2017 Fiscal Year Final Research Report
Molecular Chemistry of Electrolytic Nano-fluide and Artificial Gas Hydrate
| Project/Area Number |
15H03851
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Energy-related chemistry
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| Research Institution | Tokyo University of Science |
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Principal Investigator |
Tadokoro Makoto 東京理科大学, 理学部第一部化学科, 教授 (60249951)
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| Co-Investigator(Kenkyū-buntansha) |
松井 広志 東北大学, 理学研究科, 准教授 (30275292)
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| Co-Investigator(Renkei-kenkyūsha) |
ISODA Kyousuke 東京理科大学, 理学部, 助教 (20568620)
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| Research Collaborator |
Suzuki YOU
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | nanoporous crystal / water cluster / gas hydrate / methane hydrate / nanofluidics / ionic conductivity / Solid-state NMR / nanoporous crystal |
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| Outline of Final Research Achievements |
The 1-D water nanotube-like cluster (WNT) stabilized by channel pores in a nanoporous molecular crystal can confine some gases as methane and xenon. Their WNT forms a gas hydrate stabilized even at room temperature and in the high pressure at ~20 atm, we have found that they reversibly can take and release a great deal of methane and xenon gas. Meanwhile, when the electrolytic ions are confined to WNT, the ionic conductivity is as high as that in bulk aqueous solution. That is the reason why the coherent interaction would be probably caused of the electrolytic ions with 1-D regular arrays.
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| Free Research Field |
錯体科学
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