metal Complexes with Mercapto-1,3,4-thiadiazolate.2006

    • Author(s)
      H.Tannai, K.Tsuge, Y.Sasaki
    • Journal Title

      Bull.Chem.Soc.Jpn. 79(in press)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Mixed Re(VII)-Fe(III), and Re(VII)-Cu(II) Complexes prepared by the Use of a Complex Ligand [Re(O)_3(tpenH-κ^3N,N'''',N'''')]^<2+> (tpen N,N,N',N'-tetrakis(N-pyridylmethyl) ethylenediamine).2006

    • Author(s)
      T.Tabeya, M.Abe, Y.Sasaki
    • Journal Title

      Bull.Chem.Soc.Jpn. 79(in press)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] The largest Discrete Supramolecular Architecture based on Lanthanide Ion : La^<III>_<18>{N N'-bis(2-pyridylmethyl)-N,N'-1,2-ethanediylbis(D-alaninate)_<18>(H_2O)_<36>} Cl_<18>2006

    • Author(s)
      K.Omata, N.Hoshi, K.Kabuto, C.Kabuto, Y Sasaki
    • Journal Title

      Inorg.Chem. 45(in press)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Photoconversion of a Redox-Active Self-Assembled Monolayer : In Situ Probing of Photoinduced CO Dissociation from a Triruthenium2005

    • Author(s)
      M.Abe
    • Journal Title

      Angewante Chemie International Edition 44巻3号

      Pages: 416-419

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synthesis of Box-shaped Pentaporphyrin with Cobalt(II) Porphyrin in the Center. Reversible O_2 Binding in the Box2005

    • Author(s)
      K.Uruma
    • Journal Title

      Chemistry Letters 36巻4号

      Pages: 474-475

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Mononuclear Oxovanadium Complexes of Tris(2-pyridylmethyl)amine2005

    • Author(s)
      Y.Tajika
    • Journal Title

      Dalton Transactions 8号

      Pages: 1438-1447

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Switching of the Electronic Communication between Two {Ru(trpy)(bpy)} (trpy = 2,2' : 6',2"-Terpyridine and bpy = 4,4'-Bipyridine) Centers by Protonation on the Bridging Dimercaptothiadiazolato Ligand2005

    • Author(s)
      H.Tannai
    • Journal Title

      Inorganic Chemistry 44巻15号

      Pages: 5206-5208

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Oxidation States and CO Ligand Exchange Kinetics in a Self-Assembled Monolayer of a Triruthenium Cluster Studied by In Situ Infrared Spectroscopy2005

    • Author(s)
      W.Zhou
    • Journal Title

      Chemistry, Europian Journal 11巻17号

      Pages: 5040-5054

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Temperature Dependent Emission of Hexarhenium(III) Clusters [Re_6(μ_3-S)_8X_6]^<4-> : (X = Cl^-, Br^-, and I^-) : Analysis by Four Excited Triplet-State Sublevels2005

    • Author(s)
      N.Kitamura
    • Journal Title

      Inorganic Chemistry 44巻18号

      Pages: 6308-6313

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Spectroscopic and Excited-State Properties of Tri-9-anthrylboran III : Crystal and Spectroscopic Polmorphisms2005

    • Author(s)
      E.Sakuda
    • Journal Title

      Journal of Physical Chemistry, B 109巻47号

      Pages: 22326-22331

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Luminescence Ranging from Red to Blue : A Series of Copper(I) Halide Complexes Having Rhombic {Cu_2(μ-X)_2} (X=Br and I) Units with N-Heteroaromatic Ligands2005

    • Author(s)
      H.Araki
    • Journal Title

      Inorganic Chemistry 44巻26号

      Pages: 9667-9675

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Versatility of Technetium Chemistry as Viewed from the Recent Progress of Rhenium Cluster Chemistry2005

    • Author(s)
      Y.Sasaki
    • Journal Title

      Journal of Nuclear and Radiochemical Science 6巻3号

      Pages: 145-148

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] X-ray Structure and Electrochmical Properties of a Tpen-Bridged Hetero-Binuclear Complex fac-, fac-[Re^<VII>O_3(μ-tpen)Re^I(CO)_3](PF_6)_2 where Tpen is N,N,N',N'-Tetrakis(2-pyridylmethyl)ethylenediamine2005

    • Author(s)
      T.Tabeya
    • Journal Title

      Journal of Nuclear and Radiochemical Science 6巻3号

      Pages: 157-159

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Chiral Distortion of Di(μ-sulfido)di{oxomolybdenum(V)} Complexes of a Hexadentate Ligand N,N,N',N'-Tetrakis(2-pyridylmethyl)-R-propylenediamine and its Analogues2005

    • Author(s)
      H.-Y.Jin
    • Journal Title

      Bulletin of the Chemical Society of Japan 78巻12号

      Pages: 2161-2163

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Photoconversion of a Redox-Active Self-Assemble Monolayer : In Situ Probing of Photoinduced CO Dissociation from a Triruthenium Cluster Center on Gold.2005

    • Author(s)
      M.Abe, T.Masuda, T.Kondo, K.Uosaki, Y Sasaki
    • Journal Title

      Angew.Chem.Int.Ed. 44(3)

      Pages: 416-419

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis of Box-shaped Pentaporphyrin with Cobalt(II) Porphyrin in the Center. Reversible O_2 Binding in the Box.2005

    • Author(s)
      K.Uruma, K.Tsuge, Y.Sasaki, T.Imamura
    • Journal Title

      Chem.Lett. 36(4)

      Pages: 474-475

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Mononuclear Oxovanadium Complexes of Tris(2-pyridylmethyl)amine.2005

    • Author(s)
      Y.Tajika, K.Tsuge, Y.Sasaki
    • Journal Title

      Dalton Trans. No.8

      Pages: 1438-1447

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Switching of the Electronic Communication between Two {Ru(trpy)(bpy)} (trpy = 2,2':6',2''-Terpyridine and bpy = 4,4'-Bipyridine) Centers by Protonation on the Bridging Dimercaptothiadiazolato Ligand.2005

    • Author(s)
      H.Tannai, K.Tsuge, Y.Sasaki
    • Journal Title

      Inorg.Chem. 44(15)

      Pages: 5206-5208

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Oxidation States and CO Ligand Exchange Kinetics in a Self-Assembled Monolayer of a Triruthenium Cluster Studied by In Situ Infrared Spectroscopy.2005

    • Author(s)
      W.Zhou, S.Ye, M.Abe, T.Nishida, K.Uosaki, M.Osawa, Y.Sasaki
    • Journal Title

      Chem.Eur.J. 11(17)

      Pages: 5040-5054

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Temperature Dependent Emission of Hexarhenium(III) Clusters [Re_6(μ_3-S)_8X_6]^<4-> : (X = Cl^-, Br^-, and I^-) : Analysis by Four Excited Triplet-State Sublevels.2005

    • Author(s)
      N.Kitamura, Y.Ueda, S.Ishizaka, K.Yamada, M.Aniya, Y.Sasaki
    • Journal Title

      Inorg.Chem. 44(18)

      Pages: 6308-6313

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Spectroscopic and Excited-State Properties of Tri-9-anthrylboran III : Crystal and Spectroscopic Polmorphisms.2005

    • Author(s)
      E.Sakuda, K.Tsuge, Y.Sasaki, N.Kitamura
    • Journal Title

      J.Phys.Chem., B 109(47)

      Pages: 22326-22331

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Luminescence Ranging from Red to Blue : A Series of Copper(I) Halide Complexes Having Rhombic {Cu_2(μ-X)_2} (X = Br and I) Units with N-Heteroaromatic Ligands.2005

    • Author(s)
      H.Araki, K.Tsuge, Y.Sasaki, S.Ishizaka, N.Kitamura
    • Journal Title

      Inorg.Chem. 44(26)

      Pages: 9667-9675

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Versatility of Technetium Chemistry as Viewed from the Recent Progress of Rhenium Cluster Chemistry2005

    • Author(s)
      Y.Sasaki
    • Journal Title

      J.Nucl.Radiochem.Sci. 6(3)

      Pages: 145-148

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] X-ray Structure and Electrochmical Properties of a Tpen-Bridged Hetero-Binuclear Complex fac-, fac-[Re^<VII>O_3(μ-tpen)Re^I(CO)_3](PF_6)_2 where Tpen is N,N,N',N'-Tetrakis(2-pyridylmethyl) ethylenediamine.2005

    • Author(s)
      T.Tabeya, M.Abe, A.Mitani, K.Tsuge, Y.Sasaki
    • Journal Title

      J.Nucl.Radiochem.Sci. 6(3)

      Pages: 157-159

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Chiral Distortion of Di(μ-sulfido)di{oxomolybdenum(V)} Complexes of a Hexadentate Ligand N,N,N',N'-Tetrakis(2-pyridylmethyl)-R-propylenediamine an its Analogues.2005

    • Author(s)
      H.-Y.Jin, R.Hazama, M.Yamasaki, K.Umakoshi, K.Tsuge, Y.Sasaki
    • Journal Title

      Bull.Chem.Soc.Jpn. 78(12)

      Pages: 2161-2163

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Syntheses, Structures, and Electronic Redox Properties of Dimeric Triruthenium Clusters Bridged by Bis(diphenylphosphino)acetylene and -ethylene2004

    • Author(s)
      J.-K.Chen
    • Journal Title

      Inorganic Chemistry 43巻4号

      Pages: 1481-1490

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] A Pair of Seven Coordinate Oxorhenium Complexes, [Re^<IV>(O)(tpen)]^<2+> and [Re^V(O)(tpen)]^<3+>2004

    • Author(s)
      H.-Y.Jin
    • Journal Title

      Bulletin of the Chemical Society of Japan 77巻6号

      Pages: 1139-1146

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Electrochemical Control of CO/NO Ligand Exchange of Triruthenium Cluster Monolayer Assembled on a Gold Electrode Surface2004

    • Author(s)
      S.Ye
    • Journal Title

      Journal of the American Chemical Society 126巻24号

      Pages: 7434-7435

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Photodissociation of CO from [Ru_3(μ_3-O)(μ-OOCCH_3)_6(CO)L_2] in Acetonitrile, Where L=Pyridine, 4-Cyanopyridine and Methanol2004

    • Author(s)
      D.Akashi
    • Journal Title

      Dalton Transactions 18号

      Pages: 2883-2889

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Ligand-Based Redox Interaction through Some Metal-Cluster Units2004

    • Author(s)
      Y.Sasaki
    • Journal Title

      Chemical Records 4巻5号

      Pages: 279-290

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Syntheses, Structures, and Redox Properties of Dimeric Triruthenium Clusters Bridged by Bis(diphenylphosphino)acetylene and -ethylene.2004

    • Author(s)
      J.-K.Chen, L.-Y.Zhang, Z.-N.Chen, L.-B.Gao, M.Abe, Y.Sasaki
    • Journal Title

      Inorg.Chem. 43(4)

      Pages: 1481-1490

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] A Pair of Seven Coordinate Oxorhenium Complexes, [Re^<IV>(O)(tpen)]^<2+> and [Re^v(O)(tpen)]^<3+> (tpen = N,N,N',N'-Tetrakis(2-pyridylmethyl) ethylenediamine).2004

    • Author(s)
      H.-Y.Jin, S.Ikari, K.Kobayashi, K.Umakoshi, H.Sugimoto, A.Mitani, M.Abe, Y.Sasaki, T.Ito
    • Journal Title

      Bull.Chem.Soc.Jpn. 77(6)

      Pages: 1139-1146

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Electrochemical Control of CO/NO Ligand Exchange in a Triruthenium Cluster Monolayer Assembled on a Gold Electrode Surface.2004

    • Author(s)
      S.Ye, W.Zhou, M.Abe, T.Nishida, L.Cui, K.Uosaki, M.Osawa, Y.Sasaki
    • Journal Title

      J.Am.Chem.Soc. 126(24)

      Pages: 7434-7435

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Photodissociation of CO from [Ru_3(μ_3-O)(μ-OOCCH_3)_6(CO)L_2] in Acetonitrile, where L = Pyridine, 4-Cyanopyridine and Methanol.2004

    • Author(s)
      D.Akashi, H.Kido, M.Abe, Y.Sasaki, T.Ito
    • Journal Title

      Dalton Trans. No.18

      Pages: 2883-2889

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Ligand-Based Redox Interaction through Some Metal-Cluster Units.2004

    • Author(s)
      Y.Sasaki, M.Abe
    • Journal Title

      Chem.Rec. 4(5)

      Pages: 279-290

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis, Structure and Properties of Mono- and Dinuclear Platinum Complexes of Pyrimidine-2-thionate. Reinvestigation of the Preparation of [Pt_2Cl_2(pymS)_4]2003

    • Author(s)
      O.Asada
    • Journal Title

      Bulletin of the Chemical society of Japan 76巻3号

      Pages: 549-555

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synthesis and Properties of Rhodium(III) Porphyrin Cyclic Tetramer and Cofacial Dimer2003

    • Author(s)
      K.Fukushima
    • Journal Title

      Inorganic Chmeistry 42巻10号

      Pages: 3187-3193

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Monodentate and Bridging Coordination of 2,5-Dimercapto-1,3,4-thiadiazolate to a (2,2' : 6',2"-Terpyridine)platinum(II) Center2003

    • Author(s)
      H.Tannai
    • Journal Title

      Dalton Transactions 11号

      Pages: 2353-2358

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] η^3-Coordination of Hexadentate N,N,N',N'-Tetrakis(2-pyridyl-methyl)ethylenediamine (tpen) to a Mononuclear fac-Re^<VII> Center2003

    • Author(s)
      A.Mitani
    • Journal Title

      Chemistry Letters 34巻6号

      Pages: 502-503

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Assemblies of Mixed-metal Hexaporphyrins with an Oxo-bridged Iron(III) Porphyrin Dimer in the Center.2003

    • Author(s)
      M.Suzuki
    • Journal Title

      Chemistry Letters 34巻7号

      Pages: 564-565

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Electrochemical Control over Layer-by-layer Deposition of Metal Cluster Molecular Multilayers on Gold.2003

    • Author(s)
      M.Abe
    • Journal Title

      Angewandte Chemie, International Edition 42巻25号

      Pages: 2912-2915

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Preparation, Structures, and Redox and Emission Characteristics of Isothio-cyanate Complexes of Hexarhenium(III) Clusters, [Re_6(μ_3-E)_8(NCS)_6]^<4->.2003

    • Author(s)
      T.Yoshimura
    • Journal Title

      Inorganic Chemistry 42巻10号

      Pages: 4857-4863

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Structural Studies on the Stepwise Chelation Processes of Bidentate 2-Aminomethylpyridineand Tridentate Bis(2-pyridylmethyl)amine towards Acetate-bridged Dirhodium(II) Center2003

    • Author(s)
      T.Yoshimura
    • Journal Title

      Inorganic Chemistry 42巻22号

      Pages: 7106-7115

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synthesis, Structure and Properties of Mono- and Dinuclear Platinum Complexes of Pyrimidine-2-thionate. Reinvestigation of the Preparation of [Pt_2Cl_2(pymS)_4].2003

    • Author(s)
      O.Asada, K.Umakoshi, K.Tsuge, S.Yabuuchi, Y.Sasaki, M.Onishi
    • Journal Title

      Bull.Chem.Soc.Jpn. 76

      Pages: 549-555

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis and Properties of Rhodium(III) Porphyrin Cyclic Tetramer and Cofacial Dimer.2003

    • Author(s)
      K.Fukushima, K.Funatsu, A.Ichimura, Y.Sasaki, M.Suzuki, T.Fujihara, K.Tsuge, T.Imamura
    • Journal Title

      Inorg.Chem. 42(10)

      Pages: 3187-3193

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Monodentate and Bridging Coordination of 2,5-Dimercapto-1,3,4-thiadiazolate to a (2,2':6',2''-Terpyridine)platinum(II) Center.2003

    • Author(s)
      H.Tannai, K.Tsuge, Y.Sasaki, O.Hatozaki, N.Oyama
    • Journal Title

      Dalton Trans. No.11

      Pages: 2353-2358

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] η^3-Coordination of Hexadentate N,N,N',N'-Tetrakis(2-pyridylmethyl)-ethylenediamine (tpen) to a Mononuclear fac-Rev^<VII> Center : the Isolation of a New Class of Metal-containing Ligands.2003

    • Author(s)
      A.Mitani, M.Abe, K.Tsuge, Y.Sasaki
    • Journal Title

      Chem.Lett. 34(6)

      Pages: 502-503

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Assemblies of Mixed-metal Hexaporphyrins with an Oxo-bridged Iron(III) Porphyrin Dimer in the Center.2003

    • Author(s)
      M.Suzuki, K.Tsuge, Y.Sasaki, T.Imamura
    • Journal Title

      Chem.Lett. 34(7)

      Pages: 564-565

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Electrochemical Control over Layer-by-layer Deposition of Metal Cluster Molecular Multilayers on Gold.2003

    • Author(s)
      M.Abe, T.Michi, A.Sato, T.Kondo, W.Zhou, S.Ye, K.Uosaki, Y.Sasaki
    • Journal Title

      Angew.Chem.Int.Ed. 42(25)

      Pages: 2912-2915

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Preparation, Structures, and Redox and Emission Characteristics of the Isothiocyanate Complexes of Hexarhenium(III) Clusters, [Re_6(μ_3-E)_8(NCS)_6]^<4-> (E = S, Se).2003

    • Author(s)
      T.Yoshimura, Z.-N.Chen, A.Itasaka, M.Abe, Y Sasaki, S.Ishizaka, N.Kitamura, S.S.Yarovoi, S.F Solodovnikov, V.E.Fedorov
    • Journal Title

      Inorg.Chem. 42(10)

      Pages: 4857-4863

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Structural Studies on the Stepwise Chelation Processes of Bidentat 2-Amino-methylpyridine and Tridentate Bis(2-pyridylmethyl)amine towards Acetate-bridged Dirhodium(II) Center.2003

    • Author(s)
      T.Yoshimura, K.Umakoshi, Y.Sasaki
    • Journal Title

      Inorg.Chem. 42(22)

      Pages: 7106-7115

    • Description
      「研究成果報告書概要(欧文)」より
  • [Book] 新 水の分析2005

    • Author(s)
      佐々木陽一(分担執筆)
    • Total Pages
      472(11)
    • Publisher
      化学同人
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 先端化学シリーズV、海洋天然物、錯体、コンビナトリアル、全合成2004

    • Author(s)
      佐々木陽一(分担執筆)
    • Total Pages
      332(6)
    • Publisher
      丸善
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 第5版実験化学講座22、金属錯体、遷移金属クラスター2004

    • Author(s)
      佐々木陽一(分担執筆)
    • Total Pages
      524(10)
    • Publisher
      日本化学会
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 集積型金属錯体、第1部、第4章、集積型金属錯体の酸化還元機能と発光性2003

    • Author(s)
      佐々木陽一(分担執筆)
    • Total Pages
      273(9)
    • Publisher
      化学同人
    • Description
      「研究成果報告書概要(和文)」より

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Published: 2007-12-13  

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