2005 Fiscal Year Final Research Report Summary
Application of chiral calixarenes to supramolecular chemistry
| Project/Area Number |
15550114
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
OKADA Yukihiro GUNMA UNIVERSITY, Dept of Chem, Associate Prof., 工学部, 助教授 (80211118)
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| Project Period (FY) |
2003 – 2005
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| Keywords | calixarene / chiral / catenane / enantiomer / crown ether |
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| Research Abstract |
Catenanes based chiral calixarene were obtained in excellent yield of 38-80%. Enantiomer of catenane was also synthesized in 61% yield by using (-)-calixarene. Its temperature dependence of CD spectra showed a little change. Anion exchanging catenanes were easy preparation. They showed the large difference of movement at pyridinum moiety by VT NMR spectra. Calixarenes attaching crown ether including pyridine and benzoic acid units were obtained in mederate yields. They showed the high ion selectivity for Ba^<2+> and recognized the organic molecules like amine.
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