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2005 Fiscal Year Final Research Report Summary

Environmentally Benign Synthesis Using Nanostructure-Controlled Base Catalysts

Research Project

Project/Area Number 15350093
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental chemistry
Research InstitutionYokohama National University (2004-2005)
Gifu University (2003)

Principal Investigator

KUBOTA Yoshihiro  Yokohama National University, Graduate School of Engineering, Associate Professor, 大学院・工学研究院, 助教授 (30283279)

Co-Investigator(Kenkyū-buntansha) FUNABIKI Kazumasa  Gifu University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (50273123)
SUGI Yoshihiro  Gifu University, Faculty of Engineering, Professor, 工学部, 教授 (90281047)
Project Period (FY) 2003 – 2005
Keywordsmesoporous silica / synergistic effect / solid base catalyst / C-C bond formation / fluorine-containing material / OFMS-type catalyst / SOCM-type catalyst / composite material
Research Abstract

Basic organic group-immobilized silicate materials have been utilized as the heterogeneous catalysts for C-C bond formation reactions such as Knoevenagel condensation, aldol condensation, and Michael addition. When using the amine-immobilized mesoporous silicas as base catalysts, the real effects of amine site and silica support have not been well investigated. Here we examined the effect of amine itself on the reaction as well as the conjugate effect of silicate additives such as SBA-15, and other ordered porous silicates. As a result, the combination of some secondary amine (as a base) and periodical mesoporous silicate (as an additive) drastically enhanced the reactivity in the reaction of aromatic aldehydes with acetone leading to the selective formation of β-hydroxyketones. The yield was low in the absence of the mesoporous silicate and the mesoposous silica itself was totally inert. It was suggested that the prominent effect of the silicate is not only due to the increase in the reactant concentration on the silicate surface but also to synergistic effect of base with acid. Activity of amine-immobilized silicate (organic-functionalized molecular sieves ; OFMSs) is higher than that of the simple mixture of amine and silicate. Very often, the OFMSs were effective when the supports were ordered mesoporous material and the reaction was carried out in polar solvents ; however, the yield was low in a non-polar solvent. In contrast, silicate-organic composite materials (SOCMs) were remarkably active in a non-polar solvent. The mesoporous silicate was more active than the microporous silicate. The active sites of the SOCM catalysts were considered to be SiO^-(^+NR_4) moieties located inside the pore near the pore-entrance. Although the high activity was not due to the leached species, a gradual loss of activity was observed after repeated use.

  • Research Products

    (66 results)

All 2006 2005 2004

All Journal Article (66 results)

  • [Journal Article] Synthesis of highly ordered mesoporous p6_3/mmc and p6mm phases by adding alcohols to the system for the SBA-1 synthesis2006

    • Author(s)
      P.Srinivasu, S.Lim, Y.Kubota, T.Tatsumi
    • Journal Title

      Catalysis Today 111巻・17号

      Pages: 379-387

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Amino-functionalized mesoporous silica synthesized by a novel synthesis route using an anionic surfactant2006

    • Author(s)
      T.Yokoi, H.Yoshitake, T.Yamada, Y.Kubota, T.Tatsumi
    • Journal Title

      Journal of Materials Chemistry 16巻

      Pages: 1125-1135

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Organic-inorganic hybrid catalysts based on ordered porous structures for Michael reaction2006

    • Author(s)
      Y.Kubota, H.Ikeya, Y.Sugi, T.Yamada, T.Tatsumi
    • Journal Title

      Journal of Molecular Catalysis A: Chemical 249巻・1-2号

      Pages: 181-190

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Direct aldol reaction of trifluoroacetaldehyde ethyl hemiacetal with ketones by the combination of amines and acids2006

    • Author(s)
      K.Funabiki, H.Nagaya, M.Ishihara, M.Matsui
    • Journal Title

      Tetrahedron 62巻・21号

      Pages: 5049-5053

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Asymmetric synthesis of □-hydroxy-□-trifluromethylated ketones via in situ generation of trifluoroacetaldehyde and its asymmetric carbon-carbon bond formation reaction with chiral imines in aqueous media2006

    • Author(s)
      K.Funabiki, K.Hasegawa, Y.Murase, H.Nagaya, M.Matsui
    • Journal Title

      Journal of Fluorine Chemistry 127巻・4-5号

      Pages: 545-547

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synthesis of highly ordered mesoporous p6_3/mmc and p6mm phases by adding alcohols to the system for the SBA-1 synthesis2006

    • Author(s)
      P.Srinivasu, S.Lim, Y.Kubota, T.Tatsumi
    • Journal Title

      Catal.Today 111(3-4)

      Pages: 379-384

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Amino-functionalized mesoporous silica synthesized by a novel synthesis route using an anionic surfactant2006

    • Author(s)
      T.Yokoi, H.Yoshitake, T.Yamada, Y.Kubota, T.Tatsumi
    • Journal Title

      J.Mater.Chem. 16

      Pages: 1125-1135

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Organic-inorganic hybrid catalysts based on ordered porous structures for Michael reaction2006

    • Author(s)
      Y.Kubota, H.Ikeya, Y.Sugi, T.Yamada, T.Tatsumi
    • Journal Title

      J.Mol.Catal., A : Chemical 249(1-2)

      Pages: 181-190

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Direct aldol reaction of trifluoroacetaldehyde ethyl hemiacetal with ketones by the combination of amines and acids2006

    • Author(s)
      K.Funabiki, H.Nagaya, M.Ishihara, M.Matsui
    • Journal Title

      Tetrahedron 62(21)

      Pages: 5049-5053

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Asymmetric synthesis of β-hydroxy-β-trifluoromethylated ketones via in situ generation of trifluoroacetaldehyde and its asymmetric carbon-carbon bond formation reaction with chiral imines in aqueous media2006

    • Author(s)
      K.Funabiki, K.Hasegawa, Y.Murase, H.Nagaya, M.Matsui
    • Journal Title

      J.Fluorine Chem. 127(4-5)

      Pages: 545-547

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Heck vinylation catalyzed quinoline-derived ruthenium and platinum complexes immobilized on ordered mesoporous silica2005

    • Author(s)
      J.Horniakova, H.Nakamura, R.Kawase, K.Komura, Y.Kubota, Y.Sugi
    • Journal Title

      Journal of Molecular Catalysis A: Chemical 233巻・1-2号

      Pages: 49-54

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] The transethylation ofbiphenyl with diethylbenzenes over H-Y zeolite2005

    • Author(s)
      Q.Jun, K.Komura, Y.Kubota, Y.Sugi
    • Journal Title

      Bulletin of Chemical Society of Japan 78巻・6号

      Pages: 1160-1166

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] The hydroamination of methyl acrylates with amines over zeolites2005

    • Author(s)
      J.Horniakova, K.Komura, H.Osaki, Y.Kubota, Y.Sugi
    • Journal Title

      Catalysis Letters 102巻・3-4号

      Pages: 191-196

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Friedel-Crafts alkylation of aromatics with benzyl alcohols catalyzed by rare earth metal triflates supported on MCM-41 mesoporous silica2005

    • Author(s)
      K.Mantri, K.Komura, Y.Kubota, Y.Sugi
    • Journal Title

      Journal of Molecular Catalysis A: Chemical 236巻・1-2号

      Pages: 168-175

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] H-ZSM-5 modified with lanthanum and cerium oxides in shape-selective ethylation of ethylbenzene. The deactivation of external acid sites and the control of pore entrance2005

    • Author(s)
      Y.Sugi, Y.Kubota, K.Komura, N.Sugiyama, M.Hayashi, J.-H.Kim
    • Journal Title

      Study of Surface Science and Catalysis 158巻

      Pages: 1279-1286

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Heck reaction caltalyzed by transition metal complexes with quinoline-derived ligands immobilized on mesoporous silica2005

    • Author(s)
      J.Horniakova, H.Nakamura, K.Komura, Y.Kubota, Y.Sugi
    • Journal Title

      Study of Surface Science and Catalysis 158巻

      Pages: 1597-1604

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synthesis of aluminophosphate molecular sieves with AFI topology sybstituted by alkaline earth metal and their application to solid acid catalysis2005

    • Author(s)
      S.K.Saha, S.B.Waghmode, H.Maekawa, K.Komura, Y.Kubota, Y.Sugi, Y.Oumi, T.Sano
    • Journal Title

      Microporous and Mesoporous Materials 81巻・1-3号

      Pages: 289-303

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Magnesioaluminophosphate molecular sieves with ATS topology: Synthesis by dry-gel conversion method and catalytic properties in the isopropylation of biphenyl2005

    • Author(s)
      S.K.Saha, S.B.Waghmode, H.Maekawa, R.Kawase, K.Komura, Y.Kubota, Y.Sugi
    • Journal Title

      Microporous and Mesoporous Materials 81巻・1-3号

      Pages: 277-287

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Heck vinylation catalyzed by quinoline-derived ruthenium and platinum complexes immobilized on ordered mesoporous silica2005

    • Author(s)
      J.Horniakova, H.Nakamura, R.Kawase, K.Komura, Y.Kubota, Y.Sugi
    • Journal Title

      J.Mol.Catal., A : Chemical 233(1-2)

      Pages: 49-54

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] The transethylation of biphenyl with diethylbenzenes over H-Y Zeolite2005

    • Author(s)
      Q.Jun, K.Komura, Y.Kubota, Y.Sugi
    • Journal Title

      Bull.Chem.Soc.Jpn. 78(6)

      Pages: 1160-1166

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] The hydroamination of methyl acrylates with amines over zeolites2005

    • Author(s)
      J.Horniakova, K.Komura, H.Osaki, Y.Kubota, Y.Sugi
    • Journal Title

      Catal.Lett. 102(3-4)

      Pages: 191-196

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Friedel-Crafts alkylation of aromatics with benzyl alcohols catalyzed by rare earth metal triflates supported on MCM-41 mesoporous silica2005

    • Author(s)
      K.Mantri, K.Komura, Y.Kubota, Y.Sugi
    • Journal Title

      J.Mol.Catal.A : Chemical 236(1-2)

      Pages: 168-175

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] H-ZSM-5 modified with lanthanum and cerium oxides in shape-selective ethylation of ethylbenzene. The deactivation of external acid sites and the control of pore entrance2005

    • Author(s)
      Y.Sugi, Y.Kubota, K.Komura, N.Sugiyama, M.Hayashi, J.-H.Kim
    • Journal Title

      Stud.Surf.Sci.Catal. 158

      Pages: 1279-1286

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Heck reaction caltalyzed by transition metal complexes with quinoline-derived ligands immobilized on mesoporous silica,2005

    • Author(s)
      J.Horniakova, H.Nakamura, K.Komura, Y.Kubota, Y.Sugi
    • Journal Title

      Stud.Surf.Sci.Catal. 158

      Pages: 1597-1604

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis of aluminophosphate molecular sieves with AFI topology substituted by alkaline earth metal and their application to solid acid catalysis2005

    • Author(s)
      S.K.Saha, S.B.Waghmode, H.Maekawa, K.Komura, Y.Kubota, Y.Sugi, Y.Oumi, T.Sano
    • Journal Title

      Micropor.Mesopor.Mater. 81(1-3)

      Pages: 289-303

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Magnesioaluminophosphate molecular sieves with ATS topology : Synthesis by dry-gel conversion method and catalytic properties in the isopropylation of biphenyl2005

    • Author(s)
      S.K.Saha, S.B.Waghmode, H.Maekawa, R.Kawase, K.Komura, Y.Kubota, Y.Sugi
    • Journal Title

      Micropor.Mesopor.Mater. 81(1-3)

      Pages: 277-287

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Organic-silicate hybrid catalysts based on various defined structures for Knoevenagel condensation2004

    • Author(s)
      Y.Kubota, Y.Nishizaki, H.Ikeya, M.Saeki, T.Hida, S.Kawazu, M.Yoshida, H.Fujii, Y.Sugi
    • Journal Title

      Microporous and Mesoporous Materials 70巻

      Pages: 135-149

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Hydrothermal Synthesis of [A1]-SSZ-24 from [A1]-Beta Zeolite ([A1]-BEA) as recursors2004

    • Author(s)
      H.Maekawa, Y.Kubota, Y.Sugi
    • Journal Title

      Chemistry Letters 33巻・9号

      Pages: 1126-1127

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synthesis of AF1 aluminophosphate molecular sieves partly substituted with magnesium by dry-gel conversion (DGC) method2004

    • Author(s)
      S.K.Saha, S.B.Waghmode, Y.Kubota, Y.Sugi
    • Journal Title

      Materials Letters 58巻・22-23号

      Pages: 2918-2923

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synthesis of aluminophosphate-type molecular sieves MAPO-36 (ATS) by dry-gel conversion (DGC) method and its application to shape-selective catalysis2004

    • Author(s)
      S.K.Saha, H.Maekawa, Y.Kubota, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29巻・4号

      Pages: 2187-2190

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synthesis and characterization of alkaline warth metal substituted aluminophosphates with AF1 topology2004

    • Author(s)
      S.K.Saha, S.B.Waghmode, Y.Kubota, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29巻・5号

      Pages: 2195-2198

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Zeolite beta by dry gel conversion (DGC) method: an efficient catalyst for the isomerization of hexane2004

    • Author(s)
      Pusparatu, Y.Kubota, Y.Nishimura, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29巻・5号

      Pages: 2191-2194

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] ZSM-12 zeolite catalyzed shape-selective ethylation of biphenyl to 4,4'-diethylbiphenyl2004

    • Author(s)
      S.B.Waghmode, S.Watanabe, Y.Kubota, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29巻・5号

      Pages: 2179-2182

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Pyridine derived palladium complexes immobilized on ordered mesoporous silica as catalysts for Heck-type reactions2004

    • Author(s)
      J.Horniakova, T.Raja, Y.Kubota, Y.Sugi
    • Journal Title

      Journal of Molecular Catalysis A: Chemical 217巻1-2

      Pages: 73-80

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Palladium complexes immobilized on FSM-16 as catalysts for Heck reaction2004

    • Author(s)
      J.Horniakova, Y.Kubota, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29巻・5号

      Pages: 2207-2210

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Enviromentally benign catalysts for C-C bond forming reactions2004

    • Author(s)
      Y.Kubota, Y.Nishizaki, H.Ikeya, K.Goto, S.Miyata, J.Nagaya, S.Kwazu, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29巻・5号

      Pages: 1991-1994

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Selective isopropylation of biphenyl to 4,4'-DIPB over mordenite (MOR) type zeolite obtained from a layered sodium silicate magadiite2004

    • Author(s)
      T.Selvam, G.T.P.Mabande, W.Schwieger, Y.Sugi, I.Toyama, Y.Kubota, H.-S.Lee, J.-H.Kim
    • Journal Title

      Catalysis Letters 94巻

      Pages: 17-24

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Performance and characterization of BEA catalysts for catalytic cracking2004

    • Author(s)
      R.Nakao, Y.Kubota, N.Katada, N.Nishiyama, K.Kunimori, K.Tomishige
    • Journal Title

      Applied Catalysis A: General 273巻・1-2号

      Pages: 63-73

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Isopropylation of benzene with 2-propanol over AFI aluminophosphate molecular sieves substituted with alkaline earth metal2004

    • Author(s)
      S.B.Waghmode, S.K.Saha, Y.Kubota, Y.Sugi
    • Journal Title

      Journal of Catalysis 228巻・1号

      Pages: 192-205

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] The isopropylation of biphenyl over H-mordenites. Roles of external surface in shape-selective catalysis2004

    • Author(s)
      S.Tawada, Y.Kubota, Y.Sugi, Y.Kiyozumi, T.Hanaoka, F.Mizukami
    • Journal Title

      Journal of the Japan Institute of Energy 83巻

      Pages: 1045-1052

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Rare-earth metal triflates as versatile catalysts for the chloromethylation of aromatic hydrocarbons2004

    • Author(s)
      T.Kishida, T.Yamauchi, Y.Kubota, Y.Sugi
    • Journal Title

      Green Chemistry 6巻

      Pages: 57-62

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Rare-earth metal triflates. An environment conscious catalyst for the chloromethylation of aromatic hydrocarbons2004

    • Author(s)
      T.Kishida, T.Yamauchi, Y.Kubota, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29巻・5号

      Pages: 2203-2206

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Practical Asymmetric Synthesis of □-Hydroxy-□-trifluromethylated Ketones via the First Example of the In-situ Generation of Trifluoroacetaldehyde and Its Successive Asymmetric Carbon-carbon Bond Formation Reaction with Chiral Imines2004

    • Author(s)
      K.Funabiki, W.Hashimoto, M.Matsui
    • Journal Title

      Chemical Communications 2004巻・18号

      Pages: 2056-2057

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] First Catalytic Asymmetric Synthesis of □-Amino-□-polyfluoroalkyl Ketones via Proline-catalysed Direct Asymmetric Carbon-carbon Bond Formation Reaction of Polyfluoroalkylated Aldimines2004

    • Author(s)
      K.Funabiki, M.Nagamori, S.Goushi, M.Matsui
    • Journal Title

      Chemical Communications 2004巻・17号

      Pages: 1928-1929

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Asymmetric synthesis of □-trifluoromethylated □-amino aldehyde as well as carboxylic acid derivatives using enantiopure □-trifluoromethylated homoallylamine2004

    • Author(s)
      K.Funabiki, M.Nagamori, M.Matsui
    • Journal Title

      Journal of Fluorine Chemistry 125巻・9号

      Pages: 1347-1350

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] フッ素でチューニングされたエノール誘導体の選択的変換反応を活用する各種有機フッ素化合物の合成2004

    • Author(s)
      船曳 一正
    • Journal Title

      有機合成化学協会誌, 62(6), 607-615 (2004). 62巻・6号

      Pages: 607-615

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Organic-silicate hybrid catalysts based on various defined structures for Knoevenagel condensation2004

    • Author(s)
      Y.Kubota, Y.Nishizaki, H.Ikeya, M.Saeki, T.Hida, S.Kawazu, M.Yoshida, H.Fujii, Y.Sugi
    • Journal Title

      Micropor.Mesopore.Mater 70(1-3)

      Pages: 135-149

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Hydrothermal Synthesis of [Al]-SSZ-24 from [Al]-Beta Zeolite ([Al]-BEA) as recursors2004

    • Author(s)
      H.Maekawa, Y.Kubota, Y.Sugi
    • Journal Title

      Chem.Lett. 33(9)

      Pages: 1126-1127

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis of AFI aluminophosphate molecular sieves partly substituted with magnesium by dry-gel conversion (DGC) method2004

    • Author(s)
      S.K.Saha, S.B.Waghmode, Y.Kubota, Y.Sugi
    • Journal Title

      Mater Lett. 58(22-23)

      Pages: 2918-2923

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis of aluminophosphate-type molecular sieve MAPO-36 (ATS) by dry-gel conversion (DGC) method and its application to shape-selective catalysis2004

    • Author(s)
      S.K.Saha, H.Maekawa, Y.Kubota, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29(5)

      Pages: 2187-2190

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis and characterization of alkaline warth metal substituted aluminophosphates with AFI topology2004

    • Author(s)
      S.K.Saha, S.B.Waghmode, Y.Kubota, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29(5)

      Pages: 2195-2198

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Zeolite beta by dry gel conversion (DGC) method : an efficient catalyst for the isomerization of hexane2004

    • Author(s)
      Pusparatu, Y.Kubota, Y.Nishimura, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29(5)

      Pages: 2191-2194

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] ZSM-12 zeolite catalyzed shape-selective ethylation of biphenyl to 4,4'-diethylbiphenyl2004

    • Author(s)
      S.B.Waghmode, S.Watanabe, Y.Kubota, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29(5)

      Pages: 2179-2182

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Pyridine derived palladium complexes immobilized on ordered mesoporous silica as catalysts for Heck-type reactions2004

    • Author(s)
      J.Horniakova, T.Raja, Y.Kubota, Y.Sugi
    • Journal Title

      J.Mol.Cat.A : Chemical 217(1-2)

      Pages: 73-80

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Palladium complexes immobilized on FSM-16 as catalysts for Heck reaction2004

    • Author(s)
      J.Horniakova, Y.Kubota, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29(5)

      Pages: 2207-2210

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Enviromentally benign catalysts for C-C bond forming reactions2004

    • Author(s)
      Y.Kubota, Y.Nishizaki, H.Ikeya, K.Goto, S.Miyata, J.Nagaya, S.Kwazu, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29(5)

      Pages: 1991-1994

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Selective isopropylation of biphenyl to 4,4'-DIPB over mordenite (MOR) type zeolite obtained from a layered sodium silicate magadiite2004

    • Author(s)
      T.Selvam, G.T.P.Mabande, W.Schwieger, Y.Sugi, I.Toyama, Y.Kubota, H.-S.Lee, J.-H.Kim
    • Journal Title

      Catal.Lett. 94

      Pages: 17-24

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Performance and characterization of BEA catalysts for catalytic cracking2004

    • Author(s)
      R.Nakao, Y.Kubota, N.Katada, N.Nishiyama, K.Kunimori, K.Tomishige
    • Journal Title

      Appl.Catal.A : General 273(1-2)

      Pages: 63-73

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Isopropylation of benzene with 2-propanol over AFI aluminophosphate molecular sieves substituted with alkaline earth metal2004

    • Author(s)
      S.B.Waghmode, S.K.Saha, Y.Kubota, Y.Sugi
    • Journal Title

      J.Catal. 228(1)

      Pages: 192-205

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] The isopropylation of biphenyl over H-mordenites. Roles of external surface in shape-selective catalysis2004

    • Author(s)
      S.Tawada, Y.Kubota, Y.Sugi, Y.Kiyozumi, T.Hanaoka, F.Mizukami
    • Journal Title

      Journal of the Japan Institute of Energy 83

      Pages: 1045-1052

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Rare-earth metal triflates as versatile catalysts for the chloromethylation of aromatic hydrocarbons2004

    • Author(s)
      T.Kishida, T.Yamauchi, Y.Kubota, Y.Sugi
    • Journal Title

      Green Chem. 6

      Pages: 57-62

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Rare-earth metal triflates. An environment conscious catalyst for the chloromethylation of aromatic hydrocarbons2004

    • Author(s)
      T.Kishida, T.Yamauchi, Y.Kubota, Y.Sugi
    • Journal Title

      Transactions of the Materials Research Society of Japan 29(5)

      Pages: 2203-2206

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Practical asymmetric synthesis of β-hydroxy-β-trifluoromethylated ketones via the first example of the in-situ generation of trifluoroacetaldehyde and its successive asymmetric carbon-carbon bond formation reaction with chiral imines2004

    • Author(s)
      K.Funabiki, W.Hashimoto, M.Matsui
    • Journal Title

      Chem.Commun.

      Pages: 2056-2057

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] First catalytic asymmetric synthesis of β-amino-β-polyfluoroalkyl ketones via proline-catalysed direct asymmetric carbon-carbon bond formation reaction of polyfluoroalkylated aldimines2004

    • Author(s)
      K.Funabiki, M.Nagamori, S.Goushi, M.Matsui
    • Journal Title

      Chem.Commun.

      Pages: 1928-1929

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Asymmetric synthesis of β-trifluoromethylated β-amino aldehyde as well as carboxylic acid derivatives using enantiopure α-trifluoromethylated homoallylamine2004

    • Author(s)
      K.Funabiki, M.Nagamori, M.Matsui
    • Journal Title

      J.Fluorine Chem. 125(9)

      Pages: 1347-1350

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis of various organofluorine compounds using selective transformation of enol derivatives by tuning with fluorine atoms2004

    • Author(s)
      K.Funabiki
    • Journal Title

      Yuki Gosei Kagaku Kyokaishi 62(6)

      Pages: 607-615

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2007-12-13  

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