2017 Fiscal Year Final Research Report
Development of Oxidative Coupling Reactions Using Designer Iodine Catalysis
| Project/Area Number |
15H05484
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | ヨウ素 / 酸化 / カップリング / 触媒反応 / エナンチオ選択的反応 |
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| Outline of Final Research Achievements |
Although a great advancement has been made in the development of acid-base organocatalysis in recent years, organocatalyzed redox reactions have less investigated. We interested in the redox ability (hypervalent ability) of iodine as an alternative to heavy metals and transition metals. We developed several redox organocatalysis for the highly efficient and selective oxidative transformations based on iodine chemistry. Importantly, the catalytic active species could be generated in situ from the corresponding stable and safe precursors (iodoarenes or onium iodides) in the presence of appropriate oxidants under environmentally friendly conditions.
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| Free Research Field |
有機合成化学
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