2020 Fiscal Year Final Research Report
Development of High Performance Acid–Base Combined Nanocatalysts
| Project/Area Number |
15H05755
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| Research Category |
Grant-in-Aid for Scientific Research (S)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2015-05-29 – 2020-03-31
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| Keywords | 酸塩基複合化学 / ナノ触媒 / 均一触媒 / 分子認識 / 選択性 / 超分子 / 酸 / 塩基 |
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| Outline of Final Research Achievements |
High-performance supramolecular catalysts were rationally designed using non-covalent bonding interactions such as hydrogen bonding, halogen bonding, ionic interaction, resonance effect, pi-cation interaction, etc. based on acid-base combination chemistry. These nano-size catalysts were superior to small unimolecular catalysts regarding the selectivity and turn-over frequency.
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| Free Research Field |
有機合成化学
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| Academic Significance and Societal Importance of the Research Achievements |
医農薬品、香料、接着剤、塗料、液晶、有機伝導体等のファインケミカル、機能性材料の開発・合成に携わる研究者は標的化合物を合成するための最も優れた触媒を求めているのであって、必ずしも汎用性の高いレディメイド触媒を求めているわけではない。本研究課題の成果である、従来の単一分子触媒を凌駕するテーラーメイド超分子触媒は合成困難な有機化合物を短時間で効率のよい合成を可能にするため、環境低負荷型精密有機合成技術を格段に向させる。
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