2017 Fiscal Year Final Research Report
Spectroscopic detection and kinetic study on Criegee intermediates relevant to gas phase oxidation of atmospheric trace species
| Project/Area Number |
15K05378
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
遠藤 泰樹 東京大学, 大学院総合文化研究科, 名誉教授 (40106159)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | クリーギー中間体 / 電子スペクトル / キャビティ・リングダウン分光 / 放電生成物 |
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| Outline of Final Research Achievements |
A cavity ringdown absorption spectrometer was build to observe the A-X transition of Criegee intermediates. Combined with a discharge flow cell, a spectral survey of the simplest Criegee intermediate, CH2OO, was carried out in the region of 600-700 nm using the newly built spectrometer. However, absorption spectra originating from CH2OO have not been observed so far, mainly because of the interference of strong I2 absorption. A new generation method of the intermediate, which does not generate I2 molecules, is required for a further survey of the A-X transition of the intermediates.
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| Free Research Field |
分子分光学
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