2004 Fiscal Year Final Research Report Summary
Synergetic Molecular Recognition Sites having a Signaling Function Prepared by Molecular Imprinting
| Project/Area Number |
15510102
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Nanomaterials/Nanobioscience
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| Research Institution | Kobe University |
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Principal Investigator |
TAKEUCHI Toshifumi Kobe University, Graduate School of Science and Technology, Professor, 自然科学研究科, 教授 (70179612)
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| Project Period (FY) |
2003 – 2004
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| Keywords | molecular imprinting / molecular recognition / シナジェティックシグナリング材料 |
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| Research Abstract |
Signaling-imprinted polymers were prepared for heterocyclic compounds using a polymerizable metalloporphyrin and/or methacrylic acid as functional monomer(s), and evaluated by chromatographic tests, Scatchard analysis, and spectroscopic analysis. In the polymers, the metalloporphyrin residue and methacrylic acid residues worked cooperatively at the imprinted binding site. A linear relationship was observed between the UV-Vis absorbance of the imprinted polymer and the logarithm of target concentrations, indicating that the polymer may be used as a selective sensing material for the given target molecule. Various metalloporphyrins can be used as functionalized monomers in order to prepare signaling-imprinted polymers for a wide range of target compounds capable of coordination with metalloporphyrins.
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[Journal Article] Atrazine Transformation Using Synthetic Enzymes Prepared by Molecular Imprinting2004
Author(s)
Takeuchi, T., Ugata, S., Masuda, S., Matsui, J., Yane, T., Takase, M.
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Journal Title
Org.Biomol.Chem. 2
Pages: 2563-2566
Description
「研究成果報告書概要(和文)」より
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[Journal Article] Chiral Recognition of Octadentate Na+ Complex with Tetra-Armed Cyclen by Molecular Imprinted Polymers2004
Author(s)
Kubo, H., Player, T.N., Shinoda, S., Tsukube, H., Nariai, H., Takeuchi, T.
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Journal Title
Anal.Chim.Acta 504
Pages: 137-140
Description
「研究成果報告書概要(和文)」より
-
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[Journal Article] Atrazine Tranformation Using Synthetic Enzymes Prepared by Molecular Imprinting2004
Author(s)
Takeuchi, T., Ugata, S., Masuda, S., Matsui, J., Yane, T., Takase, M.
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Journal Title
Org.Biomol.Chem.2004 2
Pages: 2563-2566
Description
「研究成果報告書概要(欧文)」より
-
[Journal Article] Chiral Recognition of Octadentate Na+ Complex with Tetra-Armed Cyclen by Molecularly Imprinted Polymers2004
Author(s)
Kubo, H., Player, T.N., Shinoda, S Tsukube, H., Nariai, H., Takeuchi, T.
-
Journal Title
Anal.Chim.Acta 2004 504
Pages: 137-140
Description
「研究成果報告書概要(欧文)」より
-
