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2005 Fiscal Year Final Research Report Summary

Behaviors in Strain-induced Crystallization of Natural Rubber : For the Selection of Clone of Hevea Tree

Research Project

Project/Area Number 15404011
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section海外学術
Research Field Polymer/Textile materials
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

KOHJIYA Shinzo  Kyoto University, Institute for Chemical Research, Professor, 化学研究所, 教授 (50027900)

Co-Investigator(Kenkyū-buntansha) TOSAKA Masatoshi  Kyoto University, Institute for Chemical Research, Assistant Professor, 化学研究所, 助手 (10273509)
SENOO Kazunobu  Kyoto University, Institute for Chemical Research, Assistant Professor, 化学研究所, 助手 (40362389)
IKDA Yuko  Kyoto Institute of Technology, Assistant Professor, 工芸学部, 助手 (10202904)
Project Period (FY) 2003 – 2005
KeywordsNatural rubber / Clone / Strain-induced crstallization / Elastomer / International exchane of scientists / International
Research Abstract

The final objective of this study is to maximize functions and performances of natural rubber (NR) which is a very important biomass for industrial uses such as pneumatic tires.
For this purpose, strain-induced crystallization of NR samples from different clones are studied using a dynamic condition at a synchrotron radiation beam line i.e. simultaneous measurements of wide-angle X-ray diffraction and tensile-mode deformation. The results are to be of use for the selection of better NR : Strain-induced crystallization has been assumed to be the most important factor to determine superior mechanical properties of NR. Effects of micron-size dirt, non-rubber components such as aliphatic acid and proteins contained in NR, and nano-fillers such as carbon black on the behavior in strain-induced crystallization of NR were elucidated.
A few different clones of Hevea have been obtained from Sri Lank and Thailand. Using these samples, the main experiments to elucidate the effect of Hevea clones on the crystallization are now in progress and will be reported in a near future.

  • Research Products

    (18 results)

All 2006 2005 2004 Other

All Journal Article (18 results)

  • [Journal Article] スマートナノコンポジットとしての天然ゴム2006

    • Author(s)
      登坂雅聡, ?谷信三
    • Journal Title

      未来材料 6

      Pages: 28-33

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Crystallization and stress relaxation in highly-stretched samples of natural rubber and its synthetic analogue2006

    • Author(s)
      M.Tosaka, D.Kawakami, K.Senoo, S.Kohjiya, Y.Ikeda, S.Toki, B.S.Hsiao
    • Journal Title

      Macromolecules (in press)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Strain-induced crystallization of peroxide-crosslinked natural rubber2006

    • Author(s)
      Y.Ikeda, Y.Yasuda, S.Makino, S.Yamamoto, M.Tosaka, K.Senoo, S.Kohjiya
    • Journal Title

      Chem.Letters (submitted)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Natural rubber as the smart nano-composite2006

    • Author(s)
      M.Tosaka, S.Kohjiya
    • Journal Title

      Mirai zairyo (in Japanese) 6, no.3

      Pages: 28-33

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] 架橋天然ゴムの伸長結晶化における非ゴム成分、特にステアリン酸の効果について2005

    • Author(s)
      古谷昌大, 登坂雅聡, ?谷信三, 池田裕子
    • Journal Title

      接着 49

      Pages: 202-207

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] スマート in-situ ナノコンポジット : 天然ゴムの伸長結晶化2005

    • Author(s)
      〓谷信三, 登坂雅聡, 古谷昌大, S.Poompradub, 池田裕子
    • Journal Title

      日本化学繊維研究所講演集, 62

      Pages: 53-65

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Mechanism of strain-induced crystallization in filled and unfilled natural rubber vulcanizates2005

    • Author(s)
      S.Poompradub, M.Tosaka, S.Kohjiya, Y.Ikeda, S.Toki, I.Sics, B.S.Hsiao
    • Journal Title

      J.Appl.Phys. 97

      Pages: 1-9

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Effect of non rubber component, e.g. stearic acid on strain-induced crystallization of cross-linked natural rubber2005

    • Author(s)
      M.Furutani, M.Tosaka, S.Kohjiya, Y.Ikeda
    • Journal Title

      Secchaku (in Japanese) 49

      Pages: 202-207

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Smart in-situ Nano-composite : strain-induced crystallization of natural rubber2005

    • Author(s)
      S.Kohjiya, M.Tosaka, M.Fujitani, S.Poompradub Y.Ikeda
    • Journal Title

      nihon-kagakuseni-kenkyusyo (in Japanese) 62

      Pages: 53-65

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Mechanism of strain-induced crystallization in filled and unfilled natural rubber vulcanizates,2005

    • Author(s)
      S.Poompradub, M.Tosaka, S.Kohjiya, Y.Ikeda, S.Toki, I.Sics, B.S.Hsiao
    • Journal Title

      J.Appl.Phys. 97

      Pages: 103529/1-103529/9

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Lattice deformation of strain-induced crystallites in carbon-filled natural rubber2004

    • Author(s)
      S.Poompradub, M.Tosaka, S.Kohjiya, Y.Ikeda, S.Toki, I.Sics, B.S.Hsiao
    • Journal Title

      Chem. Letters 33

      Pages: 220-221

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Effect of network-chain length on strain-induced crystallization of NR and IR vulcanizates2004

    • Author(s)
      M.Tosaka, S.Kohjiya, S.Murakami, S.Poompradub, Y.Ikeda, S.Toki, I.Sics, B.S.Hsiao
    • Journal Title

      Rubber Chem. Technol. 77

      Pages: 711-723

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Orientation and crystallization of natural rubber network as revealed by WAXD using synchrotron radiation2004

    • Author(s)
      M.Tosaka, S.Murakami, S.Poompradub, S.Kohjiya, Y.Ikeda, S.Toki, I.Sics, B.S.Hsiao
    • Journal Title

      Macromolecules 37

      Pages: 3299-3309

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Lattice deformation of strain-induced crystallites in carbon-filled natural rubber,2004

    • Author(s)
      S.Poompradub, M.Tosaka, S.Kohjiya, Y.Ikeda, S.Toki, I.Sics, B.S.Hsiao
    • Journal Title

      Chem.Letters 33

      Pages: 220-221

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Effect of network-chain length on strain-induced crystallization of NR and IR vulcanizates,2004

    • Author(s)
      M.Tosaka, S.Kohjiya, S.Murakami, S.Poompradub, Y.IkedaA, S.Toki, I.Sics, B.S.Hsiao
    • Journal Title

      Rubber Chem.Technol. 77

      Pages: 711-723

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Orientation and crystallization of natural rubber network as revealed by WAXD using synchrotron radiation,2004

    • Author(s)
      M.Tosaka, S.Murakami, S.Poompradub, S.Kohjiya, Y.IkedaA, S.Toki, I.Sics, B.S.Hsiao
    • Journal Title

      Macromolecules. 37

      Pages: 3299-3309

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Crystallization and stress relaxation in highly-stretched samples of natural rubber and its synthetic analogue,

    • Author(s)
      M.Tosaka, D.Kawakami, K.Sendo, S.Kohjiya, Y.Ikeda, S.Toki, B.S.Hsiao
    • Journal Title

      Macromolecules (in press)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Strain-induced crystallization of peroxide-crosslinked natural rubber,

    • Author(s)
      Y.Ikeda, Y.Yasuda, S.Makino, S.Yamamoto, M.Tosaka, K.Senoo, S.Kohjiya
    • Journal Title

      Chem.Letters (submitted)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2007-12-13  

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