2016 Fiscal Year Final Research Report
Development of Loop-shape pi-Conjugated Polymers with Hydrogen-bond Network
| Project/Area Number |
15H06849
|
|---|
| Research Category |
Grant-in-Aid for Research Activity Start-up
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Functional solid state chemistry
|
|---|
| Research Institution | National Institute for Materials Science |
|---|
Principal Investigator |
NAGURA Kazuhiko 国立研究開発法人物質・材料研究機構, 若手国際研究センター, ICYS研究員 (60758332)
|
|---|
| Research Collaborator |
MOCHIZUKI Chihiro
TAKEUCHI Masayuki
NAKANISHI Takashi
MATSUSHITA Yoshitaka
|
|---|
| Project Period (FY) |
2015-08-28 – 2017-03-31
|
| Keywords | π共役高分子 / フォルダマー / チオフェン / イミダゾール / 水素結合 |
|---|
| Outline of Final Research Achievements |
We have designed and synthesized π-conjugated polymers with loop-shape structures constructed by hydrogen-bond network. The polythiophenes with imidazolyl side chains or fused imidazole rings, which work as hydrogen bond platform, were synthesized by the catalyst-transfer polymerization or direct CH arylation polymerization, and subsequent deprotection. The loop-shape structures of obtained polymers were confirmed by the various spectroscopic, and microscope measurements. The obtained loop-shape polymers showed distinct optical and conducting characters from linear polymers in the single molecule and aggregation states.
|
| Free Research Field |
構造有機化学，高分子化学,
|
